| Patent application number | Description | Published |
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| 20080200716 | Mixed metal oxide catalysts for the ammoxidation of propane and isobutane - A process for the ammoxidation of a saturated or unsaturated or mixture of saturated and unsaturated hydrocarbon to produce an unsaturated nitrile, said process comprising contacting the saturated or unsaturated or mixture of saturated and unsaturated hydrocarbon with ammonia and an oxygen-containing gas in the presence of a catalyst composition comprising molybdenum, vanadium, antimony, niobium, tellurium, optionally at least one element select from the group consisting of titanium, tin, germanium, zirconium, hafnium, and optionally at least one lanthanide selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium. Such catalysts are characterized by very low levels of tellurium in the composition. Such catalyst compositions are effective for the gas-phase conversion of propane to acrylonitrile and isobutane to methacrylonitrile (via ammoxidation). | 08-21-2008 |
| 20080248947 | Mixed metal oxide catalysts and catalytic processes for conversions of lower alkane hydrocarbons - Catalytic compositions and processes are disclosed for economical conversions of lower alkane hydrocarbons. Broadly, the present invention discloses solid promoter treated compositions containing mixed metal oxides that exhibit catalytic activity for ammoxidation of lower alkane hydrocarbons to produce an unsaturated nitrile in high yield. Generally, these solid oxide compositions comprise, as component elements, molybdenum (Mo), vanadium (V) niobium (Nb) and at least one active element selected from the group consisting of the elements having the ability to form positive ions. Mixed metal oxide catalytic compositions advantageously are formed process steps comprising impregnation of a base catalyst with an aqueous medium comprising sources of one or more promoter element drying the resulting material; and thereafter subjecting the dried material to heat treatment, under a gaseous atmosphere that is substantially free of dioxygen, at elevated temperatures of at least 400° C. Also described are methods for forming the improved catalysts having the desired crystalline structure and ammoxidation processes for conversion of lower alkanes. | 10-09-2008 |
| 20080249328 | Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons - Catalytic compositions and processes are disclosed for economical conversions of lower alkane hydrocarbons. Broadly, the present invention discloses solid compositions containing mixed metal oxides that exhibit catalytic activity for ammoxidation of lower alkane hydrocarbons to produce an unsaturated nitrile in high yield. Generally, these solid oxide compositions comprise, as component elements, molybdenum (Mo), vanadium (V) niobium (Nb) and at least one active element selected from the group consisting of the elements having the ability to form positive ions. Mixed metal oxide catalytic compositions advantageously comprise one or more crystalline phases at least one of which phases has predetermined unit cell volume and aspect ratio. Also described are methods for forming the improved catalysts having the desired crystalline structure and ammoxidation processes for conversion of lower alkanes. | 10-09-2008 |
| 20090198081 | PROCESS FOR THE AMMOXIDATION OF PROPANE AND ISOBUTANE - A process for the ammoxidation of a saturated or unsaturated hydrocarbon to form an unsaturated nitrile, the process including the steps of contacting the hydrocarbon with ammonia, an oxygen-containing gas, and steam, in the presence of a mixed oxide catalyst. | 08-06-2009 |
| 20090283442 | Production of Aviation Fuel from Renewable Feedstocks - A hydrocarbon product stream having hydrocarbons with boiling points in the aviation fuel range is produced from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating, deoxygenating, isomerization, and selectively hydrocracking the feedstock to produce paraffinic hydrocarbons having from about 9 to about 16 carbon atoms and a high iso/normal ratio in a single reaction zone containing a multifunctional catalyst, or set of catalysts, having hydrogenation, deoxygenation, isomerization and selective hydrocracking functions. | 11-19-2009 |
| 20090321313 | Process for Determining Presence of Mesophase in Slurry Hydrocracking - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The slurry hydrocracking reaction can be controlled by measuring the production of mesophase using X-ray diffraction. Upon a mesophase yield fraction reaching a predetermined level, reaction conditions should be moderated to avoid excessive coke production. | 12-31-2009 |
| 20090321314 | Process for Using Iron Oxide and Alumina Catalyst with Large Particle Diameter for Slurry Hydrocracking - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. Performance of the iron oxide and alumina catalyst at high mean particle diameters is comparable to performance at low mean particle diameters. | 12-31-2009 |
| 20090325789 | Catalyst Composition with Nanometer Crystallites for Slurry Hydrocracking - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron sulfide crystallites have diameters in the nanometer range. | 12-31-2009 |
| 20090326302 | Process for Using Alumina Catalyst in Slurry Hydrocracking - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The alumina in the catalyst is active in suppressing the production of mesophase. | 12-31-2009 |
| 20090326303 | Process for Using Iron Oxide and Alumina Catalyst for Slurry Hydrocracking - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron oxide and alumina catalyst does not require as much iron content relative to non-gaseous material in the reactor to obtain useable products. | 12-31-2009 |
| 20090326304 | Process for Using Catalyst with Nanometer Crystallites in Slurry Hydrocracking - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron sulfide crystallites have diameters in the nanometer range. | 12-31-2009 |
| 20100135883 | CATALYST SUPPORTS - This invention relates to a catalyst material, and its method of making and manufacture, useful for a diversity of chemical production processes as well as various emission control processes. More specifically, it relates to a catalyst composition, preferably comprising a metal oxide felt substrate, with one or more functional surface active constituents integrated on and/or in the substrate surface, which can be used in the removal of sulfur and sulfur compounds from hot gases as well as acting to trap solid particulates and trace metals within these hot gases. | 06-03-2010 |
| 20100135884 | Process for Desulfurization of Hot Fuel Gases - The present invention involves a process and materials for desulfurization of a gaseous stream comprising contacting the gas stream with a manganese aluminate catalyst. The manganese aluminate catalyst is preferably selected from the group consisting of Mn | 06-03-2010 |
| 20100135896 | SIMULTANEOUS WARM GAS DESULFURIZATION AND CO-SHIFT FOR IMPROVED SYNGAS CLEANUP - The present invention involves a process and materials for simultaneous desulfurization and water gas shift of a gaseous stream comprising contacting the gas stream with a nickel aluminate catalyst. The nickel aluminate catalyst is preferably selected from the group consisting of Ni | 06-03-2010 |
| 20100139166 | Dynamic Composition for the Removal of Sulfur from a Gaseous Stream - The present invention relates to a method of making a chemical compound comprising nickel, aluminum, oxygen and sulfur having a general formula Ni | 06-10-2010 |
| 20100143229 | Simultaneous Warm Gas Desulfurization and CO-Shift for Improved Syngas Cleanup - The present invention involves a process and materials for simultaneous desulfurization and water gas shift of a gaseous stream comprising contacting the gas stream with a nickel aluminate catalyst. The nickel aluminate catalyst is preferably selected from the group consisting of Ni | 06-10-2010 |
| 20100148121 | REACTOR EMPLOYING CATALYSTS UPON OR WITHIN A CLOTH-LIKE MATERIAL - The present invention provides a reactor containing catalysts that are situated on or within a cloth like material which is either in a filter cake-like shape or a spiral wound reactor configuration. One application is the desulfurization of synthesis gas. | 06-17-2010 |
| 20100150805 | HIGHLY STABLE AND REFRACTORY MATERIALS USED AS CATALYST SUPPORTS - This invention involves highly porous, stable metal oxide felt materials that are used as catalytic supports for a number of different applications including dehydrogenation of light paraffins to olefins, selective hydrogenation of dienes to olefins, hydrogenation of carboxylic acids, oxidation or ammoxidation reactions, epoxidation of light olefins and removal of sulfur compounds from gas streams. | 06-17-2010 |
| 20100243532 | APPARATUS AND PROCESS FOR TREATING A HYDROCARBON STREAM - One exemplary embodiment can be an apparatus for treating a hydrocarbon stream having one or more compounds with a boiling point of about 140-about 450° C. The apparatus can include an extraction zone and a regeneration zone. The extraction zone can include at least one settler. Each settler can have a height and a length. Typically the length is greater than the height. Also, the settler can form a boot, which can be adapted to receive a feed at one end. The regeneration zone may include a regenerator for an ionic liquid. The regenerator can include a column adapted to provide a regenerated ionic liquid to the extraction zone. | 09-30-2010 |
| 20100247391 | Apparatus for Oligomerizing Dilute Ethylene - The process and apparatus converts ethylene in a dilute ethylene stream that may be derived from an FCC product to heavier hydrocarbons. The catalyst may be an amorphous silica-alumina base with a Group VIII and/or VIB metal. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, hydrogen and ammonia. At least 40 wt-% of the ethylene in the dilute ethylene stream can be converted to heavier hydrocarbons. | 09-30-2010 |
| 20100249474 | Process for Oligomerizing Dilute Ethylene - The process and apparatus converts ethylene in a dilute ethylene stream that may be derived from an FCC product to heavier hydrocarbons. The catalyst may be an amorphous silica-alumina base with a Group VIII and/or VIB metal. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, hydrogen and ammonia. At least 40 wt-% of the ethylene in the dilute ethylene stream can be converted to heavier hydrocarbons. | 09-30-2010 |
| 20100249480 | Process for Oligomerizing Dilute Ethylene - The process and apparatus converts ethylene in a dilute ethylene stream that may be derived from an FCC product to heavier hydrocarbons. The catalyst may be an amorphous silica-alumina base with a Group VIII and/or VIB metal. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, hydrogen and ammonia. At least 40 wt-% of the ethylene in the dilute ethylene stream can be converted to heavier hydrocarbons. | 09-30-2010 |
| 20100327224 | Compounds for Desulfurization of Hot Fuel Gases - The present invention involves a process and materials for desulfurization of a gaseous stream comprising contacting the gas stream with a manganese aluminate catalyst. The manganese aluminate catalyst is preferably selected from the group consisting of Mn | 12-30-2010 |
| 20110000820 | CATALYST COMPOSITION WITH NANOMETER CRYSTALLITES FOR SLURRY HYDROCRACKING - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron sulfide crystallites have diameters in the nanometer range. | 01-06-2011 |
| 20110155635 | PROCESS FOR REMOVING METALS FROM RESID - A process for removing a metal from a resid feed includes contacting the resid feed comprising the metal with a resid-immiscible ionic liquid to produce a resid and resid-immiscible ionic liquid mixture, and separating the mixture to produce a resid effluent having a reduced metal content relative to the resid feed. | 06-30-2011 |
| 20110155637 | PROCESS FOR REMOVING NITROGEN FROM VACUUM GAS OIL - A process for removing a nitrogen compound from a vacuum gas oil feed includes contacting the vacuum gas oil feed comprising the nitrogen compound with a VGO-immiscible phosphonium ionic liquid to produce a vacuum gas oil and VGO-immiscible phosphonium ionic liquid mixture, and separating the mixture to produce a vacuum gas oil effluent having a reduced nitrogen content relative to the vacuum gas oil feed. | 06-30-2011 |
| 20110155638 | PROCESS FOR REMOVING SULFUR FROM VACUUM GAS OIL - A process for removing a sulfur compound from a vacuum gas oil feed includes contacting the vacuum gas oil feed comprising the sulfur compound with a VGO-immiscible ionic liquid to produce a vacuum gas oil and VGO-immiscible ionic liquid mixture, and separating the mixture to produce a vacuum gas oil effluent having a reduced sulfur content relative to the vacuum gas oil feed. | 06-30-2011 |
| 20110155644 | PROCESS FOR REMOVING METALS FROM VACUUM GAS OIL - A process for removing a metal from a vacuum gas oil feed includes contacting the vacuum gas oil feed comprising the metal with a VGO-immiscible ionic liquid to produce a vacuum gas oil and VGO-immiscible ionic liquid mixture, and separating the mixture to produce a vacuum gas oil effluent having a reduced metal content relative to the vacuum gas oil feed. | 06-30-2011 |
| 20110155645 | PROCESS FOR REMOVING METALS FROM CRUDE OIL - A process for removing a metal from a crude oil includes contacting the crude oil containing the metal with a crude-immiscible ionic liquid to produce a crude oil and crude-immiscible ionic liquid mixture, and separating the mixture to produce a crude oil effluent having a reduced metal content relative to the crude oil feed. Optionally, a de-emulsifier is added to at least one of the contacting and separating steps. | 06-30-2011 |
| 20110155647 | PROCESS FOR DE-ACIDIFYING HYDROCARBONS - A process for de-acidifying a hydrocarbon feed includes contacting the hydrocarbon feed containing an organic acid with a feed-immiscible phosphonium ionic liquid to produce a hydrocarbon and feed-immiscible phosphonium ionic liquid mixture; and separating the mixture to produce a hydrocarbon effluent having a reduced organic acid content relative to the hydrocarbon feed. Optionally, a de-emulsifier is added to at least one of the contacting and separating steps. | 06-30-2011 |
| 20110243824 | CATALYST SUPPORTS - This invention relates to a catalyst material, and its method of making and manufacture, useful for a diversity of chemical production processes as well as various emission control processes. More specifically, it relates to a catalyst composition, preferably comprising a metal oxide felt substrate, with one or more functional surface active constituents integrated on and/or in the substrate surface, which can be used in the removal of sulfur and sulfur compounds from hot gases as well as acting to trap solid particulates and trace metals within these hot gases. | 10-06-2011 |
| 20110303583 | PROCESS FOR USING SUPPORTED MOLYBDENUM CATALYST FOR SLURRY HYDROCRACKING - A process is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising molybdenum supported on a base, such as boehmite or pseudo-boehmite alumina. Iron oxide may also be in the base. The base is preferably bauxite. The heavy hydrocarbon slurry is hydrocracked in the presence of the catalyst to produce lighter hydrocarbons. | 12-15-2011 |
| 20110303584 | PROCESS FOR USING SUPPORTED MOLYBDENUM CATALYST FOR SLURRY HYDROCRACKING - A process is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising molybdenum supported on a base, such as boehmite or pseudo-boehmite alumina. Iron oxide may also be in the base. The base is preferably bauxite. The heavy hydrocarbon slurry is hydrocracked in the presence of the catalyst to produce lighter hydrocarbons. | 12-15-2011 |
| 20110305602 | APPARATUS FOR THE REDUCTION OF GASOLINE BENZENE CONTENT BY ALKYLATION WITH DILUTE ETHYLENE - The apparatus converts ethylene in a dilute ethylene stream and dilute benzene in an aromatic containing stream via alkylation to heavier hydrocarbons. The catalyst may be a zeolite such as UZM-8. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, and hydrogen and selectively converts benzene. At least 40 wt-% of the ethylene in the dilute ethylene stream and at least 20 wt-% of the benzene in the dilute benzene stream can be converted to heavier hydrocarbons. | 12-15-2011 |
| 20110306490 | COMPOSITION OF SUPPORTED MOLYBDENUM CATALYST FOR SLURRY HYDROCRACKING - A composition is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising molybdenum supported on a base, such as boehmite or pseudo-boehmite alumina. Iron oxide may also be in the base. The base is preferably bauxite. The heavy hydrocarbon slurry is hydrocracked in the presence of the catalyst to produce lighter hydrocarbons. | 12-15-2011 |
| 20110306809 | PROCESS FOR THE REDUCTION OF GASOLINE BENZENE CONTENT BY ALKYLATION WITH DILUTE ETHYLENE - The process converts ethylene in a dilute ethylene stream and dilute benzene in an aromatic containing stream via alkylation to heavier hydrocarbons. The catalyst may be a zeolite such as UZM-8. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, and hydrogen and selectively converts benzene. At least 40 wt-% of the ethylene in the dilute ethylene stream and at least 20 wt-% of the benzene in the dilute benzene stream can be converted to heavier hydrocarbons. | 12-15-2011 |
| 20110308997 | PROCESS FOR USING CATALYST WITH RAPID FORMATION OF IRON SULFIDE IN SLURRY HYDROCRACKING - A process is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron oxide in the catalyst converts to catalytically active iron sulfide in the presence of hydrogen and sulfur. | 12-22-2011 |
| 20120004448 | PROCESS FOR OXIDIZING ALKYL AROMATIC COMPOUNDS - A process and a mixture for oxidizing an alkyl-aromatic compound comprises forming a mixture comprising the alkyl-aromatic compound, a solvent, a bromine source, a catalyst, and ammonium acetate; and contacting the mixture with an oxidizing agent at oxidizing conditions to produce an oxidation product comprising at least one of an aromatic aldehyde, an aromatic alcohol, an aromatic ketone, and an aromatic carboxylic acid. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. | 01-05-2012 |
| 20120004449 | PROCESS FOR OXIDIZING ALKYL AROMATIC COMPOUNDS - A process and a mixture for oxidizing an alkyl-aromatic compound comprises forming a mixture comprising the alkyl-aromatic compound, a solvent, a bromine source, and a catalyst; and contacting the mixture with an oxidizing agent at oxidizing conditions to produce an oxidation product comprising at least one of an aromatic aldehyde, an aromatic alcohol, an aromatic ketone, and an aromatic carboxylic acid. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an ionic liquid selected from the group consisting of an imidazolium ionic liquid, a pyridinium ionic liquid, a phosphonium ionic liquid, a tetra alkyl ammonium ionic liquid, and combinations thereof. The catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. | 01-05-2012 |
| 20120004450 | PROCESS FOR PRODUCING TEREPHTHALIC ACID - A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid. | 01-05-2012 |
| 20120004451 | PROCESS FOR PRODUCING TEREPHTHALIC ACID - A process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, a catalyst, and ammonium acetate; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms, and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. | 01-05-2012 |
| 20120004454 | MIXTURES USED IN OXIDIZING ALKYL AROMATIC COMPOUNDS - A process and a mixture for oxidizing an alkyl-aromatic compound comprises forming a mixture comprising the alkyl-aromatic compound, a solvent, a bromine source, and a catalyst; and contacting the mixture with an oxidizing agent at oxidizing conditions to produce an oxidation product comprising at least one of an aromatic aldehyde, an aromatic alcohol, an aromatic ketone, and an aromatic carboxylic acid. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an ionic liquid selected from the group consisting of an imidazolium ionic liquid, a pyridinium ionic liquid, a phosphonium ionic liquid, a tetra alkyl ammonium ionic liquid, and combinations thereof. The catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. | 01-05-2012 |
| 20120004455 | SOLID TEREPHTHALIC ACID COMPOSITION - A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid. | 01-05-2012 |
| 20120004456 | PROCESS FOR PURIFYING TEREPHTHALIC ACID - A process for purifying crude terephthalic acid comprising a contaminant at a first concentration, the process comprising contacting the crude terephthalic acid with a solvent comprising an ionic liquid at purifying conditions to produce a solid terephthalic acid product having a second concentration of the contaminant lower than the first concentration. | 01-05-2012 |
| 20120085680 | PROCESS FOR DETERMINING PRESENCE OF MESOPHASE IN SLURRY HYDROCRACKING - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The slurry hydrocracking reaction can be controlled by measuring the production of mesophase using X-ray diffraction. Upon a mesophase yield fraction reaching a predetermined level, reaction conditions should be moderated to avoid excessive coke production. | 04-12-2012 |
| 20120145528 | APPARATUS AND PROCESS FOR TREATING A HYDROCARBON STREAM - One exemplary embodiment can be an apparatus for treating a hydrocarbon stream having one or more compounds with a boiling point of about 140° to about 450° C. The apparatus can include an extraction zone and a regeneration zone. The extraction zone can include at least one settler. Each settler can have a height and a length. Typically the length is greater than the height. Also, the settler can form a boot, which can be adapted to receive a feed at one end. The regeneration zone may include a regenerator for an ionic liquid. The regenerator can include a column adapted to provide a regenerated ionic liquid to the extraction zone. | 06-14-2012 |
| 20130041175 | PROCESS FOR OXIDIZING ALKYL AROMATIC COMPOUNDS - A process for oxidizing an alkyl-aromatic compound is described. The process includes contacting the alkyl-aromatic compound, a solvent comprising an ionic liquid, a bromine source, a catalyst, and an oxidizing agent in a first reaction zone to produce a first product comprising a first mother liquor and at least one of an aromatic alcohol, an aromatic aldehyde, an aromatic ketone, and an aromatic carboxylic acid. | 02-14-2013 |
| 20130153464 | PROCESS FOR REMOVING REFRACTORY NITROGEN COMPOUNDS FROM VACUUM GAS OIL - A process for removing a refractory nitrogen compound from a hydroprocessed vacuum gas oil feed includes contacting the hydroprocessed vacuum gas oil feed comprising the nitrogen compound with a VGO-immiscible phosphonium ionic liquid to produce a hydroprocessed vacuum gas oil and VGO-immiscible phosphonium ionic liquid mixture, and separating the mixture to produce a hydroprocessed vacuum gas oil effluent having a reduced refractory nitrogen compound content relative to the vacuum gas oil feed. | 06-20-2013 |
| 20130153470 | EXTRACTION OF POLYCYCLIC AROMATIC COMPOUNDS FROM PETROLEUM FEEDSTOCKS USING IONIC LIQUIDS - The present invention involves a process for removing one or more polycyclic aromatic hydrocarbon compounds from a vacuum gas oil comprising contacting the vacuum gas oil with a vacuum gas oil-immiscible phosphonium ionic liquid to produce a mixture comprising the vacuum gas oil and the vacuum gas oil-immiscible phosphonium ionic liquid; and separating the mixture to produce a vacuum gas oil effluent and a vacuum gas oil-immiscible phosphonium ionic liquid effluent, the vacuum gas oil-immiscible phosphonium ionic liquid effluent comprising the polycyclic aromatic hydrocarbon compound. | 06-20-2013 |
| 20130158279 | PROCESS FOR REMOVING METALS FROM TALLOW OIL - A process for removing a metal from a tallow feed includes contacting the tallow feed comprising the metal with a tallow oil-immiscible ionic liquid to produce a tallow oil and TALLOW-immiscible ionic liquid mixture, and separating the mixture to produce a tallow oil effluent having a reduced metal content relative to the tallow feed. The metals removed include iron, aluminum, calcium, magnesium, sodium, zinc, and potassium. | 06-20-2013 |
| 20130172605 | PROCESS FOR PRODUCING TEREPHTHALIC ACID - Methods of producing terephthalic acid are described. The methods involve using a p-xylene stream enriched with p-toluic acid. The p-xylene stream enriched with p-toluic acid, a solvent comprising an ionic liquid and optionally a carboxylic acid, a bromine source, a catalyst, and an oxidizing agent are contacted to produce a product comprising terephthalic acid. | 07-04-2013 |
| 20130172606 | PROCESS FOR PRODUCING TEREPHTHALIC ACID - Methods and apparatus for producing terephthalic acid using a p-xylene stream enriched with p-toluic acid are described. The apparatus includes first and second reactor zones. The reactor zones can be in the same reactor or in different reactors. | 07-04-2013 |
| 20130172607 | PROCESS FOR PRODUCING TEREPHTHALIC ACID - Methods of producing terephthalic acid are described. The methods involve using a substantially pure p-toluic acid stream. The substantially pure p-toluic acid stream, a solvent comprising an ionic liquid and optionally a carboxylic acid, a bromine source, a catalyst, and an oxidizing agent are contacted to produce a product comprising terephthalic acid. | 07-04-2013 |
| 20130172608 | PROCESS FOR OXIDIZING AN ALKYL-AROMATIC COMPOUND - Processes for oxidizing an alkyl-aromatic compound are described. The processes include contacting an alkyl-aromatic compound, a solvent, a bromine source, a catalyst, and an oxidizing agent to produce a product comprising at least one of an aromatic alcohol, an aromatic aldehyde, an aromatic ketone, and an aromatic carboxylic acid. The composition of the solvent is controlled to reduce the impurities in the product. | 07-04-2013 |
| 20130172609 | PROCESS FOR OXIDIZING AN ALKYL-AROMATIC COMPOUND - A process for oxidizing an alkyl-aromatic compound to reduce the level of impurities is described. The solvent pH level controlled to reduce the impurities. | 07-04-2013 |
| 20130172610 | PROCESS FOR OXIDIZING ALKYL-AROMATIC COMPOUNDS - A process for oxidizing an alkyl-aromatic compound is described. The process includes oxidizing the alkyl-aromatic compound to produce a first oxidation product; contacting at least a portion of the first oxidation product, a solvent comprising an ionic liquid, a bromine source, a catalyst, and an oxidizing agent to produce a second product comprising a mother liquor and at least one of an aromatic alcohol, an aromatic aldehyde, an aromatic ketone, and an aromatic carboxylic acid; and adding at least a portion of the mother liquor in the contacting step. | 07-04-2013 |
| 20130172611 | PROCESS FOR PRODUCING TEREPHTHALIC ACID - Methods of producing terephthalic acid are described. The methods involve using a substantially pure 4-CBA stream. The substantially pure 4-CBA stream, a solvent comprising an ionic liquid and optionally a carboxylic acid, a bromine source, a catalyst, and an oxidizing agent are contacted to produce a product comprising terephthalic acid. | 07-04-2013 |
| 20130172612 | PROCESS FOR OXIDIZING ALKYL-AROMATIC COMPOUNDS - A process for oxidizing an alkyl-aromatic compound is described. The process includes oxidizing the alkyl-aromatic compound to produce a first oxidation product; contacting at least a portion of the first oxidation product, a solvent comprising an ionic liquid, a bromine source, a catalyst, and an oxidizing agent to produce a second oxidation product comprising at least one of an aromatic alcohol, an aromatic aldehyde, an aromatic ketone, and an aromatic carboxylic acid. | 07-04-2013 |
| 20130172613 | PROCESS FOR OXIDIZING ALKYL-AROMATIC COMPOUNDS - A process for oxidizing an alkyl-aromatic compound is described. The process includes contacting the alkyl-aromatic compound, a solvent comprising a precursor of at least one ionic liquid, a bromine source, a catalyst, and an oxidizing agent to produce an oxidation product comprising at least one of an aromatic alcohol, an aromatic aldehyde, an aromatic ketone, and an aromatic carboxylic acid. | 07-04-2013 |
| 20130230437 | APPARATUS FOR THE REDUCTION OF GASOLINE BENZENE CONTENT BY ALKYLATION WITH DILUTE ETHYLENE - The apparatus converts ethylene in a dilute ethylene stream and dilute benzene in an aromatic containing stream via alkylation to heavier hydrocarbons. The catalyst may be a zeolite such as UZM-8. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, and hydrogen and selectively converts benzene. At least 40 wt-% of the ethylene in the dilute ethylene stream and at least 20 wt-% of the benzene in the dilute benzene stream can be converted to heavier hydrocarbons. | 09-05-2013 |
| 20130248423 | PROCESS FOR REMOVING NITROGEN FROM FUEL STREAMS WITH CAPROLACTAMIUM IONIC LIQUIDS - A process for removing a nitrogen compound from a fuel feed, such as vacuum gas oil or diesel fuel, wherein the process includes contacting the fuel feed comprising the nitrogen compound with a fuel-immiscible caprolactamium ionic liquid to produce a fuel and fuel-immiscible caprolactamium ionic liquid mixture, and separating the mixture to produce a vacuum gas oil or a diesel effluent having a reduced nitrogen content relative to the vacuum gas oil or diesel feed. The invention provides an alternate use for caprolactamium ionic liquid that is produced in large quantities for the manufacture of caprolactam. | 09-26-2013 |
| 20130331603 | Process for Purifying Terephthalic Acid Using Ionic Liquids - Methods of purifying crude or contaminated terephthalic acid using ionic liquids are described. Crude or contaminated terephthalic acid is contacted with a solvent in the absence of an oxidizing agent to form a purified product having at least 30 wt % less 4-carboxybenzaldehyde compared to the crude or contaminated terephthalic acid. The solvent consists essentially of an ionic liquid, optionally an ionic solid or a material capable of forming an ionic salt, and optionally an aqueous solvent. The ionic liquid is formed in situ from at least one ionic liquid precursor. | 12-12-2013 |
| 20130345482 | Alkylation Process Using Phosphonium-Based Ionic Liquids - A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary phosphonium based ionic liquid, and the reaction is performed at or near ambient temperatures. | 12-26-2013 |
| 20130345483 | Alkylation Process Using Phosphonium-Based Ionic Liquids - A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary phosphonium based ionic liquid, and the reaction is performed at or near ambient temperatures. | 12-26-2013 |
| 20130345484 | Alkylation Process Using Phosphonium-Based Ionic Liquids - A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary chloroaluminate based ionic liquid, and the reaction is performed at or near ambient temperatures. | 12-26-2013 |
| 20140001088 | PROCESS FOR REMOVING SULFUR COMPOUNDS FROM VACUUM GAS OIL | 01-02-2014 |
| 20140001091 | HYDROCARBON CONVERSION PROCESS | 01-02-2014 |
| 20140001092 | HYDROCARBON CONVERSION PROCESS TO REMOVE METALS | 01-02-2014 |
| 20140001093 | HYDROCARBON CONVERSION PROCESS | 01-02-2014 |
| 20140001094 | HYDROCARBON CONVERSION PROCESS TO REMOVE CARBON RESIDUE CONTAMINANTS | 01-02-2014 |
| 20140001099 | PROCESS FOR REMOVING SULFUR COMPOUNDS FROM VACUUM GAS OIL | 01-02-2014 |
| 20140005451 | DECONTAMINATION OF DEOXYGENATED BIOMASS-DERIVED PYROLYSIS OIL USING IONIC LIQUIDS | 01-02-2014 |
| 20140024870 | PROCESS FOR OLIGOMERIZING DILUTE ETHYLENE - The process and apparatus converts ethylene in a dilute ethylene stream that may be derived from an FCC product to heavier hydrocarbons. The catalyst may be an amorphous silica-alumina base with a Group VIII and/or VIB metal. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, hydrogen and ammonia. At least 40 wt-% of the ethylene in the dilute ethylene stream can be converted to heavier hydrocarbons. | 01-23-2014 |
| 20140100386 | PROCESS FOR PRODUCING TEREPHTHALIC ACID - Methods of producing terephthalic acid are described. The methods involve using a p-xylene stream enriched with p-toluic acid and optionally terephthalic acid at impurity levels. The p-xylene stream enriched with p-toluic acid, a solvent comprising an ionic liquid and optionally a carboxylic acid, a bromine source, a catalyst, and an oxidizing agent are contacted to produce a product comprising terephthalic acid. | 04-10-2014 |
| 20140102944 | SLURRY HYDROCRACKING PROCESS - One exemplary embodiment can be a slurry hydrocracking process. The process can include providing one or more hydrocarbon compounds having an initial boiling point temperature of at least about 340° C., and a slurry catalyst to a slurry hydrocracking zone. The slurry catalyst may have about 32- about 50%, by weight, iron; about 3- about 14%, by weight, aluminum; no more than about 10%, by weight, sodium; and about 2- about 10%, by weight, calcium. Typically, all catalytic component percentages are as metal and based on the weight of the dried slurry catalyst. | 04-17-2014 |
| 20140107375 | PROCESS FOR OXIDIZING IMPURITIES IN CRUDE TEREPHTHALIC ACID - A process for oxidizing solid crude terephthalic acid is described. The process includes contacting solid crude terephthalic acid with a solvent comprising a carboxylic acid and one or more of an ionic liquid or ammonium acetate; a bromine source; a catalyst; and an oxidizing agent to produce solid purified terephthalic acid at a temperature of about 100 to about 210° C., and a pressure of about 2 to about 4.5 MPa, for a time of about 5 to about 60 min, and recovering the solid purified terephthalic acid. | 04-17-2014 |
| 20140113804 | ASYMMETRIC PHOSPHONIUM HALOALUMINATE IONIC LIQUID COMPOSITIONS - Quaternary phosphonium haloaluminate compounds according to Formula (I): | 04-24-2014 |
| 20140163277 | PROCESS FOR THE GENERATION OF 2,5-DIMETHYLHEXENE FROM ISOBUTENE - A method of making one or more 2,5-dimethylhexenes is described. The method includes reacting isobutene with isobutanol in the presence of a platinum group metal catalyst to form one or more 2,5-dimethylhexenes. A method of making p-xylene using one or more 2,5-dimethylhexenes is also described. The p-xylene can be made from totally renewable sources, if desired. | 06-12-2014 |
| 20140171679 | OXIDATION AND CRYSTALLIZATION PROCESS FOR AROMATIC CARBOXYLIC ACID PRODUCTION - A process for oxidizing and crystallizing alkyl aromatics is described. The solvent and operating conditions are controlled to maintain the aromatic carboxylic acid in solution in the reaction zone, and the aromatic carboxylic acid is crystallized in a downstream crystallizer, resulting in reduced impurity levels in the product. | 06-19-2014 |
| 20140171680 | ANAEROBIC CONVERSION OF 4-CARBOXYBENZALDEHYDE IN IONIC LIQUIDS - A method of decreasing an amount of an aromatic aldehyde in a product is described. The method includes reacting the aromatic aldehyde in the presence of a reaction medium comprising a nucleophilic solvent, or an ionic liquid and a carboxylic acid, the reaction taking place in the absence of a hydrogenating agent and an oxidizing agent, to form aromatic carboxylic acid, an aromatic alcohol, or both. | 06-19-2014 |
| 20140213435 | PHOSPHONIUM-BASED IONIC LIQUIDS - Quaternary phosphonium haloaluminate compounds according to Formula (I): | 07-31-2014 |
| 20140291208 | PROCESS FOR REGENERATING IONIC LIQUIDS BY ADDING LIGHT HYDROCARBON STREAM - A process for removing at least one impurity from a hydrocarbon feed such as vacuum gas oil in which the process includes the steps of contacting the feed with a hydrocarbon-immiscible phosphonium ionic liquid to produce a hydrocarbon and hydrocarbon-immiscible phosphonium ionic liquid mixture, and separating the mixture to produce a hydrocarbon effluent having a reduced impurity content relative to the hydrocarbon feed. | 10-02-2014 |
| 20140318370 | MIXTURES OF PHYSICAL ABSORPTION SOLVENTS AND IONIC LIQUIDS FOR GAS SEPARATION - The invention comprises an absorbent composition and process for purification of gaseous mixtures. The composition comprises a mixture of a physical absorption solvent and an ionic liquid. It was found that the mixtures provided improved absorption of a gas component, such as carbon dioxide, when compared physical absorption solvents. | 10-30-2014 |
| 20140319419 | MIXTURES OF PHYSICAL ABSORPTION SOLVENTS AND IONIC LIQUIDS FOR GAS SEPARATION - The invention comprises an absorbent composition and process for purification of gaseous mixtures. The composition comprises a mixture of a physical absorption solvent and an ionic liquid. It was found that the mixtures provided improved absorption of a gas component, such as carbon dioxide, when compared physical absorption solvents. | 10-30-2014 |
| 20140336428 | RECYCLE GAS SCRUBBING USING IONIC LIQUIDS - A method of removing CO | 11-13-2014 |
| 20140353208 | HYDROCARBON CONVERSION PROCESSES USING IONIC LIQUIDS - A method of hydrocarbon conversion is described. The hydrocarbon feed is decontaminated using an ionic liquid and introduced into a conversion zone. The conversion of the decontaminated feed is increased compared to the conversion of the contaminated feed and the yield of the desired product made from the decontaminated hydrocarbon feed is increased compared to the yield of the desired product made from the contaminated hydrocarbon feed. | 12-04-2014 |
| 20150065747 | Process for ProducingTerephthalic Acid - A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid. | 03-05-2015 |
