Patent application number | Description | Published |
20080200726 | Method For the Continuous Production of an Amine - Processes comprising: providing an aromatic alcohol; and reacting the aromatic alcohol with ammonia at a temperature of 80 to 350° C. in the presence of hydrogen and a heterogeneous catalyst to form a crude reaction product comprising a corresponding primary aromatic amine, wherein the heterogeneous catalyst comprises a catalytically active composition which, prior to reduction with hydrogen, comprises 90 to 99.8% by weight of zirconium dioxide (ZrO | 08-21-2008 |
20080200727 | Method for Producing an Amine - Processes for preparing amines comprising reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound in the presence of a heterogeneous catalyst, wherein the heterogeneous catalyst comprises a catalyst packing prepared by applying at least one compound selected from the group consisting of catalytically active metals, compounds of catalytically active metals, and mixtures thereof to a support material selected from the group consisting of woven fabrics, knitted fabrics, foils, and combinations thereof. | 08-21-2008 |
20080214871 | Method For Producing A Xylylene Diamine - A process for preparing a xylylenediamine by heterogeneously catalyzed hydrogenation of a phthalonitrile, wherein the hydrogenation is carried out in the presence of a cobalt skeletal catalyst, of an alkali metal hydroxide and of an alcohol and/or ether as the solvent, at an absolute pressure in the range from 1 to 100 bar and a temperature in the range from 40 to 150° C. | 09-04-2008 |
20080236390 | Absorbtion Medium and Method for Removing Carbon Dioxide From Gas Streams - A description is given of an absorption medium for removing carbon dioxide from gas streams which comprises aqueous solution of an amine of the formula I | 10-02-2008 |
20080249307 | Method for Producing Ethylene Amines - Processes are described comprising: (i) providing a reactant comprising 1,2-dichloroethane; and (ii) reacting the reactant with ammonia to form a reaction product comprising one or more ethylene amines and hydrogen chloride, wherein the reaction is carried out in the presence of an organic, nitrogen- or phosphorus-containing compound which reacts with the hydrogen chloride to form an ionic liquid. | 10-09-2008 |
20080249333 | Method for the Production of Beta-Aminopropionic Acid Derivatives - The invention relates to a process for preparing β-aminopropionic acid derivatives by reacting a primary or secondary amine with an acrylic acid derivative, wherein comprises
| 10-09-2008 |
20080255351 | Method for Preparing Aminodiglycol (Adg) and Morpholine - Processes comprising: providing a starting material comprising diethylene glycol; and reacting the starting material with ammonia in the presence of a heterogeneous transition metal catalyst to form a reaction product comprising aminodiglycol and morpholine; wherein the catalyst comprises a catalytically active composition, which prior to treatment with hydrogen, comprises a mixture of oxygen-containing compounds of copper, nickel, cobalt and at least one of aluminum and zirconium; and wherein the catalyst is present as one or more shaped catalyst particles selected from spheres, extrudates, pellets and other geometries, wherein the sphere or extradate has a diameter of <3 mm, the pellet has a height of <3 mm, and the other geometries have an equivalent diameter L=1/a′ of <0.70 mm, where a′ is the external surface area per unit volume (mm | 10-16-2008 |
20080255360 | Process for Producing Ethyleneamines - Processes comprising: providing a starting material comprising monoethanolamine; and reacting the starting material with ammonia in the presence of a heterogeneous transition metal catalyst to form a reaction product comprising one or more ethylene amines; wherein the catalyst comprises a catalytically active composition, which prior to treatment with hydrogen, comprises a mixture of oxygen-containing compounds of aluminum, copper, nickel and cobalt; and wherein the catalyst is present as one or more shaped catalyst particles selected from spheres, extrudates, pellets and other geometries, wherein the sphere or extrudate has a diameter of <3 mm, the pellet has a height of <3 mm, and the other geometries have an equivalent diameter L=1/a′ of <0.70 mm, where a′ is the external surface area per unit volume (mm | 10-16-2008 |
20080262266 | Method for the Production of Xylyendiamine - Process for preparing o-, m- or p-xylylenediamine by hydrogenation of o-, m- or p-phthalonitrile in the presence of a heterogenous catalyst, which comprises feeding a solution of the phthalonitrile in the corresponding isomer of crude xylylenediamine into the hydrogenation reactor, with the crude xylylenediamine having a purity in the range from 85 to 99.7% by weight and a content of higher boilers in the range from 0.3 to 15% by weight. | 10-23-2008 |
20080293973 | Process for the Synthesis of Dmapa - The present invention relates to a process for the industrial preparation of a diamine starting from a corresponding alkenyl nitrile comprising at least one C-C double bond, which comprises the steps
| 11-27-2008 |
20080306305 | Process for Hydrogenating Nitriles to Primary Amines or Aminonitriles and Catalysts Suitable Therefor - A process for hydrogenating oligonitriles which have at least two nitrile groups in the presence of a catalyst which, before commencement of the hydrogenation, is pretreated by contacting with a compound A which is selected from alkali metal carbonates, alkaline earth metal carbonates, ammonium carbonate, alkali metal hydrogencarbonates, alkaline earth metal hydrogencarbonates, ammonium hydrogencarbonate, alkaline earth metal oxocarbonates, alkali metal carboxylates, alkaline earth metal carboxylates, ammonium carboxylates, alkali metal dihydrogen phosphates, alkaline earth metal dihydrogen phosphates, alkali metal hydrogen phosphates, alkaline earth metal hydrogen phosphates, alkali metal phosphates, alkaline earth metal phosphates and ammonium phosphate, alkali metal acetates, alkaline earth metal acetates, ammonium acetate, alkali metal formates, alkaline earth metal formates, ammonium formate, alkali metal oxalates, alkaline earth metal oxalates and ammonium oxalate. | 12-11-2008 |
20090065346 | PROCESS FOR THE DISTILLATIVE SEPARATION OF MIXTURES COMPRISING MONOETHYLENE GLYCOL AND DIETHYLENTRIAMINE - Processes comprising: providing a mixture comprising monoethylene glycol and diethylenetriamine; and subjecting the mixture to extractive distillation with a diethylenetriamine-selective solvent comprising triethylene glycol to provide a first stream comprising monoethylene glycol and a second stream comprising diethylenetriamine; wherein the first stream is substantially free of diethylenetriamine, and wherein the second stream is substantially free of monoethylene glycol. | 03-12-2009 |
20090069590 | PROCESS FOR PREPARING AMINOALKYLNITRILES AND DIAMINES FROM SUCH NITRILES - The present invention relates to a process for preparing an aminoalkyl nitrile by reaction of a corresponding monoamine with a corresponding alkenyl nitrile in a continuous mode of operation, which comprises the steps
| 03-12-2009 |
20090069603 | PROCESS FOR HYDROGENATING NITRILES TO PRIMARY AMINES OR AMINONITRILES AND CATALYSTS SUITABLE THEREFOR - The invention relates to a process for hydrogenating oligonitriles which have at least two nitrile groups in the presence of a catalyst which, before commencement of the hydrogenation, is pretreated by contacting with a compound A which is selected from alkali metal carbonates, alkaline earth metal carbonates, ammonium carbonate, alkali metal hydrogencarbonates, alkaline earth metal hydrogencarbonates, ammonium hydrogencarbonate, alkaline earth metal oxocarbonates, alkali metal carboxylates, alkaline earth metal carboxylates, ammonium carboxylates, alkali metal dihydrogenphosphates, alkaline earth metal dihydrogenphosphates, alkali metal hydrogenphosphates, alkaline earth metal hydrogenphosphates, alkali metal phosphates, alkaline earth metal phosphates and ammonium phosphate, alkali metal acetates, alkaline earth metal acetates, ammonium acetate, alkali metal formiates, alkaline earth metal formiates, ammonium formiate, alkali metal oxalates, alkaline earth metal oxalates and ammonium oxalate. | 03-12-2009 |
20090076306 | PROCESS FOR CONTINUOUS PREPARATION OF A PRIMARY AROMATIC AMINE - A process for continuously preparing a primary aromatic amine by reacting a corresponding cycloaliphatic alcohol with ammonia in the presence of hydrogen at a temperature in the range from 80 to 350° C. in the presence of a heterogeneous catalyst, wherein the catalytically active composition of the catalyst, before its reduction with hydrogen, comprises
| 03-19-2009 |
20090093654 | METHOD OF PRODUCING BENZOPHENONEIMINES - A process for the preparation of benzophenonimine (BPI) of the general formula I | 04-09-2009 |
20090234163 | Method for producing an ethylamine - Processes comprising: (a) providing a first reactant comprising a bioethanol; and (b) reacting the first reactant with a second reactant comprising a component selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of hydrogen and a catalytically effective amount of a heterogeneous hydrogenation/dehydrogenation catalyst to form an ethylamine; wherein the catalyst has been activated at a temperature of 100 to 500° C. for at least 25 minutes; wherein prior to activation the catalyst comprises: (i) 20 to 65% by weight of a support material comprising one or both of zirconium dioxide (ZrO | 09-17-2009 |
20090240084 | METHOD FOR PRODUCING ETHYLENE AMINES ETHANOL AMINES FROM MONOETHYLENE GLYCOL (MEG) - A process for preparing ethylene amines and ethanolamines by hydrogenative amination of monoethylene glycol and ammonia in the presence of a catalyst, wherein the process is carried out in two process stages in which | 09-24-2009 |
20090264652 | METHOD FOR PRODUCING AN AMINE - Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, nickel and cobalt, and one or more oxygen compounds of silver in an amount of 0.5 to 6% by weight, calculated as AgO. | 10-22-2009 |
20090275781 | METHOD FOR PRODUCING AN AMINE - Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof, and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, nickel and cobalt, and one or more oxygen compounds of molybdenum in an amount of 5.5 to 12% by weight, calculated as MoO | 11-05-2009 |
20090286977 | METHOD FOR PRODUCING AN AMINE - Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, nickel and cobalt, and one or more oxygen compounds of one or more metals selected from the group consisting of Pb, Bi, Sn, Sb and In. | 11-19-2009 |
20090312579 | METHOD FOR PRODUCING AN AMINE - Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof, and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, and nickel, and one or more oxygen compounds of silver in an amount of 0.5 to 6% by weight, calculated as AgO. | 12-17-2009 |
20100010264 | METHOD FOR PRODUCING AN AMINE - Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, and nickel, and one or more oxygen compounds of one or more metals selected from the group consisting of Sb, Pb, Bi, and In. | 01-14-2010 |
20100029976 | METHOD FOR PRODUCING TETRAETHYLENEPENTAMINE - The invention relates to a process for preparing tetraethylenepentamine (TEPA) by hydrogenation of diethylenetriaminediacetonitrile (DETDN) over a catalyst. If appropriate, DETDN can also be present as a constituent of an amino nitrile mixture which additionally comprises diethylenetriaminemonoacetonitrile (DETMN). | 02-04-2010 |
20100029991 | METHOD FOR PRODUCING TRIETHYLENETETRAMINE - The invention relates to a process for preparing triethylenetetramine (TETA), which comprises hydrogenating ethylenediaminediacetonitrile (EDDN) in the presence of a catalyst and a solvent. | 02-04-2010 |
20100036168 | CONTINUOUS PROCESS FOR THE HYDROGENATION OF 3-CYANO-3,5,5-TRIMETHYL-CYCLOHEXYLIMINE - The present invention relates to a continuous process for preparing 3-aminomethyl-3,5,5-trimethylcyclohexylamine by reacting a feed stream comprising 3-cyano-3,5,5-trimethylcyclohexylimine with hydrogen and ammonia over hydrogenation catalysts, wherein the basicity of the reaction mixture is increased during the reaction by bringing the reaction mixture into contact with a basic compound which is not ammonia and/or a basic catalyst after part of the 3-cyano-3,5,5-trimethylcyclohexylimine has been reacted. | 02-11-2010 |
20100056828 | METHOD FOR PRODUCING ETHYLENEAMINES - The invention relates to a process for preparing an ethylene amine mixture, which comprises hydrogenating an amino nitrile mixture comprising at least 30% by weight of aminoacetonitrile (AAN) and at least 5% by weight of iminodiacetonitrile (IDAN) in the presence of a catalyst. Ethylenediamine (EDA) and/or diethylenetriamine (DETA) and, if appropriate, further ethylene amines can be isolated from the ethylene amine mixtures obtained. | 03-04-2010 |
20100099872 | PRODUCTION METHOD FOR ETHYLENEAMINE MIXTURES - The invention relates to a process for preparing an ethylene amine mixture, which comprises hydrogenating an amino nitrile mixture comprising at least two α-amino nitriles in an amount of at least 5% by weight in each case in the presence of a catalyst and, if appropriate, a solvent. | 04-22-2010 |
20100105952 | PROCESS FOR THE SYNTHESIS OF DMAPA - The present invention relates to a process for the industrial preparation of a diamine starting from a corresponding alkenyl nitrile comprising at least one C—C double bond, which comprises the steps
| 04-29-2010 |
20100121064 | NOVEL METHOD FOR PRODUCING TETA BY MEANS OF EDDN - The invention relates to a process for preparing triethylenetetramine (TETA), which, comprises the following steps:
| 05-13-2010 |
20100191000 | METHOD FOR SYNTHESIZING AN N-UNSUBSTITUTED OR N-SUBSTITUTED AZIRIDINE - Process for preparing an N-unsubstituted or N-substituted aziridine of the formula | 07-29-2010 |
20100204438 | METHOD FOR PRODUCING TEDA DERIVATIVES - The present invention relates to a process for preparing triethylenediamine (TEDA) derivatives, comprising the following steps:
| 08-12-2010 |
20100240894 | METHOD FOR PRODUCING AMINES FROM GLYCERIN - The present invention relates to a process for preparing amines by reacting glycerol with hydrogen and an aminating agent from the group of ammonia and primary and secondary amines in the presence of a catalyst at a temperature of from 100° C. to 400° C. and a pressure of from 0.01 to 40 MPa (from 0.1 to 400 bar). Preference is given to using glycerol based on renewable raw materials. The catalyst preferably comprises one metal or a plurality of metals or one or more oxygen compounds of the metals of groups 8 and/or 9 and/or 10 and/or 11 of the Periodic Table of the Elements. The invention further relates to the use of the reaction products as an additive in cement or concrete production and in other fields of use. This invention further provides the compounds 1,2,3-triaminopropane, 2-aminomethyl-6-methylpiperazine, 2,5-bis(aminomethyl)piperazine and 2,6-bis(aminomethyl)piperazine. | 09-23-2010 |
20100267948 | PROCESS FOR THE PREPARATION OF AN AMINE - Process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of primary and secondary amines in the presence of a heterogeneous catalyst, wherein the reaction is carried out using a suspended catalyst as heterogeneous catalyst and is carried out in the semibatch mode in which the nitrogen compound as one reactant is placed in the reaction vessel and the aldehyde and/or the ketone as the other reactant is added during the course of the reaction and the aldehyde and/or the ketone is added in portions or continuously to the reaction mixture during the course of the reaction as a function of the achieved conversion of the nitrogen compound until a conversion of the nitrogen compound of at least 95% results, and all or part of the catalyst remains in the reaction vessel after the reaction batch and is reused for the next reaction batch. | 10-21-2010 |
20100274009 | METHOD FOR PRODUCING AN AMINE - Processes for preparing an amine, the processes comprising: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, nickel, no oxygen compounds of cobalt, and 0.2 to 5.0% by weight of at least one oxygen compound of phosphorus or gallium, calculated as H | 10-28-2010 |
20100274010 | METHOD FOR PRODUCING AN AMINE - Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, and nickel, and 0.2 to 40% by weight of an oxygen compound of cobalt, calculated as CoO, 0.1 to 5% by weight of an oxygen compound of iron, calculated as Fe | 10-28-2010 |
20100274055 | METHOD FOR PRODUCING AN AMINE - Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, nickel, and iron, and 0.2 to 5.5% by weight of at least one oxygen compound of tin, lead, bismuth, molybdenum, antimony or phosphorus, calculated as SnO, PbO, Bi | 10-28-2010 |
20110009627 | REACTOR FOR CARRYING OUT HIGH PRESSURE REACTIONS, METHOD FOR STARTING AND METHOD FOR CARRYING OUT A REACTION - The invention relates to a reactor for performing high-pressure reactions, comprising at least one tube ( | 01-13-2011 |
20110033361 | METHOD FOR REMOVING HALOGEN FROM LIQUID AMMONIA - The present invention relates to a method for depleting halide ions from liquid ammonia, wherein the liquid ammonia is brought into contact with a strongly basic ion exchanger, where the basic structure of the strongly basic ion exchanger is a covalently crosslinked polymer matrix. Furthermore, the present invention relates to the use of an ammonia obtainable according to the invention as starting material in the production of amines. | 02-10-2011 |
20110054167 | METHOD FOR PRODUCING AN AMINE - Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, nickel and tin, and 0.5 to 8.0% by weight of an oxygen compound of cobalt, calculated as CoO, and wherein the catalytically active composition does not comprise any ruthenium. | 03-03-2011 |
20110137030 | CATALYST AND PROCESS FOR PREPARING AN AMINE - A process for preparing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of ammonia and primary and secondary amines, in the presence of a supported copper-, nickel- and cobalt-containing catalyst, wherein the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises oxygen compounds of aluminum, of copper, of nickel and of cobalt, and in the range from 0.2 to 5.0% by weight of oxygen compounds of tin, calculated as SnO, and catalysts as defined above. | 06-09-2011 |
20110184210 | CONTINUOUS METHODS AND REACATOR USED FOR THE PRODUCTION OF ALKYLAMINES - In the continuous process for preparing alkylamines by reacting C | 07-28-2011 |
20110218323 | PROCESS FOR PREPARING CYCLIC DIAMINES - The present invention relates to a process for preparing a cyclic diamine, comprising the reaction of at least one cyclic alkene with a gas mixture (G) comprising dinitrogen the subsequent conversion of monoxide to give at least one cyclic ketone and then converting the at least one cyclic ketone to a cyclic diamine. The invention also relates to the use of a cyclic diamine with primary and secondary amine functions thus obtained to prepare polyamides and polyurethanes. | 09-08-2011 |
20110257437 | PROCESS FOR PREPARING PURE TRIETHANOLAMINE (TEOA) - A process for preparing pure triethanolamine (TEOA) by continuously distillatively separating an ethanolamine mixture comprising TEOA and diethanolamine (DEOA), by distilling off DEOA in a distillation column (DEOA column) and supplying the resulting bottom stream comprising TEOA to a downstream column (TEOA column) in which the pure TEOA is withdrawn as a side draw stream, wherein the residence time of the ethanolamine mixture in the bottom of the DEOA column is <20 minutes. | 10-20-2011 |
20110288337 | PROCESS FOR PREPARING 2-(2-TERT-BUTYLAMINOETHOXY)ETHANOL (TERT-BUTYLAMINODIGLYCOL, TBADG) - A process for preparing 2-(2-tert-butylaminoethoxy)ethanol (tert-butylaminodiglycol, TBADG) by reacting diethylene glycol (DG) with tert-butylamine (TBA) in the presence of hydrogen and of a copper catalyst, by effecting the reaction at a temperature in the range from 160 to 220° C. in the presence of a copper- and aluminum oxide-containing catalyst, where the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises
| 11-24-2011 |
20110288338 | METHOD FOR PRODUCING N,N-SUBSTITUTED-3-AMINOPROPAN-1-OLS - The present invention relates to a process for preparing N,N-substituted 3-aminopropan-1-ols by
| 11-24-2011 |
20110313186 | HYDROGENATION CATALYSTS, THE PRODUCTION AND THE USE THEREOF - The present invention relates to catalysts and processes for preparation thereof, said catalysts being obtainable by contacting a monolithic catalyst support with a suspension which comprises one or more insoluble or sparingly soluble compounds of the elements selected from the group of the elements cobalt, nickel and copper. The invention further relates to the use of the inventive catalyst in a process for hydrogenating organic substances, especially for hydrogenating nitriles, and to a process for hydrogenating organic compounds, which comprises using an inventive catalyst in the process. | 12-22-2011 |
20110313187 | METHOD FOR IMPROVING THE CATALYTIC ACTIVITY OF MONOLITHIC CATALYSTS - The present invention relates to a process for improving the catalytic properties of a catalyst comprising one or more elements selected from the group consisting of cobalt, nickel and copper, said catalyst being present in the form of a structured monolith, by contacting the catalyst with one or more basic compounds selected from the group of the alkali metals, alkaline earth metals and rare earth metals. The invention further relates to a process for hydrogenating compounds which comprise at least one unsaturated carbon-carbon, carbon-nitrogen or carbon-oxygen bond in the presence of a catalyst comprising one or more elements selected from the group consisting of cobalt, nickel and copper, said catalyst being present in the form of a structured monolith, by contacting the catalyst with one or more basic compounds selected from the group of the alkali metals, alkaline earth metals and rare earth metals. The present invention also relates to the use of a basic compound selected from the group of the alkali metals, alkaline earth metals and rare earth metals for improving the catalytic properties of a catalyst comprising cobalt and/or copper and/or nickel, said catalyst being present in the form of a structured monolith. | 12-22-2011 |
20110313188 | METHOD FOR IMPROVING THE CATALYTIC ACTIVITY OF MONOLITHIC CATALYSTS - The present invention relates to a catalyst comprising one or more elements selected from the group consisting of cobalt, nickel and copper, said catalyst being present in the form of a structured monolith, wherein said catalyst comprises one or more elements selected from the group of the alkali metals, alkaline earth metals and rare earth metals. The invention further relates to processes for preparing the inventive catalyst and to the use of the inventive catalyst in a process for hydrogenating organic substances, especially for hydrogenating nitriles. | 12-22-2011 |
20120004464 | PROCESS FOR PREPARING TRI-N-PROPYLAMINE (TPA) - Process for preparing tri-n-propylamine (TPA), wherein di-n-propylamine (DPA) is reacted in the presence of hydrogen and a copper-comprising heterogeneous catalyst. | 01-05-2012 |
20120029225 | DMAPN Having a Low DGN Content and a Process for Preparing DMAPA from DMAPN Having a Low DGN Content - The present invention relates to a process for preparing 3-dimethylaminopropylamine (DMAPA) by reacting 3-dimethylaminopropionitrile (DMAPN) with hydrogen in the presence of a catalyst, wherein the DMAPN used has a content of 2-(dimethylaminomethyl)glutaronitrile (DGN) of 300 ppm by weight or less, based on the DMAPN used. | 02-02-2012 |
20120035049 | PROCESSES FOR PREPARING AMINES AND ZIRCONIUM DIOXIDE- AND NICKELCONTAINING CATALYSTS FOR USE THEREIN - A catalytically active composition comprising, prior to reduction with hydrogen: 10 to 75% by weight of an oxygen compound of zirconium, calculated as ZrO | 02-09-2012 |
20120070353 | Process For Separating Off Acidic Gases By Means Of Metal-Organic Frameworks Impregnated With Amines - The present invention relates to a process for separating off at least one acidic gas from a gas mixture comprising at least one acidic gas, which comprises the step of contacting of the gas mixture with a porous metal-organic framework, where the framework adsorbs the at least one acidic gas and the framework comprises at least one at least bidentate organic compound coordinated to at least one metal ion, wherein the porous metal-organic framework is impregnated with an amine suitable for a gas scrub. The invention further provides such impregnated metal-organic frameworks. | 03-22-2012 |
20120071692 | PROCESS FOR THE PREPARATION OF AROMATIC AMINES - A process for preparing an aromatic amine by reacting a corresponding aromatic alcohol with an aminating agent selected from the group consisting of ammonia, primary amines and secondary amines, in the presence of hydrogen and a catalyst molding, at a temperature of from 60-300°. The catalyst molding comprises Zr, Pd and Pt and has an annular tablet form with an external diameter in the range from 2-6 mm, a height in the range from 1-4 mm and an internal diameter of from 1-5 mm or a topologically equivalent form with the same volume. Catalyst moldings comprising Zr, Pd and Pt are also provided. The catalyst molding has an annular tablet form with an external diameter in the range from 3-6 mm, a height in the range from 1-4 mm and an internal diameter of from 2-5 mm or a topologically equivalent form. | 03-22-2012 |
20120071694 | PROCESS FOR PREPARING AMINOALKYLNITRILES AND DIAMINES FROM SUCH NITRILES - A process for preparing a diamine from a corresponding aminoalkyl nitrile, which is prepared by reaction of a corresponding monoamine with a corresponding alkenyl nitrile in a continuous mode of operation, comprising the steps: a) introduction of the corresponding monoamine into a continuously conveyed reaction stream; b) introduction of the corresponding alkenyl nitrile into the reaction stream, with this already comprising the aminoalkyl nitrile on addition; c) reaction of the reaction stream in a first reaction region; d) at least partial transfer of the reaction stream into at least one second reaction region for further reaction; e) discharge of the reaction stream from the second reaction region after the reaction; f) introduction of the reaction stream discharged in step (a) into a reduction region; and g) reduction of the aminoalkyl nitrile present in the reaction stream to the corresponding diamine. | 03-22-2012 |
20120095221 | PROCESS FOR PREPARING A CYCLIC TERTIARY AMINE - A process for preparing a cyclic tertiary amine of the formula I | 04-19-2012 |
20120101303 | METHYL-SUBSTITUTED TETA COMPOUNDS - The invention relates to a process for preparing triethylenetetramine substituted by at least one methyl group (Me-TETA or methyl-substituted TETA compounds). Me-TETA is prepared by hydrogenating biscyanomethylimidazolidine (BCMI) in the presence of a catalyst. The present invention further relates to methyl-substituted TETA compounds as such. The present invention further relates to the use of methyl-substituted TETA compounds as a reactant or intermediate in the production of, for example, coatings or adhesives. | 04-26-2012 |
20120108816 | PROCESS FOR PREPARING 1,4-BISHYDROXYETHYLPIPERAZINE - Process for preparing 1,4-bishydroxyethylpiperazine (BHEPIP) of the formula I | 05-03-2012 |
20120157679 | PROCESS FOR PREPARING A CYCLIC TERTIARY METHYLAMINE - Process for preparing a cyclic tertiary methylamine of the formula I | 06-21-2012 |
20120157715 | PROCESS FOR PREPARING AN N,N-DIALKY-ETHANOLAMINE HAVING HIGH COLOR STABILITY - A process for preparing an N,N-dialkylethanolamine of the formula I having high color stability | 06-21-2012 |
20120245389 | PROCESS FOR HYDROGENATING NITRILES - The present invention relates to a process for hydrogenating organic nitriles by means of hydrogen in the presence of a catalyst in a reactor, where the shaped body catalyst is arranged in a fixed bed, wherein the shaped body in the shape of spheres or rods has in each case a diameter 3 mm or less, in the shape of tablets a height of 4 mm or less, and in the case of all other geometries in each case has an equivalent diameter L=1/a′ of 0.70 mm or less, where a′ is the external surface area per unit volume (mm | 09-27-2012 |
20120259139 | METHOD FOR PREPARING HIGHER ETHANOLAMINES - The present invention relates to a process for preparing ethanolamines by reacting glycolaldehyde with monoethanolamine and/or diethanolamine in the presence of a catalyst. | 10-11-2012 |
20120264979 | PROCESS FOR PREPARING N,N-DIMETHYLAMINOETHOXYETHANOL - A process for preparing N,N-dimethylaminoethoxyethanol (DMAEE), wherein
| 10-18-2012 |
20120271068 | REACTION OF GLYCOLALDEHYDE WITH AN AMINATING AGENT - The present invention relates to a process for reacting glycolaldehyde with an aminating agent in the presence of hydrogen and of a catalyst, the catalyst being activated by reducing a catalyst precursor or by reducing a passivated catalyst, which comprises effecting the reaction in the presence of a solvent and contacting the glycolaldehyde with the activated catalyst. | 10-25-2012 |
20120296121 | PROCESS FOR PRODUCING CARBON FILLERS HAVING COVALENTLY BONDED AMINO GROUPS - The invention relates to a process for producing carbon fillers having covalently bonded amino groups, by converting a mixture comprising carbon fillers and alkali metals and/or alkaline earth metals and/or amides thereof in liquid anhydrous ammonia, optionally together with an inert solvent, at temperatures of 35 to 500° C. and a pressure of 30 to 250 bar. | 11-22-2012 |
20130053536 | PROCESS FOR PREPARING EDDN AND/OR EDMN AND A PROCESS FOR PREPARING DETA AND/OR TETA - A process for preparing EDDN and/or EDMN by
| 02-28-2013 |
20130053538 | PROCESS FOR PREPARING EDFA AND/OR EDMFA AND DETA AND/OR TETA - A process for reacting ethylenediamine (EDA) with formaldehyde to give ethylenediamine-formaldehyde adduct (EDFA) and/or ethylenediamine-monoformaldehyde adduct (EDMFA), which comprises performing the reaction of FA with EDA at a temperature in the range from 20 to 70° C. | 02-28-2013 |
20130053539 | PROCESS FOR PREPARING EDDN AND/OR EDMN AND PROCESS FOR PREPARING DETA AND/OR TETA - A process for preparing EDDN and/or EDMN by conversion of FA, HCN and EDA, the reaction being effected in the presence of water, wherein the reaction mixture from the conversion of EDA, HCN and FA is cooled after leaving the reactor. | 02-28-2013 |
20130053540 | PROCESS FOR PREPARING TETA - A process for preparing TETA and/or DETA by the action of EDDN and/or EDMN with hydrogen in the presence of a catalyst, wherein the catalyst used is a catalyst of the Raney type and the pressure in the course of hydrogenation is in the range from 170 to 240 bar. | 02-28-2013 |
20130053597 | PROCESS FOR PREPARING EDDN, EDMN, TETA AND DETA - A process for preparing ethylenediaminediacetonitrile (EDDN) and/or ethylenediamine-monoacetonitrile (EDMN) by conversion of formaldehyde (FA), hydrogen cyanide (HCN) and ethylenediamine (EDA), which comprises using stabilizer-free HCN, or HCN which has been stabilized with an organic acid, in the process. | 02-28-2013 |
20130079492 | PROCESS FOR PREPARING EDDN AND EDMN - A process for preparing EDDN and/or EDMN by conversion of FA, HCN and EDA, the reaction being effected in the presence of water, and, after the conversion, water being depleted from the reaction mixture in a distillation column, which comprises performing the distillation in the presence of an organic solvent which has a boiling point between water and EDDN and/or EDMN at the distillation pressure existing in the column or which forms a low-boiling azeotrope with water. | 03-28-2013 |
20130090452 | PROCESS FOR PREPARING EDDN AND/OR EDMN BY CONVERSION OF FACH AND EDA - A process for reacting formaldehyde cyanohydrin (FACH) with ethylenediamine (EDA) in a reactor with limited backmixing at a temperature in the range from 20 to 120° C., wherein the residence time in the reactor is 300 seconds or less. | 04-11-2013 |
20130090453 | Process for preparing TETA and DETA - A process for preparing TETA and/or DETA by hydrogenating EDDN and/or EDMN with hydrogen in the presence of a catalyst, which comprises preparing EDDN and/or EDMN from FA, HCN and EDA in the presence of toluene as a solvent and performing the hydrogenation in suspension mode in the presence of THF. | 04-11-2013 |
20130131385 | Process for Preparing Ethylamines and Monoisopropylamine (MIPA) - A process for preparing ethylamines and monoisopropylamine (MIPA), in which bioethanol is reacted with ammonia in the presence of hydrogen and of a heterogeneous catalyst to give ethylamines, said bioethanol having a content of sulfur and/or sulfur compounds of ≧0.1 ppm by weight (calculated S), and then isopropanol is reacted with ammonia in the presence of the same catalyst and in the presence of hydrogen to give MIPA. | 05-23-2013 |
20130310560 | PROCESSES FOR PREPARING AMINES AND CATALYSTS FOR USE THEREIN - Processes for preparing an amine are described which comprise reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of ammonia, primary and secondary amines, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst. The catalytically active composition of the catalyst, before its reduction with hydrogen, comprises oxygen compounds of zirconium, of copper, of nickel, in the range from 1.0 to 5.0% by weight of oxygen compounds of cobalt, calculated as CoO, and in the range from 0.2 to 5.0% by weight of oxygen compounds of sulfur, of phosphorus, of gallium, of lead and/or of antimony, calculated in each case as H2SO4, H3PO4, Ga203, PbO and Sb203 respectively. | 11-21-2013 |
20130324732 | Process for the Preparation of a Mono-N-Alkypiperazine - Process for the preparation of a mono-N-alkylpiperazine of the formula I | 12-05-2013 |
20140018547 | Process for Preparing Pyrrolidine - Process for preparing pyrrolidine of the formula I | 01-16-2014 |
20150018457 | USE OF LINEAR TRIETHYLENTETRAMINE AS CURING AGENT FOR EPOXY RESINS - The present invention relates to an amine composition comprising linear triethylenetetramine and one or more amine compounds selected from the group consisting of tertiary amines derived from the condensation of ethylenediamine and methyl-substituted compounds derived from linear triethylenetetramine as well as a method of production for said composition. | 01-15-2015 |