Patent application number | Description | Published |
20090054225 | Hydroprocessing Bulk Catalyst and Uses Thereof - A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (M | 02-26-2009 |
20090054226 | Hydroprocessing Bulk Catalyst and Uses Thereof - An improved hydroprocessing catalyst having improved morphology/dispersion characteristics is provided. The hydroprocessing catalyst has the formula (M | 02-26-2009 |
20090057201 | HYDROPROCESSING BULK CATALYST AND USES THEREOF - A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (M | 03-05-2009 |
20090107880 | METHOD OF UPGRADING HEAVY HYDROCARBON STREAMS TO JET PRODUCTS - A process of upgrading a heavy hydrocarbon feedstock comprising contacting a heavy hydrocarbon feedstock with a catalyst in the presence of hydrogen in a reactor system, containing the catalyst as the only catalyst, wherein the catalyst, is prepared by sulfiding a catalyst precursor obtained by mixing at reaction conditions, to form a precipitate or cogel, at least a Group VIII metal compound in solution; at least a Group VIB metal compound in solution; and, at least an organic oxygen containing ligand in solution, and thereby producing a fuel product. | 04-30-2009 |
20090107883 | Hydroconversion Processes Employing Multi-Metallic Catalysts and Method for Making Thereof - A catalyst precursor composition and methods for making such catalyst precursor is disclosed. In one embodiment, the catalyst precursor is of the general formula A | 04-30-2009 |
20090107889 | Hydroconversion Processes Employing Multi-Metallic Catalysts and Method for Making Thereof - A process for upgrading a hydrocarbon feedstock by hydroprocessing using multi-metallic catalysts is disclosed. In one aspect, the invention relates to hydroprocessing of a hydrocarbon feedstock using a catalyst derived from a catalyst precursor of the formula A | 04-30-2009 |
20090107891 | PROCESS FOR PREPARING HYDROPROCESSING BULK CATALYSTS - A process to prepare hydroprocessing bulk catalysts is provided. The hydroprocessing catalyst has the formula (M | 04-30-2009 |
20090111685 | Hydroconversion Processes Employing Multi-Metallic Catalysts and Method for Making Thereof - A catalyst precursor composition and methods for making such catalyst precursor is disclosed. The catalyst precursor comprises at least one of a Group IIB metal compound, a Group IVA metal compound, a Group IIA metal compound, and combinations thereof, at least one Group VIB metal, at least one organic, oxygen-containing ligand, and optionally a cellulose-containing material. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds. In one embodiment, the catalyst precursor is of the formula A | 04-30-2009 |
20090112010 | Hydroconversion Processes Employing Multi-Metallic Catalysts and Method for Making Thereof - A catalyst precursor composition and methods for making such a catalyst precursor are disclosed. The catalyst precursor comprises at least a promoter metal selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof having an oxidation state of +2 or +4, at least one Group VIB metal having an oxidation state of +6, and at least one organic oxygen-containing ligand. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds. | 04-30-2009 |
20090114566 | METHOD OF UPGRADING HEAVY HYDROCARBON STREAMS TO JET PRODUCTS - A process of upgrading a heavy hydrocarbon feedstock comprising contacting a heavy hydrocarbon feedstock with a catalyst in the presence of hydrogen in a reactor system, containing the catalyst as the only catalyst, wherein the catalyst, is prepared by sulfiding a catalyst precursor obtained by mixing at reaction conditions, to form a precipitate or cogel, at least a Promoter metal compound in solution; at least a Group VIB metal compound in solution; and, at least an organic oxygen containing ligand in solution, and thereby producing a fuel product. | 05-07-2009 |
20090200204 | Hydroprocessing Bulk Catalyst and Uses Thereof - A hydroprocessing catalyst is provided. The hydroprocessing catalyst has the formula (M | 08-13-2009 |
20090218061 | PROCESS FOR GENERATING A HYDROCARBON FEEDSTOCK FROM LIGNIN - The present invention discloses processes for generating a hydrocarbon feedstock for biofuels synthesis from lignin via hydroprocessing. Embodiments of the present invention can occur in a refinery setting or in a paper mill setting. Embodiments of the present invention can utilize the separated lignin or the entire black liquor solution. | 09-03-2009 |
20090218062 | PROCESS FOR GENERATING A HYDROCARBON FEEDSTOCK FROM LIGNIN - The present invention discloses processes for generating a hydrocarbon feedstock for biofuels synthesis from lignin via hydroprocessing. Embodiments of the present invention can occur in a refinery setting or in a paper mill setting. Embodiments of the present invention can utilize the separated lignin or the entire black liquor solution. | 09-03-2009 |
20090314684 | System and method for pretreatment of solid carbonaceous material - This invention encompasses systems and methods for pretreating a carbonaceous material, comprising heating to a suitable temperature and for a suitable reaction time, a mixture comprising the carbonaceous material, one or more catalysts or catalyst precursors, and a hydrocarbonaceous liquid. | 12-24-2009 |
20100044277 | SYSTEM AND METHOD FOR PRETREATMENT OF SOLID CARBONACEOUS MATERIAL - This invention encompasses systems and methods for pretreating a carbonaceous material, comprising heating to a suitable temperature and for a suitable reaction time, a mixture comprising the carbonaceous material, one or more catalysts or catalyst precursors and a hydrocarbonaceous liquid. | 02-25-2010 |
20100084311 | HYDRODEMETALLIZATION CATALYST AND PROCESS - This invention is directed to hydrodemetallization catalysts and hydrodemetallization processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic | 04-08-2010 |
20100084312 | HYDROCRACKING CATALYST AND PROCESS USING A MAGNESIUM ALUMINOSILICATE CLAY - This invention is directed to hydrocracking catalysts and hydrocracking processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic | 04-08-2010 |
20100087313 | MAGNESIUM ALUMINOSILICATE CLAYS-SYNTHESIS AND CATALYSIS - This invention is directed to a synthesis process for preparing magnesium aluminosilicate clays and to the products of said process. Briefly, a silicon component, an aluminum component, and a magnesium component are combined, under aqueous conditions and at an acidic pH, to form a first reaction mixture and subsequently the pH of the first reaction mixture is adjusted to greater than 7.5 to form a second reaction mixture. The second reaction mixture is allowed to react under conditions sufficient to form the magnesium aluminosilicate clay of the present invention. The invention is also directed to catalyst compositions comprising the magnesium aluminosilicate clays synthesized according to the process of the invention. The resulting magnesium aluminosilicate clay can be used as a catalyst or as a component in catalyst compositions. The invention is further directed to a magnesium aluminosilicate clay with a characteristic | 04-08-2010 |
20100158825 | COSMETIC AND PERSONAL CARE PRODUCTS CONTAINING SYNTHETIC MAGNESIUM ALUMINO-SILICATE CLAYS - The invention provides for cosmetic and personal care compositions comprising a synthetic magnesium aluminosilicate clay. The synthetic magnesium aluminosilicate clay is formed at ambient pressure by a series of reaction steps and a pH change from acidic pH to basic pH. The characteristics of the magnesium aluminosilicate clay, including platelet size, degree of stacking, and porosity can be tuned depending on the cosmetic or personal care product desired. In addition, these cosmetic and personal care compositions optionally include one or more of the following components: odor controlling agents, skin protectants, diluents, lipophilic skin health benefit agents, sunscreens, humectants, emollients, slip compounds, and moisturizers. | 06-24-2010 |
20100200811 | Method for Making Hydrogen Using a Gold Containing Water-Gas Shift Catalyst - The present invention relates to a method for oxidizing CO, comprising: passing a first feed comprising CO and a second feed comprising oxygen, in an oxidation zone, over a catalyst comprising highly dispersed gold on sulfated zirconia, at oxidation conditions, to produce an effluent comprising a lower level of CO than in the first feed. | 08-12-2010 |
20100234212 | HYDROPROCESSING BULK CATALYST AND USES THEREOF - A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (M | 09-16-2010 |
20100276338 | Hydroconversion Multi-Metallic Catalyst and Method for Making Thereof - A process for preparing a bulk multi-metallic catalyst for hydrotreating heavy oil feeds is provided. The catalyst is particularly suitable for hydrotreating heavy oil feeds having a boiling point in the range of 343° C. (650° F.)- to 454° C. (850° F.), an average molecular weight Mn ranging from 300 to 400, and an average molecular diameter ranging from 0.9 nm to 1.7 nm. The bulk multi-metallic catalyst is prepared by sulfiding a catalyst precursor that has an essentially monomodal pore volume distribution with at least 95% of the pores being macropores, and having a total pore volume of at least 0.08 g/cc. | 11-04-2010 |
20100279849 | Hydroconversion Multi-Metallic Catalyst and Method for Making Thereof - The invention relates to a bulk multi-metallic catalyst for hydrotreating heavy oil feeds and to a method for preparing the catalyst. The bulk multi-metallic catalyst is prepared by sulfiding a catalyst precursor having a poorly crystalline structure with disordered stacking layers, with a type IV adsorption-desorption isotherms of nitrogen with a hysteresis starting point value of about 0.35, for a sulfided catalyst that will facilitate the reactant's and product's diffusion in catalytic applications. In another embodiment, the precursor is characterized as having a type H3 hysteresis loop. In a third embodiment, the hysteresis loop is characterized as having a well developed plateau above P/P | 11-04-2010 |
20100279851 | Hydroconversion Multi-Metallic Catalyst and Method for Making Thereof - A catalyst precursor for preparing a bulk multi-metallic catalyst upon sulfidation is provided. The precursor has an essentially monomodal pore volume distribution with at least 90% of the pores being macropores, and a total pore volume of at least 0.08 g/cc. The bulk multi-metallic prepared from the precursor is particularly suitable for hydrotreating heavy oil feeds having a boiling point in the range of 343° C. (650° F.)—to 454° C. (850° F.), an average molecular weight Mn ranging from 300 to 400, and an average molecular diameter ranging from 0.9 nm to 1.7 nm. | 11-04-2010 |
20100279853 | Hydroconversion Multi-Metallic Catalyst and Method for Making Thereof - A method for preparing a bulk multi-metallic suitable for hydrotreating heavy oil feeds is provided. In the process of preparing the catalyst precursor which is subsequently sulfided to form the bulk catalyst, a catalyst precursor filter cake is treated with at least a chelating agent, resulting in a catalyst precursor with optimum porosity with at least 90% of the pores being macropores, and having a total pore volume of at least 0.12 g/cc. | 11-04-2010 |
20100279854 | Hydroconversion Multi-Metallic Catalyst and Method for Making Thereof - A catalyst and a process for making a catalyst from a precursor composition containing rework materials are disclosed. The catalyst is made by sulfiding a catalyst precursor containing 5-95 wt. % rework material. The catalyst precursor employing rework materials can be a hydroxide or oxide material. Rework can be materials generated in the forming or shaping of the catalyst precursor, or formed upon the breakage or handling of the shaped catalyst precursor. Rework can also be in the form of catalyst precursor feed material to the shaping process, e.g., extrusion process, or catalyst precursor material generated as reject or scrap in the shaping process. In some embodiment, rework may be of the consistency of shapeable dough. In another embodiment, rework is in the form of small pieces or particles, e.g., fines, powder. | 11-04-2010 |
20100279855 | Hydroconversion Multi-Metallic Catalyst and Method for Making Thereof - A stable catalyst with low volumetric shrinkage and a process for making the stable catalyst with low volumetric shrinkage is disclosed. The catalyst is made by sulfiding a catalyst precursor containing at least a Group VIB metal compound; at least a promoter metal compound selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, having an oxidation state of either +2 or +4; optionally at least a ligating agent; optionally at least a diluent. In the process of making the catalyst, the catalyst precursor is first shaped then heat treated at a temperature of 50° C. to 200° C. for about 15 minutes to 12 hours, wherein the catalyst precursor still has a low (less than 12%) volumetric shrinkage after exposure to a temperature of at least 100° C. | 11-04-2010 |
20100279856 | Hydroconversion Multi-Metallic Catalyst and Method for Making Thereof - A method for preparing a bulk multi-metallic suitable for hydrotreating heavy oil feeds is provided. In the process of preparing the catalyst precursor which is subsequently sulfided to form the bulk catalyst, non-agglomerative drying is employed to keep the catalyst precursor from aggregating/clumping, resulting in a catalyst precursor with optimum porosity with at least 90% of the pores being macropores, and having a total pore volume of at least 0.08 g/cc. | 11-04-2010 |
20110017636 | Systems and Methods for Producing a Crude Product - A process for hydroprocessing heavy oil feedstock is disclosed. The process operates in once-through mode, employing a plurality of contacting zones and at least a separation zone to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock. At least an additive material selected from inhibitor additives, anti-foam agents, stabilizers, metal scavengers, metal contaminant removers, metal passivators, and sacrificial materials, in an amount of less than 1 wt. % of the heavy oil feedstock, is added to at least one of the contacting zones. In one embodiment, the additive material is an anti-foam agent. In another embodiment, the additive material is a sacrificial material for trapping heavy metals in the heavy oil feed and/or deposited coke, thus prolonging the life of the slurry catalyst. | 01-27-2011 |
20110120914 | HYDROGENATION OF SOLID CARBONACEOUS MATERIALS USING MIXED CATALYSTS - This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of zinc at a reaction temperature of greater than 350° C. and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product. | 05-26-2011 |
20110120915 | HYDROGENATION OF SOLID CARBONACEOUS MATERIALS USING MIXED CATALYSTS - This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of copper and at least one active source of a second metal at a reaction temperature of greater than 350° C. and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product. | 05-26-2011 |
20110120916 | HYDROGENATION OF SOLID CARBONACEOUS MATERIALS USING MIXED CATALYSTS - This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of cobalt and at least one active source of a second metal at a reaction temperature of greater than 350° C. and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product. | 05-26-2011 |
20110120917 | HYDROGENATION OF SOLID CARBONACEOUS MATERIALS USING MIXED CATALYSTS - This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of titanium and at least one active source of a second metal at a reaction temperature of greater than 350° C. and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product. | 05-26-2011 |
20110120918 | HYDROGENATION OF SOLID CARBONACEOUS MATERIALS USING MIXED CATALYSTS - This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of nickel and at least one active source of a second metal at a reaction temperature of greater than 350° C. and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product. | 05-26-2011 |
20110124493 | Hydroprocessing Bulk Catalyst and Methods of Making Thereof - A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (R | 05-26-2011 |
20110124494 | Hydroprocessing Bulk Catalyst and Methods of Making Thereof - A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (R | 05-26-2011 |
20110124496 | Hydroprocessing Bulk Catalyst and Methods of Making Thereof - A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (R | 05-26-2011 |
20110124498 | Hydroprocessing Bulk Catalyst and Methods of Making Thereof - A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (R | 05-26-2011 |
20120000828 | HYDRODEMETALLIZATION CATALYST AND PROCESS - This invention is directed to hydrodemetallization catalysts and hydrodemetallization processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic | 01-05-2012 |
20120039777 | PROCESS FOR SEPARATING AND RECOVERING METALS - A process for treating spent catalyst containing heavy metals, e.g., Group VIB metals and Group VIII metals is provided. In one embodiment after deoiling, the spent catalyst is treated with an ammonia leach solution under conditions sufficient to dissolve the group VIB metal and the Group VIII metal into the leaching solution, forming a leach slurry. After solid-liquid separation to recover a leach solution, chemical precipitation and solids repulping is carried out to obtain an effluent stream containing ammonium sulfate (Amsul), ammonium sulfamate, Group VB, Group VIB and Group VIII metals. Following sulfidation, the Group VIII metal is fully removed and Group VB and Group VI metals are partially removed from the Amsul stream. In the additional steps of oxydrolysis and iron precipitation, an effective amount of ferric ion at a pre-select pH is added to form insoluble complexes with the Group VB and Group VIB metals, which upon liquid-solid separation produces an effluent ammonium sulfate stream containing less than 10 ppm each of the Group VB and Group VIB metals. | 02-16-2012 |
20120074042 | PROCESS FOR REDUCING THE TOTAL ACID NUMBER OF A HYDROCARBON FEED - Disclosed are embodiments relating to a process for reducing the total acid number of a hydrocarbon feed by contacting the feed with a metal titanate catalyst having an MTiO | 03-29-2012 |
20120122653 | HYDROCONVERSION MULTI-METALLIC CATALYST AND METHOD FOR MAKING THEREOF - In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant. In the present disclosure, the metals can be recovered in an electro-coagulation reactor, wherein portion of the metal residuals in the supernatant reacts with the electrodes to form a slurry containing insoluble metal compounds. The insoluble metal compounds are isolated and recovered, forming an effluent stream. The insoluble metal compounds and/or the effluent stream can be further treated to form at least a metal precursor feed which can be used in the co-precipitation reaction. | 05-17-2012 |
20120122654 | HYDROCONVERSION MULTI-METALLIC CATALYST AND METHOD FOR MAKING THEREOF - In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant as metal residuals. In the present disclosure, the metals can be recovered in a chemical precipitation step, wherein the supernatant is mixed with at least one of an acid, a sulfide-containing compound, a base, and combinations thereof to precipitate at least 50% of metal ions in at least one of the metal residuals, wherein the precipitation is carried out at a pre-select pH. The precipitate is isolated and recovered, yielding an effluent stream. The precipitate and/or the effluent stream can be further treated to form at least a metal precursor feed which can be used in the co-precipitation reaction. The process generates an effluent to waste treatment containing less than 50 ppm metals. | 05-17-2012 |
20120122655 | HYDROCONVERSION MULTI-METALLIC CATALYST AND METHOD FOR MAKING THEREOF - In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant. In the present disclosure, the metals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of metal ions in at least one of the metal residuals, and for at least one of the metal residuals is recovered as a metal precursor feed, which can be recycled for use in the co-precipitation reaction. An effluent stream from the process to waste treatment contains less than 50 ppm metal ions. | 05-17-2012 |
20120122656 | HYDROCONVERSION MULTI-METALLIC CATALYST AND METHOD FOR MAKING THEREOF - In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and stay in the supernatant. In one embodiment, at least a precipitant is added to the product mixture at a molar ratio of precipitant to metal residuals in the supernatant ranging from 1.5:1 to 20:1 to precipitate at least 50 mole % of metal ions in the residuals forming additional catalyst precursor. The remaining metal residuals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of at least one of the metal residuals. In one embodiment, at least one of the metal residuals is recovered and recycled for use as a metal precursor feed in the co-precipitation reaction. | 05-17-2012 |
20120122658 | HYDROCONVERSION MULTI-METALLIC CATALYST AND METHOD FOR MAKING THEREOF - In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of metal ions in at least one of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant as metal residuals. In the present disclosure, the metals can be recovered via ion-exchange, wherein an exchange resin is provided for a portion of the metal ions in the supernatant to be exchanged and bound onto the resin. The previously resin-bound metals can be subsequently recovered, or the effluent stream for the exchange resin column can also be recovered, forming at least a metal precursor feed which can be used in the co-precipitation reaction. | 05-17-2012 |
20120122659 | HYDROCONVERSION MULTI-METALLIC CATALYST AND METHOD FOR MAKING THEREOF - In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds end up in the supernatant. The metals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of metal ions in at least one of the metal residuals, and for at least one of the metal residuals recovered as a metal precursor feed for use in the co-precipitation reaction. In one embodiment, the resin functions as an anion exchange resin with an acidic supernatant to recover Group VIB metal residuals, and a cation exchange resin with a basic supernatant to recover Promoter metal residuals. An effluent stream from the process to waste treatment contains less than 50 ppm metals. | 05-17-2012 |
20120122661 | HYDROCRACKING CATALYST AND PROCESS USING A MAGNESIUM ALUMINOSILICATE CLAY - This invention is directed to hydrocracking catalysts and hydrocracking processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic | 05-17-2012 |
20120168350 | HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF - An improved process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs a polar aprotic solvent to mix with the inorganic metal precursor feed to form an oil-dispersible inorganic metal precursor, at a weight ratio of solvent to inorganic metal precursor of 1:1 to 10:1; the oil-dispersible inorganic metal precursor is subsequently sulfided forming the slurry catalyst. In one embodiment, the sulfiding is in-situ upon mixing the oil-dispersible inorganic metal precursor with a hydrocarbon diluent containing a heavy oil feedstock under in-situ sulfiding conditions. | 07-05-2012 |
20120172198 | HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF - A process for making an improved slurry catalyst for the upgrade of heavy oil feedstock is provided. In the process, a metal precursor solution comprising at least a water-soluble molybdenum compound and a water-soluble metal zinc compound is mixed under high shear mixing conditions to generate an emulsion. The emulsion is subsequently sulfided with a sulfiding agent ex-situ, or in-situ in a heavy oil feedstock to form the slurry catalyst. The in-situ sulfidation in heavy oil is under sufficient condition for the heavy oil feedstock to generate the sulfiding source needed for the sulfidation. | 07-05-2012 |
20120172200 | HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF - A single metal slurry catalyst for the upgrade of heavy oil feedstock is provided. The slurry catalyst is prepared by sulfiding a Primary metal precursor, then mixing the sulfided metal precursor with a hydrocarbon diluent to form the slurry catalyst. The single-metal slurry catalyst has the formula (M | 07-05-2012 |
20120172202 | HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF - A process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs a pressure leach solution obtained from a metal recovery process as part of the metal precursor feed. In one embodiment, the process comprises: sulfiding a pressure leach solution having at least a Group VIB metal precursor compound in solution forming a catalyst precursor, and mixing the sulfided catalyst precursor with a hydrocarbon diluent to form the slurry catalyst. In another embodiment, the pressure leach solution is mixed with a hydrocarbon diluent under high shear mixing conditions to form an emulsion, which emulsion can be sulfided in-situ upon contact with a heavy oil feedstock in the heavy oil upgrade process. | 07-05-2012 |
20120172203 | HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF - An improved process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. In the process, high shear mixing is employed to generate an emulsion containing droplets of metal precursor in oil with droplet sizes ranging from 0.1 to 300 μm. The emulsion is subsequently sulfided with a sulfiding agent, or in-situ in a heavy oil feedstock to form a slurry catalyst. The in-situ sulfidation in heavy oil is under sufficient condition for the heavy oil feedstock to generate the sulfiding source needed for the sulfidation. | 07-05-2012 |
20120172204 | HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF - An improved hydroprocessing slurry catalyst is provided for the upgrade of heavy oil feedstock. The catalyst comprises dispersed particles in a hydrocarbon medium with the dispersed particles have an average particle size ranging from 1 to 300 μm. The catalyst has a total pore volume of at least 0.5 cc/g and a polymodal pore distribution with at least 80% of pore sizes in the range of 5 to 2,000 Angstroms in diameter. The catalyst is prepared from sulfiding and dispersing a metal precursor solution in a hydrocarbon diluent, the metal precursor comprising at least a Primary metal precursor and optionally a Promoter metal precursor, the metal precursor solution having a pH of at least 4 and a concentration of less than 10 wt. % of Primary metal in solution. | 07-05-2012 |
20120172205 | HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF - An improved hydroprocessing slurry catalyst is provided for the upgrade of heavy oil feedstock. The slurry catalyst is prepared from at least a Group VIB metal precursor compound and optionally at least a Promoter metal precursor compound. The catalyst comprises dispersed particles in a hydrocarbon medium with the dispersed particles have an average particle size ranging from 1 to 300 μm. The catalyst has a total surface area of at least 100 m | 07-05-2012 |
20120172206 | HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF - A method for preparing an improved slurry catalyst for the upgrade of heavy oil feedstock is provided. In one embodiment, the process comprises: sulfiding at least a metal precursor solution with at least a sulfiding agent forming a sulfided Group VIB catalyst precursor, the metal precursor solution having a pH of at least 4 and a concentration of less than 10 wt. % of Primary metal in solution; and mixing the catalyst precursor with a hydrocarbon diluent to form the slurry catalyst composition. The slurry catalyst prepared therefrom has a BET total surface area of at least 100 m | 07-05-2012 |
20120193295 | METHOD FOR TREATING EFFLUENT WATERS - A process for treating waste water, effluent streams, e.g., acid mine drainage, containing heavy metals and soluble contaminants is provided. In one embodiment, at least a metal cation is added to the effluent water at a pre-selected pH to form insoluble heavy metal complexes. In one embodiment, the metal cation is a trivalent metal ion, e.g., ferric iron such as in ferric sulfate. In another embodiment, a divalent metal ion such as ferrous sulfate is used. After the removal of the heavy metal complexes, the effluent water is treated with an aluminum salt such as calcium aluminate to remove remaining soluble contaminants, thus producing a treated water stream with reduced levels of contaminants. | 08-02-2012 |
20130068662 | HYDROCONVERSION MULTI-METALLIC CATALYST AND METHOD FOR MAKING THEREOF - A method for hydroprocessing a hydrocarbon feedstock is provided. The method comprises contacting the feedstock with a catalyst under hydroprocessing conditions, wherein the catalyst is formed by sulfiding an unsupported catalyst precursor of the general formula A | 03-21-2013 |
20130150600 | HYDROCONVERSION OF RENEWABLE FEEDSTOCKS - A hydrocarbon conversion process comprises contacting a renewable feedstock under hydroprocessing conditions with a bulk catalyst to form oleochemicals such as fatty alcohols, esters, and normal paraffins. Advantageously, the reaction conditions can be selected to directly convert the renewable feedstock to the desired product(s). | 06-13-2013 |
20130150631 | HYDROCONVERSION OF RENEWABLE FEEDSTOCKS - A hydrocarbon conversion process comprises contacting a renewable feedstock under hydroprocessing conditions with a bulk catalyst to form oleochemicals such as fatty alcohols, esters, and normal paraffins. Advantageously, the reaction conditions can be selected to directly convert the renewable feedstock to the desired product(s). | 06-13-2013 |
20130150635 | HYDROCONVERSION OF RENEWABLE FEEDSTOCKS - A hydrocarbon conversion process comprises contacting a renewable feedstock under hydroprocessing conditions with a bulk catalyst to form oleochemicals such as fatty alcohols, esters, and normal paraffins. Advantageously, the reaction conditions can be selected to directly convert the renewable feedstock to the desired product(s). | 06-13-2013 |
20140057775 | HYDROCRACKING CATALYST AND PROCESS USING A MAGNESIUM ALUMINOSILICATE CLAY - This invention is directed to hydrocracking catalysts and hydrocracking processes employing a magnesium aluminosilicate clay and a zeolite. The magnesium aluminosilicate clay has a characteristic | 02-27-2014 |
20140066293 | Hydroconversion Multi-Metallic Catalyst and Method For Making Thereof - The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The self-supported MMS catalyst contains Ni:W in a mole ratio of 1:3 to 4:1, on a transition metal basis. The self supported MMS catalyst is characterized as having an HYD reaction rate constant of at least 15% higher than that of a catalyst comprising nickel sulfide alone or a catalyst comprising tungsten sulfide alone, when compared on same metal molar basis in hydrotreating of benzene as a feedstock at identical process conditions. | 03-06-2014 |
20140066294 | Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof - The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The self-supported MMS catalyst consists essentially of molybdenum sulfide and tungsten sulfide, wherein the catalyst contains at least 0.1 mol % of Mo and at least 0.1 mol % of W, on a transition metal basis. | 03-06-2014 |
20140066295 | Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof - A self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock is disclosed. The self-supported MMS catalyst is characterized by an HDN reaction rate constant of at least 100 g feed hr | 03-06-2014 |
20140066296 | Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof - The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The MMS catalyst has molar ratios of metal components Ni:Mo:W in a region defined by five points ABCDE of a ternary phase diagram, and wherein the five points ABCDE are defined as: A (Ni=0.72, Mo=0.00, W=0.25), B (Ni=0.25, Mo=0.00, W=0.75), C (Ni=0.25, Mo=0.25, W=0.50), D (Ni=0.60, Mo=0.25, W=0.15), E (Ni=0.72, Mo=0.13, W=0.15). | 03-06-2014 |
20140066297 | Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof - The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The MMS catalyst is characterized as having a multi-phased structure comprising five phases: a molybdenum sulfide phase, a tungsten sulfide phase, a molybdenum tungsten sulfide phase, an active nickel phase, and a nickel sulfide phase. | 03-06-2014 |
20140066298 | Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof - The invention relates to a method for preparing a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock. The method comprises mixing a sufficient amount of a nickel (Ni) metal precursor, a sufficient amount of a molybdenum (Mo) metal precursor, and a sufficient amount of a tungsten (W) metal precursor to produce a catalyst precursor having a molar ratio Ni:Mo:W in relative proportions defined by a region of a ternary phase diagram showing transition metal elemental composition in terms of nickel, molybdenum, and tungsten mol-%, wherein the region is defined by five points ABCDE and wherein the five points are: A (Ni=0.72, Mo=0.00, W=0.28), B (Ni=0.55, Mo=0.00, W=0.45), C (Ni=0.48, Mo=0.14, W=0.38), D (Ni=0.48, Mo=0.20, W=0.33), E (Ni=0.62, Mo=0.14, W=0.24); and sulfiding the catalyst precursor under conditions sufficient to convert the catalyst precursor into a sulfide catalyst. | 03-06-2014 |
20140135207 | Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof - The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The MMS catalyst is characterized as having a BET surface area of at least 20 m | 05-15-2014 |
20140163249 | HYDROCONVERSION OF RENEWABLE FEEDSTOCKS - A hydroconversion process comprises contacting a feedstock comprising renewable materials under hydroprocessing conditions with a promoted catalyst selected from a self-supported catalyst, a supported catalyst and combinations thereof, wherein the reaction conditions can be tailored to directly convert the renewable feedstock to the desired product(s) including fatty alcohols, esters, normal paraffins, or combinations thereof. The catalyst comprising at least a Group VIB metal selected from molybdenum and tungsten, a Group VIII metal selected from cobalt and nickel to convert the feedstock into any of fatty alcohols, esters, and normal paraffins. In some embodiments, the process further comprising additional steps to generate various desirable products, including α-olefins (or PAO, by dehydrating the fatty alcohol products), lubricants and bright stocks (from the oligomerizing of the PAO), and Group 3 lubricants (from co-oligomerizing of the PAO with some short chain olefins). | 06-12-2014 |
20140348729 | PROCESS FOR SEPARATING AND RECOVERING METALS - A process for treating spent catalyst containing heavy metals, e.g., Group VIB metals and Group VIII metals is provided. In one embodiment after deoiling, the spent catalyst is treated with an ammonia leach solution under conditions sufficient to dissolve the group VIB metal and the Group VIII metal into the leaching solution, forming a leach slurry. After solid-liquid separation to recover a leach solution, chemical precipitation and solids repulping is carried out to obtain an effluent stream containing ammonium sulfate (Amsul), ammonium sulfamate, Group VB, Group VIB and Group VIII metals. Following sulfidation, the Group VIII metal is fully removed and Group VB and Group VI metals are partially removed from the Amsul stream. In the additional steps of oxydrolysis and iron precipitation, an effective amount of ferric ion at a pre-select pH is added to form insoluble complexes with the Group VB and Group VIB metals, which upon liquid-solid separation produces an effluent ammonium sulfate stream containing less than 10 ppm each of the Group VB and Group VIB metals. | 11-27-2014 |