Patent application number | Description | Published |
20100130709 | Procatalyst Composition Including Silyl Ester Internal Donor and Method - The present disclosure provides silyl esters and silyl diol esters suitable as internal electron donors in procatalysts for polymer production. Disclosed are procatalyst compositions formed from a procatalyst precursor and an internal electron donor that is a silyl ester or a silyl diol ester. The procatalyst compositions can be used with a cocatalyst and optionally an external electron donor and/or an activity limiting agent to form a Ziegler-Nana catalyst composition. The present catalyst compositions exhibit high catalyst activity and form olefin-based polymers with broad molecular weight distribution, favorable flexural modulus, and high isotacticity. | 05-27-2010 |
20100174105 | Production of Substituted Phenylene Aromatic Diesters - The present disclosure is directed to the production of 5-tert-butyl-3-methyl-1,2-phenylene dibenzoate and the purification thereof. Synthesis pathways for a precursor to 5-tert-butyl-3-methyl-1,2-phenylene dibenzoate are provided. The precursor is 5-tert-butyl-3-methylcatechol. | 07-08-2010 |
20100204506 | Production of Substituted Phenylene Aromatic Diesters and Compositions - The present disclosure provides processes for the production of substituted phenylene aromatic diesters and the resultant compositions. The processes include reacting an aromatic diol with an aromatic carboxylic acid or a derivative thereof. The aromatic diol and/or the aromatic carboxylic acid (or derivative thereof) is/are substituted. The reaction forms a substituted phenylene aromatic diester with the structure (II): | 08-12-2010 |
20100222530 | Procatalyst Composition with Substitute 1,2-Phenylene Aromatic Diester Internal Donor and Method - Disclosed are procatalyst compositions having an internal electron donor which include a substituted phenylene aromatic diester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit high activity and produce propylene-based olefins with broad molecular weight distribution. | 09-02-2010 |
20100267911 | Procatalyst Composition with Silyl Glutarate and Method - Disclosed are procatalyst compositions having an internal electron donor which includes a silyl glutarate and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit strong activity and produce propylene-based olefins with high isotacticity. | 10-21-2010 |
20100273966 | Procatalyst Composition with Adamantane and Method - Disclosed are procatalyst compositions having an internal electron donor which includes an adamantanedicarboxylate and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions produce propylene-based olefins with broad molecular weight distribution. | 10-28-2010 |
20110130529 | THREE AND FOUR ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE - A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: | 06-02-2011 |
20110130530 | TWO ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE - A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: | 06-02-2011 |
20120157295 | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product - Disclosed herein are processes for preparing procatalyst compositions with an internal electron donor containing greater than 4.5 wt % of a compounded alkoxyalkyl ester. Also disclosed are catalyst compositions containing the procatalyst composition and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions improve catalyst selectivity, catalyst activity, procatalyst morphology and polymer particle morphology, and improve hydrogen response during olefin polymerization. | 06-21-2012 |
20120157296 | Catalyst Composition with Halo-Malonate Internal Electron Donor and Polymer From Same - Disclosed herein are procatalyst compositions, catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions contain a halo-malonate and a 2-fluoro-malonate in particular. The present catalyst compositions improve catalyst selectivity, improve catalyst activity, and also improve hydrogen response during polymerization. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 50 g/10 min. | 06-21-2012 |
20120157643 | Procatalyst Composition with Alkoxyalkyl 2-Propenoate Internal Electron Donor and Polymer from Same - Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions contain an internal electron donor of an alkoxyalkyl 2-propenoate and optionally a mixed external electron donor. The present catalyst compositions improve catalyst selectivity and polymer stiffness. Polypropylene homopolymer produced from the present catalyst composition has a xylene solubles content less than 4 wt % and a T | 06-21-2012 |
20120157645 | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same - Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions include an internal electron donor with an alkoxypropyl ester. The present catalyst compositions improve catalyst selectivity. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 4 g/10 min. | 06-21-2012 |
20120316299 | Amide Ester Internal Electron Donor and Process - Disclosed is a process for producing a procatalyst composition having an amide ester internal electron donor. The process includes pre-halogenating a procatalyst precursor before reaction with the amide ester and forming the procatalyst composition. Ziegler-Natta catalyst compositions containing the present procatalyst composition exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution. | 12-13-2012 |
20120322962 | Procatalyst Composition with Substituted Amide Ester Internal Electron Donor - Disclosed are procatalyst compositions having an internal electron donor which includes a substituted amide ester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution. | 12-20-2012 |
20120322964 | Halogenated Amide Ester and Internal Electron Donor with Same - Disclosed are halogenated amide esters that are suitable as internal electron donors in procatalyst compositions. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution. | 12-20-2012 |
20130035227 | Procatalyst Composition with Substituted 1,2-Phenylene Aromatic Diester Internal Donor and Method - Disclosed are procatalyst compositions having an internal electron donor which include a substituted phenylene aromatic diester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit high activity and produce propylene-based olefins with broad molecular weight distribution. | 02-07-2013 |
20130150234 | Catalyst Composition with Halo-Malonate Internal Electron Donor and Polymer From Same - Disclosed herein are procatalyst compositions, catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions contain a halo-malonate and a 2-fluoro-malonate in particular. The present catalyst compositions improve catalyst selectivity, improve catalyst activity, and also improve hydrogen response during polymerization. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 50 g/10 min. | 06-13-2013 |
20130225398 | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product - Disclosed herein are processes for preparing procatalyst compositions with an internal electron donor containing greater than 4.5 wt % of a compounded alkoxyalkyl ester. Also disclosed are catalyst compositions containing the procatalyst composition and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions improve catalyst selectivity, catalyst activity, procatalyst morphology and polymer particle morphology, and improve hydrogen response during olefin polymerization. | 08-29-2013 |
20130245306 | TWO ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE - A compound suitable for use as an internal electron donor having a structure: | 09-19-2013 |
20130261273 | Process for Production of High Melt Flow Propylene-Based Polymer and Product from Same - Disclosed are catalyst compositions having an internal electron donor which includes a 3,6-di-substituted-1,2-phenylene aromatic diester. Ziegler-Natta catalyst compositions containing the present catalyst compositions exhibit very high hydrogen response, high activity, high selectivity and produce propylene-based olefins with high melt flow rate. | 10-03-2013 |
20130289228 | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer from Same - Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions include an internal electron donor with an alkoxypropyl ester. The present catalyst compositions improve catalyst selectivity. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 4 g/10 min. | 10-31-2013 |
20140012035 | Production of Substituted Phenylene Aromatic Diesters - Synthesis pathways for a precursor to 5-tert-butyl-3-methyl-1, 2-phenylene dibenzoate are provided. The precursor is methylcatechol and/or 5-tert-butyl-3-methylcatechol. | 01-09-2014 |
20140046009 | Procatalyst Composition with Alkoxyalkyl 2-Propenoate Internal Electron Donor and Polymer from Same - Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions contain an internal electron donor of an alkoxyalkyl 2-propenoate and optionally a mixed external electron donor. The present catalyst compositions improve catalyst selectivity and polymer stiffness. Polypropylene homopolymer produced from the present catalyst composition has a xylene solubles content less than 4 wt % and a T | 02-13-2014 |
20140163184 | Procatalyst Composition with Substituted Amide Ester Internal Electron Donor - Disclosed are procatalyst compositions having an internal electron donor which includes a substituted amide ester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution. | 06-12-2014 |