Patent application number | Description | Published |
20130137151 | PROCESSES FOR THE CONVERSION OF BIOMASS TO OXYGENATED ORGANIC COMPOUND, APPARATUS THEREFOR AND COMPOSITIONS PRODUCED THEREBY - Processes are disclosed for the conversion of biomass to oxygenated organic compound using a simplified syngas cleanup operation that is cost effective and protects the fermentation operation. The processes of this invention treat the crude syngas from the gasifier by non-catalytic partial oxidation. The partial oxidation reduces the hydrocarbon content of the syngas such as methane, ethylene and acetylene to provide advantageous gas feeds for anaerobic fermentations to produce oxygenated organic compounds such as ethanol, propanol and butanol. Additionally, the partial oxidation facilitates any additional cleanup of the syngas as may be required for the anaerobic fermentation. Producer gases and partial oxidation processes are also disclosed. | 05-30-2013 |
20130177957 | SULFIDE GENERATION PROCESS AND SYSTEM FOR SYNGAS FERMENTATION - A process that generates sulfide in production of liquid products from syngas and a system for syngas fermentation including a sulfide generation process to convert feed gas to liquid product, the process including: partially oxidizing high-temperature gas, input gas, and molten sulfur to generate sulfide gas, the high-temperature gas containing oxygen, the input gas containing carbonaceous fuel and the sulfide gas containing hydrogen sulfide, CO, CO | 07-11-2013 |
20130266997 | INTEGRATED PROCESSES FOR REFINING SYNGAS AND BIOCONVERSION TO OXYGENATED ORGANIC COMPOUND - Integrated processes are provided for syngas refining and bioconversion of syngas to oxygenated organic compound. In the integrated processes ammonia contained in the syngas is recovered and used as a source of nitrogen and water for the fermentation. The integrated processes first remove tars from syngas by scrubbing using a first aqueous medium under conditions that ammonium bicarbonate is unstable. With tars removed, contact between the syngas and a second aqueous medium enables ammonia and carbon dioxide to be removed from the syngas without undue removal of components adverse to the fermentation, processing or oxygenated product such as benzene, toluene, xylene, ethylene, acetylene, and hydrogen cyanide. At least a portion of the second aqueous medium is supplied as a source of water and ammonia for the fermentation. | 10-10-2013 |
20140273125 | PROCESSES FOR THE ANAEROBIC BIOCONVERSION OF SYNGAS TO OXYGENATED ORGANIC COMPOUND WITH IN SITU PROTECTION FROM HYDROGEN CYANIDE - Processes are disclosed for the anaerobic bioconversion of syngas to oxygenated organic compound that use an in situ method for protecting the microorganisms from hydrogen cyanide contained in the syngas that passes to the fermentation broth. The fermentation broth is maintained at a pH of between about 4 and 6, and dissolved metal cation of one or more of iron, cobalt, nickel and zinc is provided to the fermentation broth in an amount sufficient to form, under the conditions of the fermentation broth, a substantially insoluble metal complex with the metal cation and cyanide anion. The rate of formation of the insoluble complex is sufficiently high that that the amount of cyanide that is taken up by microorganisms does not result in an undue adverse effect on the population of microorganisms. | 09-18-2014 |
20150028260 | PROCESSES FOR THE CONVERSION OF BIOMASS TO OXYGENATED ORGANIC COMPOUND, APPARATUS THEREFOR AND COMPOSITIONS PRODUCED THEREBY - Processes are disclosed for the conversion of biomass to oxygenated organic compound using a simplified syngas cleanup operation that is cost effective and protects the fermentation operation. The processes of this invention treat the crude syngas from the gasifier by non-catalytic partial oxidation. The partial oxidation reduces the hydrocarbon content of the syngas such as methane, ethylene and acetylene to provide advantageous gas feeds for anaerobic fermentations to produce oxygenated organic compounds such as ethanol, propanol and butanol. Additionally, the partial oxidation facilitates any additional cleanup of the syngas as may be required for the anaerobic fermentation. Producer gases and partial oxidation processes are also disclosed. | 01-29-2015 |
20150184093 | INTEGRATED PROCESSES FOR REFINING SYNGAS AND BIOCONVERSION TO OXYGENATED ORGANIC COMPOUND - Integrated processes are provided for syngas refining and bioconversion of syngas to oxygenated organic compound. In the integrated processes ammonia contained in the syngas is recovered and used as a source of nitrogen and water for the fermentation. The integrated processes first remove tars from syngas by scrubbing using a first aqueous medium under conditions that ammonium bicarbonate is unstable. With tars removed, contact between the syngas and a second aqueous medium enables ammonia and carbon dioxide to be removed from the syngas without undue removal of components adverse to the fermentation, processing or oxygenated product such as benzene, toluene, xylene, ethylene, acetylene, and hydrogen cyanide. At least a portion of the second aqueous medium is supplied as a source of water and ammonia for the fermentation. | 07-02-2015 |
20150225748 | PROCESSES FOR ANAEROBIC BIOCONVERSION OF HYDROGEN-CONTAINING GASES TO OXYGENATED ORGANIC COMPOUNDS - Anaerobic processes for the bioconversion of syngas to oxygenated organic compounds in an aqueous menstruum are disclosed where exogenous carbon dioxide is used to provide a syngas-containing substrate gas having a desired electron to carbon ratio. The exogenous carbon dioxide contains free oxygen, and the aqueous menstruum withdrawn for product recovery is contacted with the exogenous carbon dioxide to reduce its oxygen concentration before being supplied as part of the substrate gas. | 08-13-2015 |
20160130610 | PROCESSES FOR THE ACIDIC, ANAEROBIC CONVERSION OF HYDROGEN AND CARBON OXIDES TO OXYGENATED ORGANIC COMPOUND - Processes for the bioconversion of syngas to oxygenated organic compound are disclosed that reliably, cost-effectively and efficiently supply sulfur nutrient to microorganisms contained in acidic, aqueous fermentation menstrua. In the processes of this invention, basic, aqueous solution used to maintain the pH of the aqueous fermentation menstruum is used to remove hydrogen sulfide from the off-gas from the fermentation menstruum for recycle to the fermentation menstruum. | 05-12-2016 |