| Patent application number | Description | Published |
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| 20080234147 | Method of Treating Subterranean Formation with Crosslinked Polymer Fluid - A method of treating a subterranean formation penetrated by a wellbore utilizes a treating fluid formed from an aqueous solution of a water-soluble polymer. The treating fluid further contains a crosslinking agent and an optional delayed release alkaline additive. The delayed release alkaline additive may be at least one of urea, a urea derivative, a solid alkaline earth metal carbonate, a solid alkaline earth metal oxide and combinations of these. The treating fluid further includes an acidic pH adjusting agent used in an amount to provide the treating fluid with a pH of less than about 5. The treating fluid is then introduced into the formation. | 09-25-2008 |
| 20080269081 | Internal Breakers for Viscoelastic Surfactant Fluids - Internal breakers are given that break fluids viscosified with non-polymeric viscosifiers such as viscoelastic surfactants, inside formation pores. The breakers are polyols, for example natural and synthetic sugars, monoalcohols, and mixtures of the two. The sugars may be ketones and aldehydes. The sugars are also breaker aides for oxidizing agents used as breakers. Methods of using the breakers and breaker aides in oilfield treatment fluids are given. | 10-30-2008 |
| 20080287323 | Treatment and Reuse of Oilfield Produced Water - The invention discloses treatment and reuse of oilfield produced water. A method of inhibiting enzymes/bacteria in an aqueous medium for viscosification comprises contacting the aqueous medium with a denaturant and/or a bactericide and thereafter mixing a gelling agent in the aqueous medium. The viscosified fluid can be used as a well treating fluid for fracturing and other applications. A well treatment fluid comprises a metal denaturant and/or a bactericide and a gelling agent in an amount effective to viscosify the fluid. Also disclosed is oilfield produced water denatured with from 1 to 2000 ppm by weight of a zirconium compound. | 11-20-2008 |
| 20080305971 | Polysaccharide Treatment Fluid and Method of Treating A Subterranean Formation - A treatment fluid for treating a subterranean formation penetrated by a wellbore is formed from an aqueous medium, a diutan heteropolysaccharide having a tetrasaccharide repeating unit in the polymer backbone and a peroxide breaker. A method of treating a subterranean formation penetrated by a wellbore may be carried out by introducing the treatment fluid into the formation through the wellbore. Breaking aids or catalysts may also be used with the treatment fluid. | 12-11-2008 |
| 20090023613 | Polysaccharide Treatment Fluid and Method of Treating a Subterranean Formation - A treatment fluid for treating a subterranean formation penetrated by a wellbore is formed from an aqueous medium, a diutan heteropolysaccharide having a tetrasaccharide repeating unit in the polymer backbone and a peroxide breaker. A method of treating a subterranean formation penetrated by a wellbore may be carried out by introducing the treatment fluid into the formation through the wellbore. Breaking aids or catalysts may also be used with the treatment fluid. | 01-22-2009 |
| 20090145607 | High Temperature Fracturing Fluids and Method of Use - A treatment fluid for treating a subterranean formation is formed from an aqueous solution of a polysaccharide, a polyacrylamide, a crosslinking agent, which may be a Group 4 transition metal crosslinking agent, and less than 0.1% by weight of any clay component. In certain embodiments, the polyacrylamide may have an average molecular weight of from greater than 0.5 million to about 20 million and may be present in the fluid in an amount of from about 0.01% to 1% by weight of the fluid. A method of treating a subterranean formation penetrated by a wellbore may be carried out by introducing the treatment fluid into the formation through the wellbore. In certain embodiments, the treatment fluid may be introduced into a portion of the formation having a temperature of 120° C. or higher. | 06-11-2009 |
| 20090281004 | Composition and Method for Fluid Recovery from Well - A well treatment microemulsion for use in a subterranean formation is disclosed, the microemulsion comprises a solvent blend comprising a solvent and a co-solvent; a surfactant blend comprising a surfactant, wherein the surfactant blend is able to give formation intermediate wettability properties; an alcohol; and a carrier fluid; wherein the alcohol, the solvent and surfactant blends are combined with the carrier fluid to produce the well treatment microemulsion. By intermediate wettability it is meant that the water has an advancing contact angle on the surface between 62 and 133 degrees. The associate method of treating a subterranean formation of a well with the microemulsion and the associate method of modifying the wettability of the formation with the microemulsion are also disclosed. | 11-12-2009 |
| 20090305914 | Phosphorus-Free Gelled Hydrocarbon Compositions and Method for Use Thereof - A method of forming a gelled organic-based fluid is disclosed. The method comprises combining an organic solvent, a viscoelastic surfactant, and a metal carboxylate crosslinker; and forming the gelled organic-based fluid. In a further aspect, the method is used to treat a subterranean formation of a well, for example for a stimulation job as fracturing or the like. | 12-10-2009 |
| 20090318313 | Slickwater Treatment Fluid and Method - A treatment fluid for treating a subterranean formation penetrated by a wellbore is formed from water, a polyacrylamide in an amount of less than about 0.5% by weight of the fluid for reducing friction of the fluid and a stabilized peroxide breaker. A method of treating a subterranean formation penetrated by a wellbore is carried out by forming treatment fluid comprising water, a polyacrylamide in an amount of less than about 0.5% by weight of the fluid for reducing friction of the fluid and a stabilized peroxide breaker. The treatment fluid is introduced into the formation through the wellbore at a pressure above the fracture pressure of the formation. | 12-24-2009 |
| 20100056402 | Acid Internal Breaker for Viscoelastic Surfactant Fluids in Brine - Compositions and methods are given for delayed breaking of viscoelastic surfactant gels inside formation pores, particularly for use in hydraulic fracturing. Breaking inside formation pores is accomplished without mechanical intervention or use of a second fluid. Acidic internal breakers such as sulfuric acid and nitric acid are used. The break may be accelerated, for example with a free radical propagating species, or retarded, for example with an oxygen scavenger. | 03-04-2010 |
| 20100093891 | Self-Viscosifying and Self-Breaking Gels - The invention provides a method. The method injects into a wellbore, a fluid comprising at least one of an acrylamide polymer and an acrylamide copolymer, and at least one of an oxidizing agent and a radical initiator; and allows viscosity of the fluid to increase for a first period of time; and subsequently, allows viscosity of the fluid to decrease for a second period of time. In a further aspect the invention provides a fluid for use in a well within a subterranean formation penetrated by a wellbore. The fluid is in a first embodiment, made of an acrylamide polymer and/or copolymer and an oxidizing agent or radical initiator, wherein concentration of the oxidizing agent or radical initiator is such that the fluid increases its viscosity for a period of time and after said period of time decreases its viscosity. The fluid is in a second embodiment, made of an acrylamide polymer and/or copolymer and an oxidizing agent or radical initiator, wherein the oxidizing agent or radical initiator is such that the fluid increases its viscosity for a period of time and after said period of time decreases its viscosity. | 04-15-2010 |
| 20100132944 | DIFFERENTIAL FILTERS FOR REMOVING WATER DURING OIL PRODUCTION - A method of removing a partial amount of water in a well, comprises deploying a differential filter downhole; and performing a downhole operation, wherein the differential filter comprises a swellable polymer that swells after contacting water such that permeability of the differential filter is reduced by removing said partial amount of water, the swellable polymer being non-soluble in the water and/or hydrocarbon and wherein the swellable polymer comprises at least one selected from the group consisting of polyacrylic acid, polyacrylate, polymethacrylic acid, poly maleic anhydride, polyacrylamide, polyvinyl alcohol, latex, polyamide, polyester, and a co-polymer thereof. | 06-03-2010 |
| 20100190666 | METHOD FOR TREATING FRACTURING WATER - A method of treating a medium for water fracturing is disclosed, the method comprises: introducing at least one biocide and at least one metabolic inhibitor in the medium, using the medium for water fracturing. In another aspect a method of controlling the post-fracture reservoir souring by the metabolic activities of sulfate reducing bacteria of a well is described: at least one biocide and at least one metabolic inhibitor are introduced in a medium made of water, the medium is used for fracturing the well, and the medium remains in the reservoir to kill and/or inhibit growth of sulfate reducing bacteria. | 07-29-2010 |
| 20100248997 | Treatment and Reuse of Oilfield Produced Water For Operations In A Well - The invention discloses method of treatment and reuse of oilfield produced water. The method comprises: providing an aqueous medium comprised at least in part of oilfield produced water; contacting the aqueous medium with a zirconium compound; whereby the fluid viscosity and/or fluid drag reduction ability of the combination of the aqueous medium and zirconium compound is improved compared to the aqueous medium alone; introducing the combination in to the well; and allowing the combination to contact the formation. In another embodiment, the aqueous medium is further contacted by a friction-reduction additive. Still in another embodiment, the aqueous medium is further contacted by a gelling additive. Still in another embodiment, the fluid is energized with a gas. | 09-30-2010 |
| 20100307757 | AQUEOUS SOLUTION FOR CONTROLLING BACTERIA IN THE WATER USED FOR FRACTURING - Methods and apparatus of embodiments of the invention relate to a system for treating a subterranean formation including mixing equipment to form a fluid comprising sodium hypochlorite and sodium diacetate; and pumps and a tubular to introduce the fluid into the subterranean formation, wherein a surface of the subterranean formation contains at least 15 percent less microorganisms than if no sodium hypochlorite were in the fluid. Methods and apparatus of embodiments of the invention relate to a method of producing a petroleum product from a wellbore including using a well treatment system comprising mixing equipment, pumps, and a tubular, forming a fluid comprising sodium hypochlorite and sodium diacetate; and introducing the fluid to the well treatment system to achieve a reduced population of microorganisms in the system. Methods and apparatus of embodiments of the invention relate to a system, comprising: a subterranean formation, a well treatment apparatus comprising mixing equipment, pumps, and a tubular, and a fluid comprising sodium hypochlorite and sodium diacetate to achieve a reduced population of microorganisms in the system. Methods and apparatus of embodiments of the invention relate to a method for treating a subterranean formation, comprising forming a fluid comprising sodium hypochlorite, a buffer, and a polymer; introducing the fluid to a surface of a subterranean formation; and decreasing a population of microorganisms, wherein the surface of the subterranean formation contains at least 15 percent less microorganisms than if no sodium hypochlorite were in the fluid, and wherein the fluid exhibits a pH of about 4.0 to about 7.5. Methods and apparatus of embodiments of the invention relate to a method for treating a subterranean formation, comprising forming a fluid comprising sodium hypochlorite and sodium diacetate; and introducing the fluid to a subterranean formation, wherein forming the fluid does not include introducing an acid, and wherein forming the fluid does not include forming a precipitate. | 12-09-2010 |
| 20100331223 | Acidic Viscosity Enhancer for Viscoelastic Surfactant Fluids - The invention discloses method of treating a subterranean formation of a well bore, the method comprising: providing a treatment fluid comprising: an aqueous base fluid; a viscosity enhancer; and a viscoelastic surfactant, wherein the enhancer is acid in the aqueous base fluid and co-operates with the viscoelastic surfactant to enhance viscosity compared to viscoelastic surfactant alone in the aqueous base fluid; and introducing the treatment fluid into the well bore. | 12-30-2010 |
| 20110017457 | ENVIRONMENTAL COMPOSITIONS AND METHODS FOR WELL TREATMENT - The invention provides a well treatment composition comprising: a viscoelastic surfactant or a cementing composition and an environmentally friendly component made of cellulosic matrix with organic acid trapped within. A method is disclosed comprising introducing into a wellbore penetrating a subterranean formation an environmentally friendly component made of cellulosic matrix with organic acid trapped within. | 01-27-2011 |
| 20110030953 | GELLED LIQUID HYDROCARBON TREATMENT FLUIDS AND THEIR ASSOCIATED METHODS OF USE - The invention provides a method of forming a gelled liquid hydrocarbon treatment fluid, comprising: combining a liquid hydrocarbon, a phosphoric acid ester and a pre-mixed solution comprising water, ferrous ion (Fe2+) and an amine; and forming the gelled liquid hydrocarbon treatment fluid. A method of treating a portion of a subterranean formation is also disclosed and comprises: providing a gelled liquid hydrocarbon treatment fluid, by combining a liquid hydrocarbon, a phosphoric acid ester and a pre-mixed solution comprising water, ferrous ion and an amine, and treating the portion of the subterranean formation with the gelled liquid hydrocarbon treatment fluid. | 02-10-2011 |
| 20110034352 | RHEOLOGY MODIFIER FOR POLYMER FLUIDS - Embodiments of this invention relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and a polymer, and exposing the fluid to a temperature of about 20° C. to about 200° C., wherein a viscosity is observed that is at least about 5 percent different than if no salt were present. Embodiments of this invention also relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and diutan and/or guar and/or guar derivatives and/or a combination thereof, and exposing the fluid to a temperature of about 20° C. to about 163° C., wherein a viscosity is observed that is at least about 5 percent lower than if no salt were present. Embodiments of this invention also relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and xanthan, and exposing the fluid to a temperature of about 20° C. to about 200° C., wherein a viscosity is observed that is at least about 5 percent higher than if no salt were present. | 02-10-2011 |
| 20110111989 | COMPOSITIONS AND METHODS TO STABILIZE ACID-IN-OIL EMULSIONS - A method and apparatus for treating a subterranean formation traversed by a wellbore including forming an emulsion comprising oil, acid, and particulate, wherein the forming the emulsion is prepared on the fly, and introducing the emulsion into a wellbore. | 05-12-2011 |
| 20110111991 | Gelled Hydrocarbon System and Method With Dual-Function Viscosifier/Breaker Additive - A gelled organic-based fluid system and method of forming and using the system. The fluid system is prepared by gelling an organic solvent, a viscoelastic surfactant, and a nitrogen compound having a free electron pair such as urea in an amount effective to both increase viscosity and increase a rate of breaking the viscosity, relative to the gelled system without the nitrogen compound. In a further aspect, the method is used to treat a well penetrating a subterranean formation, for example, in a coiled tubing cleanout, or the like. | 05-12-2011 |
| 20110166050 | TREATMENT AND REUSE OF OILFIELD PRODUCED WATER - The invention discloses treatment and reuse of oilfield produced water. A method of inhibiting enzymes/bacteria in an aqueous medium for viscosification comprises contacting the aqueous medium with a denaturant and/or a bactericide and thereafter mixing a gelling agent in the aqueous medium. The viscosified fluid can be used as a well treating fluid for fracturing and other applications. A well treatment fluid comprises a metal denaturant and/or a bactericide and a gelling agent in an amount effective to viscosify the fluid. Also disclosed is oilfield produced water denatured with from 1 to 2000 ppm by weight of a zirconium compound. | 07-07-2011 |
| 20110237470 | METHOD TO DECREASE VISCOSITY OF GELLED OIL - A method of decreasing the viscosity of a gelled organic-based fluid is disclosed. The method comprises combining an organic solvent, a gelling agent, and a metal crosslinker; forming the gelled organic-based fluid; and adding a chelating agent forming a complex with the metal to decrease the viscosity of the gelled organic-based fluid. The chelating agent may be chosen within nitrilotriacetic acid (NTA), citric acid; ascorbic acid, hydroxyethylethylenediaminetriacetic acid (HEDTA) or its salts, ethylenediaminetetraacetic acid (EDTA) or its salts, diethylenetriaminepentaacetic acid (DTPA) or its salts, phosphinopolyacrylate, thioglycolates, or a combination thereof. | 09-29-2011 |
| 20110315383 | GELATION ACCELERATION - The invention provides a method made of steps of injecting into a wellbore, a composition comprising a solvent, a crosslinkable polymer, a crosslinking agent capable of crosslinking the polymer or forming a polymer, and a gelling accelerator selected from the group consisting of carbon dioxide, polylactic acid, encapsulated acid and latent acid; and allowing viscosity of the composition to increase and form a gel more quickly with the gelling accelerator than without. | 12-29-2011 |
| 20110315384 | GELLED FOAM COMPOSITIONS AND METHODS - The invention provides a method made of steps of injecting into a wellbore, a composition comprising a solvent, a surfactant, a foaming gas, a foam enhancer, a crosslinkable polymer, and a crosslinking agent capable of crosslinking the polymer, wherein the foam enhancer increases the foam half-life of the gel composition compared to the gel composition without the foam enhancer; and allowing viscosity of the composition to increase and form a gel. | 12-29-2011 |
| 20110315385 | CALCIUM CARBONATE TO INCREASE VISCOSITY OF POLYACRYLAMIDE FLUIDS - Compositions and methods of treating a subterranean formation including forming a fluid comprising polyacrylamide and calcium carbonate and introducing the fluid to the formation, wherein the viscosity of the fluid is higher than if no calcium carbonate is present. Compositions and methods of treating a subterranean formation penetrated by a well bore including forming a fluid comprising polyacrylamide, calcium carbonate, and crosslinker, and introducing the fluid to the formation, wherein the fluid viscosity at 100 s-1 is increased from 300 cP to 600 cP at a temperature of 93 degC. Compositions and methods of treating a subterranean formation penetrated by a well bore including forming a fluid comprising polyacrylamide and barium carbonate and introducing the fluid to the formation, wherein the viscosity of the fluid is higher than if no barium carbonate is present. | 12-29-2011 |
| 20110319302 | METHOD OF TREATING A WELLBORE AT HIGH TEMPERATURE IN CONTACT WITH CARBON DIOXIDE - A method for treating a subterranean formation is made of steps of providing a composition comprising a carrier fluid, a polymer viscosifying agent, carbon dioxide and a formate salt or formic acid; injecting into a wellbore, the composition; contacting the composition with the subterranean formation, wherein the temperature is above 100 degrees Celsius at this contact; and allowing the composition to treat the subterranean formation. | 12-29-2011 |
| 20120111567 | FORMATE SALTS FOR INCREASED STABILITY OF POLYACRYLAMIDE FLUIDS - Methods and apparatus for using a fluid within a subterranean formation, including forming a fluid comprising an acrylamide copolymer and a formate salt, and introducing the fluid to the subterranean formation, wherein a temperature of the formation is about 149° C. or warmer. Also, methods and apparatus for a fluid for use within a subterranean formation, including an acrylamide copolymer comprising polyacrylamide, a formate salt comprising potassium, and a crosslinker comprising zirconium. Additionally, methods and apparatus for using a fluid within in a subterranean formation, including forming a fluid comprising an acrylamide copolymer and a formate salt, and introducing proppant into the fluid to form a mixture, introducing the mixture to the subterranean formation, wherein a temperature of the formation is about 149° C. or warmer. | 05-10-2012 |
| 20120157354 | FRICTION REDUCER - Disclosed herein is a composition comprising from about 0.1 wt % to about 50 wt % of a plant based product comprising mucilage. Methods of making the composition, a well treatment fluid comprising the composition, and methods of using the composition are also disclosed. | 06-21-2012 |
| 20120247774 | SLOW RELEASE BREAKER TREATMENT FLUIDS AND THEIR ASSOCIATED METHODS OF USE - A method of treating a portion of a subterranean formation comprises providing a treatment fluid comprising a carrier fluid, a viscosifying agent, a breaker, and a breaker aid wherein the breaker aid slowly releases a catalyst, wherein the viscosifying agent and the breaker in the carrier fluid have an initial viscosity and the catalyst and the breaker cooperate to decrease the viscosity of the treatment fluid below half of the initial viscosity after at least 30 minutes; and treating the subterranean formation. | 10-04-2012 |
| 20120252707 | METHODS AND COMPOSITIONS TO DELAY VISCOSIFICATION OF TREATMENT FLUIDS - The current application discloses a method of treating a portion of a subterranean formation comprises providing a treatment fluid comprising a carrier fluid, a non-hydrolyzed polyacrylamide or a nonhydrolyzed non ionic copolymer of acrylamide, and a delaying agent; and treating the subterranean formation. | 10-04-2012 |
| 20130000916 | RECYCLABLE CLEANOUT FLUIDS - A method for treating a wellbore or a subterranean formation penetrated by a wellbore includes preparing a gelled oil at the surface, introducing the gelled oil into the wellbore, recovering the gelled oil at the surface, adding a base to the gelled oil to reduce the viscosity, allowing entrained solids to settle out, adding an acid to increase the viscosity, and re-injecting the gelled oil. | 01-03-2013 |
| 20130045899 | Compositions And Methods To Stabilize Acid-In-Oil Emulsions - A method and apparatus for treating a subterranean formation traversed by a wellbore including forming an emulsion comprising oil, acid, and particulate, wherein the forming the emulsion is prepared on the fly, and introducing the emulsion into a wellbore. | 02-21-2013 |
| 20130118748 | Gelled Foam Compositions And Methods - The invention provides a method made of steps of injecting into a wellbore, a composition comprising a solvent, a surfactant, a foaming gas, a foam enhancer, a crosslinkable polymer, and a crosslinking agent capable of crosslinking the polymer, wherein the foam enhancer increases the foam half-life of the gel composition compared to the gel composition without the foam enhancer; and allowing viscosity of the composition to increase and form a gel. | 05-16-2013 |
| 20140090848 | COMPOSITIONS AND METHODS FOR TREATING A WELL PENETRATING A SUBTERRANEAN FORMATION - A method for treating a well penetrating subterranean formations comprising injecting into the well a composition comprising a high temperature stabilizer composition which comprises at least one mineral-reactive compound; wherein at least a part of the well is at a temperature of at least 120° C. is provided. Also provided is a composition for treating a well comprising a mineral-reactive compound. | 04-03-2014 |
| 20140196897 | OXIDATIVE INTERNAL BREAKER SYSTEM WITH BREAKING ACTIVATORS FOR VISCOELASTIC SURFACTANT FLUIDS - Compositions and methods are given for delayed breaking of viscoelastic surfactant gels inside formation pores, particularly for use in hydraulic fracturing. Breaking inside formation pores is accomplished without mechanical intervention or use of a second fluid. Bromate oxidizing agents are used along with selected breaking activators for the bromate breaking compounds. Useful bromate breaking activators include acid-generating breaking activators, oxidizing sulfur containing breaking activators, and reducing agent breaking activators. | 07-17-2014 |
| 20140262276 | VISCOSITY ENHANCEMENT OF POLYSACCHARIDE FLUIDS - A method of treating a subterranean formation includes providing a treatment composition comprising at least one hydroxyl carboxylic acid, a crosslinkable component and a crosslinking agent. The treatment composition is then introduced to the subterranean formation, such that the combination of the hydroxyl carboxylic acid, a crosslinkable component and a crosslinking agent in the treatment composition increases the viscosity of the well treatment composition. | 09-18-2014 |
| 20140332214 | HYDRAULIC FRACTURING COMPOSITION, METHOD FOR MAKING AND USE OF SAME - A hydraulic fracturing composition includes: a superabsorbent polymer in an expanded state; a plurality of proppant particles disposed in the superabsorbent polymer; an additive comprising a surfactant, a viscose polymer, or a combination thereof, and a fluid to expand the superabsorbent polymer into the expanded state. A process for disposing a plurality of proppant particles in a fracture comprises: disposing a hydraulic fracturing composition in a downhole environment; forming a fracture; disposing the hydraulic fracturing composition in the fracture; breaking the superabsorbent polymer after forming the fracture; and releasing the plurality of proppant particles from superabsorbent polymer. The process also comprises injecting a proppant-free fluid and a proppant-containing fluid in an alternating order into a subterranean formation. | 11-13-2014 |
