Patent application number | Description | Published |
20090318740 | METHOD OF CONVERTING FEEDSTOCKS FROM RENEWABLE SOURCES TO GOOD-QUALITY DIESEL FUEL BASES USING A ZEOLITE TYPE CATALYST - The invention relates to a method of treating feedstocks from renewable sources in order to produce diesel fuel bases of excellent quality. The feedstocks used can be, for example, raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The invention relates to a method allowing high diesel fuel base yields to be obtained from such feedstocks. | 12-24-2009 |
20090326290 | METHOD OF CONVERTING FEEDSTOCKS FROM RENEWABLE SOURCES TO GOOD-QUALITY DIESEL FUEL BASES USING A ZEOLITE CATALYST WITHOUT INTERMEDIATE GAS-LIQUID SEPARATION - The invention relates to a method of treating feedstocks from renewable sources without intermediate gas-liquid separation in order to produce diesel fuel bases of excellent quality. The feedstocks used can be raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The invention relates to a method allowing high diesel fuel base yields to be obtained from such feedstocks. | 12-31-2009 |
20100163458 | METHOD OF CONVERTING EFFLUENTS OF RENEWABLE ORIGIN INTO FUEL OF EXCELLENT QUALITY BY USING A MOLYBDENUM-BASED CATALYST - The invention is concerned with a supported or unsupported catalyst comprising an active phase constituted by a sulfur-containing group VIB element, the group VIB element being molybdenum, and a hydrodeoxygenation process with a yield of hydrodeoxygenation product which is greater than or equal to 90% of charges from renewable sources using a catalyst according to the invention. | 07-01-2010 |
20100240942 | PROCESS FOR HYDRODEOXYGENATION OF FEEDS DERIVED FROM RENEWABLE SOURCES WITH LIMITED DECARBOXYLATION CONVERSION USING A CATALYST BASED ON NICKEL AND MOLYBDENUM - The invention concerns a process for hydrodeoxygenation of feeds derived from renewable sources with conversion by decarboxylation/decarbonylation limited to at most 10%, using a bulk or supported catalyst comprising an active phase constituted by at least one element from group VIB and at least one element from group VIII, said elements being in the sulphide form, and the atomic ratio of the metal (or metals) from group VIII to the metal (or metals) from group VIB being strictly more than 0 and less than 0.095, said process being carried out at a temperature in the range 120° C. to 450° C., at a pressure in the range 1 MPa to 10 MPa, at an hourly space velocity in the range 0.1 h | 09-23-2010 |
20100242349 | PROCESS FOR THE CONTINUOUS HYDROGENATION OF TRIGLYCERIDE CONTAINING RAW MATERIALS - Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising hydrogenation catalyst. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio. Further, a sufficient excess of hydrogen is used so that no valuable product is lost through decarb-reactions. | 09-30-2010 |
20100292517 | PRODUCTION OF VAPOUR-CRACKING LOADS WITH A HIGH YIELD OF THE RESULTING ETHYLENE, PROPYLENE AND POLYMERS BY HYDROPROCESSING OF VEGETABLE OILS - The invention describes a process for treatment of a feedstock that is obtained from a renewable source that comprises a hydrotreatment stage in the presence of at least one fixed-bed catalyst, whereby said catalyst comprises a hydro-dehydrogenating function and an amorphous substrate, at a temperature of between 50 and 450° C., at a pressure of between 1 MPa and 10 MPa, at an hourly volumetric flow rate of between 0.1 h−1 and 10 h−1, and in the presence of a total quantity of hydrogen that is mixed with the feedstock such that the hydrogen/feedstock ratio is between 50 and 1000 Nm3 of hydrogen/m3 of feedstock, followed by a separation from the hydrotreated effluent that is obtained from stage a) of hydrogen, gases, and at least one liquid hydrocarbon effluent that consists of at least 50% linear n-paraffins, and a steam-cracking of at least one portion of the liquid hydrocarbon effluent that is obtained from stage b). | 11-18-2010 |
20100292518 | TWO-STEP HYDROTREATMENT OF A FEED DERIVED FROM A RENEWABLE SOURCE USING A FIRST, METALLIC, CATALYST AND A SECOND, SULPHURIZED, CATALYST - The invention describes a two-step process for hydrotreatment of a feed derived from a renewable source, comprising:
| 11-18-2010 |
20100325943 | PROCESS FOR EBULLATED BED HYDROCONVERSION OF FEEDS OF BIO-RENEWABLE ORIGIN FOR THE PRODUCTION OF FUEL BASES - The invention concerns a process for hydrotreatment and/or hydroconversion of a feed of bio-renewable origin containing triglyceride and/or fatty acid structures and wherein the fatty chains contain in the range 8 to 25 carbon atoms, said process comprising the following steps:
| 12-30-2010 |
20110094148 | METHOD OF HYDROTREATING FEEDS FROM RENEWABLE SOURCES WITH INDIRECT HEATING - The invention describes a method of treating feeds from renewable sources comprising:
| 04-28-2011 |
20110094149 | METHOD OF HYDROTREATING FEEDS FROM RENEWABLE SOURCES WITH INDIRECT HEATING USING A CATALYST BASED ON MOLYBDENUM - The invention describes a method of treating feeds from renewable sources comprising a hydrotreatment stage comprising at least two catalytic zones in which the entry stream comprising said feed mixed with at least a part of a hydrotreated liquid effluent from stage b) is introduced into the first catalytic zone at a temperature comprised between 150 and 260° C., and the effluent from the first catalytic zone is then introduced, mixed with at least a part of a hydrotreated liquid effluent from stage b) and preheated, into the following catalytic zone or zones at a temperature comprised between 260 and 320° C., and a stage of separation of the effluent from the hydrotreatment stage permitting the separation of a gaseous effluent and a hydrotreated liquid effluent of which at least a part is recycled at the top of each catalytic zone, said method using, in at least the catalytic zone or zones following the first, a bulk or supported catalyst comprising an active phase constituted by a sulphidized group VIB element, the group VIB element being molybdenum. | 04-28-2011 |
20110098494 | METHOD OF HYDROTREATING FEEDS FROM RENEWABLE SOURCES WITH INDIRECT HEATING USING A CATALYST BASED ON NICKEL AND MOLYBDENUM HAVING A PARTICULAR ATOMIC RATIO - The invention describes a method of treating feeds from renewable sources comprising a hydrotreatment stage comprising at least two catalytic zones in which the entry stream comprising said feed mixed with at least a part of a hydrotreated liquid effluent from stage b) is introduced into the first catalytic zone at a temperature comprised between 150 and 260° C., and the effluent from the first catalytic zone is then introduced, mixed with at least a part of a hydrotreated liquid effluent from stage b) and preheated, into the following catalytic zone or zones at a temperature comprised between 260 and 320° C., and a stage of separation of the effluent from the hydrotreatment stage permitting the separation of a gaseous effluent and a hydrotreated liquid effluent of which at least a part is recycled at the top of each catalytic zone, said method using, in at least the catalytic zone or zones following the first, a bulk or supported catalyst comprising an active phase constituted by at least one group VIB element and at least one group VIII element, said elements being in sulphide form and the atomic ratio of the group VIII metal to the group VIB metal being strictly greater than 0 and less than 0.095. | 04-28-2011 |
20110138680 | PROCESS FOR CONVERTING FEEDS DERIVED FROM RENEWABLE SOURCES WITH PRE-TREATMENT OF FEEDS BY HOT DEPHOSPHATATION - The invention concerns a process for the pre-treatment of an unrefined vegetable or animal oil, consisting of passing said oil through a reactor comprising at least one fixed bed of at least one adsorbent comprising a porous refractory oxide which is free of catalytic metals, at a temperature in the range 130° C. to 320° C., at a pressure in the range 0.1 to 7 MPa and with a residence time for said oil on said fixed bed in the range 0.1 to 1 hour. The invention concerns a process for pre-treatment of a semi-refined vegetable or animal oil, integrated upstream of a hydrotreatment step for the production of green gas oil. | 06-16-2011 |
20120059209 | PROCESS FOR THE CONTINUOUS HYDROGENATION OF TRIGLYCERIDE CONTAINING RAW MATERIALS USING A NICKEL AND MOLYBDENUM-BASED CATALYST - Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising at least e hydrogenation catalyst comprising an active phase constituted by a nickel and molybdenum element. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio. | 03-08-2012 |
20120165581 | PRODUCTION OF PARAFFINIC FUELS FROM RENEWABLE MATERIALS USING A CONTINUOUS HYDROTREATMENT PROCESS - The invention concerns a process for hydrotreating a feed originating from renewable sources such as vegetable oils to produce paraffinic hydrocarbons in the presence of hydrogen in excess over the theoretical hydrogen consumption and under hydrotreatment conditions in a fixed bed reactor having a plurality of catalytic zones disposed in series and comprising a hydrotreatment catalyst. The total feed flow is divided into a certain number of different part flows equal to the number of catalytic zones in the reactor; the various part flows are injected into the successive catalytic zones in increasing proportions to produce an effluent comprising paraffinic hydrocarbons. The effluent undergoes a separation step in order to separate a gas fraction and a liquid fraction containing the paraffinic hydrocarbons. At least a portion of said liquid fraction is recycled to the first catalytic zone so that the weight ratio between said recycle and the part flow introduced into the first catalytic zone is 10 or more. | 06-28-2012 |
20120216450 | METHOD OF CONVERTING FEEDS FROM RENEWABLE SOURCES IN CO-PROCESSING WITH A PETROLEUM FEED USING A CATALYST BASED ON NICKEL AND MOLYBDENUM - The invention relates to a method of hydrotreatment in co-processing of petroleum feeds, in a mixture with at least one feed obtained from renewable sources, for producing fuel bases (kerosene and/or gas oil) having a sulphur content below 10 ppm, said method comprising the following stages:
| 08-30-2012 |
20130116490 | PRODUCTION OF PARAFFIN FUELS USING RENEWABLE MATERIALS BY A CONTINUOUS HYDROTREATMENT COMPRISING A PRE-TREATMENT STEP - A process for hydrotreatment of a feed from renewable sources such as vegetable oils for the production of paraffinic hydrocarbons comprising pre-treatment by crystallisation and/or precipitation allowing the elimination of insoluble inorganic impurities under hydrotreatment conditions. The flow of the total feed is divided up into a certain number of different, part flows equal to the number of catalytic zones in the reactor, and the different part flows are injected in the successive catalytic zones in increasing proportions to produce an effluent containing paraffinic hydrocarbons. | 05-09-2013 |
20130116491 | PRODUCTION OF PARAFFIN FUELS USING RENEWABLE MATERIALS BY A CONTINUOUS HYDROTREATMENT COMPRISING A PRE-TREATMENT STEP UNDER HYDROGEN - A process for hydrotreatment of a feed from renewable sources such as vegetable oils for the production of paraffinic hydrocarbons comprising a pre-treatment step by crystallisation and/or precipitation and pre-hydrogenation of the feed under hydrogen allowing the elimination of insoluble inorganic impurities under hydrotreatment conditions and improved exothermal management of the reaction. The effluent is separated to a gas fraction and a liquid fraction containing paraffinic hydrocarbons, a portion of said liquid fraction is recycled. | 05-09-2013 |
20140291200 | PROCESS FOR CONVERSION OF FEEDSTOCKS OBTAINED FROM RENEWABLE SOURCES BASED ON MARINE FUELS - The invention relates to a process for the production of diesel fuel bases comprising a sulfur content that is less than 100 ppm, starting from a feedstock that is obtained from a renewable source, comprising the following stages:
| 10-02-2014 |