Patent application number | Description | Published |
20100233481 | CELLULOSE NANOFIBER PRODUCTION METHOD OF SAME AND CELLULOSE NANOFIBER DISPERSION - The cellulose nanofiber production method of the present invention comprises an oxidation treatment step for oxidizing native cellulose in a neutral or acidic reaction solution containing an N-oxyl compound and an oxidizing agent that oxidizes aldehyde groups, and a dispersion step for dispersing the native cellulose in a medium following the oxidation treatment step. According to the production method of the present invention, a cellulose nanofiber is provided that has long fibers and demonstrates high strength. | 09-16-2010 |
20100282422 | PROCESSES FOR PRODUCING CELLULOSE NANOFIBERS, CELLULOSE OXIDATION CATALYSTS AND METHODS FOR OXIDIZING CELLULOSE - The present invention aims to provide a process for producing cellulose nanofibers using a 4-hydroxy TEMPO derivative less expensive than TEMPO and a process capable of rapidly producing homogeneous cellulose nanofibers. Wood cellulose can be efficiently converted into nanofibers by a process for producing cellulose nanofibers comprising treating a cellulosic material with an oxidizing agent in water in the presence of a cellulose oxidation catalyst comprising an N-oxyl compound represented by formula 1 below: | 11-11-2010 |
20100316863 | GAS BARRIER MATERIAL - Provided is a material for gas barrier containing cellulose fibers having an average fiber diameter of not more than 200 nm, wherein the content of the carboxyl group in a cellulose composing the cellulose fiber is 0.1 to 2 mmol/g. A molded composite having gas barrier properties such as high oxygen barrier properties can be produced by applying the material for gas barrier on a substrate and drying. | 12-16-2010 |
20110008638 | PAPERMAKING ADDITIVE AND PAPER CONTAINING THE SAME - A papermaking additive comprising cellulose nanofibers whose aqueous solution at a concentration of 2% (w/v) has a B-type viscosity (60 rpm, 20° C.) of 500 to 7000 mPa·s, preferably 500 to 2000 mPa·s is used to prepare a paper having improved air resistance and smoothness. This additive is prepared by oxidizing a cellulosic material with an oxidizing agent in the presence of (1) N-oxyl compound (s) and (2) bromide, iodide or a mixture thereof to prepare oxidized cellulose, and finely grinding the oxidized cellulose in a wet condition to convert the oxidized cellulose into nanofibers. | 01-13-2011 |
20110281487 | GAS BARRIER MOLDED ARTICLE AND METHOD FOR PRODUCING THE SAME - The present invention provides the gas barrier molded article having high permeation barrier properties against oxygen gas, water vapor and the like. A gas barrier material containing cellulose fibers having an average fiber diameter of not more than 200 nm wherein the content of carboxyl group in a cellulose ranges from 0.1 to 2 mmol/g; and further a cross-linking agent having a reactive functional group or the cellulose fibers being dried or heated or a gas barrier molded article containing a molded substrate and a layer composed of the gas barrier material on the surface of the molded substrate. | 11-17-2011 |
20120000392 | SUSPENSION OF CELLULOSE FIBERS AND METHOD FOR PRODUCING THE SAME - A suspension of cellulose fibers, containing a cellulose fiber, wherein the cellulose fiber contains a cellulose fiber with an average fiber diameter of not more than 200 nm, a content of carboxyl groups in cellulose composing the cellulose fibers is 0.1 to 2 mmol/g, and a metal selected from a polyvalent metal and a monovalent metal (with the proviso that single sodium is excluded) is contained in the cellulose fiber to form a counter ion for the carboxyl group. | 01-05-2012 |
20120009661 | PROCESS FOR PRODUCING CELLULOSE GEL DISPERSION - A cellulosic material is oxidized with an oxidizing agent in the presence of (1) an N-oxyl compound and (2) a bromide, an iodide or a mixture thereof. The resulting material is subjected to defibration and dispersion treatment to prepare a cellulose nanofiber dispersion liquid. The dispersion liquid thus obtained is acidified so that the cellulose nanofibers are aggregated to form a gelatinous substance. Ultimately, the gelatinous substance is treated mechanically to obtain a cellulose gel dispersion liquid which has low water absorbency and does not tend to swell. | 01-12-2012 |
20120065389 | METHOD FOR RECOVERY/REUSE OF N-OXYL COMPOUND - An effluent produced in oxidation of a cellulosic material with an oxidizing agent in the presence of an N-oxyl compound and a bromide and/or iodide is deionized by electrodialysis to an inorganic salt concentration of less than 0.4%, whereby the N-oxyl compound in the effluent is concentrated and recovered. The N-oxyl compound thus recovered can be reused in oxidation of a cellulosic material. Preferably, the effluent is subjected to reduction treatment and ion exchange resin treatment prior to the electrodialysis. | 03-15-2012 |
20120130064 | METHOD FOR THE HYDROPHILIC PROCESSING OF CELLULOSE FIBRE AND PRODUCTION METHOD FOR HYDROPHILIC CELLULOSE FIBRE - This invention provides a method for hydrophilic treatment of cellulose fibers that can prevent coloring or decrease in fiber strength. The hydrophilic treatment method comprises a first oxidation step of oxidizing cellulose fibers in a first reaction solution containing an N-oxyl compound and a re-oxidizing agent for the N-oxyl compound; and a second oxidation step of oxidizing oxycellulose fibers obtained in the first oxidation step in a second reaction solution containing an oxidizing agent for oxidizing aldehyde groups. | 05-24-2012 |
20120283363 | COMPOSITE MATERIAL - A composite material of the invention is a mixture of cellulose microfibers having a carboxyl group content of 0.1 to 3 mmol/g and a moldable polymeric material selected from the group consisting of a biomass-derived polymer and a petroleum-derived polymer. The biomass-derived polymer is preferably polylactic acid or pulp. The cellulose microfibers are preferably present in an amount of 0.01% to 60% by mass. Another composite material of the invention is a mixture of cellulose composite microfibers and a moldable resin, the cellulose composite microfibers being obtained by adsorbing a surfactant onto cellulose microfibers having a carboxyl group content of 0.1 to 3 mmol/g. | 11-08-2012 |
20140249305 | METHOD FOR PRODUCING HYDROPHILIC CELLULOSE FIBER - The present invention provide a hydrophilized cellulose fiber producing method, comprising oxidizing cellulose fibers in a reaction solution containing a N-oxyl compound, an oxidizing agent, and a co-catalyst and oxidizing other cellulose fibers using the reaction solution again. | 09-04-2014 |
20150075406 | POROUS BODY AND PROCESS FOR MANUFACTURING SAME - The object of the present invention is to provide a porous body having fluid permeance, which contains cellulose-based nanofibers having an extremely thin fiber diameter and high hydrophilicity, and to manufacture a porous body at low cost. The porous body according to the present invention is a porous body in which nanofibers are entangled to form net-like structural bodies in pores of a porous support having many pores that are connecting with one another, wherein the nanofibers are cellulose-based nanofibers, and have a number average fiber diameter of from 1 to 100 nm. | 03-19-2015 |