| Patent application number | Description | Published |
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| 20080202744 | Methods and Compositions for Fracturing Subterranean Formations - Viscoelastic surfactant (VES) gelled aqueous fluids containing water, a VES, an internal breaker, a VES stabilizer, a fluid loss control agent and a viscosity enhancer are useful as treating fluids and particularly as fracturing fluids for subterranean formations. These VES-based fluids have faster and more complete clean-up than polymer-based fracturing fluids. The use of an internal breaker permits ready removal of the unique VES micelle based pseudo-filter cake with several advantages including reducing the typical VES loading and total fluid volume since more VES fluid stays within the fracture, generating a more optimum fracture geometry for enhanced reservoir productivity, and treating reservoirs with permeability above the present VES limit of approximately 400 md to at least 2000 md. | 08-28-2008 |
| 20080220995 | Suspension of Concentrated Particulate Additives Containing Oil for Fracturing and Other Fluids - The handling, transport and delivery of particulate materials, particularly fine particles, may be difficult. Alkaline earth metal oxide particles such as magnesium oxide (MgO) may be suspended in glycerin and/or alkylene glycols such as propylene glycol up to loadings of 51 wt %. Such suspensions or slurries make it easier to deliver MgO and similar agents into fluids, such as aqueous fluids gelled with viscoelastic surfactants (VES). These concentrated suspensions or slurries may be improved in their stability by the inclusion of minor amounts of a vegetable oil and/or a fish oil. The MgO serves as stabilizers and/or fluid loss control agents for VES-gelled fluids used to treat subterranean formations, e.g. for well completion or stimulation in hydrocarbon recovery operations. The particle size of the magnesium oxide or other agent may be between 1 nanometer to 0.4 millimeter. | 09-11-2008 |
| 20080227672 | Unsaturated Fatty Acids and Mineral Oils as Internal Breakers for VES-Gelled Fluids - Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of a synergistic internal breaker composition that contains at least one first internal breaker that may be a mineral oil and a second breaker that may be an unsaturated fatty acid. The internal breakers may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. This combination of different types of internal breakers break the VES-gelled aqueous fluid faster than if one of the breaker types is used alone in an equivalent total amount. | 09-18-2008 |
| 20080248978 | Compositions and Methods for Water and Gas Shut-Off in Subterranean Wells With VES Fluids - Viscoelastic surfactant (VES) based fluid systems for zone isolation and flow control are effective in water and/or gas shutoff applications. The fluid systems may include brine, a viscosity enhancer, as well as the VES, and optionally a stabilizer for high temperature applications. The stabilizer may be an alkali earth metal oxide, alkali earth metal hydroxide, alkali metal oxide, alkali metal hydroxide, Al | 10-09-2008 |
| 20080271888 | Methods of Using Viscoelastic Surfactant Gelled Fluids to Pre-Saturate Underground Formations - Viscoelastic surfactant (VES) based fluid systems are effective to pre-saturate high permeability subterranean formations prior to a treatment operation that would undesirably suffer from high fluid leakoff. The fluid systems may include brine, a viscosity enhancer, as well as the VES, and a high temperature stabilizer. The stabilizer may be an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxide, alkali metal hydroxide, Al | 11-06-2008 |
| 20080296024 | Procedures and Compositions for Reservoir Protection - A flow conduit having at least one orifice is placed in the vicinity of a flow source, which in one non-limiting embodiment may be a hydrocarbon reservoir. The flow pathway between the orifice and the source is temporarily blocked with a degradable barrier. Once the flow pathway is physically placed, the degradable barrier is removed under the influence of an acid, a solvent, time and/or temperature. The flow source and the flow pathways are at least partially covered (and flow blocked by) a temporary coating such as a pseudo-filter cake formed by a viscoelastic surfactant-gelled aqueous drill-in fluid, and the flow conduit is extended to the flow source. The pseudo-filter cake is removed when viscosity is reduced by an internal breaker, and flow is then allowed. The method is useful in one context of recovering hydrocarbons where the flow conduit is a telescoping sleeve or tube that contacts the borehole wall. | 12-04-2008 |
| 20080300153 | Use of Nano-Sized Clay Minerals in Viscoelastic Surfactant Fluids - Nano-sized clay minerals enhance the viscosity of aqueous fluids that have increased viscosity due to the presence of viscoelastic surfactants (VESs). In one non-limiting theory, the nano-sized clay mineral viscosity enhancers associate, link, connect, or relate the VES micelles thereby increasing the viscosity of the fluid, possibly by mechanisms involving chemisorption or surface charge attractions. The nano-sized clay particles may have irregular surface charges. The higher fluid viscosity is beneficial to crack the formation rock during a fracturing operation, to reduce fluid leakoff, and to carry high loading proppants to maintain the high conductivity of fractures. | 12-04-2008 |
| 20090065209 | Multifunctional Nanoparticles for Downhole Formation Treatments - An aqueous, viscoelastic fluid gelled with a viscoelastic surfactant (VES) is stabilized and improved with an effective amount of an alkaline earth metal oxide alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, and post-transition metal hydroxides. These fluids are more stable and have a reduced or no tendency to precipitate, particularly at elevated temperatures, and may also help control fluid loss. When the particle size of the magnesium oxide or other particulate agent is a nanometer scale, for instance having a mean particle size of 100 nm or less, that scale may provide unique particle charges that use chemisorption, “crosslinking” and/or other chemistries to associate and stabilize the VES fluids, and also help trap or fixate formation fines when deposited into a proppant pack in a fracture. | 03-12-2009 |
| 20090107673 | Nano-Sized Particle-Coated Proppants for Formation Fines Fixation in Proppant Packs - A fracturing fluid, gravel pack fluid and/or frac pack fluid containing particles such as proppants, gravel and/or sand, may contain an effective amount of a nano-sized particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The nano-sized particulate additive is bound to the particles with a coating agent such as an oil. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that help fixate the formation fines. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based. | 04-30-2009 |
| 20090192053 | Methods and Compositions for Delayed Release of Chemicals and Particles - Agents, chemicals and particles may be controllably released at remote locations, such as pre-selected or predetermined portions of subterranean formations, by binding or associating or trapping them with an association of micelles formed by a viscoelastic surfactant (VES) in an aqueous base fluid to increase the viscosity of the fluid. An internal breaker within the association of micelles disturbs the association of micelles at some later, predictable or predetermined time thereby reducing the viscosity of the aqueous viscoelastic treating fluid and releasing the agent, chemical or particle at a predetermined or selected location. | 07-30-2009 |
| 20090192056 | Friction Loss Reduction in Viscoelastic Surfactant Fracturing Fluids Using Low Molecular Weight Water-Soluble Polymers - Adding relatively low molecular weight water-soluble friction loss reduction polymers to an aqueous fluid gelled with a viscoelastic surfactant (VES) increases the critical generalized Reynold's number at which the Fanning friction factor increases and friction pressure starts to increase rapidly. The water-soluble polymeric friction loss reduction additives lower surface pumping pressure in VES-gelled fracturing fluids for a given pump rate, thus lowering hydraulic horsepower (HHP) requirements for pumping fluids downhole, e.g. for hydraulic fracturing or frac packing treatments of subterranean formations. | 07-30-2009 |
| 20090253596 | FLUID LOSS CONTROL AGENTS FOR VISCOELASTIC SURFACTANT FLUIDS - Alkaline earth metal compounds may be fluid loss control agents for viscoelastic surfactant (VES) fluids used for well completion or stimulation in hydrocarbon recovery operations. The VES fluid may further include proppant or gravel, if it is intended for use as a fracturing fluid or a gravel packing fluid, although such uses do not require that the fluid contain proppant or gravel. The fluid loss control agents may include, but not be limited to, oxides and hydroxides of alkaline earth metal, and in one case magnesium oxide where the particle size of the magnesium oxide is between 1 nanometer to 0.4 millimeter. The fluid loss agent appears to associate with the VES micelles and together form a novel pseudo-filter cake crosslinked-like viscous fluid layer that limits further VES fluid flow into the porous media. The fluid loss control agent solid particles may be added along with VES fluids. | 10-08-2009 |
| 20090266765 | Methods for Recharging Nanoparticle-Treated Beds - Nanoparticle-treated particle packs, such as sand beds, may effectively filter and purify liquids such as waste water. Proppant beds treated with nanoparticles may fixate or reduce fines migration therethrough. When tiny contaminant particles or fines in these fluids flow through the nanoparticle-treated bed or pack, the nanoparticles will capture and hold the tiny contaminant or fines particles within the pack due to the nanoparticles' surface forces, including, but not necessarily limited to van der Waals and electrostatic forces. Nanoparticle-treated beds or packs may be recharged by contacting the bed with an inorganic acid (but not hydrofluoric acid) or an organic acid, and optionally followed by subsequent treatment with hydrofluoric acid. This treating substantially removes the nanoparticles and the fine particulates that have been removed from a fluid (e.g. wastewater being treated, produced fluids in a formation, etc.). The particle pack may then be re-treated or recharged with nanoparticles. | 10-29-2009 |
| 20090266766 | Wastewater Purification With Nanoparticle-Treated Bed - Nanoparticle-treated particle packs, such as sand beds, may effectively filter and purify liquids such as waste water. When tiny contaminant particles in waste water flow through the particle pack, the nanoparticles will capture and hold the tiny contaminant particles within the pack due to the nanoparticles' surface forces, including, but not necessarily limited to van der Waals and electrostatic forces. Coating agents such as alcohols, glycols, polyols, vegetable oil, and mineral oils may help apply the nanoparticles to the particle surfaces in the filter beds or packs. | 10-29-2009 |
| 20090272534 | METHODS OF USING VISCOELEASTIC SURFACTANT GELLED FLUIDS TO PRE-SATURATE UNDERGROUND FORMATIONS - Viscoelastic surfactant (VES) based fluid systems are effective to pre-saturate high permeability subterranean formations prior to a treatment operation that would undesirably suffer from high fluid leakoff. The fluid systems may include brine, a viscosity enhancer, as well as the VES, and a high temperature stabilizer. The stabilizer may be an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxide, alkali metal hydroxide, Al | 11-05-2009 |
| 20090286702 | Using Nanoparticles for Water Flow Control in Subterranean Formations - Non-aqueous carrier fluids containing nano-sized particles in high concentration are effective for zone isolation and flow control in water shutoff applications for subterranean formations. The nanoparticles interact with water and solidify it to inhibit its flow, but do not have the same effect on hydrocarbons and thus selectively assist the production of hydrocarbons while suppressing water. Suitable nanoparticles include alkaline earth metal oxides, alkaline earth metal hydroxides, alkali metal oxides, alkali metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides, piezoelectric crystals, and/or pyroelectric crystals. | 11-19-2009 |
| 20090305915 | SUSPENSION OF CONCENTRATED PARTICULATE ADDITIVES CONTAINING OIL FOR FRACTURING AND OTHER FLUIDS - The handling, transport and delivery of particulate materials, particularly fine particles, may be difficult. Alkaline earth metal oxide particles such as magnesium oxide (MgO) may be suspended in glycerin and/or alkylene glycols such as propylene glycol up to loadings of 51 wt %. Such suspensions or slurries make it easier to deliver MgO and similar agents into fluids, such as aqueous fluids gelled with viscoelastic surfactants (VES). These concentrated suspensions or slurries may be improved in their stability by the inclusion of minor amounts of a vegetable oil and/or a fish oil. The MgO serves as stabilizers and/or fluid loss control agents for VES-gelled fluids used to treat subterranean formations, e.g. for well completion or stimulation in hydrocarbon recovery operations. The particle size of the magnesium oxide or other agent may be between 1 nanometer to 0.4 millimeter. | 12-10-2009 |
| 20090312201 | Nano-Sized Particles for Formation Fines Fixation - A treating fluid may contain an effective amount of a particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that help fixate the formation fines. These treating fluids may be used as treatment fluids for subterranean hydrocarbon formations, such as in hydraulic fracturing, completion fluids, gravel packing fluids and fluid loss pills. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based. | 12-17-2009 |
| 20100010106 | Metal-Mediated Viscosity Reduction of Fluids Gelled With Viscoelastic Surfactants - Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of a composition that contains at least one metal ion source and optionally at least one second source. An optional second source may be a chelating agent where at least one reducing agent source may be additionally optionally used. Another optional component with the metal ion source includes a second, different metal ion source. The breaking composition is believed to directly attack the VES itself, possibly by disaggregating or otherwise attacking the micellar structure of the VES-gelled fluid, and/or possibly by changing the chemical structure of the VES to give two or more products. | 01-14-2010 |
| 20100071957 | Drill-In Fluids For Oil and Gas Reservoirs With High Carbonate Contents - Compositions Including Relatively Low Reactivity Acids, Mixed with viscoelastic surfactants (VESs) and internal breakers may serve as drill-in fluids to open underground hydrocarbon reservoirs with carbonate contents of 10 wt % or above. The drill-in fluids have low viscosities in the drilling pipe. After the fluid flows out of the drill bit, the acids react with carbonates in the formation thereby increasing the pH of the drill-in fluids causing the VES to gel the fluid at the bottom of the hole and the downhole annulus between the drilling pipe and the formation rock. The viscosified drill-in fluid will reduce fluid loss and will carry no dissolved drilling debris to the surface. After drilling through the targeted formation, the internal breakers in the viscosified drill-in fluids will break down the fluids to permit their removal, and the well is ready to produce with very little or no near well bore damage. | 03-25-2010 |
| 20100108613 | Methods and Compositions to Remove Coal Fines From Aqueous Fluids - Nanoparticle-treated particle packs, such as sand beds, may effectively remove coal fines from aqueous fluids, such as contaminated water. A porous substrate treated with nanoparticles, such as alkaline earth metal oxides/hydroxides, transition metal oxides/hydroxides, post-transition metal oxides/hydroxides, piezoelectric crystals, and/or pyroelectric crystals, may remove a substantial portion of coal fines from an aqueous fluid. It is believed that the nanoparticles capture and hold the coal fines in the particle pack due to surface forces, including van der Waals and/or electrostatic forces. The nanoparticles may be applied to the substrate via a coating agent, such as alcohol, glycol, polyol, olefin, vegetable oil, fish oil, and/or mineral oil. | 05-06-2010 |
| 20100197531 | Use of Oil-Soluble Surfactants as Breaker Enhancers for VES-Gelled Fluids - Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of an internal breaker composition that contains at least one mineral oil, at least one polyalphaolefin oil, at least one saturated fatty acid and/or at least one unsaturated fatty acid. The internal breaker may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the internal breaker, e.g. mineral oil, is added to the fluid after it has been substantially gelled. An oil-soluble surfactant is present to enhance or accelerate the reduction of viscosity of the gelled aqueous fluid. | 08-05-2010 |
| 20100234248 | Saponified Fatty Acids as Breakers for Viscoelastic Surfactant-Gelled Fluids - Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities affected (increased or reduced, e.g. gels broken) by the indirect or direct action of a composition that contains at least one fatty acid that has been affected, modified or reacted with an alkali metal base, an alkali earth metal base, ammonium base, and/or organic base compound, optionally with an alkali metal halide salt, an alkali earth metal halide salt, and/or an ammonium halide salt. The composition containing the resulting saponification product is believed to either act as a co-surfactant with the VES itself to increase viscosity and/or possibly by disaggregating or otherwise affecting the micellar structure of the VES-gelled fluid. In a specific, non-limiting instance, a brine fluid gelled with an amine oxide surfactant may have its viscosity broken with a composition containing naturally-occurring fatty acids in canola oil or corn oil affected with CaOH, MgOH, NaOH and the like. | 09-16-2010 |
| 20100252266 | Organic Acid Treating Fluids With Viscoelastic Surfactants and Internal Breakers - An aqueous fluid system that contains an aqueous dicarboxylic acid solution, a viscoelastic surfactant as a gelling agent to increase the viscosity of the fluid, and an internal breaker such as mineral oil and/or fish oil to controllably break the viscosity of the fluid provides a self-diverting acid treatment of subterranean formations. The internal breaker may be at least one mineral oil, a polyalphaolefin oil, a saturated fatty acid, and/or is an unsaturated fatty acid. The VES gelling agent does not yield viscosity until the organic acid starts to spend. Full viscosity yield of the VES gelling agent typically occurs at about 6.0 pH. The internal breaker allows the VES gelling agent to fully viscosify the spent organic acid at 6.0 pH and higher, but as the spent-acid VES gelled fluid reaching reservoir temperature, controllable break of the VES fluid viscosity over time can be achieved. | 10-07-2010 |
| 20100261622 | Methods and Compositions for Fracturing Subterranean Formations - Viscoelastic surfactant (VES) gelled aqueous fluids containing water, a VES, an internal breaker, a VES stabilizer, a fluid loss control agent and a viscosity enhancer are useful as treating fluids and particularly as fracturing fluids for subterranean formations. These VES-based fluids have faster and more complete clean-up than polymer-based fracturing fluids. The use of an internal breaker permits ready removal of the unique VES micelle based pseudo-filter cake with several advantages including reducing the typical VES loading and total fluid volume since more VES fluid stays within the fracture, generating a more optimum fracture geometry for enhanced reservoir productivity, and treating reservoirs with permeability above the present VES limit of approximately 400 md to at least 2000 md. | 10-14-2010 |
| 20100261624 | Unsaturated Fatty Acids and Mineral Oils As Internal Breakers for VES-Gelled Fluids - Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of a synergistic internal breaker composition that contains at least one first internal breaker that may be a mineral oil and a second breaker that may be an unsaturated fatty acid. The internal breakers may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. This combination of different types of internal breakers break the VES-gelled aqueous fluid faster than if one of the breaker types is used alone in an equivalent total amount. | 10-14-2010 |
| 20100263866 | Multifunctional Particles for Downhole Formation Treatments - An aqueous, viscoelastic fluid gelled with a viscosifier, e.g. a viscoelastic surfactant, is stabilized and improved with an effective amount of a particulate additive such as alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, and post-transition metal hydroxides. These fluids are more stable and have a reduced or no tendency to precipitate, particularly at elevated temperatures, and may also help control fluid loss. These particulate additives have unique particle charges that use chemisorption, “crosslinking” and/or other chemistries to associate and stabilize the VES fluids, and also help trap or fixate formation fines when placed in a gravel pack or a proppant pack in a fracture. Some of these effects may be more pronounced the smaller the size of the particulate additive. | 10-21-2010 |
| 20100270022 | Deep Water Completions Fracturing Fluid Compositions - It has been discovered that fracturing fluid compositions can be designed for successful deep water completion fracturing fluid operations. These fluids must be pumped relatively long distances from offshore platforms to the reservoir, and they are often subjected to a wide temperature range. Under these conditions, it is necessary to inhibit the formation of gas hydrates in the fracturing fluid compositions, as well as to delay the crosslinking of the gels that are formed to increase the viscosity of the fluids prior to fracturing the formation. Preferably, two different gas hydrate inhibitors are used to ensure placement of a gas hydrate inhibitor in most parts of the operation. In addition, as with all offshore or deep water hydrocarbon recovery operations, it is important that the components of the fracturing fluid compositions be environmentally benign and biodegradable. | 10-28-2010 |
| 20100286000 | Nano-Sized Particle-Coated Proppants for Formation Fines Fixation in Proppant Packs - A fracturing fluid, gravel pack fluid and/or frac pack fluid containing particles such as proppants, gravel and/.or sand, may contain an effective amount of a nano-sized particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The nano-sized particulate additive is optionally bound to the particles with a coating agent such as an oil, alcohol, glycol, glycol ethers, ketones, terpenes, etc. The particle size of the magnesium oxide or other agent may be nanometer scale but may be a larger scale than nanometer but still relatively small, which scale may provide unique particle charges that help fixate the formation fines. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based. | 11-11-2010 |
| 20100314108 | Dual-Function Nano-Sized Particles - Dual-function nano-sized particles or nanoparticles may be effective at fixating or reducing fines migration and they may facilitate identification of a particular zone in a well having more than one zone. In some embodiments the dual-function nanoparticles are tagged with a detectable material that is distinguishable from the composition of the primary nanoparticle component. In these embodiments, the taggant material rather than the primary component of the nanoparticles may be used to enable identification of a particular zone. The nanoparticles (with or without taggant) may be added to a treatment fluid containing carrier particles such as proppant. The treatment fluid is pumped downhole to one of the zones; each zone receiving its own unique or uniquely-tagged nanoparticles. Should one of the zones fail, the composition of the nanoparticles (or its taggant) produced on the carrier particles may be correlated to the zone from which it was received, and hence produced. | 12-16-2010 |
| 20100314113 | Dual-Functional Breaker for Hybrid Fluids of Viscoelastic Surfactant and Polymer - Incorporating water-based polymer breakers, such as oxidizers, enzymes and/or acids, into a mixture of an oil and oil-soluble surfactants creates an emulsion that can then perform as a dual-functional breaker for reducing the viscosity of hybrid fluids gelled with both a viscoelastic surfactant (VES) and a polymer. The outer phase of the dual-functional breaker emulsion is oil, e.g. a mineral oil, containing an oil-soluble surfactant that will, over time and with heat, break the VES portion of the gel. As it does so, the polymer breaker in the internal aqueous phase will be released to then break the polymer portion of the gel. The polymer breaker will not start to break the polymer gel before the oil-soluble surfactant starts to break the VES gel. The overall breaking using the emulsion is slower as compared to introducing the polymer breaker and the oil-soluble surfactant in a non-emulsified form. | 12-16-2010 |
| 20110030952 | METHODS OF GRAVEL PACKING LONG INTERVAL WELLS - Changing concentrations of brine in a gravel pack carrier fluid gelled with a viscoelastic surfactant (VES) increases the fluid efficiency for gravel packing long interval wells, such as wellbore producing interval greater than about 100 feet (about 30 m). VES-gelled fluids used as gravel packing fluids herein also include surfactants, fluid loss control agents, internal breakers and brine in addition to the grave. The viscoelasticity of fluid system can suspend and deliver high concentration of the gravels while reducing carrier fluid volume. | 02-10-2011 |
| 20110083902 | Lost Circulation Control Fluids for Naturally Fractured Carbonate Formations - Compositions including relatively low reactivity acids and having a pH of from about 2 to about 5, mixed with viscoelastic surfactants (VESs) and internal breakers may serve as fluids, in a non-limiting embodiment as drill-in fluids, to open underground hydrocarbon reservoirs with carbonate contents of 10 wt % or above. The fluids initially have low viscosities. After the fluid flows out of the drill bit, the acids react with carbonates in the formation thereby increasing the pH of the fluids causing the VES to gel the fluid at the bottom of the hole and within the formation rock. Even when the subterranean formation contains naturally-occurring fractures, the viscosified fluid will reduce fluid loss into the formation. After drilling through the targeted formation, internal breakers in the viscosified fluids will break down the fluids to permit their removal, and production of the well with very little or no near well bore damage. | 04-14-2011 |
| 20110098377 | Method of Controlling Water Production Through Treating Proppants With RPMS - Water production from a subterranean formation is inhibited or controlled by pumping a fluid containing coated particles through a wellbore into the formation. The particles have been previously coated with a relative permeability modifier (RPM). Upon contact with water, the RPM coating expands or swells and inhibits and controls the production of water. The RPM may be a water hydrolyzable polymer having a weight average molecular weight greater than 100,000. The particles may be conventional proppants or gravel. | 04-28-2011 |
| 20110108270 | Re-Use of Surfactant-Containing Fluids - The components of surfactant-laden fluids, such as those used in hydrocarbon recovery operations such as for stimulation, e.g. hydraulic fracturing, may be re-used and re-cycled into components for subsequent use in a wide range of similar or different operational fluids. In particular, aqueous fluids gelled with viscoelastic surfactants and having components therein to pseudo-crosslink the elongated VES micelles and for internal breaking may be separated into its component parts by relatively inexpensive methods such as filtration. One filtration method includes contacting the surfactant-containing fluid with a particle pack having particulate additives therein which filter out or extract fine solids from the fluid. In an alternate embodiment the surfactant-laden fluid is a nano- and/or micro-emulsion wellbore cleanup fluid. | 05-12-2011 |
| 20110224110 | Particles in Oil for Viscoelastic Surfactant Gelled Fluids - Fluids viscosified with viscoelastic surfactants (VESs) may have their fluid loss properties improved with the presence of at least one mineral oil in combination with at least one particulate fluid loss control agent that may be an alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof. The mineral oil may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the mineral oil is added to the fluid after it has been substantially gelled. The particulate fluid loss control agent may be added in any order relative to the VES and the mineral oil fluid loss control agent. The mineral oil may enhance the ability of a particulate fluid loss control agent to reduce fluid loss. The presence of the mineral oil may also eventually reduce the viscosity of the VES-gelled aqueous fluid. | 09-15-2011 |
| 20110253365 | Methods for Removing Residual Polymer From a Hydraulic Fracture - Viscoelastic surfactant (VES) gelled aqueous fluids containing water, a VES in an amount effective to increase the viscosity of the water, and an internal breaker may be useful in removing a residual polymer from a hydraulic fracture. Optionally, a pseudo-crosslinker may be present to further improve the properties related to treatment fluid placement and polymer clean-up. A plurality of aliquots of VES gelled fluid may be injected into a subterranean formation. A stop-start interval may exist between the injection of each aliquot. The VES gelled fluid may contact at least some of the residual polymer in the hydraulic fracture, and a broken fluid is formed once the viscosity of the VES gelled fluid is reduced with the internal breaker. At least a portion of the residual polymer and a majority of the broken fluid may be removed. | 10-20-2011 |
| 20110284228 | Increasing the Viscosity of Viscoelastic Fluids - In hydrocarbon recovery applications, viscoelastic surfactant (VES) gelled fluids may be preheated to a temperature that will increase viscosity of the VES gelled fluid. The preheated VES gelled fluid retains at least a portion of its preheated viscosity when cooled such as by introduction into a low temperature condition. In an embodiment, the VES gelled fluid may be a drilling fluid, completion fluid, or fracturing fluid, and the low temperature condition may be an offshore operation, an operation in a locality having a cold climate, and/or a shallow oil, gas, or both land-based operation where the formation temperature is 120° F. or less. The surfactant in the VES gelled fluid may be one or more of an amine, amine salt, quaternary ammonium salt, betaine, amidoamine oxide, amine oxide, and combinations thereof. | 11-24-2011 |
| 20110303414 | Method for Improving the Clean-Up of Emulsified Acid Fluid Systems - Using a complex emulsion for treating a subterranean formation, such as to dissolve minerals therein (e.g. carbonates, scales, and/or filter cake) to improve permeability, substantially improves post treatment fluid clean-up for improved hydrocarbon production. The complex emulsion is made by mixing an acid aqueous phase with an oil external microemulsion to give an initial product, where the acid aqueous phase is an external phase and the microemulsion is an internal phase. Then the initial product is mixed with a second oil (e.g. xylene, diesel, toluene, kerosene, other aromatics, refined hydrocarbons and the like) containing an emulsifier to make a complex emulsion. | 12-15-2011 |
| 20120090845 | Stabilizing Emulsified Acids for Carbonate Acidizing - Emulsified acids have been used to increase production rates of oil and gas in carbonate reservoirs through acid fracturing and matrix acidizing operations. An emulsifier is used to emulsify the aqueous acid with an oil, usually diesel. Very small particles, such as colloidal clay particles and/or nanoparticles increase the stability of the emulsified acids over an elevated temperature range. | 04-19-2012 |
| 20120135896 | Compositions and Methods for Controlling Fluid Loss - Alkaline earth metal compounds may be fluid loss control (FLC) agents for viscoelastic surfactant (VES) fluids used for fluid loss control pills, lost circulation material pills and kill pills in hydrocarbon recovery operations. The FLC agents may include, but not be limited to oxides and hydroxides of alkaline earth metal, and in one case magnesium oxide where the particle size of the magnesium oxide is between 1 nanometer to 0.4 millimeter. The FLC agent may alternatively be transition metal oxides and/or transition metal hydroxides. The FLC agent appears to associate with the VES micelles and together form a novel pseudo-filter cake quasi-crosslinked viscous fluid layer that limits further VES fluid flow into the porous media. The FLC agent solid particles may be added along with VES fluids. The pills may also contain internal breakers to reduce the viscosity thereof so that the components of the pill may be recovered. | 05-31-2012 |
| 20120138538 | Rechargeable Surface Active Porous Media For Removal of Organic Materials From Aqueous Fluids - Organic material may be removed from a fluid, such as an aqueous fluid, by contacting the fluid with a surface active porous medium. The surface active porous medium includes a bed of substrate particles (e.g. sand), at least a partial coating of nanoparticles on the substrate bed, and a plurality of absorbing particles fixated on the nanoparticles. The absorbing particles may include, but are not necessarily limited to, coal fines, activated carbon, activated charcoal, activated coal and combinations thereof. The surface active porous medium may be regenerated by contacting the surface active porous medium with an acid solution to substantially remove the organic materials therefrom. | 06-07-2012 |
| 20120247765 | High Permeability Frac Proppant - Disintegrative particles are designed to be blended with and pumped with typical proppant materials, e.g. sand, ceramics, bauxite, etc, into the fractures of a subterranean formation. With time and/or change in wellbore or environmental condition, these particles will either disintegrate partially or completely, in non-limiting examples, by contact with downhole fracturing fluid, formation water, or a stimulation fluid such as an acid or brine. Once disintegrated, the proppant pack within the fractures will lead to greater open space enabling higher conductivity and flow rates. The disintegrative particles may be made by compacting and/or sintering metal powder particles, for instance magnesium or other reactive metal or their alloys. Alternatively, particles coated with compacted and/or sintered nanometer-sized or micrometer sized coatings could also be designed where the coatings disintegrate faster or slower than the core in a changed downhole environment. | 10-04-2012 |
| 20120267102 | Nano-Sized Particles for Formation Fines Fixation - A treating fluid may contain an effective amount of a particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that help fixate the formation fines. These treating fluids may be used as treatment fluids for subterranean hydrocarbon formations, such as in hydraulic fracturing, completion fluids, gravel packing fluids and fluid loss pills. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based. | 10-25-2012 |
| 20120273426 | Wastewater Purification With Nanoparticle-Treated Bed - Nanoparticle-treated particle packs, such as sand beds, may effectively filter and purify liquids such as waste water. When tiny contaminant particles in waste water flow through the particle pack, the nanoparticles will capture and hold the tiny contaminant particles within the pack due to the nanoparticles' surface forces, including, but not necessarily limited to van der Waals and electrostatic forces. Coating agents such as alcohols, glycols, polyols, vegetable oil, and mineral oils may help apply the nanoparticles to the particle surfaces in the filter beds or packs. | 11-01-2012 |
| 20120283154 | Saponified Fatty Acids as Breakers for Viscoelastic Surfactant-Gelled Fluids - Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities affected (increased or reduced, e.g. gels broken) by the indirect or direct action of a composition that contains at least one fatty acid that has been affected, modified or reacted with an alkali metal base, an alkali earth metal base, ammonium base, and/or organic base compound, optionally with an alkali metal halide salt, an alkali earth metal halide salt, and/or an ammonium halide salt. The composition containing the resulting saponification product is believed to either act as a co-surfactant with the VES itself to increase viscosity and/or possibly by disaggregating or otherwise affecting the micellar structure of the VES-gelled fluid. In a specific, non-limiting instance, a brine fluid gelled with an amine oxide surfactant may have its viscosity broken with a composition containing naturally-occurring fatty acids in canola oil or corn oil affected with CaOH, MgOH, NaOH and the like. | 11-08-2012 |
| 20120283155 | Controlling Coal Fines in Coal Bed Operations - The migration of coal fines within a bed is reduced, inhibited or constrained by contacting the fines with nanoparticles, such as magnesium oxide crystals having an average particle size of about 30 nm. These nanoparticles may coat a proppant during the fracturing of a subterranean formation to produce methane from a coal bed therein. The nanoparticles may also treat a proppant pack in a fractured coal bed. The nanoparticles cause the coal fines to thus bind to or associate with the proppants. Thus, most of the coal fines entering fractures away from the near-wellbore region will be restrained or controlled near their origin or source and the production of methane at a desired level will be maintained much longer than a similar situation than where the nanoparticles are not used. | 11-08-2012 |
| 20120322700 | Nano-Sized Particles for Stabilizing Viscoelastic Surfactant Fluids - An aqueous, viscoelastic fluid gelled with a viscoelastic surfactant (VES) is stabilized and improved with an effective amount of an alkaline earth metal oxide alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, and post-transition metal hydroxides. These fluids are more stable and have a reduced or no tendency to precipitate, particularly at elevated temperatures. The additives may reduce the amount of VES required to maintain a given viscosity. These stabilized, enhanced, aqueous viscoelastic fluids may be used as treatment fluids for subterranean hydrocarbon formations, such as in hydraulic fracturing. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that use chemisorption, crosslinking and/or other chemistries to associate and stabilize the VES fluids. | 12-20-2012 |
| 20120329685 | Particles Slurried in Oil for Viscoelastic Surfactant Gelled Fluids - Fluids viscosified with viscoelastic surfactants (VESs) may have their fluid loss properties improved with the presence of at least one mineral oil slurried together in combination with at least one particulate fluid loss control agent that may be an alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof. The mineral oil having the particulate fluid loss control agents slurried within it may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the slurry is added to the fluid after it has been substantially gelled. The mineral oil/particulate slurry may enhance the ability of a particulate fluid loss control agent to reduce fluid loss. The presence of the mineral oil may also eventually reduce the viscosity of the VES-gelled aqueous fluid. | 12-27-2012 |
| 20130000985 | RECONFIGURABLE DOWNHOLE ARTICLE - A reconfigurable downhole article is disclosed. The article comprises a base material. The article also comprises a removable material disposed on or within the base material that is configured for removal from the base material in response to a wellbore condition, wherein the base material and the removable material define a base article that is configured to perform a first function, and wherein upon removal of the removable material, the base material defines a modified article that is configured to perform a second function that is different than the first function. | 01-03-2013 |
| 20130004664 | METHOD OF MAKING AND USING A RECONFIGURABLE DOWNHOLE ARTICLE - A method of making a reconfigurable article is disclosed. The method includes providing a powder comprising a plurality of base material particles. The method also includes providing a powder comprising a plurality of removable material particles; and forming a base article from the base material comprising a plurality of removable material particles. A method of using a reconfigurable article is also disclosed. The method includes forming a base article, the base article comprising a base material and a removable material, wherein the base article comprises a downhole tool or component. The method also includes inserting the base article into a wellbore. The method further includes performing a first operation utilizing the base article; exposing the removable material of the base article to a wellbore condition that is configured to remove the removable material and form a modified article; and performing a second operation using the article. | 01-03-2013 |
| 20130037274 | Electrolytic Composition for Degrading Polymeric Filter Cake - An aqueous breaking fluid having an aqueous fluid, powder particles, and at least one reducing sugar may be helpful in degrading a polymeric filter cake downhole. The aqueous breaking fluid may be introduced through a wellbore. The aqueous fluid may be or include water, brine, acid, alcohol, a mutual solvent, and mixtures thereof. A coating material of each metallic powder particle may be disintegrated such that the particle core may be released from the powder particle. The aqueous breaking fluid, which may include the reducing sugar and the released particle core, may contact and degrade the polymeric filter cake. | 02-14-2013 |
| 20130056215 | Disintegrative Particles to Release Agglomeration Agent for Water Shut-Off Downhole - Disintegrative particles having a disintegrative coating surrounding a disintegrative core may be pumped within an aqueous treatment fluid downhole to a subterranean formation. With time and/or change in wellbore or environmental condition, these particles will either disintegrate partially or completely, in non-limiting examples, by contact with downhole wellbore fluid, formation water, or a stimulation fluid (e.g. acid or brine). Once disintegrated, metals or compounds are released which raises the fluid pH and forms a structure that selectively inhibits or shuts-off the production of water from water-producing zones. The disintegrative particles may be made by compacting and/or sintering metal powder particles, for instance magnesium or other reactive metal or their alloys. Alternatively, particles coated with nanometer-sized or micrometer sized coatings may be designed where the coatings disintegrate faster or slower than the core in a changed downhole environment. | 03-07-2013 |
| 20130090270 | Method to Complex Metals in Aqueous Treating Fluids for Ves-Gelled Fluids - Aqueous treating fluids may include a viscoelastic surfactant (VES) and an aqueous base fluid, e.g. a drilling fluid, whereby the VES may increase and/or maintain the viscosity of the aqueous treating fluid. Metal ions may be present within the aqueous treating fluid that break, reduce, and/or digest the VES within the aqueous treating fluid. An effective amount of complexation particles may be added to the aqueous treating fluid for complexing at least a portion of these metal ions and thereby disallowing the metal ions from breaking, reducing, and/or altering the VES within the aqueous treating fluid. | 04-11-2013 |
| 20130112429 | ENHANCED ELECTROLYTIC DEGRADATION OF CONTROLLED ELECTROLYTIC MATERIAL - A method for degrading a downhole article includes exposing the downhole article to a composition comprising a corrosive agent selected from a reducing sugar, ester, aminocarboxylic acid, or a combination thereof. The method also includes contacting the downhole article with the corrosive agent to degrade the downhole article. Additionally, a composition for degrading a downhole article includes water, salt, and a corrosive agent selected from a reducing sugar, ester, aminocarboxylic acid, or a combination thereof. | 05-09-2013 |
| 20130118759 | AGENTS FOR ENHANCED DEGRADATION OF CONTROLLED ELECTROLYTIC MATERIAL - A method for degrading a downhole article includes exposing the downhole article comprising a controlled electrolytic material to a composition that comprises a reducing agent. The method also includes contacting the downhole article with the reducing agent to degrade the downhole article. Additionally, a composition for degrading a downhole article includes water, chelant, metal ions, and a reducing agent that includes ascorbic acid, erythorbic acid, a derivative thereof, a salt thereof, or a combination thereof. | 05-16-2013 |
| 20130123150 | METALLIC PARTICLE INDUCED SAPONIFICATION OF FATTY ACIDS AS BREAKERS FOR VISCOELASTIC SURFACTANT-GELLED FLUIDS - A method for affecting the viscosity of an aqueous fluid gelled with a VES includes providing an aqueous fluid and adding to the aqueous fluid, in any order: at least one VES comprising a non-ionic surfactant, cationic surfactant, amphoteric surfactant or zwitterionic surfactant, or a combination thereof, in an amount sufficient to form a gelled aqueous fluid comprising a plurality of elongated micelles, a glyceride oil comprising a fatty acid, and a plurality of metallic particles to produce a mixture comprising dispersed metallic particles. The method also includes dissolving at least a portion of the metallic particles in the aqueous fluid to provide a compound comprising a metallic base and forming in situ a soap reaction product of the fatty acid with the compound, wherein the soap reaction product is present in an amount effective to increase, decrease, or increase and then decrease a viscosity of the gelled aqueous fluid. | 05-16-2013 |
| 20130123151 | METALLIC PARTICLE MEDIATED VISCOSITY REDUCTION OF VISCOELASTIC SURFACTANTS - A method for breaking the viscosity of an aqueous fluid gelled with a viscoelastic surfactant (VES) is disclosed. The method includes providing an aqueous fluid and adding to the aqueous fluid, in any order: at least one VES comprising a non-ionic surfactant, cationic surfactant, amphoteric surfactant or zwitterionic surfactant, or a combination thereof, in an amount sufficient to form a gelled aqueous fluid comprising a plurality of elongated micelles and having a viscosity, and a plurality of metallic particles to produce a mixture comprising dispersed metallic particles dispersed within the gelled aqueous fluid. The method also includes dissolving the metallic particles in the gelled aqueous fluid to provide a source of at least one transition metal ion in an amount effective to reduce the viscosity. | 05-16-2013 |
| 20130130943 | MONO- AND POLYENOIC ACID AND METAL PARTICLE MIXTURES FOR BREAKING VES-GELLED FLUIDS - A method for breaking the viscosity of an aqueous fluid gelled with a viscoelastic surfactant (VES) includes: providing an aqueous fluid; adding to the aqueous fluid, in any order, components comprising: a VES comprising a non-ionic surfactant, cationic surfactant, amphoteric surfactant or zwitterionic surfactant, or a combination thereof, in an amount sufficient to form a gelled aqueous fluid comprising a plurality of elongated micelles, an unsaturated fatty acid comprising a monoenoic acid or a polyenoic acid; or a combination thereof; and a plurality of metallic particles to produce a mixture comprising dispersed metallic particles in the gelled aqueous fluid. The method also includes dissolving the metallic particles in the gelled aqueous fluid to provide a source of metal ions and heating the gelled aqueous fluid to a temperature sufficient to cause the unsaturated fatty acid to auto-oxidize to products present in an amount effective to reduce the viscosity. | 05-23-2013 |
| 20130130948 | METALLIC PARTICLE ACTIVATED OXIDATIVE BREAKING METHOD AND SYSTEM - A method for breaking the viscosity of an aqueous fluid gelled with a water soluble polymer or a VES is disclosed. The method includes providing an aqueous fluid. The method also includes adding to the aqueous fluid, in any order: a water soluble polymer in an amount sufficient to form a gelled aqueous fluid having a viscosity, a water soluble oxidizing agent configured to generate free radicals and a plurality of metallic particles to produce a mixture comprising dispersed metallic particles dispersed within the gelled aqueous fluid, the metallic particles configured to dissolve in the gelled aqueous fluid and provide a reducing agent to accelerate the generation of free radicals. The method further includes dissolving the metallic particles in the gelled aqueous fluid to provide a source of at least one transition metal ion in an amount effective accelerate the generation of free radicals and reduce the viscosity. | 05-23-2013 |
| 20130137610 | Dual-Functional Breaker for Hybrid Fluids of Viscoelastic Surfactant and Polymer - Incorporating water-based polymer breakers, such as oxidizers, enzymes and/or acids, into a mixture of an oil and oil-soluble surfactants creates an emulsion that can then perform as a dual-functional breaker for reducing the viscosity of hybrid fluids gelled with both a viscoelastic surfactant (VES) and a polymer. The outer phase of the dual-functional breaker emulsion is oil, e.g. a mineral oil, containing an oil-soluble surfactant that will, over time and with heat, break the VES portion of the gel. As it does so, the polymer breaker in the internal aqueous phase will be released to then break the polymer portion of the gel. The polymer breaker will not start to break the polymer gel before the oil-soluble surfactant starts to break the VES gel. The overall breaking using the emulsion is slower as compared to introducing the polymer breaker and the oil-soluble surfactant in a non-emulsified form. | 05-30-2013 |
| 20130152824 | ELECTROLYTIC COMPOSITE MATERIALS - A composition comprising a metallic composition, an inorganic oxide-based polymer, and a solvent. A cure product of the metallic composition, inorganic oxide-based polymer, and solvent, the cure product having a network structure, are also disclosed. | 06-20-2013 |
| 20130157906 | Nano-Sized Particle-Coated Proppants for Formation Fines Fixation in Proppant Packs - A fracturing fluid, gravel pack fluid and/or frac pack fluid containing particles such as proppants, gravel and/.or sand, may contain an effective amount of a nano-sized particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The nano-sized particulate additive is optionally bound to the particles with a coating agent such as an oil, alcohol, glycol, glycol ethers, ketones, terpenes, etc. The particle size of the magnesium oxide or other agent may be nanometer scale but may be a larger scale than nanometer but still relatively small, which scale may provide unique particle charges that help fixate the formation fines. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based. | 06-20-2013 |
| 20130178400 | Stabilizing Emulsified Acids for Carbonate Acidizing - Emulsified acids have been used to increase production rates of oil and gas in carbonate reservoirs through acid fracturing and matrix acidizing operations. An emulsifier is used to emulsify the aqueous acid with an oil, usually diesel. Very small particles, such as colloidal clay particles and/or nanoparticles increase the stability of the emulsified acids over an elevated temperature range. | 07-11-2013 |
| 20140014338 | Method of Increasing the Permeability of a Subterranean Formation by Creating a Multiple Fracture Network - The stimulated rock volume (SRV) of a subterranean formation may be increased by pumping viscous fracturing fluid into the formation in a first stage to create or enlarge a primary fracture, decreasing the pumping in order for the fluid to increase in viscosity within the primary fracture, and then continuing to pump viscous fluid into the formation in a second stage. The fluid pumped into the second stage is diverted away from the primary fracture and a secondary fracture is created. The directional orientation of the secondary fracture is distinct from the directional orientation of the primary fracture. The fluid of the first stage may contain a viscosifying polymer or viscoelastic surfactant or may be slickwater. | 01-16-2014 |
| 20140090849 | Methods and Compositions for In Situ Microemulsions - A plurality of first VES micelles may be converted into second VES micelles for subsequent formation of an in situ microemulsion downhole. The in situ microemulsion may include at least a portion of second VES micelles, e.g. spherical micelles, and a first oil-based internal breaker to initially aid in breaking the VES gelled aqueous fluid. The in situ microemulsion may increase the rate of flowback of an internally broken VES treatment fluid, increase the volume of treatment fluid recovered, increase the relative permeability or decrease water saturation of a hydrocarbon stream, e.g. oil, gas, and the like; reduce capillary pressure and water-block in the reservoir; enhance the solubilization and dispersion of VES molecules, internal breakers, and/or internal breaker by-products produced when breaking a VES gel; reduce the interfacial tension and/or the contact angle at the fluid-rock interface, reduce the water/oil interfacial tension, keep the reservoir surfaces water-wet, etc. | 04-03-2014 |
| 20140290937 | SHALE FRACTURE FLOW SIMULATION APPARATUS - An apparatus having conduits, flattened tubing or pipes of varying widths, heights and/or lengths may simulate a network of fractures that may be used to experimentally evaluate the flow of treatment fluids (e.g. fracturing fluids) within narrow, shale-type fractures. The tubing or pipes each have an interior space with a height and a width, and in one non-limiting embodiment the ratio of height/width is at least 10. The conduits may be constructed of flattened tubing or constructed from components designed and engineered to have the correct height/width ratio. The apparatus may be used to empirically develop diversion principles, more precise numeric models and the parameter relationships that control fluid diversion, secondary fracture initiation and the development of complex fracture networks. | 10-02-2014 |
| 20140299318 | METHOD OF INCREASING FRACTURE NETWORK COMPLEXITY AND CONDUCTIVITY - A complex fracture network within a hydrocarbon-bearing subterranean formation is created by first pumping a first fluid into the formation to create or enlarge a primary fracture and then pumping a second fluid into the formation wherein the second fluid contains a viscous material and the first fluid. By diverting the flow of the second flow, a secondary fracture is created having a directional orientation distinct from the directional orientation of the primary fracture. | 10-09-2014 |
| 20140299326 | Method to Generate Diversion and Distribution For Unconventional Fracturing in Shale - Relatively high viscosity materials and methods for introducing them as discrete bodies or masses into relatively low viscosity fluids, such as brine, give fracturing fluids that help control the diversion and distribution of fluids as they are pumped downhole against a subterranean formation, particularly shale, to fracture it. A wide range of relatively viscous materials may be used, including polymers, crosslinked polymers and/or surfactant gels, for instance gels created with viscoelastic surfactants (VESs). Once the fracturing fluids containing these bodies or masses are within the hydraulic fracture, the processes of paths of least resistance, flow deviation, viscous material flow displacement, total fluid diversion, in situ fluid viscosity generation and distribution of delayed release treatment additives may be deployed. | 10-09-2014 |
| 20140326673 | WASTEWATER PURIFICATION WITH NANOPARTICLE-TREATED BED - Nanoparticle-treated particle packs, such as sand beds, may effectively filter and purify liquids such as waste water. When tiny contaminant particles in waste water flow through the particle pack, the nanoparticles will capture and hold the tiny contaminant particles within the pack due to the nanoparticles' surface forces, including, but not necessarily limited to van der Waals and electrostatic forces. Coating agents such as alcohols, glycols, polyols, vegetable oil, and mineral oils may help apply the nanoparticles to the particle surfaces in the filter beds or packs. | 11-06-2014 |
| 20140367117 | AGENTS FOR ENHANCED DEGRADATION OF CONTROLLED ELECTROLYTIC MATERIAL - A method for degrading a downhole article includes exposing the downhole article comprising a controlled electrolytic material to a composition that comprises a reducing agent. The method also includes contacting the downhole article with the reducing agent to degrade the downhole article. Additionally, a composition for degrading a downhole article includes water, chelant, metal ions, and a reducing agent that includes ascorbic acid, erythorbic acid, a derivative thereof, a salt thereof, or a combination thereof. | 12-18-2014 |
| 20140374086 | RECONFIGURABLE DOWNHOLE ARTICLE - A reconfigurable downhole article is disclosed. The article comprises a base material. The article also comprises a removable material disposed on or within the base material that is configured for removal from the base material in response to a wellbore condition, wherein the base material and the removable material define a base article that is configured to perform a first function, and wherein upon removal of the removable material, the base material defines a modified article that is configured to perform a second function that is different than the first function. | 12-25-2014 |
| 20150057197 | Use of Oil-Soluble Surfactants as Breaker Enhancers for VES-Gelled Fluids - Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of an internal breaker composition that contains at least one mineral oil, at least one polyalphaolefin oil, at least one saturated fatty acid and/or at least one unsaturated fatty acid. The internal breaker may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the internal breaker, e.g. mineral oil, is added to the fluid after it has been substantially gelled. An oil-soluble surfactant is present to enhance or accelerate the reduction of viscosity of the gelled aqueous fluid. | 02-26-2015 |
| 20150083416 | METHOD OF USING SURFACE MODIFYING TREATMENT AGENTS TO TREAT SUBTERRANEAN FORMATIONS - A well treatment fluid contains a surface modifying treatment agent having an anchor and a hydrophobic tail. The surface modifying treatment agent is an organophosphorus acid derivative. After the well treatment fluid is pumped into a well penetrating the subterranean formation, the anchor binds to the surface of the formation. The subterranean formation is a siliceous formation or a metal oxide-containing subterranean formation. The anchor bonds to a Si atom when the formation is a siliceous formation and to the metal of the metal oxide when the formation is a metal oxide-containing formation. After being bound to the surface of the formation, frictional drag within the well is reduced. This allows for faster recovery of formation fluids. The bonding of the surface modifying treatment agent onto the formation may further be enhanced by first pre-treating the formation with a non-aqueous fluid. By increasing the number of sites for the surface modifying treatment agent to bind onto the surface of the subterranean formation, productivity is improved. | 03-26-2015 |
| 20150083417 | METHOD OF USING SURFACE MODIFYING METALLIC TREATMENT AGENTS TO TREAT SUBTERRANEAN FORMATIONS - A method of treating a subterranean formation comprises pumping into a well penetrating the formation a surface modifying treatment agent having a metallic anchor and at least one hydrophobic tail attached to the metal of the anchor. The surface modifying treatment agent is covalently bound to the surface of the subterranean formation through the metal of the anchor. | 03-26-2015 |
