Patent application number | Description | Published |
20100048958 | METHOD FOR PURIFYING TEREPHTHALALDEHYDE - The present invention relates to a method for preparing high-purity terephthalaldehyde which comprises re-crystallizing terephthalaldehyde crystals containing impurities, using an anti-solvent. Specifically, the present invention relates to a method for preparing terephthalaldehyde which comprises dissolving low-purity terephthalaldehyde prepared by a conventional method in dimethylsulfoxide and then re-crystallizing the solution, using water as an anti-solvent. The present invention is not only environment-friendly because it uses water only as an anti-solvent, but also economical because it may simply prepare high-purity terephthalaldehyde in a short time. | 02-25-2010 |
20100130791 | METHOD FOR PURIFYING TEREPHTHALADEHYDE - The present invention relates to a method for purifying terephthalaldehyde which comprises a first step of dissolving terephthalaldehyde containing impurities in an aromatic solvent at high temperature to prepare a solution; and a second step of quenching the solution to re-crystallize it into terephthalaldehyde. In accordance with the present invention, high pure terephthalaldehyde may be economically prepared. | 05-27-2010 |
20100254865 | HYDROGEN GENERATING APPARATUS USING STEAM REFORMING REACTION - Disclosed herein is an apparatus for generating hydrogen by steam reforming. The apparatus comprises: a casing having provided in the central portion thereof a combustion section for producing high-temperature reaction heat; a flame guide provided such that it forms the outer wall of the combustion section while a space is provided outside thereof; a plurality of catalytic tubes arranged concentrically with respect to the combustion section in the space outside the flame guide; a feed supply manifold disposed at one side of the inside of the casing so as to distribute a feed supplied from the outside of the apparatus to each of the catalytic tubes; a reformate manifold connected with one end of each of the catalytic tubes so as to discharge a reformate obtained by the reforming reaction to the outside of the apparatus; and a support member which consists of an inner ring plate formed at one side of the inside of the casing and an outer ring plate disposed concentrically around the outer circumference of the inner ring plate and which has formed at the boundary between the inner and outer ring plates tube holes into which one end of each of the catalytic tubes is inserted. In the hydrogen generating apparatus, the structure of the support member supporting the plurality of catalytic tubes is simply divided into the inner ring plate and the outer ring plate, such that the expansion and shrinkage of the support member by thermal stress can be efficiently compensated for. As a result, deformation and breakdown of the support member caused by thermal stress can be prevented, thus improving the overall durability and stability of the hydrogen generating apparatus. | 10-07-2010 |
20100254893 | HYDROGEN GENERATING APPARATUS USING STEAM REFORMING REACTION - The present invention provides a hydrogen generator for generating hydrogen through a steam-reforming process using hydrocarbons as a raw material and a method of operating the same, and, more particularly, provides a hydrogen generator for generating hydrogen through a steam reforming process, which can be stably operated because water is introduced into the hydrogen generator in the form of single phase vapor, and which can achieve high thermal efficiency using a proper heat exchanging method, and to a method of operating the same. According to the present invention, there is provided a heat exchanger network, in which heat necessary for a reforming reaction are obtained by the heat exchange of high-temperature exhaust gas or reformed gas, and in which, in a water gas converting reaction and a PSA reaction conducted at low temperatures compared to the reforming reaction, heat exchange is performed by low-temperature air or water, and the heat-exchanged air and the residual gas in the PSA reaction are used as a heat supply source for the reforming reactor together with fuel hydrocarbons, thereby minimizing the thermal loss of the hydrogen generator. | 10-07-2010 |
20110097251 | HYDROGEN GENERATING APPARATUS USING STEAM REFORMING REACTION - Disclosed herein is a hydrogen generating apparatus for producing hydrogen from a hydrocarbon feed through a steam reforming reaction, in which a pressure drop device is installed between a feed distributor and each of reactor tubes in order to prevent the feed from being unevenly distributed to the reactor tubes. In the hydrogen generating apparatus, the pressure drop device for artificially dropping the supply pressure of the feed is installed between the feed distributor and each of the reactor tubes which are concentrically arranged with respect to a heat source. Accordingly, if the feed is unevenly distributed, the pressure drop device can suppress an abnormal temperature rise in some of the reactor tubes to induce the smooth production of hydrogen and to greatly improve the operational safety of the hydrogen generating apparatus. | 04-28-2011 |
20110194998 | HYDROGEN GENERATOR USING STEAM-REFORMING REACTION - Disclosed herein is a hydrogen generator for producing hydrogen by the steam-reforming reaction of hydrocarbons, in which a pressure loss induction structure for artificially reducing the pressure of exhaust gas is provided between a combustion unit and an exhaust gas discharge pipe, thus improving the uneven distribution of exhaust gas. | 08-11-2011 |
20150064588 | APPARATUS AND METHOD FOR CONTROLLING FUEL CELL SYSTEM - Disclosed herein is an apparatus for controlling a fuel cell system, including: a plurality of stack state detecting units for detecting respective states of a plurality of fuel cell stacks; a switching unit for connecting at least parts of the plurality of fuel cell stacks to each other in series or in parallel; and a control unit for detecting at least one degraded stack based on the states of the stacks detected by the plurality of stack state detecting units, and forming at least one degraded stack unit including the detected at least one degraded stack by controlling the operation of the switching unit, so the apparatus can quickly and easily connect the stacks to each other in series, in parallel or in series-parallel using cheap electric switches instead of using a plurality of power conditioning system (PCS). | 03-05-2015 |
20150104726 | DEVICE AND METHOD FOR HEATING FUEL CELL STACK AND FUEL CELL SYSTEM HAVING THE DEVICE - Provided is device and method for heating fuel cell stack and fuel cell system having the device. The fuel cell system includes: a power generating unit having fuel cell stacks arranged with an interval defined between the stacks; an outlet manifold unit provided outside each fuel cell stack and guiding a reaction mixture discharged from each stack to outside; an inlet manifold unit provided on each stack at a location opposed to the outlet manifold unit based on the stack, the inlet manifold unit supplying fuel and air supplied through a fuel supply pipe and an air supply pipe into the stack; and a subsidiary fuel supply unit for supplying subsidiary fuel into the outlet manifold unit such that the subsidiary fuel is burnt in the outlet manifold unit so as to heat both the outlet manifold unit and the stack coming into contact with the outlet manifold unit. | 04-16-2015 |