Patent application number | Description | Published |
20080242905 | Alkylaromatics Production Using Dilute Alkene - process for producing an alkylated aromatic product in a reactor by reacting an alkylatable aromatic compound feedstock with another feedstock comprising alkene component and alkane component in a reaction zone containing an alkylation catalyst. The reaction zone is operated in predominantly liquid phase without inter-zone alkane removal. The polyalkylated aromatic compounds can be separated as feed stream for transalkylation reaction in a transalkylation reaction zone. | 10-02-2008 |
20080281137 | Process of Using a High Activity Catalyst for the Transalkylation of Aromatics - A process for producing an alkylated aromatic compound from polyalkylated aromatic compound(s) having bi-alkylated aromatic compound(s) and tri-alkylated aromatic compound(s), comprising the step of contacting alkylatable aromatic compound(s) with the polyalkylated aromatic compound(s) at a transalkylation condition in the presence of a transalkylation catalyst. The transalkylation catalyst has high activity sufficient to achieve a ratio of bi-alkylated aromatic compound(s) conversion over tri-alkylated aromatic compound(s) conversion in a range of from about 0.5 to about 2.5. | 11-13-2008 |
20090036722 | Alkylaromatics production - A process is described for producing an alkylaromatic compound, in which a first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into a first alkylation reaction zone comprising a first alkylation catalyst. The first alkylation reaction zone is operated under conditions effective to cause alkylation of the alkylatable aromatic compound by the alkene to produce said alkylaromatic compound, the conditions being such that the alkylatable aromatic compound is at least predominantly in the vapor phase. A first effluent comprising the alkylaromatic compound and unreacted alkylatable aromatic compound is withdrawn from the first alkylation reaction zone and at least part of the unreacted alkylatable aromatic compound is treated to remove catalyst poisons therefrom and produce a treated unreacted alkylatable aromatic stream. At least part of the unreacted alkylatable aromatic compound and a third feed comprising said alkene is introduced into a second alkylation reaction zone comprising a second alkylation catalyst. The second alkylation reaction zone is operated under conditions effective to cause alkylation of the unreacted alkylatable aromatic compound by the alkene to produce said alkylaromatic compound, the conditions being such that the alkylatable aromatic compound is at least predominantly in the liquid phase. A second effluent comprising said alkylaromatic compound is withdrawn from the second alkylation reaction zone. | 02-05-2009 |
20090137855 | Alkylaromatics Production - A process is described for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene and one or more alkanes are introduced into said first alkylation reaction zone. The operating conditions, e.g. temperature and pressure, of the first alkylation reaction zone are controlled effective to cause the alkylatable aromatic compound to be partly in the vapor phase and partly in the liquid phase, and the ratio of the volume of liquid to the volume of vapor of the feed in each zone to be from about 0.1 to about 10. The aromatic compound and the alkene of the feed are reacted in the presence of the alkylation catalyst to form an effluent comprising the alkylaromatic compound, unreacted alkylatable aromatic compound, any unreacted alkene and the alkane. The effluent is withdrawn from the first alkylation reaction zone and then supplied to the second alkylation reaction zone without removal of the alkane. | 05-28-2009 |
20100069693 | Liquid Phase Alkylation with Multiple Catalysts - A process is disclosed for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones, each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into the first alkylation reaction zone. The first and second alkylation reaction zones are operated under conditions of temperature and pressure effective to cause alkylation of the aromatic compound with the alkene in the presence of the alkylation catalyst, the temperature and pressure being such that the aromatic compound is at least partly in the liquid phase. The alkylation catalyst in the first alkylation reaction zone, which may be a reactor guard bed, has more acid sites per unit volume of catalyst than the alkylation catalyst in the second reaction zone. | 03-18-2010 |
20100191028 | Process for Preparing Ethylbenzene Using Vapor Phase Alkylation and Liquid Phase Transalkylation - Disclosed are ethylbenzene processes in which a series-arranged or combined vapor phase alkylation/transalkylation reaction zone is retrofitted to have a vapor phase alkylation reactor and a liquid phase transalkylation reactor, and in which a parallel-arranged vapor phase alkylation reactor and vapor phase transalkylation reactor is retrofitted to have a vapor phase alkylation reactor and liquid phase transalkylation reactor, wherein the xylenes content of the ethylbenzene product is less than 700 wppm. | 07-29-2010 |
20100249472 | Alkylaromatics Production - A process is described for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene and one or more alkanes are introduced into said first alkylation reaction zone, having operating conditions, e.g., temperature and pressure, which are controlled effective to cause the alkylatable aromatic compound to be partly in the vapor phase and partly in the liquid phase with the ratio of liquid volume to vapor volume of the feed in each zone to be from about 0.5 to about 10. The aromatic compound and the alkene are reacted in the presence of the alkylation catalyst to form an effluent comprising the alkylaromatic compound, unreacted alkylatable aromatic compound, any unreacted alkene and the alkane, which is withdrawn and then supplied to the second alkylation reaction zone without removal of the alkane. | 09-30-2010 |
20110160506 | Alkylaromatics Production Using Dilute Alkene - A process for producing an alkylated aromatic product in a reactor by reacting an alkylatable aromatic compound feedstock with another feedstock comprising alkene component and alkane component in a reaction zone containing an alkylation catalyst. The reaction zone is operated in predominantly liquid phase without inter-zone alkane removal. The polyalkylated aromatic compounds can be separated as feed stream for transalkylation reaction in a transalkylation reaction zone. | 06-30-2011 |
20110178352 | Process For Preparing Ethylbenzene Using Vapor Phase Alkylation And Liquid Phase Transalkylation - Disclosed are ethylbenzene processes in which a series-arranged or combined vapor phase alkylation/transalkylation reaction zone is retrofitted to have a vapor phase alkylation reactor and a liquid phase transalkylation reactor, and in which a parallel-arranged vapor phase alkylation reactor and vapor phase transalkylation reactor is retrofitted to have a vapor phase alkylation reactor and liquid phase transalkylation reactor, wherein the xylenes content of the ethylbenzene product is less than 700 wppm. | 07-21-2011 |
20110224469 | Alkylated Aromatics Production - Disclosed is a process for the production of alkylated aromatics by contacting a feed stream comprising an alkylatable aromatic, an alkylating agent and trace amounts of water and impurities in the presence of first and second alkylation catalysts wherein the water and impurities are removed in order to improve the cycle length of such alkylation catalysts. Water and a portion of impurities are removed in a dehydration zone. A first alkylation zone having a first alkylation catalyst which, in some embodiments is a large pore molecular sieve, acts to remove a larger portion of impurities, such as nitrogenous and other species, and to alkylate a smaller portion of the alkylatable aromatic compound. A second alkylation zone, which in some embodiments is a medium pore molecular sieve, acts to remove a smaller portion of impurities, and to alkylate a larger portion of the alkylatable aromatic compound. | 09-15-2011 |
20130137910 | Alkylation Process - The present invention provides an improved process for the catalytic conversion of a feedstock comprising an alkylatable aromatic compound and an alkylating agent to form a conversion product comprising the desired alkylaromatic compound by contacting said feedstock in at least partial liquid phase under catalytic conversion conditions with a catalyst composition comprising a porous crystalline material having a structure type of FAU, BEA* or MWW, or a mixture thereof, wherein the porous crystalline material has a Relative Activity measured at 220° C. as an RA | 05-30-2013 |
20140135548 | Alkylated Aromatics Production - Disclosed is a process for the production of alkylated aromatics by contacting a feed stream comprising an alkylatable aromatic, an alkylating agent and trace amounts of water and impurities in the presence of a first catalyst and an alkylation catalyst wherein such water and impurities are removed in order to improve the cycle length of such alkylation catalysts. Water and at least a portion of impurities are removed in a dehydration zone. A reaction zone having a first catalyst which, in some embodiments is a large pore molecular sieve, acts to remove another portion of impurities, such as nitrogenous and other species. An alkylation zone having an alkylation catalyst which, in some embodiments is a medium pore molecular sieve or a MCM-22 family material, acts to remove additional impurities, and to alkylate the alkylatable aromatic compound. | 05-15-2014 |