Class / Patent application number | Description | Number of patent applications / Date published |
554163000 | The -C(=O)O- is part of an ester group | 81 |
20100217022 | Enhanced Oligomeric Polyols and Polymers Made Therefrom - Enhanced oligomeric polyols are reported. The enhanced oligomeric polyols may be prepared by a method comprising the steps of: (a) providing an oligomeric polyol that comprises at least one glycerol fatty acid ester having at least one glycerol fatty acid ester bond; wherein at least 5% of the ethyldenyl groups (*C═C*) in the glycerol fatty acid ester are substituted with a bonding structure selected from the group consisting of: C—*C—C*—C; O—*C—C*—O; C═*C—C*—C, and mixtures thereof, where * is used to denote the original carbon atoms in the ethylidenyl group; and (b) cleaving at least a portion of the glycerol fatty acid ester bonds to form the enhanced oligomeric polyol. The enhanced oligomeric polyols are useful in making polymers such as polyurethanes. | 08-26-2010 |
20100222606 | METHOD FOR PRODUCING BISABOLOL WHICH IS FARNESOL FREE OR IS LOW IN FARNESOL - The present invention relates to a method of producing pure or enriched bisabolol by separating substance mixtures comprising bisabolol and farnesol by selective esterification of farnesol and subsequent distillative separation. The invention relates specifically to a method as specified above comprising the selective transesterification of mixtures comprising formyl-bisabolol and formyl-farnesol and subsequent distillative separation. | 09-02-2010 |
20100261921 | Integrated System for the Production and Separation of Biodiesel and Method Thereof - The present invention relates to an integrated method and system for the simultaneous production of biodiesel from free fatty acids (via esterification) and from triglycerides (via transesterification) within the same reaction chamber. More specifically, one preferred embodiment of the invention relates to a method and system for the production of biodiesel using an electrodeionization stack, wherein an ion exchange resin matrix acts as a heterogeneous catalyst for simultaneous esterification and transesterification reactions between a feedstock and a lower alcohol to produce biodiesel, wherein the feedstock contains significant levels of free fatty acid. In addition, because of the use of a heterogeneous catalyst, the glycerol and biodiesel have much lower salt concentrations than raw biodiesel produced by conventional transesterification processes. The present invention makes it much easier to purify glycerol and biodiesel. | 10-14-2010 |
20100286420 | METHOD FOR PRODUCING FATTY ACID ALKYL ESTERS AND/OR GLYCERIN USING FAT OR OIL - The present invention has an object to provide the following method for producing fatty acid alkyl esters and/or glycerin and the following catalyst used in the production method. | 11-11-2010 |
20110071309 | Methods and Systems for Utilization of HCI - Systems and methods are disclosed for generating a proton removing agent and an acidic solution in a low voltage electrochemical system and utilizing the proton removing agent to sequester carbon dioxide from a waste gas in a carbon dioxide sequestration system and utilizing the acidic solution to catalyze at least one step of a chemical syntheses in combination with a plant based material. | 03-24-2011 |
20110092725 | Catalysis Of Fats And Oils To Alkyl Esters Using Hydrolysis As Pretreatment - A process that employs hydrolysis of fats and oils as a pretreatment step to prevent or drastically reduce the formation of glycerin decomposition products that occur in systems that use fixed bed or heterogeneous catalysts for simultaneous trans-esterification and esterification of fats and oils to alkyl esters of fatty acids for use as Biofuels, soaps, detergents, solvents or other applications of fatty acid alkyl esters. The pretreatment step is particularly effective for processes using fixed bed catalytic reactors operating at elevated temperatures and pressures sufficient to cause formation of decomposition products of glycerin which is known to be a problem associated with these processes. The pretreatment hydrolysis step allows the formation, separation and recovery of better quality glycerin by-product and minimizing the formation of glycerin decomposition products in the reactors. | 04-21-2011 |
20120289724 | Process For Purifying Crude Fatty Alcohols - Described is a process for simultaneously purifying fatty alcohols and obtaining a fraction of free fatty acids, wherein:
| 11-15-2012 |
20130085288 | METHODS OF REFINING AND PRODUCING DIBASIC ESTERS AND ACIDS FROM NATURAL OIL FEEDSTOCKS - Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters. | 04-04-2013 |
20130217906 | DIENE-SELECTIVE HYDROGENATION OF METATHESIS DERIVED OLEFINS AND UNSATURATED ESTERS - Methods are provided for refining natural oil feedstocks and partially hydrogenating polyunsaturated olefins and polyunsaturated esters. The methods comprise reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the polyunsaturated olefins from the polyunsaturated esters in the metathesized product. In certain embodiments, the methods further comprise partially hydrogenating the polyunsaturated olefins in the presence of a hydrogenation catalyst, wherein at least a portion of the polyunsaturated olefins are converted to monounsaturated olefins. In other embodiments, the methods further comprise partially hydrogenating the polyunsaturated esters in the presence of a hydrogenation catalyst, wherein at least a portion of the polyunsaturated esters are converted to monounsaturated esters. | 08-22-2013 |
20130331586 | METHODS OF REFINING NATURAL OILS, AND METHODS OF PRODUCING FUEL COMPOSITIONS - A method for suppressing dehydrogenation includes reacting an optionally functionalized olefin reactant in a metathesis reaction to form an olefin metathesis product; and providing a dehydrogenation suppression agent in admixture with (a) the olefin metathesis product and/or the optionally functionalized olefin reactant, and (b) a metal-containing material selected from the group consisting of residual metathesis catalyst, a hydrogen transfer agent, and a combination thereof, under conditions that are sufficient to passivate at least a portion of the metal-containing material. Methods of refining natural oils and methods of producing fuel compositions are also described. | 12-12-2013 |
20140031571 | PROCESS FOR PRODUCING MONOBRANCHED FATTY ACIDS OR ALKYL ESTERS - A process for producing C | 01-30-2014 |
20140046082 | HETEROGENEOUS CATALYSTS FOR TRANSESTERIFICATION OF TRIGLYCERIDES AND PREPARATION METHODS OF SAME - Method for transesterification of fatty acid esters. The method includes contacting (i) a catalyst comprising at least one of barium oxide and apatite with (ii) a reaction medium comprising at least one of vegetable oil and fats. | 02-13-2014 |
20140336398 | METHODS OF REFINING AND PRODUCING FUEL AND SPECIALTY CHEMICALS FROM NATURAL OIL FEEDSTOCKS - Methods are provided for refining natural oil feedstocks. The methods include reacting the feedstock with a low-molecular-weight olefin or mid-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product including olefins and esters. In certain embodiments, the methods further include separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further include transesterifying the esters in the presence of an alcohol to form a transesterified product. | 11-13-2014 |
20140336399 | Methods of Refining and Producing Fuel and Specialty Chemicals from Natural Oil Feedstocks - Methods are provided for refining natural oil feedstocks. The methods include reacting the feedstock with a molar excess of low-molecular-weight olefins in the presence of a metathesis catalyst. In certain embodiments, the methods further include separating at least a portion of the unreacted low-molecular-weight olefins. In certain embodiments, the methods further include recycling the separated unreacted low-molecular-weight olefins. | 11-13-2014 |
20150105570 | SYSTEMS AND METHODS FOR MAKING BIOPRODUCTS - Processes for continuous preparation of bioproducts are described herein. The processes include contacting fatty acid glycerides with alcohols in the presence of an acidic heterogeneous catalyst and separating the fatty acid alkyl esters from the reaction products. | 04-16-2015 |
20150291912 | PROCESS FOR PRODUCING MONOBRANCHED FATTY ACIDS OR ALKYL ESTERS THEREOF - A process for producing a composition having a ratio by weight of C | 10-15-2015 |
20160074843 | USE OF CATALYST PREPARED WITH A SUBGROUP VI ELEMENT FOR THE PRODUCTION OF ORGANIC CHEMICALS AND FUELS FROM LIGNIN - A subgroup VI element to prepare a catalyst for the production of organic chemicals and fuels from lignin with the involvement of solvent molecules. The catalytic reaction use a catalyst composed of a molybdenum or tungsten compound as the active phase, with mixing a kind of lignin, a catalyst, and a reactive solvent. An inert or reductive gas such as H2, N2 or Ar is used to purge or fill the reaction vessel. The temperature is above 200° C., the reaction time is sufficient. The liquid product is separated and analyzed; a catalytic process with a very high product yield, up to 90% if calculated accounting the parts from lignin of the product molecules, or up to over 100% if calculated as the mass products. The product includes aromatic compounds, esters, alcohols, monophenols and benzyl alcohols in different ratios according to the composition, the solvent and the other reaction conditions. | 03-17-2016 |
554165000 | Another reactant is a carboxylic acid | 3 |
20090156845 | Acrylate Hybride Polymer Based On Natural Fatty Acids And Method For The Manufacture Thereof - The invention relates to acrylate modified, natural fatty acid based hybride polymers, and to a method for their preparation. The invention also relates to the use of the modified natural fatty acid based hybride polymers as binding agents especially in water based coatings, adhesives and composites and as environmentally friendly wood impregnating agents. The acrylate-modified natural fatty acid based hybride polymer is a block polymer formed of acrylate segments and fatty acid segments. | 06-18-2009 |
20130046105 | METHOD FOR OBTAINING A LIPID-CONTAINING COMPOSITION FROM MICROBIAL BIOMASS - Methods are provided for pelletizing a microbial biomass, extracting a refined lipid composition from the pelletized biomass under supercritical conditions and distilling the refined lipid composition, at least once under short path distillation conditions, to obtain a lipid-containing fraction. Also disclosed are methods of making lipid-containing oil concentrates therefrom, by transesterifying and enriching the lipid-containing fraction. | 02-21-2013 |
554166000 | Polycarboxylic or hydroxy acid (i.e., containing additional -C(=O)OH or an -OH group) | 1 |
20150141683 | ESTER FORMATION OF FATTY ACID AND HYDROXYCARBOXYLIC ACID - The present invention relates to a process for the transesterification of a fatty acid ester of a lower alcohol and a salt hydroxycarboxylic acid without making use of organic solvents. The process can also be carried out without added anionic surface active agents. | 05-21-2015 |
554167000 | Another reactant contains alcoholic or phenolic hydroxy (e.g., methy ricinoleate, etc.) | 50 |
20080227994 | Process For the Production of Carboxylic Acid Esters - The invention relates to a process for the production of carboxylic acid esters by esterification of carboxylic acids and/or transesterification of carboxylic acid esters with alcohols in the presence of a liquid metal catalyst, characterized in that the liquid metal catalyst is the alkaline earth metal salt of a carboxylic acid. | 09-18-2008 |
20080249325 | Method and Device For Continuous Process of Transesterification of Carboxylic Acid Esters in a Supercritical Monovalent Alcohol - A method for continuous process of transesterification of carboxylic acid esters in supercritical monovalent alcohol, wherein, accordingly formula R—OH, R is discretionary aliphatic hydrocarbon radical having 1-10 carbon atoms and in which as initial substance are used synthetic carboxylic acid esters or their compositions, for example fats and oils, which are esters of different fatty acids and glycerol. A device for continuous process of transesterification of carboxylic acid esters in supercritical monovalent alcohol, which comprises alcohol inlet ( | 10-09-2008 |
20090005582 | VESSELS AND METHODS FOR SYNTHESIS OF BIOFUEL - Vessels and methods for esterification and transesterification of fatty acids under near critical or supercritical reaction conditions are disclosed herein. Alkyl esters produced in the vessel with the disclosed methods are used to create biofuel, such as biodiesel. | 01-01-2009 |
20090099380 | Fatty acid alkyl ester production from oleaginous seeds - A process is described for producing fatty acid alkyl esters for both diesel fuel and non-fuel uses. The feed material includes whole oleaginous seeds slurried in a liquid triglyceride oil containing at least two weight percent free fatty acid, wherein oil from inside the seeds is first extracted with concurrent esterification of free fatty acids from all sources in an acidic environment. Following sufficient free fatty acid reaction, the intermediate product is subjected to base-catalyzed concurrent extraction and transesterification. Decanting of the byproduct glycerin is followed by water washing. Subsequently, the fatty acid ester product is concurrently purified and fractionated into a biodiesel fuel stream and a non-fuel fraction, each of which undergoes post treatment as needed. The process is optionally integrated with glycerin purification and/or methanol recovery. | 04-16-2009 |
20100105935 | PROCESS FOR CONTINUOUSLY PREPARING FATTY ACID METHYL ESTERS OR FATTY ESTERS - In a process for producing fatty acid methyl ester (FAME) from fats or oils by transesterification with methanol in the presence of an alkaline catalyst in at least two reaction stages traversed in succession, each consisting of a stirred-tank reactor and a downstream separator, a phase containing FAME and a phase containing glycerol are generated, which are separated in the separator, wherein the phase containing FAME is recirculated into the stirred-tank reactor of the next succeeding reaction stage and the phase containing glycerol is recirculated into the stirred-tank reactor of the first reaction stage, and the crude FAME withdrawn from the separator of the last reaction stage is transferred into a separator and the FAME withdrawn is dried. To increase the yield of FAME, the aqueous phase containing glycerol, methanol, undissociated soaps and FAME, which is obtained upon withdrawal of the FAME, is thoroughly mixed with the phases withdrawn from the separators of the first to penultimate reaction stages, which contain glycerol and FAME, and the mixture is separated in a separator into a phase containing FAME and a phase containing glycerol. | 04-29-2010 |
20100121087 | Method for esterification of free fatty acids in triglycerides - A method for esterification of free fatty acids with methanol. The method has steps of: (a) contacting a heterogeneous esterification catalyst in a reactor with a reaction mixture containing: (i) methanol and (ii) a triglyceride mixture containing 70-99.8 wt % triglycerides and 0.2-30 wt % free fatty acids, under conditions suitable for esterification, to produce a product stream; (b) separating water and methanol from the product stream to produce a dried product stream; (c) contacting the dried product stream with methanol to produce a methanol-rich phase and a triglyceride-rich phase; and (d) separating the methanol-rich phase and recycling it to the reactor. | 05-13-2010 |
20100125145 | Trans-Esterification Reaction System And Method Thereof - The trans-esterification system for trans-esterifying a triglyceride includes a reaction tank, a separation tank, a first pipe and a second pipe. The reaction tank is inputted with the triglyceride and a monohydric alcohol for undergoing a trans-esterification reaction to produce a mixture. The separation tank is inputted with the mixture for a phase separation to generate an ester phase solution and a glycerol phase solution having a first part and a second part. The first pipe connects the reaction tank and the separation tank, and transports the mixture from the reaction tank to the separation tank. The second pipe connects the reaction tank and the separation tank, and transports the first part of the glycerol phase solution from the separation tank to the reaction tank for undergoing the trans-esterification reaction. | 05-20-2010 |
20100130763 | PROCESSES FOR THE PRODUCTION OF FATTY ACID ALKYL ESTERS - The present invention provides processes for the formation of fatty acid alkyl esters, which may be used as biodiesel. In particular, the invention provides an esterification process in which a lipid material is contacted with an alcohol in the presence of a metal halide or metal alkoxide conjugated to a solid support. Also provided is a transesterification process in which a lipid material is contacted with an alcohol in the presence of an N-heterocyclic carbene. Also provided is a combination esterification and transesterification process in which a lipid material is contacted with a metal halide or metal alkoxide conjugated to a solid support, and then is contacted with an N-heterocyclic carbene or an alkaline catalyst. | 05-27-2010 |
20100274034 | METHOD AND APPARATUS FOR PRODUCING FATTY ACID ALKYL ESTER AND/OR GLYCERIN - The present invention provides a method of producing a fatty acid alkyl ester and/or glycerin by bringing an oil and an alcohol into contact with each other, the method including: reacting the oil and alcohol with each other; performing solid-liquid separation for removing a solid sterol from a reaction liquid obtained in the step of reacting; and performing phase separation for separating the reaction liquid into a hydrophobic phase and a hydrophilic phase after the reaction liquid is subjected to the step of performing the solid-liquid separation, the hydrophobic phase containing the fatty acid alkyl ester, and the hydrophilic phase containing glycerin. Thereby, the present invention provides a method allowing stable continuous operation for a long time period for production of a fatty acid alkyl ester and/or glycerin. | 10-28-2010 |
20100311997 | METHOD FOR PRODUCING FATTY ACID METHYL ESTERS OR FATTY ACID ETHYL ESTERS - Method for producing C | 12-09-2010 |
20110060152 | Methods and Systems for Improved Biodiesel Production - In a method and system to produce biodiesel using an improved catalytic transesterification process, a first reactant and a second reactant are dispersed to form a laminar slug flow pattern within a microchannel of a microreactor, the first reactant and the second reactant being immiscible. The first reactant and the second reactant are mixed, thereby triggering a reaction between them to produce the biodiesel and glycerol, the mixing being convection-enhanced by shear stress induced circulation occurring within each slug of the reactants. The reaction takes place under a pressure that is less than 5 psi and under a temperature that is less than 70 degrees Celsius. Separation of the glycerol from the biodiesel occurs simultaneously with the mixing. Several microreactors are coupled in parallel to improve throughput of the biodiesel. | 03-10-2011 |
20110060153 | SYSTEMS AND METHODS FOR REFINING ALKYL ESTER COMPOSITIONS - The present invention relates to systems and methods for producing and/or refining alkyl ester compositions. In an embodiment the invention includes a method of producing a refined fatty acid alkyl ester composition. The method can include contacting a fatty acid feedstock and an alcohol with a first metal oxide catalyst at a temperature of greater than 200 degrees Celsius and a pressure of greater than 500 psi to form an unrefined fatty acid alkyl ester composition. The method can further include combining the unrefined fatty acid alkyl ester composition with dimethyl carbonate to form a refining mixture. The method can also include contacting the refining mixture with a second metal oxide catalyst at a temperature of greater than 100 degrees Celsius to form a refined fatty acid alkyl ester composition. Other embodiments are also described herein. | 03-10-2011 |
20110105775 | METHOD OF CONVERTING FREE FATTY ACID (FFA) FROM OIL TO METHYL ESTER - The present invention provides a method of converting free fatty acid (FFA) from oil to methyl ester, the method includes the steps (a) esterifying the FFA using an acidic catalyst dissolved in an alcohol, (b) separating excess alcohol, solid acid catalyst, water, glycerol, soap and other non-lipid soluble impurities from oil obtained from step (a), (c) neutralizing the oil from step (b), (d) drying the oil from step (c) and (e) transesterifying the oil from step (d) using an alkaline catalyst and an alcohol. | 05-05-2011 |
20110144364 | METHOD OF PRODUCING ALKYL ESTERS FROM VEGETABLE OR ANIMAL OIL AND AN ALIPHATIC MONOALCOHOL WITH FIXED-BED HOT PURIFICATION - The present invention relates to a method of producing alkyl esters and glycerin from a crude or semi-refined vegetable oil and an aliphatic monoalcohol, comprising a deep pretreatment purification stage to eliminate the species based on phosphorus, calcium, magnesium, zinc or iron, insoluble under the temperature conditions of the heterogeneous catalytic reactor. | 06-16-2011 |
20110224451 | PROCESS FOR PRODUCTION OF BIODIESEL - The invention relates to a process for producing alkyl esters, the process comprising reacting a feedstock that includes one or more fatty acid glycerol esters or one or more fatty acid or mixture thereof with a C | 09-15-2011 |
20120004433 | METHOD OF PREPARING ALCOHOL ESTERS FROM TRIGLYCERIDES AND ALCOHOLS USING HETEROGENEOUS CATALYSTS BASED ON NITROGEN-CONTAINING METALLOPHOSPHATES - A method of preparing a composition of alcohol esters of linear monocarboxylic acids with 6 to 26 carbon atoms from a vegetable or animal oil, neutral or acid, virgin or recycled, with monoalcohols having 1 to 18 carbon atoms, in the presence of a catalyst of nitrogen-containing metallophosphate type. | 01-05-2012 |
20120022279 | CATALYST COMPRISING AT LEAST ONE IZM-2 ZEOLITE, AND ITS USE IN THE TRANSFORMATION OF HYDROCARBON FEEDS - A catalyst is described which comprises at least one IZM-2 zeolite and at least one matrix, said zeolite having a chemical composition expressed as the anhydrous base in terms of moles of oxides by the following general formula: XO | 01-26-2012 |
20120101288 | PROCESS FOR THE PRODUCTION OF ALKYL ESTERS FROM ANIMAL OR VEGETABLE OIL AND AN ALIPHATIC MONO-ALCOHOL WITH THERMAL INTEGRATION - The present invention describes a process for the production of alkyl esters of fatty acids and glycerine employing, in a reaction section, at least one transesterification reaction between an animal or vegetable oil and an aliphatic mono-alcohol, and using a heterogeneous solid catalyst, in which the energy balance is improved by thermal integration of the energy released during the mono-alcohol condensation step. | 04-26-2012 |
20120123140 | Production of Biodiesel and Glycerin from High Free Fatty Acid Feedstocks - A system and method for the conversion of free fatty acids to glycerides and the subsequent conversion of glycerides to glycerin and biodiesel includes the transesterification of a glyceride stream with an alcohol. The fatty acid alkyl esters are separated from the glycerin to produce a first liquid phase containing a fatty acid alkyl ester rich (concentrated) stream and a second liquid phase containing a glycerin rich (concentrated) stream. The fatty acid alkyl ester rich stream is then subjected to distillation, preferably reactive distillation, wherein the stream undergoes both physical separation and chemical reaction. The fatty acid alkyl ester rich stream is then purified to produce a purified biodiesel product and a glyceride rich residue stream. Neutralization of the alkaline stream, formed during the alkali-catalyzed transesterfication process, may proceed by the addition of a mineral or an organic acid. | 05-17-2012 |
20120130101 | CERAMIC CATALYST USED IN MANUFACTURE OF FATTY ACID ALKYL ESTERS AND METHOD FOR PREPARING HIGH PURITY FATTY ACID ALKYL ESTERS USING THE SAME - The present invention relates to a catalyst used in the manufacture of fatty acid alkyl esters and a method for preparing fatty acid alkyl esters using the same. The invention provides a high hardness solid ceramic metal catalyst obtained by mixing and sintering 0 wt %-80 wt % active catalyst material with a support material, wherein the support material is a silica alumina that is a mixed metal oxide and the active catalyst material is at least one of oxides, carbonates, and hydroxides of any kind selected from magnesium (Mg), calcium (Ca), zinc (Zn), titanium (Ti), manganese (Mn), vanadium (V), beryllium (Be), copper r (Cu), zirconium (Zr), strontium (Sr), tin (Sn), and barium (Ba). In addition, the invention provides a method for preparing fatty acid alkyl esters by performing transesterification and esterification of animal and vegetable oils and alcohols in the state where the ceramic metal catalyst is fixed within a reactor without processes for removing and purifying the catalyst. | 05-24-2012 |
20120142952 | SYSTEMS FOR ALKYL ESTER PRODUCTION - In one embodiment, a method for the production of alkyl esters comprises: introducing liquid biomass and an alcohol to a first transesterification reactor at a point in a lower 25% of the reactor; reacting the liquid biomass and the alcohol to form a liquid glycerol and a liquid alkyl ester, wherein greater than or equal to about 75 mass % of the liquid glycerol moves towards a bottom of the first transesterification reactor; removing a liquid alkyl ester stream from the first transesterification reactor; and removing the liquid glycerol from the first transesterification reactor. The liquid biomass and the alcohol form a combined liquid stream that flows through the first transesterification reactor in a laminar flow. | 06-07-2012 |
20120157699 | PROCESS FOR PRODUCTION OF BIODIESEL - A multi-stage reactor system for preparing biodiesel is used to increase efficiency and yield and reduce impurities. A three-stage transesterification reaction for preparing biodiesel can include one high-shear cavitation reactor and two low-shear cavitation reactors, preferably in series, and optionally one or more separation vessels for removing waste and recycling triglyceride feedstock, catalyst and alcohol to the high-shear cavitation reactor. | 06-21-2012 |
20120184758 | Continuous Transesterification Method - The invention relates to a continuous method for producing esters, in which at least one polyol ester of formula (I) (R | 07-19-2012 |
20120197031 | METHODS OF REFINING NATURAL OILS AND METHODS OF PRODUCING FUEL COMPOSITIONS - A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent selected from the group consisting of phosphorous acid, phosphinic acid, and a combination thereof; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described. | 08-02-2012 |
20120232300 | SYSTEMS AND METHODS FOR MAKING BIOPRODUCTS - Processes for continuous preparation of bioproducts are described herein. The processes include contacting fatty acid glycerides with alcohols in the presence of an acidic heterogeneous catalyst and separating the fatty acid alkyl esters from the reaction products. | 09-13-2012 |
20120253057 | Continuous Production Of Bioderived Esters Via Supercritical Solvent Processing Using Solid Heterogeneous Catalysts - A method for the continuous production of ester based organic compounds from renewable natural products via supercritical solvent processing in the presence of heterogeneous nano-structured catalysts. Fatty acid triglycerides may therefore be transesterified using heterogeneous nano-structured catalysts in the presence of supercritical alcohols to provide alkyl ester compounds and glycerine. | 10-04-2012 |
20120283459 | METALOXIDE - Zr02 CATALYSTS FOR THE ESTERIFICATION AND TRANSESTERIFICATION OF FREE FATTY ACIDS AND TRIGLYCERIDES TO OBTAIN BIO-DIESEL - Mixed metal oxide catalysts (ZnO, CeO, La2O3, NiO, Al203, Si02, TiO2, Nd2O3, Yb2O3, or any combination of these) supported on zirconia (ZrO2) or hydrous zirconia are provided. These mixed metal oxide catalysts can be prepared via coprecipitation, impregnation, or sol-gel methods from metal salt precursors with/without a Zirconium salt precursor. Metal oxides/ZrO2 catalyzes both esterification and transesterification of oil containing free fatty acids in one batch or in single stage. In particular, these mixed metal oxides supported or added on zirconium oxide exhibit good activity and selectivity for esterification and transesterification. The low acid strength of this catalyst can avoid undesirable side reaction such as alcohol dehydration or cracking of fatty acids. Metal oxides/ZrO2 catalysts are not sensitive to any water generated from esterification. Thus, esterification does not require a water free condition or the presence of excess methanol to occur when using the mixed metal oxide catalyst. The FAME yield obtained with metal oxides/ZrO2 is higher than that obtained with homogeneous sulfuric acid catalyst. Metal oxides/ZrO2 catalasts can be prepared as strong pellets and in various shapes for use directly in a flow reactor. Furthermore, the pellet has a strong resistance toward dissolution to aqueous or oil phases. | 11-08-2012 |
20120283460 | Renewable Chemical Production From Novel Fatty Acid Feedstocks - Disclosed herein are methods of manufacturing renewable chemicals through the manufacture of novel triglyceride oils followed by chemical modification of the oils. Methods such as transesterification, hydrogenation, hydrocracking, deoxygenation, isomerization, interesterification, hydroxylation, hydrolysis and saponification are disclosed. Novel oils containing fatty acid chain lengths of C8, C10, C12 or C14 are also disclosed and are useful as feedstocks in the methods of the invention. | 11-08-2012 |
20120289725 | SYNTHESIS OF FATTY ALCOHOL ESTERS OF ALPHA-HYDROXY CARBOXYLIC ACIDS AND THEIR USE AS PERCUTANEOUS ABSORPTION ENHANCERS - The present invention provides a novel approach for the preparation of fatty alcohol esters of α-hydroxy carboxylic acids. In one form of the invention, the target fatty alcohol ester of α-hydroxy carboxylic acid is produced by converting a lower alkyl ester of α-hydroxy carboxylic acid into a fatty alcohol ester of α-hydroxy carboxylic acid via alcoholysis (i.e., transesterification). The transesterification process is an equilibrium reaction, catalyzed chemically (i.e., with acids or bases) or enzymatically, that is shifted in the desired direction to produce the desired product. One way of shifting the reaction in the direction of the desired product is by reducing the concentration of one of the products (e.g., distillation of a lower-boiling alcohol as it is formed). Another preferred way of shifting the reaction in the direction of the desired product is by increasing the concentration of one of the reactants. | 11-15-2012 |
20130041167 | METHOD OF TREATING TALL OIL PITCH - A method of treating tall oil pitch, which comprises sterol esters of fatty acids. According to the present invention, the esters of sterols and fatty acids are broken down, in which case especially formic acid esters or acetic acid esters of sterols are formed instead. The free fatty acids and sterol esters generated are distilled or separated in another way. Use of the present invention increases the yield of fatty acids and also facilitates the separation of sterols from tall oil pitch. | 02-14-2013 |
20130072706 | Recovery of Oleaginous Tricyglycerols from Wastewater Title of Invention Treatment Plant Foams - Tricyglycerols that may be converted to biofuel are recovered from oleaginous organisms in the natural and induced foam of wastewater treatment process plants. Growing oleaginous organisms in the form of comparatively dry foam simplifies harvest and is more efficient and efficacious than skimming the biomass off the top of the liquids that rely on less efficient centrifugation or filtration methods typically required to concentrate cells grown in liquids. | 03-21-2013 |
20130131363 | Surfactant Composition for Agricultural Chemicals - A surfactant composition for agricultural chemicals, containing fatty acid polyoxyalkylene alkyl ether expressed by the following general formula (I), | 05-23-2013 |
20130331587 | Process For The Preparation Of Fatty Acid Alkyl Esters (Biodiesel) From Triglyceride Oils Using Eco-Friendly Solid Base Catalysts - This invention relates to an improved process for the preparation of green fatty acid methyl esters (FAME; commonly called as biodiesel) from different triglyceride oils using mixed metal oxides derived from layered double hydroxides (referred here as LDHs) as reusable solid heterogeneous base catalysts. This process uses very low alcohohoil molar ratio and catalyst and/or products are easily separable after the reaction through simple physical processes. The properties of thus obtained biodiesel meet the standard biodiesel values and can directly be used as transport fuel. | 12-12-2013 |
20140005424 | Production of Biodiesel and Glycerin from High Free Fatty Acid Feedstocks | 01-02-2014 |
20140121394 | Cosmetic Compositions Containing Esters Based on 2-Propylheptanol - Esters of 2-propylheptanol with linear or branched, saturated or unsaturated C | 05-01-2014 |
20140194635 | Production of Biodiesel and Glycerin from High Free Fatty Acid Feedstocks - A system and method for the conversion of free fatty acids to glycerides and the subsequent conversion of glycerides to glycerin and biodiesel includes the transesterification of a glyceride stream with an alcohol. The fatty acid alkyl esters are separated from the glycerin to produce a first liquid phase containing a fatty acid alkyl ester rich (concentrated) stream and a second liquid phase containing a glycerin rich (concentrated) stream. The fatty acid alkyl ester rich stream is then subjected to distillation, preferably reactive distillation, wherein the stream undergoes both physical separation and chemical reaction. The fatty acid alkyl ester rich stream is then purified to produce a purified biodiesel product and a glyceride rich residue stream. Neutralization of the alkaline stream, formed during the alkali-catalyzed transesterfication process, may proceed by the addition of a mineral or an organic acid. | 07-10-2014 |
20140330033 | MECHANICALLY ENHANCED SEPARATION OF REACTION PRODUCTS IN BIODIESEL PRODUCTION - Apparatus and related methods for reacting a natural oil with a short chain alcohol in the presence of an alkaline catalyst and mesh to produce biodiesel, significantly decreasing the amount of time for the glycerol byproduct to settle out of the reaction mixture. The process for the production of biodiesel includes providing animal or vegetable oil to create a first component, combining a short chain alcohol with a strong base to create a second component, and combining the first and second components together in the presence of a mesh, such that the mesh is in contact with the combined components. The combined compositions represent a reaction mixture that undergo a transesterification reaction and produce fatty acid methyl ester biodiesel and also a glycerol byproduct. The mesh material that is present during the transesterification reaction decreases the amount of time required for the glycerol byproduct to settle out of the reaction mixture. | 11-06-2014 |
20150322378 | DIRECT TRANSESTERIFICATION OF ALGAL BIOMASS FOR SYNTHESIS OF FATTY ACID ETHYL ESTERS (FAEE) - Methods of producing fatty acid ethyl esters (FAEE) using a direct transesterification process are described. The direct transesterification process uses low levels of chemical solvents, acid catalysts, and heating energy to produce the FAEE in a method with increased efficiency in a co-solvent system. The FAEE produced may be used in a variety of products including health, beauty, nutraceutical, and cosmetic products. | 11-12-2015 |
20160032203 | COMPOSITIONS AND METHODS OF MAKING BIOFUEL - The present disclosure concerns embodiments of a catalyst system, such as a mixed catalyst composition, that can be used to make biofuel. In some embodiments, the mixed catalyst composition can comprise an inorganic catalyst and an organic catalyst, such as a cyclic organic catalyst. In particular disclosed embodiments, a mixed catalyst composition comprising, consisting essentially of, or consisting of an inorganic catalyst and an organic catalyst can be used to enhance the production of biofuel, such as biodiesel, by reducing the amount of time needed to make the biofuel as compared to that needed for the inorganic catalyst or the organic catalyst independently. Also disclosed herein are combinations and kits comprising, consisting essentially of, or consisting of embodiments of a mixed catalyst composition. | 02-04-2016 |
20160067693 | Method for Preparation of a Group 4 Metal Silicate and Use Thereof - The invention provides a method for the preparation of an amorphous silicate of at least one metal from the Group 4 of the Periodic Table of Elements with a total pore volume of at least 0.3 mL/g. The method of preparation involves the use of pore shaping conditions, which can be the use of a pore shaper and optionally an increased precipitation temperature, e.g. at least 60° C. The silicate of the invention is especially suitable in catalytic reactions such as esterifications, Michael additions, transesterifications, (ep)oxidations, hydroxylations, or in adsorbance of small inorganic and organic molecules e.g. CO | 03-10-2016 |
20160102041 | HETEROGENEOUS CATALYST FOR TRANSESTERIFICATION AND METHOD OF PREPARING SAME - A transesterification catalyst that is heterogeneous and a method for preparing said transesterification catalyst are provided. The catalyst can be used in a variety of transesterification reactor configurations including CSTR (continuous stirred tank reactors), ebullated (or ebullating) beds or any other fluidized bed reactors, and PFR (plug flow, fixed bed reactors). The catalyst can be used for manufacturing commercial grade biodiesel, biolubricants and glycerin. | 04-14-2016 |
20160108344 | PROCESS AND SYSTEM FOR PRODUCING A FATTY ACID ALKYL ESTER - A process and a system for producing a fatty acid alkyl ester from an alcohol and a feedstock containing transesterifiable lipids are provided. | 04-21-2016 |
20160152908 | METHOD FOR PREPARING FATTY ACID ALKYL ESTER USING FAT | 06-02-2016 |
20160185706 | SOLID, HETEROGENEOUS CATALYSTS AND METHODS OF USE - Solid mixed catalysts and methods for use in conversion of triglycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. The described catalysts are thermostable, long lasting, and highly active. | 06-30-2016 |
20160194581 | SYSTEM AND METHODS FOR MAKING BIOPRODUCTS | 07-07-2016 |
554168000 | Plural alcoholic or phenolic hydroxys (e.g., glycerol, castor oil, etc.) | 5 |
20090005583 | Preparation of Propylene Glycol Fatty Acid Ester or Other Glycol or Polyol Fatty Acid Esters - A method for the preparation of a polyol fatty acid ester utilizes a combination of methyl soyate and a polyol in a molar ratio of approximately 2:1 in the presence of a basic catalyst to produce a fatty acid ester. Methanol is removed during a distillation process to drive the reaction process. Optionally, gas sparging can be utilized to aide in methanol recovery. In one embodiment, the method is employed to produce a propylene glycol disoyate product that does not require further purification or distillation to remove a relatively high boiling methyl soyate reactant. | 01-01-2009 |
20090187035 | Process for production of fatty acid alkyl esters - A system and method for producing fatty acid alkyl esters is provided. The method includes forming a reactant stream, which includes triacylglycerides, alkanol, basic transesterification catalyst and, optionally, glycerol, and mixing the reactant stream under high shear mixing conditions to provide a mixed stream comprising fatty acid alkyl ester. | 07-23-2009 |
20150087850 | BIO-POLYOLS FOR BIO-LUBRICANT AND BIO-POLYMER AND METHODS FOR THE PREPARATION THEREOF - A method for producing an ester polyol, comprising transesterifying a first ester polyol with a primary polyol to produce a second ester polyol, wherein the second ester polyol has a higher hydroxyl value than the first ester polyol. | 03-26-2015 |
20150148554 | PROCESS FOR PREPARING BIODEGRADABLE LUBRICANT BASE OILS - The invention discloses an improved process for preparing fatty acid esters with 100 mol % selectivity suitable as biodegradable lubricant base oils, comprising contacting a fatty compound with an alcohol in presence of a solid, phosphonate catalyst having molecular formula: M(X)2-nYn.mH2O where X refers to phenyl phosphonate, Y refers to HPO42− or HPO32−, M refers to a metal or metalloid ion preferably taken from the group consisting of Zr, Zn, Cd, Al, Sn, La and Ce, the value of n varies from 0.2 to 1.8 and the value of m varies from 0 to 5, wherein the fatty compound is a fatty acid or fatty acid methyl or ethyl ester or vegetable oil or animal fat or their mixture thereof and alcohol is a monohydric alcohol with 6 to 22 carbon atoms or a polyol with at least two hydroxyl groups. | 05-28-2015 |
20150307794 | PROCESS FOR MANUFACTURING BIOFUELS - The present invention relates to a process for obtaining simultaneously several compositions comprising fatty acid alkyl esters (biodiesel), glycerol formal and fatty acid glycerol formal esters. | 10-29-2015 |
554169000 | Molecular rearrangement of the acid moieties of glyceride esters (e.g., random or directed low temperature intra- or inter-esterification of fats, oils, etc.) | 11 |
20080293956 | METHOD OF PRODUCING BIODIESEL - This invention involves a kind of fatty acid methyl ester (bio-diesel fuel), especially the method of obtaining ester-like substances by means of chemical alterations of oil. | 11-27-2008 |
20090062559 | METHOD FOR PRODUCTION OF BIOFUEL - Alkyl esters boiling largely within the specification range for jet fuel may be made from triglycerides without a water-washing step, by centrifugation in a timely manner and at a sufficiently high time/G-force/distance product so as to bring about separation of a transitory second phase containing the residual catalyst. The esters or fractions thereof may be combined with jet or diesel fuels to lower the freezing and cloud points respectively. | 03-05-2009 |
20100010246 | METHODS AND CATALYSTS FOR MAKING BIODIESEL FROM THE TRANSESTERIFICATION AND ESTERIFICATION OF UNREFINED OILS - A method of forming a biodiesel product and a heterogeneous catalyst system used to form said product that has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock is disclosed. This catalyst system may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system according to one aspect of the present disclosure represents a class of zinc and lanthanum oxide heterogeneous catalysts that include different ratios of zinc oxide to lanthanum oxides (Zn:La ratio) ranging from about 10:0 to 0:10. The Zn:La ratio in the catalyst is believed to have an effect on the number and reactivity of Lewis acid and base sites, as well as the transesterification of glycerides, the esterification of fatty acids, and the hydrolysis of glycerides and biodiesel. | 01-14-2010 |
20100063309 | BIODIESEL PROCESSES IN THE PRESENCE OF FREE FATTY ACIDS AND BIODIESEL PRODUCER COMPOSITIONS - Glyceride-containing feed for a base catalyzed transesterification with lower alkanol to make biodiesel is pretreated with glycerin separated during the transesterification to partially convert glycerides with lower alkanol contained in the separated glycerin using base catalyst in the separated glycerin while reducing the free fatty acid and phosphorus compound concentrations in the glyceride-containing feed. Unique producer compositions are provided by the pretreatment processes. | 03-11-2010 |
20110054200 | Systems and Processes for Biodiesel Production - Described herein are systems and processes for the transesterification of a variety of feedstocks, such as in the form of glyceride-containing vegetable oils, glyceride-containing animal oils, and glyceride-containing algal oils, into biodiesel products using solid, heterogeneous catalysts. | 03-03-2011 |
20120142953 | METHOD FOR THE TRANSESTERIFICATION OF HYDROXYLATED OILS - The present invention relates to a method for the transesterification of a hydroxylated oil including two consecutive transesterification steps performed in the presence of a light alcohol (methanol or ethanol) and a basic catalyst under temperature, pressure and alcohol/oil weight ratio conditions enabling the nearly total conversion of the hydroxylated oil into fatty acid esters. Characteristically, a resulting directly from the first transestrefication step in order to obtain a reaction mixture including, in particular, hydroxylated fatty acid esters and glycerol. Said reaction mixture is subjected to a separation step that makes it possible to obtain a less dense phase predominantly consisting of fatty esters and a denser phase predominantly consisting of glycerol and water and fatty acid soaps. The second transesterification step is performed on the less dense phase, with said light alcohol and said basic catalyst are added thereto. | 06-07-2012 |
20130096331 | INTERESTERIFICATION OF LOW SATURATE SUNFLOWER OIL AND RELATED METHODS AND COMPOSITIONS - A method of producing a interesterified oil includes providing sunflower oil comprising no more than about 4% total saturated fat and interesterifying the sunflower oil. Another method of producing a interesterified oil includes providing sunflower oil comprising about 3.3% or less total combined palmitic acid (16:0) and stearic acid (18:0), and interesterifying the sunflower oil. | 04-18-2013 |
20130158277 | PROCESSES FOR PREPARING ESTOLIDE BASE OILS AND OLIGOMERIC COMPOUNDS THAT INCLUDE CROSS METATHESIS - Provided herein are estolide base oils and oligomeric compounds prepared from processes that include cross metathesis. Exemplary processes include the preparation of terminally-unsaturated fatty acids by cross metathesis, and the subsequent oligomerization of terminally-unsaturated fatty acids to provide estolide compounds, such as the process set forth below: | 06-20-2013 |
20150329791 | Biodiesel Cold Filtration Process - An improved biodiesel production process includes the steps of processing a feedstock to produce biodiesel, cooling the biodiesel so as to form sediment, and filtering the biodiesel to remove the sediment. The resulting biodiesel from the cold filtration process avoids problems of sediment formation during storage and transportation. | 11-19-2015 |
20150368585 | RECIPROCATING BIOMASS CONVERSION SCHEME - A method for converting a biomass to a bio-oil includes providing a four-stroke internal combustion engine having at least one cylinder, at least one piston, and a crankshaft coupled to each of the at least one piston. The method also includes coupling a power source to the crankshaft in a manner such that the power source drives rotation of the crankshaft. The method also includes injecting a first mixture including a biomass and a non-oxidizing compression gas into one of the cylinders. The method also includes compressing and heating the first mixture during a compression stroke of the pistons. The compression and heating of the first mixture pyrolizes the biomass to produce a second mixture including a bio-oil and the compression gas. The method also includes decompressing and cooling the second mixture during an expansion stroke of the pistons. The decompression and cooling of the second mixture quenches secondary pyrolysis. | 12-24-2015 |
20160201011 | INTERESTERIFICATION CATALYST AND PROCESS | 07-14-2016 |