Patent application number | Description | Published |
20080214389 | Platinum/Ruthenium Catalyst for Direct Methanol Fuel Cells - The invention relates to a carbon-supported PtRu anode catalyst for direct methanol fuel cells (DMFC) which has a platinum/ruthenium content in the range from 80 to 98 wt. %, preferably in the range from 85 to 98 wt. %, particularly preferably in the range from 85 to 95 wt. % (based on the total weight of the catalyst), on a carbon-based electrically conductive support material and has a mean particle size of less than 3 nm. The catalyst is prepared using a carbon black support material having a specific surface area (measured by the BET method) in the range from 1000 to 2000 m | 09-04-2008 |
20100086832 | CORE / SHELL-TYPE CATALYST PARTICLES AND METHODS FOR THEIR PREPARATION - The invention discloses core/shell type catalyst particles comprising a M | 04-08-2010 |
20100092841 | CORE / SHELL-TYPE CATALYST PARTICLES COMPRISING METAL OR CERAMIC CORE MATERIALS AND METHODS FOR THEIR PREPARATION - The invention is directed to core/shell type catalyst particles comprising a M | 04-15-2010 |
20100190641 | Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith - The present invention provides a method for manufacture of supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method is based on the use of polyol solvents as reaction medium and comprises of a two-step reduction process in the presence of a support material. In the first step, the first metal (M1 =transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (M2=noble metal; e.g. Pt, Pd, Au and mixtures thereof) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300° C. Due to this two-step method, an uniform reduction occurs, resulting in noble metal based catalysts with a high degree of alloying and a small crystallite size of less than 3 nm. Due to the high degree of alloying, the lattice constants are lowered. The catalysts manufactured according to the method are used as electrocatalysts for polymer electrolyte membrane fuel cells (PEMFC), direct-methanol fuel cells (DMFC) or as gas phase catalysts for CO oxidation or exhaust gas purification. | 07-29-2010 |
20100273085 | Method for the Electrochemical Deposition of Catalyst Particles Onto Carbon Fibre-Containing Substrates and Apparatus Therefor - The present invention describes a method and an apparatus for the electrochemical deposition of fine catalyst particles onto carbon fibre-containing substrates which have a compensating layer (“microlayer”). The method comprises the preparation of a precursor suspension containing ionomer, carbon black and metal ions. This suspension is applied to the substrate and then dried. The deposition of the catalyst particles onto the carbon fibre-containing substrate is effected by a pulsed electrochemical method in an aqueous electrolyte. The noble metal-containing catalyst particles produced by the method have particle sizes in the nanometer range. The catalyst-coated substrates are used for the production of electrodes, gas diffusion electrodes and membrane electrode units for electrochemical devices, such as fuel cells (membrane fuel cells, PEMFC, DMFC, etc.), electrolysers or electrochemical sensors. | 10-28-2010 |
20110086295 | CORE / SHELL-TYPE CATALYST PARTICLES AND METHODS FOR THEIR PREPARATION - The invention discloses core/shell type catalyst particles comprising a M | 04-14-2011 |
20110166009 | Ink For Producing Catalyst Layers - The invention relates to an ink for producing catalyst layers for electrochemical devices. The ink comprises catalyst materials, ionomer material, water and at least one organic solvent. The organic solvent belongs to the class of tertiary alcohols and/or the class of aliphatic diketones and bears functional groups which are stable to oxidative degradation in the ink. This prevents formation of decomposition products in the ink. The ink of the invention displays a high storage stability and is used for producing catalyst-coated substrates for electrochemical devices, in particular fuel cells (PEMFCs, DMFCs). | 07-07-2011 |
20110223523 | Precious Metal Oxide for Water Electrolysis - The invention is directed to iridium oxide based catalysts for use as anode catalysts in PEM water electrolysis. The claimed composite catalyst materials comprise iridium oxide (IrO | 09-15-2011 |
20120058888 | Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith - The invention provides a method for manufacturing supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method involves using polyol solvents as reaction medium and comprises a two-step reduction process in the presence of a support material. In the first step, the first metal (transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (noble metal; e.g. Pt, Pd, Au) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300° C. The catalysts manufactured according to the method are used as electrocatalysts for polymer electrolyte membrane fuel cells (PEMFC), direct-methanol fuel cells (DMFC) or as gas phase catalysts for CO oxidation or exhaust gas purification. | 03-08-2012 |
20120316054 | CORE / SHELL-TYPE CATALYST PARTICLES AND METHODS FOR THEIR PREPARATION - The invention discloses core/shell, type catalyst particles comprising a M | 12-13-2012 |
20140349203 | ELECTROCATALYST FOR FUEL CELLS AND METHOD FOR PRODUCING SAID ELECTROCATALYST - The invention relates to a carbon-free electrocatalyst for fuel cells, containing an electrically conductive substrate and a catalytically active species, wherein the conductive substrate is an inorganic, multi-component substrate material of the composition 0X1-0X2, in which 0X1 means an electrically non-conductive inorganic oxide having a specific surface area (BET) in the range of 50 to 400 mVg and 0X2 means a conductive oxide. The non-conductive inorganic oxide 0X1 is coated with the conductive oxide 0X2. The multi-component substrate preferably has a core/shell structure. The multi-component substrate material 0X1-0X2 has an electrical conductivity in the range>0.01 S/cm and is coated with catalytically active particles containing noble metal. The electrocatalysts produced therewith are used in electrochemical devices such as PEM fuel cells and exhibit high corrosion stability. | 11-27-2014 |