Patent application number | Description | Published |
20080236451 | WELLBORE SERVICING COMPOSITIONS - A wellbore servicing comprising a calcium aluminate cement and at least one gelation inhibitor wherein the calcium aluminate cement comprises less than about 50 wt. % alumina, greater than about 2 wt. % iron oxide, or both. A wellbore servicing composition comprising calcium aluminate cement and a gelation inhibitor, wherein the gelation inhibitor comprises a copolymer comprising one or more sulfonated aromatic monomers and one or more acrylate monomers. A wellbore servicing composition comprising calcium aluminate cement and a gelation inhibitor, wherein the gelation inhibitor comprises a copolymer comprising alkylbenzene sulfonic acid, at least one methallyl sulfonic acid monomer; at least one copolymerizable nonionic monomer, and at least one copolymerizable olefinically unsaturated carboxylic acid monomer. | 10-02-2008 |
20080236826 | METHODS OF USING WELLBORE SERVICING COMPOSITIONS - A method of servicing a wellbore comprising placing in the wellbore a composition comprising a calcium aluminate cement and at least one gelation inhibitor, and allowing the composition to set. A method of servicing a wellbore comprising adjusting the thickening time of calcium aluminate cement by contacting the cement with a salt and a gelation inhibitor, wherein the gelation inhibitor comprises a copolymer comprising one or more sulfonated aromatic monomers and one or more acrylate monomers, placing the cement in the wellbore, and allowing the cement to set. A method of servicing a wellbore comprising preventing premature gelation of calcium aluminate cement by contacting the calcium aluminate cement with a gelation inhibitor comprising a copolymer, wherein the copolymer comprises alkylbenzene sulfonic acid, at least one methallyl sulfonic acid monomer, at least one copolymerizable nonionic monomer, and at least one copolymerizable olefinically unsaturated carboxylic acid monomer, placing the cement in the wellbore, and allowing the cement to set. | 10-02-2008 |
20080280786 | DEFOAMER/ANTIFOAMER COMPOSITIONS AND METHODS OF USING SAME - A method of servicing a wellbore comprising contacting a solid defoamer/antifoamer composition with a wellbore servicing fluid, wherein the solid defoamer/antifoamer composition comprises at least one water-insoluble compound or slightly water-soluble compound having defoaming/antifoaming activity and at least one emulsifier, and placing the wellbore servicing fluid in the wellbore. | 11-13-2008 |
20080300149 | Polysaccharide based cement additives - A composition comprising a carboxylated, sulfonated polysaccharide and a wellbore servicing fluid. A wellbore servicing composition comprising a hydraulic cement and a carboxylated, sulfonated polysaccharide. A wellbore servicing composition comprising a polysaccharide having carboxylate and sulfonate groups. | 12-04-2008 |
20080300150 | Methods of using polysaccharide based cement additives - A method of servicing a wellbore comprising introducing to the wellbore a wellbore servicing fluid comprising an additive composition comprising a polysaccharide having carboxylate and sulfonate groups. A method of servicing a wellbore comprising preparing at the well site an additive composition comprising a polysaccharide having carboxylate and sulfonate groups,introducing the additive composition into a wellbore servicing fluid, and placing the wellbore servicing fluid into a subterranean formation. A method of preparing a wellbore servicing fluid comprising contacting a polysaccharide composition with an oxidizing agent to form an oxidized polysaccharide, and contacting the oxidized polysaccharide with a sulfonating agent to form a carboxylated sulfonated polysaccharide, and contacting the carboxylated sulfonated polysaccharide with a wellbore servicing fluid. | 12-04-2008 |
20090038855 | Variable Density Fluids and Methods of Use in Subterranean Formations - Herein provided are variable density fluid compositions and methods for using such compositions in a subterranean formation. One exemplary embodiment of the variable density fluid compositions of the present invention comprises a variable density fluid comprising: a base fluid; and a portion of elastic particles, the elastic particles having an isothermal compressibility factor in the range of from about 1.5×10 | 02-12-2009 |
20090120642 | METHODS TO ENHANCE GAS PRODUCTION FOLLOWING A RELATIVE-PERMEABILITY-MODIFIER TREATMENT - Provided embodiments relate to introducing a water-drainage-rate-enhancing agent into a subterranean formation to enhance gas production following a relative-permeability-modifier treatment to decrease undesired water production. An exemplary embodiment provides a method of treating a subterranean formation such that initiation of gas production is enhanced following the treatment, the method comprising: introducing a relative-permeability modifier into at least a portion of the subterranean formation such that the relative-permeability modifier reduces permeability of the portion to aqueous fluids; and introducing a water-drainage-rate-enhancing agent into at least a portion of the subterranean formation. Another exemplary embodiment provides a treatment fluid comprising a carrier fluid, a relative-permeability modifier, and a water-drainage-rate-enhancing agent. | 05-14-2009 |
20090133606 | Cement Compositions Comprising High Aspect Ratio Materials and Methods of Use in Subterranean Formations - The present invention relates to subterranean well cementing operations, and more particularly, to cement compositions that include high aspect ratio materials, and methods for using such cement compositions in subterranean formations. An example of a method of the present invention is a method of cementing in a subterranean formation. An example of a composition of the present invention is a cement composition for use in a subterranean formation. | 05-28-2009 |
20090137431 | Oilwell sealant compositions comprising alkali swellable latex - Sealant compositions comprising an alkali swellable latex and a pH increasing material and methods of using the same to service a wellbore are provided. In one embodiment, the sealant composition can be used in a wellbore and includes an alkali swellable latex and a pH increasing material. The sealant composition can have a pH of from about 7 to about 14. In other embodiments, the pH increasing material includes a base-producing material. The base-producing material can include alkali and alkali earth metal carbonates, alkali and alkali earth metal bicarbonates, alkali and alkali earth metal hydroxides, alkali and alkali earth metal oxides, alkali and alkali earth metal phosphates, alkali and alkali earth metal hydrogen phosphates, alkali and alkaline earth metal sulphides, alkali and alkaline earth metal salts of silicates, alkali and alkaline earth metal salts of aluminates, water soluble or water dispersible organic amines, polymeric amine, amino alcohols, or combinations thereof. | 05-28-2009 |
20090145602 | Cement compositions comprising crystalline organic materials and methods of using same - A method of servicing a wellbore comprising placing a composition comprising cement, water, and a heat sink material into a wellbore, and allowing the composition to set, wherein at least a portion of the heat sink material undergoes a phase transition by absorbing at least a portion of the heat released upon hydration of the cement. A method of completing a wellbore, comprising forming a wellbore in a subterranean formation comprising permafrost, gas hydrates, or both, preparing a cement composition comprising cement, water, and a heat sink material, placing the cement composition into an annulus formed between a casing and the wellbore, and allowing the composition to set, wherein at least a portion of the heat sink material undergoes a phase transition by absorbing at least a portion of the heat released upon hydration of the cement, thereby reducing an amount of heat transferred from the annular cement to the surrounding permafrost and/or gas hydrates. | 06-11-2009 |
20090163388 | Variable Density Treatment Fluids - The present invention provides variable density fluid compositions and methods for using such compositions in a subterranean formation. One exemplary embodiment of the variable density fluid compositions of the present invention comprises a variable density fluid comprising: a base fluid, and a portion of variable pressure weighting material particles. | 06-25-2009 |
20090181866 | Methods and compositions for altering the viscosity of treatment fluids used in subterranean operations - An embodiment of the present invention includes a method comprising introducing a cyclodextrin modifier into a well bore penetrating a subterranean formation. Another embodiment of the present invention includes a method of reducing viscosity of a treatment fluid comprising contacting a treatment fluid comprising a base fluid and a viscosifying agent with at least a cyclodextrin modifier wherein the cyclodextrin modifier interacts with the viscosifying agent to reduce viscosity of the treatment fluid. Another embodiment of the present invention includes a method of increasing viscosity of an aqueous fluid comprising contacting at least a hydrophobically modified polymer and a cyclodextrin modifier in the presence of at least the aqueous fluid, wherein the cyclodextrin modifier interacts with the hydrophobically modified polymer to viscosify the aqueous fluid. Another embodiment of the present invention includes a subterranean treatment fluid comprising a base fluid and a cyclodextrin modifier. | 07-16-2009 |
20090188670 | Additives for High Alumina Cements and Associated Methods - The present invention includes methods and compositions that include a composition comprising a high alumina cement; a salt comprising at least one salt selected from the group consisting of an acidic salt, a neutral salt, and a low basicity salt; and a swellable clay; and methods of using that composition in subterranean formations. | 07-30-2009 |
20090266543 | Gelation Inhibiting Retarders for Highly Reactive Calcium Silicate Based Binder Compositions and Methods of Making and Using Same - A method of servicing a wellbore comprising placing in the wellbore a composition comprising a non-API compliant reactive calcium silicate based hydraulic binder and at least one gelation inhibiting retarder, and allowing the composition to set. A method of servicing a wellbore comprising placing in a wellbore a cement composition comprising an industrial waste product selected from the group consisting of Class C Fly ash, cement kiln dust, and combinations thereof and a gelation inhibitor, and allowing the composition to set. A method of controlling the thickening time of a cementitious composition comprising contacting a material having greater than 15 wt. % of tricalcium aluminate and tetracalcium aluminoferrite with a gelation inhibitor comprising a alkylbenzene sulfonic acid, at least one methallyl sulfonic acid monomer; at least one copolymerizable nonionic monomer, and at least one copolymerizable olefinically unsaturated carboxylic acid monomer. | 10-29-2009 |
20100035772 | Sealant compositions comprising solid latex - A wellbore sealant composition including a modified latex and a cross-linking agent, wherein the modified latex has undergone a dry particulate state, the modified latex is present in an amount of from 5% to 50% by total weight of the composition, and the modified latex is prepared by removing water from an emulsion polymerized latex system. | 02-11-2010 |
20100095871 | Cement Compositions Comprising Sub-Micron Alumina and Associated Methods - Methods and compositions that comprise sub-micron alumina for accelerating setting of a cement composition. An embodiment includes a method of cementing in a subterranean formation. The method may comprise introducing a cement composition into the subterranean formation, wherein the cement composition comprises hydraulic cement, sub-micron alumina, and water. The method further may comprise allowing the cement composition to set in the subterranean formation. Another embodiment includes a cement composition that may comprise hydraulic cement, sub-micron alumina, and water. | 04-22-2010 |
20100116170 | Cement compositions comprising crystalline organic materials and methods of using same - A method of servicing a wellbore comprising placing a composition comprising cement, water, and a heat sink material into a wellbore, and allowing the composition to set, wherein at least a portion of the heat sink material undergoes a phase transition by absorbing at least a portion of the heat released upon hydration of the cement. A method of completing a wellbore, comprising forming a wellbore in a subterranean formation comprising permafrost, gas hydrates, or both, preparing a cement composition comprising cement, water, and a heat sink material, placing the cement composition into an annulus formed between a casing and the wellbore, and allowing the composition to set, wherein at least a portion of the heat sink material undergoes a phase transition by absorbing at least a portion of the heat released upon hydration of the cement, thereby reducing an amount of heat transferred from the annular cement to the surrounding permafrost and/or gas hydrates. | 05-13-2010 |
20100116497 | Method of servicing a wellbore with a sealant composition comprising solid latex - A method of servicing a wellbore comprising placing a sealant composition comprising solid latex into the wellbore. | 05-13-2010 |
20100323929 | Methods for Treating a Well with a Cross-Linked Water-Soluble Polymer-Complexed Metal Cation Network and an Aromatic Compound Capable of Forming a Chelating Agent to Uncross-Link the Polymer - Methods are provided for treating a portion of a well. The method according to this aspect comprises the steps of: (A) forming a treatment fluid, the treatment fluid comprising: (i) water; (ii) a water-soluble polymer; (iii) a complexed metal cation that: (a) has a valence state of at least three; and (b) is capable of cross-linking the water-soluble polymer; and (iv) an aromatic compound that is capable of dissolving, melting, or chemically decomposing, dissociating, or reacting, to form a chelating agent, wherein the chelating agent comprising vicinal substituents containing donor heteroatoms, and wherein the chelating agent is capable of chelating the metal cation; and (B) introducing the treatment fluid into the well. | 12-23-2010 |
20110034351 | Hydrophobically and Cationically Modified Relative Permeability Modifiers and Associated Methods - Methods and compositions including a method comprising introducing a hydrophobically and cationically modified relative permeability modifier into a portion of a subterranean formation, wherein the hydrophobically and cationically modified relative permeability modifier comprises a hydrophilic polymer backbone with a hydrophobic modification and a cationic modification. | 02-10-2011 |
20110067864 | Compositions for Improving Thermal Conductivity of Cement Systems - The present invention relates to methods of cementing in subterranean formations and associated compositions. A method of cementing in a subterranean formation comprises placing a cement composition comprising a non-metallic thermally conductive fiber into the subterranean formation, and allowing the composition to set therein, wherein the non-metallic thermally conductive fiber has a thermal conductivity greater than about 500 W/m·K. Another method of cementing in a subterranean formation comprises providing a cement composition comprising a pitch-based carbon fiber, a hydraulic cement material, and water, placing the cement composition in a formation, and allowing the cement composition to set therein, wherein said pitch-based carbon fiber has a density of from about 2.0 grams/cc to about 2.3 grams/cc. A cement composition comprising a cementitious material, water, and a non-metallic thermally conductive fiber having a thermal conductivity greater than about 500 W/m·K, or a pitch-based carbon fiber having a density of from about 2.0 grams/cc to about 2.3 grams/cc. | 03-24-2011 |
20110067867 | Wellbore Servicing Fluid Compositions and Use Thereof - A method of servicing a wellbore in contact with a subterranean formation comprising placing a wellbore servicing fluid comprising a polyuronide polymer within the wellbore, contacting the wellbore servicing fluid with a divalent ion source, and allowing the wellbore servicing fluid to form a gel within the wellbore wherein the divalent ion source is located within the wellbore. A method of servicing a wellbore in contact with a subterranean formation comprising (a) placing a wellbore servicing fluid comprising a polyuronide polymer into the wellbore wherein the wellbore servicing fluid contacts a calcium ion source, (b) shutting the wellbore and allowing the servicing fluid to set into place for a period of time, and (c) repeating steps (a) and (b) until the permeability of a structure within the wellbore is reduced by about 50%. | 03-24-2011 |
20110094742 | Casing Shoes and Methods of Reverse-Circulation Cementing of Casing - A method having the following steps: running a circulation valve comprising a reactive material into the well bore on the casing; reverse-circulating an activator material in the well bore until the activator material contacts the reactive material of the circulation valve; reconfiguring the circulation valve by contact of the activator material with the reactive material; and reverse-circulating a cement composition in the well bore until the reconfigured circulation valve decreases flow of the cement composition. A circulation valve for cementing casing in a well bore, the valve having: a valve housing connected to the casing and comprising a reactive material; a plurality of holes in the housing, wherein the plurality of holes allow fluid communication between an inner diameter of the housing and an exterior of the housing, wherein the reactive material is expandable to close the plurality of holes. | 04-28-2011 |
20110105369 | WELL TREATMENT FLUIDS CONTAINING A VISCOELASTIC SURFACTANT AND A CROSS-LINKING AGENT COMPRISING A WATER-SOLUBLE TRANSITION METAL COMPLEX - The invention is directed to methods for treating a portion of a well. The methods include the steps of: (A) forming a viscoelastic treatment fluid, wherein the treatment fluid comprises: (i) water; (ii) a viscoelastic surfactant (“VES”), wherein the VES is soluble in the water and wherein the VES is in the form of micelles; and (iii) a cross-linking agent for the VES molecules, wherein: (a) the cross-linking agent comprises cross-linking agent molecules having at least one complexed transition metal, wherein the transition metal has a valence state of at least three; and (b) the cross-linking agent is soluble in the water; and (B) introducing the treatment fluid into a portion of the well. According to a first aspect of the invention, (a) the VES comprises VES molecules having an alkyl group of greater than 14 carbon atoms and (b) the VES comprises VES molecules having at least one functional group selected from a carboxylate group, an amino group, an alcohol group, and an ether group. According to a second aspect of the invention, the VES comprises VES molecules having both an alkyl group of greater than 14 carbon atoms and at least one functional group selected from a carboxylate group, an amino group, an alcohol group, and an ether group. | 05-05-2011 |
20110114318 | Compositions and systems for combatting lost circulation and methods of using the same - A method of servicing a wellbore in a subterranean formation comprising preparing a composition comprising a base fluid, a thixotropic viscosifier, a gellable composition and a bridging material, applying a shear force to the composition such that the composition viscosity decreases, introducing the composition into a lost circulation zone in the subterranean formation, wherein the lost circulation zone comprises cavities greater than about 200 microns in diameter, decreasing the shear force applied to the composition, and allowing the composition to set in the lost circulation zone. A method of servicing a wellbore in a subterranean formation comprising placing a first stream comprising a dilute solution of a metal acrylate into a lost circulation zone in the subterranean formation, placing a second stream comprising an activator into the lost circulation zone, and forming a lost circulation material upon contacting of the metal acrylate and the activator, wherein the lost circulation material forms in from about 0 to about 60 minutes. | 05-19-2011 |
20110214865 | WEAK ORGANIC ACID AS GELATION RETARDER FOR CROSSLINKABLE POLYMER COMPOSITIONS - According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a weak organic acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition. According to another embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated; (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming a treatment fluid that is a crosslinkable polymer composition comprising: (i) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (ii) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (iii) a weak organic acid; and (iv) water; (d) selecting the water-soluble polymer, the crosslinker, the weak organic acid, and the water, and the proportions thereof, such that the gelation time of the treatment fluid is at least 1 hour when tested under the estimated treatment conditions; and (e) injecting the treatment fluid through the wellbore into the portion of the subterranean formation. | 09-08-2011 |
20110214866 | SALT OF WEAK BRONSTED BASE AND BRONSTED ACID AS GELATION RETARDER FR CROSSLINKABLE POLYMER COMPOSITIONS - According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a salt of a weak Bronsted base and a Bronsted acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition. According to another embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated; (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming a treatment fluid that is a crosslinkable polymer composition comprising: (i) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (ii) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (iii) a salt of a weak Bronsted base and a Bronsted acid; and (iv) water; (d) selecting the water-soluble polymer, the crosslinker, the salt of a weak Bronsted base and a Bronsted acid, and the water, and the proportions thereof, such that the gelation time of the treatment fluid is at least 1 hour when tested under the estimated treatment conditions; and (e) injecting the treatment fluid through the wellbore into the portion of the subterranean formation. | 09-08-2011 |
20110214867 | LEWIS ACID AS GELATION RETARDER FOR CROSSLINKABLE POLYMER COMPOSITIONS - According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a Lewis acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition. According to another embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated; (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming a treatment fluid that is a crosslinkable polymer composition comprising: (i) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (ii) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (iii) a Lewis acid; and (iv) water; (d) selecting the water-soluble polymer, the crosslinker, the Lewis acid, and the water, and the proportions thereof, such that the gelation time of the treatment fluid is at least 1 hour when tested under the estimated treatment conditions; and (e) injecting the treatment fluid through the wellbore into the portion of the subterranean formation. | 09-08-2011 |
20110294704 | Permeability-Modifying Drilling Fluids and Methods of Use - Methods of reducing the permeability of a subterranean formation to aqueous-based fluids using a water-soluble relative permeability modifier that comprises a hydrophobically modified polymer, wherein the hydrophobically modified polymer is a reaction product of: a hydrophilic polymer that comprises a polymer selected from the group consisting of a polyvinylamine, a poly(vinylamine/vinyl alcohol), and an alkyl acrylate polymer; and, a hydrophobic compound comprising at least one alkyl chain having a carbon chain length between about 4 and about 22 carbons. The water-soluble relative permeability modifier may be placed within a subterranean drilling operation such that the water-soluble relative permeability modifier attaches onto surfaces within the subterranean formation to effect permeability of aqueous fluids. | 12-01-2011 |
20110297378 | Wellbore servicing compositions and methods of making and using same - A method of servicing a wellbore in a subterranean formation comprising preparing a wellbore servicing fluid comprising cement, water and a polyuronide polymer, placing the wellbore servicing fluid in the wellbore, and allowing the wellbore servicing fluid to set. A method of servicing a wellbore in a subterranean formation comprising preparing a wellbore servicing fluid comprising a highly methylated pectin, cementitious material and water into the wellbore, placing the wellbore servicing fluid in the wellbore, and allowing the wellbore servicing fluid to set. A wellbore servicing fluid comprising cement, water and a polyuronide polymer. | 12-08-2011 |
20120090841 | Wellbore cementing compositions and methods of making and using same - A method of cementing a wellbore comprising preparing a wellbore cementing composition comprising a cementitious materials and a modified biopolymer additive wherein the modified biopolymer additive is the reaction product of a process comprising contacting a biopolymer and an organic carbonate to form a reaction mixture and subjecting the reaction mixture to a temperature of from about 100° F. to about 250° F. and placing the wellbore cementing fluid in the wellbore. A method of cementing a wellbore comprising contacting a modified biopolymer additive with a cementitious slurry to produce a wellbore cementing composition having an initial viscosity, v | 04-19-2012 |
20120090846 | MODIFICATION OF SOLID POLYSACCHARIDE WITH TRANSESTERIFICATION AGENT - Polysaccharides, for example xanthan, diutan, scleroglucan, gums, celluloses, and starches, and derivatives of the foregoing, are reacted with organic carbonates forming products that: (1) have increased viscosifying efficiency, i.e., higher viscosities at reduced concentrations compared to the unmodified polysaccharide; or (2) are insolubilized at temperature ranges for which the unmodified polysaccharide would hydrate fully; or (3) both properties. In some cases, the insolubilized polysaccharides can be activated to dissolve and viscosify at specific temperature ranges by using pH modifiers. A method of treating a well is provided, including the steps of: (a) obtaining a modified polysaccharide characterized by having been made by the process of combining: (i) a water-soluble polysaccharide, wherein the polysaccharide is in a solid form during the combining step; and (ii) a transesterification agent, wherein the transesterification agent is in liquid form; wherein the step of combining is in the presence of less than 10% by weight water relative to the water-soluble polysaccharide and wherein any water present is at a pH of 8 or less; (b) forming a treatment fluid comprising the modified polysaccharide and water; and (c) introducing the treatment fluid into the well. | 04-19-2012 |
20120090848 | MODIFICATION OF SOLID POLYSACCHARIDE WITH TRANSESTERIFICATION AGENT - Polysaccharides are reacted with transesterification agents forming modified products that: (1) have increased viscosifying efficiency, i.e., higher viscosities at reduced concentrations compared to the unmodified polysaccharide; or (2) are insolubilized at temperature ranges for which the unmodified polysaccharide would hydrate fully; or (3) both properties. In some cases, the insolubilized polysaccharides can be activated to dissolve and viscosify at specific temperature ranges by using pH modifiers. A method of treating a well is provided, including the steps of: (a) forming a treatment fluid comprising water and a modified polysaccharide, wherein the modified polysaccharide is characterized by having been made by the process of combining: (i) a water-soluble polysaccharide, wherein the polysaccharide is in a solid form during the combining step; and (ii) a transesterification agent, wherein the transesterification agent is in liquid form; wherein the step of combining is in the presence of less than 10% by weight water relative to the water-soluble polysaccharide and wherein any water present is at a pH of 8 or less; and (b) introducing the treatment fluid into the well. | 04-19-2012 |
20120111564 | Methods and Compositions for Altering the Viscosity of Treatment Fluids Used in Subterranean Operations - Methods of decreasing the viscosity of a treatment fluid through contact with a cyclodextrin modifier. Such methods include providing a cyclodextrin modifier; providing a treatment fluid that comprises a base fluid and a viscosifying agent wherein the viscosifying agent is selected from the group consisting of a hydrophobically modified polymer, a viscoelastic surfactant, a phosphonate surfactant, or a combination thereof; and, introducing the cyclodextrin modifier and the treatment fluid into a well bore penetrating a subterranean formation wherein the viscosity of the treatment fluid is decreased due to the combination of the hydrophobically modified polymer and the cyclodextrin modifier. | 05-10-2012 |
20120138299 | Wellbore servicing compositions comprising a fluid loss agent and methods of making and using same - A method of servicing a wellbore comprising preparing a composition comprising a calcium aluminate cement, water, and a fluid loss additive wherein the fluid loss additive comprises an acid gelling polymer, placing the composition in the wellbore, and allowing the composition to set. A method of servicing a wellbore comprising placing into a wellbore having a bottom hole static temperature of greater than about 50° F. and/or a pH of from about 3 to about 9 a cement slurry comprising a calcium aluminate cement having an aluminum oxide content of greater than about 60 wt. % based on the total weight of the calcium aluminate cement and an acid-gelling polymer wherein the cement slurry has a fluid loss at 10 cc/10 min. to about 600 cc/30 min. | 06-07-2012 |
20120168166 | Methods Useful for Diverting Aqueous Fluids in Subterranean Operations - Method of diverting fluids in a subterranean formation including the steps of providing a first fluid comprising an aqueous fluid and a hydrophobically modified water-soluble relative permeability modifier; introducing the first fluid into a well bore such that the first treatment fluid penetrates into a portion of the subterranean formation in a sufficient amount so as to substantially divert a second treatment fluid to another portion of the subterranean formation. Then, a second aqueous fluid is introduced into the well bore and substantially diverted from the portion of the subterranean formation penetrated with the first treatment fluid. In some cases, a well treatment operation, such as acid stimulation operation, a clay stabilization operation, or a scale inhibition operation, is performed using the second fluid. | 07-05-2012 |
20120180698 | Biodegradable Retarder for Cementing Applications - Cement compositions comprising carboxylated inulin and methods of using the same to cement a workspace. In one embodiment, a method of cementing includes providing a cement composition comprising a carboxylated inulin, for example, in a subterranean formation. The method further includes allowing the cement composition to set. In some embodiments, the cement composition has a thickening time of from about 2 hours to about 11 hours. In other embodiments, the cement composition has a viscosity that is about constant for a period of time after the cement composition is placed. | 07-19-2012 |
20120190769 | Cement Compositions Comprising Sub-Micron Alumina and Associated Methods - Methods and compositions that comprise sub-micron alumina for accelerating setting of a cement composition. An embodiment includes a method of cementing in a subterranean formation. The method may comprise introducing a cement composition into the subterranean formation, wherein the cement composition comprises hydraulic cement, sub-micron alumina, and water. The method further may comprise allowing the cement composition to set in the subterranean formation. Another embodiment includes a cement composition that may comprise hydraulic cement, sub-micron alumina, and water. | 07-26-2012 |
20120196777 | Variable Pressure Weighting Material Particles - Variable pressure weighting material particles that include a hollow, elastically deformable particle which itself comprises a wall and an internal fluid at a pressure of 15 psi to about 100 psi. The variable pressure weighting material particles generally include a hollow, elastically deformable particle that compresses during introduction into a subterranean formation and returns to substantially the same shape when removed from the subterranean formation. | 08-02-2012 |
20120205577 | Compositions for Improving Thermal Conductivity of Cement Systems - A method of cementing in a subterranean formation comprises placing a cement composition comprising a non-metallic thermally conductive fiber into the subterranean formation, and allowing the composition to set therein, wherein the non-metallic thermally conductive fiber has a thermal conductivity greater than about 500 W/m.K. Another method of cementing in a subterranean formation comprises providing a cement composition comprising a pitch-based carbon fiber, a hydraulic cement material, and water, placing the cement composition in a formation, and allowing the cement composition to set therein, wherein said pitch-based carbon fiber has a density of from about 2.0 grams/cc to about 2.3 grams/cc. A cement composition comprising a cementitious material, water, and a non-metallic thermally conductive fiber having a thermal conductivity greater than about 500 W/m.K, or a pitch-based carbon fiber having a density of from about 2.0 grams/cc to about 2.3 grams/cc. | 08-16-2012 |
20120214712 | Methods of Using Polysaccharide Based Cement Additives - A method of servicing a wellbore comprising introducing to the wellbore a wellbore servicing fluid comprising an additive composition comprising a polysaccharide having carboxylate and sulfonate groups. A method of servicing a wellbore comprising preparing at the well site an additive composition comprising a polysaccharide having carboxylate and sulfonate groups, introducing the additive composition into a wellbore servicing fluid, and placing the wellbore servicing fluid into a subterranean formation. A method of preparing a wellbore servicing fluid comprising contacting a polysaccharide composition with an oxidizing agent to form an oxidized polysaccharide, and contacting the oxidized polysaccharide with a sulfonating agent to form a carboxylated sulfonated polysaccharide, and contacting the carboxylated sulfonated polysaccharide with a wellbore servicing fluid. | 08-23-2012 |
20120231978 | Permeability-Modifying Drilling Fluids and Methods of Use - Drilling fluids comprising a base fluid and a hydrophobically modified polymer. The hydrophobically modified polymer consisting of alkyl chains having a carbon chain length between about 4 and about 22 carbons bound to a hydrophilic polymer. The hydrophilic polymer (1) consists of a polymer backbone that contains polar heteroatoms, at least one of which is not a nitrogen atom, and at least a portion of the polar heteroatoms are functionalized with the alkyl chains; and, (2) comprises at least one hydrophilic polymer selected from the group consisting of a cellulose, a chitosan, a polyetheramine, a polyhydroxyetheramine, a polylysine, and a polysulfone. | 09-13-2012 |
20120258894 | Treatment Fluids Containing a Relative Permeability Modifier and a Companion Polymer Interacting Synergistically Therewith and Methods for Use Thereof - Methods and compositions are described for treating water- and hydrocarbon-producing subterranean formations with a relative permeability modifier at concentrations below those conventionally used in the art, while not substantially impacting the treatment fluid's performance. Treatment fluids described herein comprise a base fluid, a relative permeability modifier comprising a hydrophobically modified hydrophilic polymer, and a companion polymer interacting synergistically with the relative permeability modifier such that the treatment fluid is operable to reduce the water permeability or to increase an aqueous fluid injection pressure of at least a portion of a subterranean formation by more than the relative permeability modifier or the companion polymer acting alone at like concentration. The water permeability reduction and/or the aqueous fluid injection pressure increase can be more than additive. Methods described herein comprise placing such treatment fluids in at least a portion of a subterranean formation. | 10-11-2012 |
20120279708 | SALT OF WEAK BRONSTED BASE AND BRONSTED ACID AS GELATION RETARDER FR CROSSLINKABLE POLYMER COMPOSITIONS - According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a salt of a weak Bronsted base and a Bronsted acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition. According to another embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated; (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming a treatment fluid that is a crosslinkable polymer composition comprising: (i) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (ii) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (iii) a salt of a weak Bronsted base and a Bronsted acid; and (iv) water; (d) selecting the water-soluble polymer, the crosslinker, the salt of a weak Bronsted base and a Bronsted acid, and the water, and the proportions thereof, such that the gelation time of the treatment fluid is at least 1 hour when tested under the estimated treatment conditions; and (e) injecting the treatment fluid through the wellbore into the portion of the subterranean formation. | 11-08-2012 |
20120298357 | Compositions and systems for combatting lost circulation and methods of using the same - A method of servicing a wellbore in a subterranean formation comprising placing a first stream comprising a dilute solution of a metal acrylate into a lost circulation zone in the subterranean formation; placing a second stream comprising an activator into the lost circulation zone; and forming a lost circulation material upon contacting of the metal acrylate and the activator, wherein the lost circulation material forms in from about 0 to about 60 minutes. A method of servicing a wellbore in a subterranean formation comprising placing a composition comprising a dilute solution of a cross-linkable material and an encapsulated activator into a lost circulation zone in the subterranean formation; and allowing the composition to set. | 11-29-2012 |
20130000905 | Gellable Treatment Fluids Comprising Amino Group Gel-Time Modifiers and Methods for Use Thereof - Methods for reducing the amount of water produced from a subterranean formation can include the use of a gellable treatment fluid that comprises a gel-time modifier comprising at least one amino group. The gellable treatment fluids can comprise an aqueous base fluid, a base polymer comprising an acrylamide monomer unit, an organic crosslinking agent, and a get-time modifier comprising at least one amino group. | 01-03-2013 |
20130000911 | Gellable Treatment Fluids Comprising Quaternary Ammonium Salt Gel-Time Modifiers and Methods for Use Thereof - Methods for reducing the amount of water produced from a subterranean formation can include the use of a gellable treatment fluid that comprises a quaternary ammonium salt as a gel-time modifier. The gellable treatment fluids can comprise an aqueous base fluid, a base polymer comprising an acrylamide monomer unit, an organic crosslinking agent, and a gel-time modifier comprising a quaternary ammonium salt. | 01-03-2013 |
20130041068 | METHODS FOR CEMENTING IN A SUBTERRANEAN FORMATION USING A CEMENT COMPOSITION CONTAINING A SET RETARDER OF A POLYESTER - According to an embodiment, a cement composition for use in an oil or gas well, the cement composition comprises: cement; water; and a polymer, wherein the polymer: (i) comprises a monomer or monomers capable of forming a polyester; and (ii) is capable of providing a thickening time of at least 2 hours at a temperature of 400° F. (204.4° C.) and a pressure of greater than about 500 psi (3.4 MPa) for a test composition consisting essentially of: the cement; the water; and the polymer, and in the same proportions as in the cement composition. According to another embodiment, a method of cementing in a subterranean formation comprises: introducing the cement composition into the subterranean formation; and allowing the cement composition to set. | 02-14-2013 |
20130056199 | LEWIS ACID AS GELATION RETARDER FOR CROSSLINKABLE POLYMER COMPOSITIONS - A treatment fluid for a well including: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a Lewis acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition. According to an embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated; (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming the treatment fluid; and (d) injecting the treatment fluid through the wellbore into the portion of the subterranean formation. | 03-07-2013 |
20130153223 | Wellbore Servicing Compositions and Methods of Making and Using Same - A method of servicing a wellbore in a subterranean formation comprising preparing a wellbore servicing fluid comprising cement, an aqueous fluid, and a cyclodextrin, a cyclodextrin derivative, or combination thereof; placing the wellbore servicing fluid in the wellbore and allowing the fluid to set. A wellbore servicing fluid comprising cement, aqueous fluid, and a cyclodextrin, cyclodextrin derivative, or combination thereof. | 06-20-2013 |
20140011908 | METHODS FOR CEMENTING IN A SUBTERRANEAN FORMATION USING A CEMENT COMPOSITION CONTAINING A SET RETARDER OF A POLYESTER - A cement composition for use in an oil or gas well, the cement composition comprises: cement; water; and a polymer, wherein the polymer: (i) comprises a monomer or monomers capable of forming a polyester; and (ii) is capable of providing a thickening time of at least 2 hours at a temperature of 400° F. (204.4° C.) and a pressure of greater than about 500 psi (3.4 MPa) for a test composition consisting essentially of: the cement; the water; and the polymer, and in the same proportions as in the cement composition. A method of cementing in a subterranean formation comprises: introducing the cement composition into the subterranean formation; and allowing the cement composition to set. | 01-09-2014 |
20140138092 | WELLBORE SERVICING METHODS AND COMPOSITIONS COMPRISING DEGRADABLE POLYMERS - Methods of servicing a wellbore comprising: providing a degradable polymer within a portion of a wellbore and/or a subterranean formation; providing a wellbore servicing fluid comprising a particulate salt degradation accelerator and a neutralizer activator, wherein the particulate salt degradation accelerator is formed by reacting a degradation accelerator solution selected from the group consisting of an alkanolamine; an oligomer of aziridine; a polymer of aziridine; a diamine; and any combination thereof, with an acid, and wherein the neutralizer activator is capable of dissociating the acid by neutralization from the particulate salt degradation accelerator so as to form a neutralized degradation accelerator; introducing the wellbore servicing fluid into a wellbore and/or a subterranean formation; contacting the degradable polymer with the neutralized degradation accelerator; and degrading the degradable polymer. | 05-22-2014 |