Patent application number | Description | Published |
20080221351 | Method for the Production of Adipodinitrile by Hydrocyanation of 1,3-Butadiene - A process is described for preparing adiponitrile by hydrocyanating 1,3-butadiene over a catalyst, by, in a first process step, hydrocyanating 1,3-butadiene to 3-pentenenitrile over at least one nickel(0) catalyst, and, in a second process step, hydrocyanating 3-pentenenitrile to adiponitrile over at least one nickel(0) catalyst with addition of at least one Lewis acid, wherein at least one of the at least one nickel(0) catalysts used in the particular process steps is transferred into the other process step. | 09-11-2008 |
20080227214 | Method for the Hydrocyanation of 1,3-Butadiene - A process is described for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene in the presence of at least one catalyst, wherein unhydrocyanated 1,3-butadiene is removed from the effluent of the hydrocyanation and recycled into the process, and the recycled 1,3-butadiene is monitored for the content of hydrogen cyanide. | 09-18-2008 |
20080227998 | Method For Producing 3-Pentenenitrile - A process is described for preparing 3-pentenenitrile, characterized by the following process steps:
| 09-18-2008 |
20080242883 | Method for the Hydrocyanation of Butadiene - A process is described for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene in the presence of at least one catalyst, wherein the reaction is carried out in a loop reactor having external pumped circulation and jet nozzle for driving the internal circulation. | 10-02-2008 |
20080242885 | Method for Hydrocyanation - A process is described for removing hydrogen cyanide from mixtures comprising pentenenitrile, wherein the removal is effected by an azeotropic distillation of hydrogen cyanide with 1,3-butadiene. | 10-02-2008 |
20080242886 | Continuous Method for the Production of Linear Pentene Nitriles - A process is described for continuously hydrocyanating 1,3-butadiene in the presence of at least one nickel(0) catalyst with chelate ligands, wherein 1,3-butadiene and hydrogen cyanide are used in a molar ratio of from 1.6:1 to 1.1:1. | 10-02-2008 |
20080275266 | Method for the Production of Pentene Nitriles From N-Butane - A process is described for hydrocyanating 1,3-butadiene over at least one nickel(0) complex having phosphorus ligands as a catalyst, wherein the 1,3-butadiene is used in a mixture with n-butane and the mixture contains from 60 to 90% by volume of 1,3-butadiene and from 40 to 10% by volume of n-butane. | 11-06-2008 |
20080281119 | Separation of Nickel(0) Complexes and Phosphorus-Containing Ligands from Nitrile Mixtures - A process for extractively removing nickel(0) complexes having phosphorus ligands and/or free phosphorus ligands from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles by extraction by means of a hydrocarbon, a phase separation of the hydrocarbon and of the reaction effluent into two phases being effected at a temperature T (in ° C.), | 11-13-2008 |
20080281120 | Method for Producing Linear Pentenenitrile - A process is described for preparing 3-pentenenitrile, characterized by the following process steps:
| 11-13-2008 |
20090054671 | PROCESS FOR PRODUCING NICKEL(0)-PHOSPHORUS LIGAND COMPLEXES - A process for preparing nickel(0)-phosphorus ligand complexes comprising at least one nickel(0) central atom and at least one phosphorus ligand by reacting a nickel(II) compound with a reducing agent in the presence of the ligand to give a reaction mixture, wherein
| 02-26-2009 |
20090187039 | Production of 3-pentenenitrile from 1,3-butadiene - A process is described for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene, wherein 1,3-butadiene is reacted with hydrogen cyanide in the presence of at least one catalyst and the stream resulting therefrom is purified distillatively, the bottom temperature during the distillation not exceeding 140° C. | 07-23-2009 |
20090247779 | METHOD FOR PRODUCING 3-PENTENENITRILE BY MEANS OF THE HYDROCYANATION OF 1,3-BUTADIENE - A method for producing 3-pentenenitrile by means of the hydrocyanation of 1,3-butadiene, which comprises the following process steps:
| 10-01-2009 |
20090270645 | METHOD FOR THE SEPARATION OF NICKEL(0) COMPLEXES AND PHOSPHOROUS-CONTAINING LIGANDS FROM NITRILE MIXTURES - A process for extractively removing nickel(0) complexes having phosphorus ligands from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles by extraction by means of a hydrocarbon, a phase separation of the hydrocarbon and of the nitrile-containing solution into two phases being effected, by feeding at least one polar additive to the hydrocyanation effluent (feedstream) and/or to the extraction stage. | 10-29-2009 |
20090281356 | METHOD FOR PRODUCING ORGANIC PHOSPHOROUS COMPOUNDS CONTAINING HALOGENE - Method of producing compounds of the general formula | 11-12-2009 |
20100284889 | METHOD FOR PRODUCING HYDROCYANIC ACID BY CATALYTIC DEHYDRATION OF GASEOUS FORMAMIDE - A process for preparing hydrogen cyanide by catalytically dehydrating gaseous formamide in a tubular reactor formed from at least one reaction channel in which the catalytic dehydration proceeds, said reaction channel having an inner surface which is formed from a material having an iron content of ≧50% by weight, and no additional catalysts and/or internals being present in the reaction channel, and the at least one reaction channel having a mean hydraulic diameter of from 0.5 to 6 mm, and a reactor with the features specified above and the use of the inventive reactor for preparing hydrogen cyanide by catalytically dehydrating gaseous formamide. | 11-11-2010 |
20100316552 | PROCESS FOR PREPARING HYDROGEN CYANIDE BY CATALYTIC DEHYDRATION OF GASEOUS FORMAMIDE - A process for preparing hydrogen cyanide, comprising the provision of gaseous formamide by evaporating liquid formamide in an evaporator (step i)) and the catalytic dehydration of the gaseous formamide (step ii)), and also an apparatus for performing the process according to the invention, comprising at least one microevaporator and a tubular reactor, and the use of a microevaporator for evaporating formamide in a process for preparing hydrogen cyanide from formamide. | 12-16-2010 |
20110166377 | METHOD FOR THE SEPARATION OF PENTENENITRILE ISOMERS - A process is described for separating mixtures of isomeric pentenenitriles, in which at least one isomer is removed from the mixture, wherein the separation of the substance mixtures of isomeric pentenenitriles is effected distillatively under reduced pressure. | 07-07-2011 |
20110182798 | SINGLE-CHAMBER VAPORIZER AND USE THEREOF IN CHEMICAL SYNTHESIS - The invention relates to an improved process for vaporizing organic compounds and the further conversion thereof. | 07-28-2011 |
20110288326 | PROCESS FOR ISOMERIZING CIS-2-PENTENENITRILE TO 3-PENTENENITRILES - A process for isomerizing cis-2-pentenenitrile to 3-pentenenitriles, by isomerizing cis-2-pentenenitrile with amidines, tertiary amines or mixtures thereof as a catalyst at temperatures of 80 to 200° C. and a pressure of 0.01 to 50 bar. | 11-24-2011 |
20120178958 | METHOD FOR PRODUCING LINEAR PENTENENITRILE - A method for producing 3-pentenenitrile is provided that includes: (a) isomerizing an educt stream containing 2-methyl-3-butenenitrile on at least one dissolved or dispersed isomerisation catalyst to form a stream (1), which contains the isomerisation catalyst(s), 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile; (b) distilling the stream (1) to obtain a stream (2) as the overhead product, which contains 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile and a stream (3) as the bottom product, which contains the isomerisation catalyst(s); (c) distilling the stream (2) to obtain a stream (4) as the overhead product, which is enriched with (Z)-2-methyl-2-butenenitrile in comparison to stream (2), and a stream (5) as the bottom product, which is enriched with 3-pentenenitrile and 2-methyl-3-butenenitrile in comparison to stream (2); (d) distilling stream (5) to obtain a stream (6) as the bottom product, which contains 3-pentenenitrile and a stream (7) as the head product containing 2-methyl-3-butenenitrile. | 07-12-2012 |
20130053536 | PROCESS FOR PREPARING EDDN AND/OR EDMN AND A PROCESS FOR PREPARING DETA AND/OR TETA - A process for preparing EDDN and/or EDMN by
| 02-28-2013 |
20130053537 | PROCESS FOR REGENERATING RANEY CATALYSTS - A process for regenerating Raney catalysts by treating the catalyst with liquid ammonia with a water content of less than 5% by weight and with hydrogen having a partial pressure of 0.1 to 40 MPa in the temperature range from 50 to 350° C. for at least 0.1 hour. | 02-28-2013 |
20130053538 | PROCESS FOR PREPARING EDFA AND/OR EDMFA AND DETA AND/OR TETA - A process for reacting ethylenediamine (EDA) with formaldehyde to give ethylenediamine-formaldehyde adduct (EDFA) and/or ethylenediamine-monoformaldehyde adduct (EDMFA), which comprises performing the reaction of FA with EDA at a temperature in the range from 20 to 70° C. | 02-28-2013 |
20130053539 | PROCESS FOR PREPARING EDDN AND/OR EDMN AND PROCESS FOR PREPARING DETA AND/OR TETA - A process for preparing EDDN and/or EDMN by conversion of FA, HCN and EDA, the reaction being effected in the presence of water, wherein the reaction mixture from the conversion of EDA, HCN and FA is cooled after leaving the reactor. | 02-28-2013 |
20130053540 | PROCESS FOR PREPARING TETA - A process for preparing TETA and/or DETA by the action of EDDN and/or EDMN with hydrogen in the presence of a catalyst, wherein the catalyst used is a catalyst of the Raney type and the pressure in the course of hydrogenation is in the range from 170 to 240 bar. | 02-28-2013 |
20130053584 | PROCESS FOR PREPARING EDDN AND/OR EDMN BY REACTING EDFA AND/OR EDMFA WITH HCN - A process for reacting ethylenediamine-formaldehyde adduct (EDFA) and/or ethylene-diamine-monoformaldehyde adduct (EDMFA) with hydrogen cyanide (HCN) in a reactor with limited backmixing at a temperature in the range from 20 to 120° C., wherein the residence time in the reactor is 300 seconds or less. | 02-28-2013 |
20130053597 | PROCESS FOR PREPARING EDDN, EDMN, TETA AND DETA - A process for preparing ethylenediaminediacetonitrile (EDDN) and/or ethylenediamine-monoacetonitrile (EDMN) by conversion of formaldehyde (FA), hydrogen cyanide (HCN) and ethylenediamine (EDA), which comprises using stabilizer-free HCN, or HCN which has been stabilized with an organic acid, in the process. | 02-28-2013 |
20130060002 | PROCESS FOR WORKING UP REACTION OUTPUTS FROM THE HYDROGENATION OF EDDN OR EDMN - A process is disclosed for separating the output from the reaction of EDDN or EDMN with hydrogen in the presence of THF, a catalyst, TETA or DETA, water, and optionally organic compounds having higher and lower boiling points than TETA or DETA. Hydrogen is removed, and the output is supplied to a distillation column DK1 in which an azeotrope, optionally comprising organic compounds with a boiling point lower than TETA or DETA, is removed from the top. A product comprising TETA or DETA is removed from the bottom and passed cinto a distillation column DK2, removing THF. A stream comprising TETA or DETA passes from the bottom of DK2. The DK1 azeotrope is condensed. Phase separation is induced by the addition of an organic solvent essentially immiscible with water, and the mixture is separated. The organic phase is recycled into DK1 and the water phase is discharged. | 03-07-2013 |
20130079492 | PROCESS FOR PREPARING EDDN AND EDMN - A process for preparing EDDN and/or EDMN by conversion of FA, HCN and EDA, the reaction being effected in the presence of water, and, after the conversion, water being depleted from the reaction mixture in a distillation column, which comprises performing the distillation in the presence of an organic solvent which has a boiling point between water and EDDN and/or EDMN at the distillation pressure existing in the column or which forms a low-boiling azeotrope with water. | 03-28-2013 |
20130085286 | Unknown - A process for preparing amines of the formula (II) | 04-04-2013 |
20130090452 | PROCESS FOR PREPARING EDDN AND/OR EDMN BY CONVERSION OF FACH AND EDA - A process for reacting formaldehyde cyanohydrin (FACH) with ethylenediamine (EDA) in a reactor with limited backmixing at a temperature in the range from 20 to 120° C., wherein the residence time in the reactor is 300 seconds or less. | 04-11-2013 |
20130090453 | Process for preparing TETA and DETA - A process for preparing TETA and/or DETA by hydrogenating EDDN and/or EDMN with hydrogen in the presence of a catalyst, which comprises preparing EDDN and/or EDMN from FA, HCN and EDA in the presence of toluene as a solvent and performing the hydrogenation in suspension mode in the presence of THF. | 04-11-2013 |
20130129612 | Process for Ion Exchange on Zeolites - Aspects of the present invention relate to an improved process for exchanging alkali metal or alkaline earth metal ions in zeolites for ammonium ions. For this exchange, aqueous solutions of ammonium salts, for example ammonium sulfate, ammonium nitrate or ammonium chloride, are currently being used. The resulting “ammonium zeolites” are calcined to convert them, with release of ammonia, to the H form of the zeolites suitable as a catalyst. Certain methods provided herein use ammonium carbonate instead of the ammonium compounds mentioned. As excess ammonium carbonate, in contrast to the nitrates, sulfates or chlorides, can be recycled in the form of carbon dioxide and ammonia, the amount of salt which has to be discharged is lowered significantly. | 05-23-2013 |
20130129613 | Process for Ion Exchange on Zeolites - Aspects of the present invention relate to an improved process for exchanging sodium ions in zeolites comprising sodium ions and rare earth metal ions for ammonium ions. For this exchange, aqueous solutions of ammonium salts, for example ammonium sulfate, ammonium nitrate or ammonium chloride, are currently being used. The resulting “ammonium zeolites” are calcined to convert them, with release of ammonia, to the H form of the zeolites suitable as a catalyst. The use of ammonium carbonate also minimizes the amount of rare earth metal ions which are leached out of the zeolites comprising rare earth metal ions. | 05-23-2013 |
20130289299 | Process for Isomerization of CIS-2-Pentenenitrile to 3-Pentenenitriles - The present invention relates to an improved process for batchwise or continuous isomerization of cis-2-pentenenitrile to 3-pentenenitriles in the presence of 1,4-diazabicyclo[2.2.2]octane as catalyst. | 10-31-2013 |