Patent application number | Description | Published |
20100081076 | PRODUCTION OF POLYESTERS IN A CONTINUOUS PACKED-BED REACTOR USING IMMOBILIZED ENZYME CATALYSTS - In accordance with various embodiments, there is a method of making a polyester. The method can include providing a monomer solution, the monomer solution including one or more cyclic esters in a concentration ranging from about 1 to about 100% and one or more solvents in a concentration ranging from about 99% to about 0%. The method of making a polyester can also include providing a packed-bed reactor including one or more immobilized enzymes, wherein the packed-bed reactor has an inlet and an outlet. The method can further include circulating the monomer solution through the packed-bed reactor to generate a solution enriched with polyester, such that the one or more immobilized enzymes convert the one or more cyclic esters to polyester in the packed-bed reactor during circulation and collecting the solution enriched with polyester exiting through the outlet. | 04-01-2010 |
20100316946 | SELF EMULSIFYING GRANULES AND SOLVENT FREE PROCESS FOR THE PREPARATION OF EMULSIONS THEREFROM - A process for making a self-emulsifying composite suitable for use in forming latex emulsions includes contacting a resin with a solid or highly concentrated surfactant, a solid neutralizing agent in the absence of water and an organic solvent to form a mixture, melt mixing the mixture, and forming a self-emulsifying composite of the melt mixed mixture such as a granule. Self-emulsifying granules are also provided and configured to form a latex emulsion when added to water, which may then be utilized to form a toner. | 12-16-2010 |
20110015320 | CONTINUOUS MICROREACTOR PROCESS FOR THE PRODUCTION OF POLYESTER EMULSIONS - A process and system for continuously making a resin emulsion suitable for use in forming toner particles includes at least one micromixer for micromixing a resin mixture and aqueous phase to continuously produce an emulsion of a high solids content. | 01-20-2011 |
20110027710 | SELF EMULSIFYING GRANULES AND PROCESS FOR THE PREPARATION OF EMULSIONS THEREFROM - A process for making a self-emulsifying granule suitable for use in forming latex emulsions includes contacting a resin with a solid or highly concentrated surfactant, a solid neutralization agent and water in the absence of an organic solvent to form a mixture, melt mixing the mixture, and forming self-emulsifying granules of the melt mixed mixture. Self-emulsifying granules are also provided and configured to form a latex emulsion when added to water, which may then be utilized to form a toner. | 02-03-2011 |
20110028570 | SELF EMULSIFYING GRANULES AND PROCESS FOR THE PREPARATION OF EMULSIONS THEREFROM - A process for making a self-emulsifying granule suitable for use in forming latex emulsions includes contacting a resin with a solid or highly concentrated surfactant, a solid neutralization agent and water in the absence of an organic solvent to form a mixture, melt mixing the mixture, and forming self-emulsifying granules of the melt mixed mixture. Self-emulsifying granules are also provided and configured to form a latex emulsion when added to water. | 02-03-2011 |
20110028620 | PROCESSES FOR PRODUCING POLYESTER LATEXES VIA SOLVENT-FREE EMULSIFICATION - A process for making a latex emulsion suitable for use in a toner composition includes contacting a resin with a solid neutralizing agent in the absence of an organic solvent to form a mixture either via a co-feeding process or a pre-blend mixture, and adding a solid or aqueous surfactant to the pre-blend mixture or prior to melt mixing the mixture. | 02-03-2011 |
20110070372 | Reactive Ink Components And Methods For Forming Images Using Reactive Inks - An ink set comprising at least two inks. A first ink includes an optional colorant, a first multi-functional monomer, a second multi-functional monomer that is different from the first multi-functional monomer, and a peroxide initiator comprising a thermal free radical initiator. A second ink includes an optional colorant, a first multi-functional monomer, a second multi-functional monomer that is different from the first multi-functional monomer, and an amine activator comprising a catalyst which catalyzes the homolytic cleavage of the thermal free-radical initiator at low temperatures into radicals. The first ink is free of the amine activator and the second ink is free of the peroxide initiator. The first multi-functional monomer and the second multi-functional monomer accelerate reaction kinetics through a Trommsdorff effect. The components are each present in an amount relative to the other that provides a) early onset of gelation that accelerates polymerization, and b) an ink viscosity that is suitable for jetting from an ink jet printer. | 03-24-2011 |
20110104609 | SYNTHESIS AND EMULSIFICATION OF RESINS - The present disclosure provides processes for producing resins suitable for use in forming toner compositions. In embodiments, the processes described herein comprise formation of latexes, including latexes for use in toners, produced without use of solvents. | 05-05-2011 |
20110123924 | TONER COMPOSITIONS - The present disclosure provides for enzymatic polymerization to produce polyester resins suitable for use in manufacturing toners. In embodiments, crystalline copolymers, which are polyesters, may be synthesized from lactones, cyclic anhydrides, cyclic carbonates, and combinations thereof. These crystalline copolymers, in turn, may be utilized in the synthesis of toner particles. | 05-26-2011 |
20110130481 | MACRO-PHOTOINITIATOR VIA ENZYMATIC POLYMERIZATION - Disclosed herein is a macro-photoinitiator comprising a photoinitiator covalently bound to a polymer. Also disclosed herein is a process for the enzymatic polymerization of monomers and photoinitiators performed at atmospheric pressure and relatively low temperatures to form the macro-photoinitiator. | 06-02-2011 |
20110136058 | EMULSION AGGREGATION METHODS - A method of making toner particles, including: mixing, at less than about 17° C. and without homogenizing, a resin emulsion with a coagulant, a colorant, an optional wax, and optional additives, to form pre-aggregated particles in a slurry; heating the slurry to form aggregated toner particles; freezing aggregation of the particles in the slurry once at a desired aggregated particle size; and further heating the aggregated particles in the slurry to coalesce the aggregated particles into toner particles. | 06-09-2011 |
20110196066 | PROCESSES FOR PRODUCING POLYESTER LATEXES VIA SOLVENT-FREE EMULSIFICATION - A process for making a latex emulsion suitable for use in a toner composition includes contacting at least one amorphous polyester resin with a viscosity reducing additive in the absence of an organic solvent to form a resin mixture either via an extruder or batch process, and adding a surfactant, neutralizing agent, and deionized water to the resin mixture. | 08-11-2011 |
20110200930 | PROCESSES FOR PRODUCING POLYESTER LATEXES VIA SOLVENT-BASED AND SOLVENT-FREE EMULSIFICATION - A process for making a latex emulsion suitable for use in a toner composition includes contacting at least one polyester resin optionally with an organic solvent to form a resin mixture, adding a primary amine, optionally a surfactant, and deionized water to the mixture. | 08-18-2011 |
20110281215 | PROCESSES FOR PRODUCING POLYESTER LATEXES VIA SOLVENT-BASED EMULSIFICATION - A process for making a latex emulsion suitable for use in a toner composition includes contacting at least one amorphous polyester resin with an organic solvent to form a resin mixture, adding a neutralizing agent, and deionized water to the resin mixture, removing the solvent from the formed latex, separating the solvent from water, and recycling the solvent from the resin mixture for utilization in a subsequent phase inversion emulsion process. | 11-17-2011 |
20110286296 | SCREW EXTRUDER FOR CONTINUOUS AND SOLVENT-FREE RESIN EMULSIFICATION - A screw extruder is presented including a feed hopper for receiving materials and a body member having at least one supply port and at least one outlet port. The screw extruder also includes a screw positioned within the body member and movable along a channel defining a longitudinal axis. The screw extruder further includes a drive shaft for rotatably driving the screw along the channel. The screw extruder may be configured to mix the materials received via the feed hopper with a series of one or more forward, neutral, and reverse kneading elements. | 11-24-2011 |
20110313079 | SOLVENT-ASSISTED CONTINUOUS EMULSIFICATION PROCESSES FOR PRODUCING POLYESTER LATEXES - Various solvent-assisted extrusion processes are disclosed that are suitable for forming high yield, low coarse content, polyester latexes that may be utilized in forming a toner. | 12-22-2011 |
20120108775 | PHOTOCHROMIC POLYESTERS AND METHODS OF PRODUCING PHOTOCHROMIC POLYESTERS - A method for producing a photochromic polyester, the method including: a) providing a reaction solution having at least one ester monomer, a photochromic compound having or functionalized to have at least one hydroxyl group, and a metal-free catalyst; b) reacting the at least one ester monomer and the photochromic compound using the metal-free catalyst to produce a polymeric product, where the polymeric product has a photochromic polyester; and c) separating the polymeric product from the reaction solution. A photochromic polyester includes a photochromic compound covalently linked to a polyester and the polyester is obtained by polymerizing a lactone. | 05-03-2012 |
20120128881 | PHASE CHANGE COMPOSITION FOR PRINTING - A phase change composition including at least one crystalline polyester and at least one acrylate monomer. Examples of suitable crystalline polyesters include aliphatic crystalline polyesters and polylactones. A method of making the phase change composition, and a method for applying the phase change composition to a substrate. | 05-24-2012 |
20120145947 | PYROPHORIC IRON NANOPARTICLES AND CONTINUOUS PROCESSES FOR PRODUCTION THEREOF - Pyrophoric nanoparticles and methods of producing the same are provided herein. An exemplary method of producing pyrophoric nanoparticles can include providing a first aqueous solution comprising at least one metal salt and an aliphatic polyether; providing a second solution comprising a metal hydride reducing agent; continuously combining the first and second solutions to produce nanoparticles in a liquid phase; separating the nanoparticles from the liquid phase; and drying the nanoparticles to form pyrophoric nanoparticles. The pyrophoric nanoparticles can have a diameter ranging from about 1 nm to about 50 nm. | 06-14-2012 |
20120148951 | SOLVENT-FREE BIO-BASED EMULSION - Solvent-free extrusion processes are disclosed that are suitable for forming high bio-based polyester latexes that may be utilized in forming a toner, as well as other commercial products. | 06-14-2012 |
20120189955 | EMULSION AGGREGATION TONERS - The present disclosure provides processes for producing toners. In embodiments, silica is added as a chelating agent during the toner production process contributing to enhanced triboelectric charging properties of the toner particles. | 07-26-2012 |
20120189956 | SOLVENT-FREE TONER PROCESSES - The present disclosure provides processes for producing toners. In embodiments, alkyl or alkyl ether sulfates are used in a solvent-free toner production process as surfactants to provide for higher parent particle charge without adversely affecting particle size, distribution control and circularity of the toner particles. The present disclosure also provides a new formulation and process for the emulsification of polyester resins to form nano-scale particles dispersed in water (latex) without the use of organic solvents by an extrusion process. | 07-26-2012 |
20120208122 | Continuous emulsification-aggregation process for the production of particles - A continuous emulsion aggregation process for the production of particles is presented including a plurality of continuous stirred-tank reactors (CSTR). The plurality of continuous stirred-tank reactors includes at least one feed tank of raw materials, at least one reactor for facilitating cold addition, at least two reactors for facilitating an aggregation process, at least one reactor for facilitating a shell addition process; at least one reactor for facilitating a freeze process, at least one reactor for facilitating a chelating process, at least one reactor for facilitating a ramp-up process and at least one reactor for facilitating a coalescence process, wherein the reactors are sequentially assembled in a series configuration and separated by short conduits to produce toner particles that are narrowly distributed. | 08-16-2012 |
20130046110 | Continuous production of arylamine - A process for forming arylamines by continuous Buchwald-Hartwig reaction using, in part, a plug flow reactor with a fluid flow path greater than about 1 mm in diameter and a single solvent under pressure to form a product with a space time yield of at least 100 g/L/hr. | 02-21-2013 |
20130122418 | Alkyl Benzene Sulfonate Surfactant Having An Ammonium Salt Counter Ion For Reduced Sodium Content In Emulsions - A process including contacting an alkyl benzene sulfonate surfactant having an ammonium salt counter ion with a component to be emulsified or dispersed, wherein the alkyl benzene sulfonate surfactant is substantially free of sodium salt counter ions such that the sodium content of the alkyl benzene sulfonate surfactant is less than about 5,000 parts per million, and water to form a mixture; using the alkyl benzene sulfonate surfactant to emulsify the component and form an emulsion; or using the alkyl benzene sulfonate surfactant to disperse the component and form a dispersion. | 05-16-2013 |
20130164664 | MIXER APPARATUS AND METHOD OF MAKING DEVELOPER - The present teachings describe an apparatus for mixing developer. The apparatus includes a first loader for dispensing a predetermined amount of toner particles into a container and a second loader for dispensing a predetermined amount and carrier particles in the container. A sealer seals the container. An acoustic mixer is provided for mixing the container, toner particles and carrier particles at a resonant frequency. A method of mixing developer is disclosed. | 06-27-2013 |
20130244151 | Chemical Toner Including A Robust Resin For Solvent-Free Emulsification - A toner comprising a branched polyester suitable for use in solvent-free emulsification, the branched polyester having a first original weight average molecular weight before undergoing solvent-free emulsification and a second weight average molecular weight after undergoing solvent-free emulsification, wherein the branched polyester has a structure that limits degradation of the polyester during solvent-free emulsification to less than about 20 percent of the first original weight average molecular weight, wherein the branched polyester comprises a compound of the formula described; an optional wax, and an optional colorant. | 09-19-2013 |
20130244173 | SOLVENT-FREE BIO-BASED EMULSION - A process comprising:
| 09-19-2013 |
20130245197 | Robust Resin For Solvent-Free Emulsification - A branched polyester suitable for use in solvent-free emulsification, the branched polyester having a first original weight average molecular weight before undergoing solvent-free emulsification and a second weight average molecular weight after undergoing solvent-free emulsification, wherein the branched polyester has a structure that limits degradation of the polyester during solvent-free emulsification to less than about 20 percent of the first original weight average molecular weight, wherein the branched polyester comprises a compound of the formula described. | 09-19-2013 |
20130255190 | CUSTOM COLOR TONER PRODUCTION SYSTEMS AND METHODS - A custom color toner production system includes a toner delivery system, a cartridge sealing system, a mixing system, and a packaging system. The toner delivery system includes selectively engageable fluid delivery lines for delivering toner of particular color to a cartridge as need for producing a custom color toner in response to an electronically submitted user request. Cartridge containing the unmixed delivered toner may be sealed by a sealing system, and blended using a resonant mixer to produce a custom color toner. The cartridge containing the mixed custom color toner may be packaged using a packaging system. | 10-03-2013 |
20130260310 | TONER PROCESS USING ACOUSTIC MIXER - A process for making emulsion aggregation (EA) toners is provided. In embodiments, the process comprises aggregating a mixture comprising a latex resin, and at least one colorant in a reactor to form aggregated toner particles, adding a shell resin to form a shell over the aggregated toner particles, coalescing the aggregated toner particles, and recovering the toner particles. | 10-03-2013 |
20140045116 | EMULSION AGGREGATION TONER PROCESS COMPRISING DIRECT ADDITION OF SURFACE-TREATED PIGMENT - A method of making a toner that includes adding pigments into an emulsion aggregation toner without first preparing a pigment dispersion. The method eliminates the pigment dispersion step in the manufacture of emulsion aggregation toilers by surface-treating pigments. Dry surface-treated pigments can be directly incorporated into the toner prior to aggregation in the aggregation coalescence process without the need to first prepare aqueous pigment dispersions. | 02-13-2014 |
20140046102 | METHOD FOR OBTAINING WAX FROM RECYCLED POLYETHYLENE - An economical and environmentally friendly method for producing waxes. In particular, the methods use thermolytic degradation concurrently with a distillation process to obtaining distilled waxes from recycled polyethylene. The resulting waxes have desirable properties, such as reduced molecular weight and narrow polydispersity, that makes the waxes useful in various applications. | 02-13-2014 |
20140134533 | Recycled Polyethylene Terephthalate-Based Toner - The present disclosure describes toner comprising a portion of resin comprising a polyethylene terephthalate oligomer. | 05-15-2014 |
20140134534 | Sustainable Toner - The present disclosure describes toner that is composed substantially of biodegradable and recycled materials. | 05-15-2014 |
20140170548 | Continuous Production of Toner - Continuous and semi-continuous emulsion aggregation processes for the production of toner particles are presented. | 06-19-2014 |
20140170551 | Tunable Gloss Toner - The disclosure describes an emulsion aggregation toner process wherein aspartic acid derivatives are employed as chelating agents. Also disclosed is a process for preparing toner using aspartic acid derivatives to freeze/stop toner particle growth where coalescence occurs following acidification of the reaction mixture. | 06-19-2014 |
20140170557 | Batch/Continuous Production of Toner - A process for forming toner using an emulsion/aggregation scheme wherein particle aggregation occurs in a batch reactor and coalescence occurs in a continuous reactor, with a space time yield of at least 200 g/L/hr. | 06-19-2014 |
20140170558 | Batch/Continuous Production of Toner - A process for forming toner using an emulsion/aggregation scheme wherein particle aggregation occurs in a batch reactor and coalescence occurs in a continuous reactor. In embodiments, a continuous reactor comprises four sections joined in series. | 06-19-2014 |
20140199352 | POROUS NANOPARTICLES PRODUCED BY SOLVENT-FREE EMULSIFICATION - The process for manufacturing porous nanoparticles disclosed herein includes feeding a dry-blended mixture of at least one resin and a neutralizing agent into a feed section of a screw extruder, injecting a surfactant solution downstream of the hopper, and adding an aqueous composition both directly after the surfactant solution as well as further downstream. Porous nanoparticles having a particle size of from about 50 nm to about 2 μm and a pore diameter of from about 20 nm to about 400 nm may be continuously recovered from the extruder following this process. | 07-17-2014 |
20140199625 | Preparing Amorphous Polyester Resin Emulsions - A process for making a latex emulsion including contacting at least one amorphous polyester resin with at least two organic solvents to form a resin mixture, adding a neutralizing agent, and deionized water to the resin mixture, removing the solvent from the formed latex, and separating the solvent from water. Further, the process is carried out above the resin Tg for making the latex, which drives the latex particle size under 100 nm, where toners made from the latex show improved charging performance. | 07-17-2014 |
20140248558 | Preparing Colorant Dispersions Using Acoustic Mixing - The present disclosure provides processes for making inorganic or organic colorant dispersions using an acoustic mixer, where such dispersion may be used to make toner. Such processes apply low frequency, high intensity acoustic energy and a consistent shear field throughout an entire mixing vessel and provide uniform dispersion of colorants within minutes. | 09-04-2014 |
20140248559 | Acoustic Method to Prepare Polyester Resin Emulsions - The disclosure relates to a process for making a latex emulsion suitable for use in a toner comprising at least one amorphous polyester resin and a solvent to form a resin mixture, including that the process is carried out at room temperature using acoustic mixing. | 09-04-2014 |
20140295346 | EMULSION AGGREGATION PROCESS - The method of manufacturing toners disclosed herein includes a continuous temperature ramp and coalescence process that involves continuously passing toner slurry, such as an aggregated toner slurry, through at least one heat exchanger before being subjected to a cooling step. The heat exchanger is pressurized, so the temperature of the slurry may be increased above the atmospheric boiling point of water without boiling the water component of the slurry. Because of these higher temperatures, the coalescence step can be completed more quickly than in conventional batch processes. More than two heat exchangers may be connected in the coalescence step, yielding multiple ramping/cooling temperature steps, ability to inject components, or recycling heat from the process to reduce energy consumption. | 10-02-2014 |
20140303297 | LOW COST PROCESS FOR SOLID INK USING DRY FLUSHED PIGMENTS - A dry flushed pigment comprises a dry pigment and a flushing agent. Particles of the dry pigment are dispersed into the flushing agent. The dry flushed pigment may have at least 20 percent by weight dry pigment. The dry flushed pigment may have a range of 20 to 80 percent dry pigment by weight. A pigment concentrate comprising a dry flushed pigment and one or more of a group of an ink carrier, a dispersant, or a synergist, where the dry flushed pigment is mixed with one or more of the ink carrier, dispersant or synergist and then milled to create the pigment concentrate. The pigment in the pigment concentrate has a Z-average particle size in the range of 75 nm to 250 nm. The pigment in the pigment concentrates is present in the amount from about 15 to 60 percent by weight of the pigment concentrate. | 10-09-2014 |
20150013567 | Phase Change Ink Pigment Dispersion Process - A process for preparing a pigment dispersion including melting a phase change ink carrier and an optional dispersant at a temperature of from about 100° C. to about 170° C. in a jacketed vessel comprising a jacket surrounding an immersion mill or basket mill attachment and a dispersion blade attachment disposed within the jacketed vessel; mixing the melted phase change ink carrier and optional dispersant with a dispersion blade in the jacketed vessel; adding a pigment to the melted, mixed phase change ink carrier and optional dispersant in the jacketed vessel; wetting the pigment; after pigment wetting, reducing the pigment particle size using an immersion mill or basket mill attachment in the jacketed vessel; and discharging the pigment dispersion. | 01-15-2015 |