Patent application number | Description | Published |
20120255443 | OXYGEN SEPARATION MODULE AND APPARATUS - A module and an apparatus incorporating such module utilizing a plurality of tubular membrane elements, each configured to separate oxygen from an oxygen containing feed stream when an electric potential difference is applied to induce oxygen ion transport in an electrolyte thereof. The tubular membrane elements can be arranged in a bundle that is held in place by end insulating members. The insulating members can be positioned within opposed openings of end walls of a heated enclosure and can incorporate bores to allow an oxygen containing feed stream to flow past exposed ends of the tubular membrane elements for cooling the end seals of such elements. Further, first and second manifolds can be provided in a module in accordance with the present invention to collect separated oxygen from two separate portions of the tubular membrane elements. | 10-11-2012 |
20130009100 | SYNTHESIS GAS METHOD AND APPARATUS - A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube. | 01-10-2013 |
20130009102 | OXYGEN TRANSPORT MEMBRANE SYSTEM AND METHOD FOR TRANSFERRING HEAT TO CATALYTIC/PROCESS REACTORS - A method and apparatus for producing heat used in a synthesis gas production process is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the steam reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5. | 01-10-2013 |
20130072374 | CATALYST CONTAINING OXYGEN TRANSPORT MEMBRANE - A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a microstructure exhibiting substantially uniform pore size distribution as a result of using PMMA pore forming materials or a bi-modal particle size distribution of the porous support layer materials. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer. | 03-21-2013 |
20130072375 | CATALYST CONTAINING OXYGEN TRANSPORT MEMBRANE - A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a microstructure exhibiting substantially uniform pore size distribution as a result of using PMMA pore forming materials or a bi-modal particle size distribution of the porous support layer materials. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer. | 03-21-2013 |
20130084221 | SYNTHESIS GAS METHOD AND APPARATUS - A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube. | 04-04-2013 |
20130220127 | OXYGEN SEPARATION MODULE AND APPARATUS - A module and an apparatus incorporating such module utilizing a plurality of tubular membrane elements, each configured to separate oxygen from an oxygen containing feed stream when an electric potential difference is applied to induce oxygen ion transport in an electrolyte thereof. The tubular membrane elements can be arranged in a bundle that is held in place by end insulating members. The insulating members can be positioned within opposed openings of end walls of a heated enclosure and can incorporate bores to allow an oxygen containing feed stream to flow past exposed ends of the tubular membrane elements for cooling the end seals of such elements. Further, first and second manifolds can be provided in a module in accordance with the present invention to collect separated oxygen from two separate portions of the tubular membrane elements. | 08-29-2013 |
20140044604 | ELECTROCHEMICAL CARBON MONOXIDE PRODUCTION - A method and apparatus for producing a carbon monoxide containing product in which cathode and anode sides of an electrically driven oxygen separation device are contacted with carbon dioxide and a reducing agent, respectively. The carbon dioxide is reduced to carbon monoxide through ionization of oxygen and the reducing agent lowers the partial pressure of oxygen at the anode side to partially drive oxygen ion transport within the device through the consumption of the oxygen and to supply heat. The lowering of oxygen partial pressure reduces voltage and therefore, electrical power required to be applied to the device and the heat is supplied to heat the device to an operational temperature and to the reduction of the carbon dioxide occurring at the cathode side. The device can be used as part of an integrated apparatus in which the carbon dioxide is supplied from a waste stream of a process plant. | 02-13-2014 |
20140056774 | OXYGEN TRANSPORT MEMBRANE SYSTEM AND METHOD FOR TRANSFERRING HEAT TO CATALYTIC/PROCESS REACTORS - A method and apparatus for producing heat used in a synthesis gas production process is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the steam reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5. | 02-27-2014 |
20140219884 | HIGH EMISSIVITY AND HIGH TEMPERATURE DIFFUSION BARRIER COATINGS FOR AN OXYGEN TRANSPORT MEMBRANE ASSEMBLY - An oxygen transport membrane assembly having a coating or overlay system is provided. The overlay or coating system is disposed on the one or more surfaces of the metal containing components within the oxygen transport membrane assembly and comprises a plurality of protective layers providing oxidation resistance, chromium diffusion barrier and high emissivity. The disclosed overlay or coating system may include at least one layer of an aluminum oxide or magnesium-aluminum oxide to provide an effective oxidation resistance and/or chromium diffusion barrier. In addition, the overlay or coating system includes a high emissivity layer such as a high porosity ceramic-oxide layer or an aluminum-phosphate layer including a plurality of carbon encapsulated within the aluminum-phosphate matrix. | 08-07-2014 |
20140311346 | COMPOSITE OXYGEN TRANSPORT MEMBRANE - A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln | 10-23-2014 |