Class / Patent application number | Description | Number of patent applications / Date published |
585323000 | Including an alkylation step | 67 |
20080228018 | Transalkylation of Heavy Alkylate Using a Layered Catalyst - A layered catalyst is disclosed for use in transalkylation of polyalkylated benzenes. The catalyst comprises an inner core material with a molecular sieve bonded over the core. The process minimizes the cracking of the alkyl groups during the transalkylation reaction. | 09-18-2008 |
20080242905 | Alkylaromatics Production Using Dilute Alkene - process for producing an alkylated aromatic product in a reactor by reacting an alkylatable aromatic compound feedstock with another feedstock comprising alkene component and alkane component in a reaction zone containing an alkylation catalyst. The reaction zone is operated in predominantly liquid phase without inter-zone alkane removal. The polyalkylated aromatic compounds can be separated as feed stream for transalkylation reaction in a transalkylation reaction zone. | 10-02-2008 |
20080242906 | Alkylation Process - A process for the production of ethylbenzene by the ethylation of benzene in the critical phase in a reaction zone containing a molecular sieve aromatic alkylation catalyst comprising cerium-promoted zeolite beta. A polyethylbenzene is supplied into the reaction zone and into contact with the cerium-promoted zeolite beta having a silica/alumina mole ratio within the range of 20-500. The reaction zone is operated at temperature and pressure conditions in which benzene is in the supercritical phase to cause ethylation of the benzene and the transalkylation of polyethylbenzene and benzene in the presence of the zeolite beta catalyst. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated byproducts of no more than 60 wt. % of the ethylbenzene. The alkylation reaction zone is operated under conditions providing a composite byproduct yield of propyl benzene and butyl benzene relative to ethylbenzene, which is no more than one half of the corresponding yield byproduct for zeolite beta promoted with lanthanum. The production of ethylbenzene in the critical phase alkylation reaction zone is attended by recycle of a polyalkylated aromatic component of the reaction product back to the reaction zone. | 10-02-2008 |
20080255397 | Promotors for Controlling Acidity and Pore Size of Zeolite Catalysts for Use in Alkylation - A metal-modified alkylation catalyst including a metal/zeolite is provided where the metal is one or two selected from the group consisting of yttrium and a rare earth of the lanthanide series other than cerium. Where two metals are used, one may be Ce or La. The metal-promoted zeolite is useful as a molecular sieve aromatic alkylation catalyst for the production of ethylbenzene by the ethylation of benzene in the liquid phase or critical phase. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated by-products of no more than 10-60 wt % of the ethyl benzene. | 10-16-2008 |
20090023968 | CATALYST AND PROCESS FOR PRODUCING LIGHT AROMATIC HYDROCARBONS AND LIGHT ALKANES FROM HYDROCARBONACEOUS FEEDSTOCK - The present invention provides a catalyst comprising metallic Pt and/or Pd supported on a binder-free zeolite for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock, wherein the amount of metallic Pt and/or Pd is of 0.01-0.8 wt %, preferably 0.01-0.5 wt % on the basis of the total weight of the catalyst, and the binder-free zeolite is selected from the group consisting of mordenite, beta zeolite, Y zeolite, ZSM-5, ZSM-11 and composite or cocrystal zeolite thereof. The present invention also provides a process for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock using said catalyst. | 01-22-2009 |
20090149685 | Treatment of Alkylation Catalyst Poisons with Dehydrogenation - Methods and processes for reducing alkylation catalyst poisoning are described herein. Such methods generally include providing a dehydrogenation system including a dehydrogenation reactor and a separation system, wherein the separation system includes a first column and a second column, introducing an alkyl aromatic hydrocarbon into the dehydrogenation reactor, contacting the alkyl aromatic hydrocarbon with a dehydrogenation catalyst disposed within the dehydrogenation reactor to form a dehydrogenation output stream comprising a vinyl aromatic hydrocarbon, passing at least a portion of the dehydrogenation output stream to first column, recovering a first overhead fraction including benzene and a first bottoms fraction from the first column, passing at least a portion of the benzene from the first column to an alkylation system including an alkylation catalyst, passing the first bottoms fraction from the first column to the second column, recovering a second overhead fraction and a second bottoms fraction from the second column, withdrawing offtest from effluent streams selected from the dehydrogenation output stream, the first bottoms fraction, the second bottoms fraction and combinations thereof to form withdrawn offtest and introducing the withdrawn offtest into the separation system downstream from the first column. | 06-11-2009 |
20090281361 | Organic Compound Conversion Process - The present invention provides a process for conversion of feedstock comprising organic compounds to desirable conversion product at organic compound conversion conditions in the presence of catalyst comprising an acidic, porous crystalline material and having a Proton Density Index of greater than 1.0, for example, from greater than 1.0 to about 2.0, e.g. from about 1.01 to about 1.85. The acidic, porous crystalline material of the catalyst may comprise a porous, crystalline material or molecular sieve having the structure of zeolite Beta, an MWW structure type material, e.g. MCM-22, MCM-36, MCM-49, MCM-56, or a mixture thereof. | 11-12-2009 |
20100004496 | Integrated Processes for Making Detergent Range Alkylbenzenes from C5-C6-Containing Feeds - Integrated processes for making detergent range alkylbenzenes from C | 01-07-2010 |
20100004497 | Integrated Processes for Making Detergent Range Alkylbenzenes from C5-C6-Containing Feeds - Integrated processes for making detergent range alkylbenzenes from C | 01-07-2010 |
20100056835 | Process for Producing Cumene - A process for producing cumene is provided which comprises the step of contacting benzene and propylene under at least partial liquid phase alkylating conditions with a particulate molecular sieve alkylation catalyst, wherein the particles of said alkylation catalyst have a surface to volume ratio of about 80 to less than 200 inch | 03-04-2010 |
20100069693 | Liquid Phase Alkylation with Multiple Catalysts - A process is disclosed for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones, each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into the first alkylation reaction zone. The first and second alkylation reaction zones are operated under conditions of temperature and pressure effective to cause alkylation of the aromatic compound with the alkene in the presence of the alkylation catalyst, the temperature and pressure being such that the aromatic compound is at least partly in the liquid phase. The alkylation catalyst in the first alkylation reaction zone, which may be a reactor guard bed, has more acid sites per unit volume of catalyst than the alkylation catalyst in the second reaction zone. | 03-18-2010 |
20100076237 | Alkylaromatics Production - A process for alkylation or transalkylation of an alkylatable aromatic compound having reactive impurities with an alkylating agent to produce a monoalkylated aromatic compound, comprising the steps of contacting at least a portion of said alkylatable aromatic compounds and said alkylating agent with a first molecular sieve catalyst in a guard bed under suitable conditions to remove said reactive impurities and form a first effluent comprising monoalkylated aromatic compound, unreacted alkylatable aromatic compounds and unreacted alkylating agent; contacting said first effluent with a second molecular sieve catalyst different from said first molecular sieve catalyst in said reaction zone under suitable alkylation or transalkylation conditions to produce additional said monoalkylated aromatic compounds; and maintaining said water content from about 1 wppm to about 10 wt. % based on the combined weight of said alkylatable aromatic compound and said alkylating agent in said reaction zone for the majority of the on-oil time. | 03-25-2010 |
20100081853 | Alkylaromatics Production - A process for alkylation of an alkylatable aromatic compound to produce a monoalkylated aromatic compound, comprising the steps of: (a) providing at least one reaction zone having a water content with at least one alkylation catalyst having an activity and a selectivity for said monoalkylated benzene, said alkylation catalyst comprising a porous crystalline molecular sieve of a MCM-22 family material, said MCM-22 family material is characterized by having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 3.57±0.07 and 3.42±0.07 Angstroms; (b) supplying the reaction zone with at least one alkylatable aromatic compound and at least one alkylating agent; (c) operating the reaction zone under suitable alkylation or transalkylation conditions, to produce at least one effluent which comprises a monoalkylated aromatic compound and a polyalkylated aromatic compound(s); (d) monitoring the amount of the monoalkylated aromatic compound or the amount of the polyalkylated aromatic compound(s) in the effluent; (e) adjusting the water content in the reaction zone to secure a desired amount of the monalkylated aromatic compound or the polyalkylated aromatic compound(s) in the effluent, the water content in the reaction zone being in a range from about 1 wppm to about 900 wppm; and wherein the polyalkylated aromatic compound(s) produced is reduced as compared to the reaction zone having a water content of about 0 wppm when the reaction zone is operated under equivalent conditions. | 04-01-2010 |
20100105971 | SEPARATION METHOD OF AROMATIC COMPOUNDS COMPRISING SIMULATED MOVING BED XYLENE MIXTURE PRE - TREATMENT PROCESS AND ADDITIONAL XYLENE ISOMERIZATION PROCESS - Disclosed is a method for separating aromatic compounds using a simulated moving bed adsorptive chromatography and a crystallization process, comprising a sulfolan process that is a non-aromatic compound removing process, a benzene/toluene fractionation process, an aromatic compound fractionation process, a selective toluene disproportionation process, a transalkylation process, a crystallization process for para-xylene separation, a simulated moving bed para-xylene separation process and a xylene isomerization process, wherein the method is characterized by further comprising a simulated moving bed xylene mixture pre-treatment process and an additional xylene isomerization process. The separation method of aromatic compounds according to the present invention can make significant improvement in para-xylene and benzene production in the overall process, as compared to the conventional aromatic compound separation process. | 04-29-2010 |
20100145119 | SEPARATION METHOD OF AROMATIC COMPOUNDS COMPRISING SIMULATED MOVING BED XYLENE MIXTURE PRE-TREATMENT PROCESS AND ADDITIONAL XYLENE ISOMERIZATION PROCESS - Disclosed is a method for separating aromatic compounds using a simulated moving bed adsorptive chromatography, comprising a sulfolan process that is a non-aromatic compound removing process, a benzene/toluene fractionation process, an aromatic compound fractionation process, a selective toluene disproportionation process, a transalkylation process, a simulated moving bed para-xylene separation process and a xylene isomerization process, wherein the method is characterized by further comprising a simulated moving bed xylene mixture pre-treatment process and an additional xylene isomerization process. The separation method of aromatic compounds according to the present invention can make significant improvement in para-xylene and benzene production in the overall process, as compared to the conventional aromatic compound separation process. | 06-10-2010 |
20100210886 | Production of High Purity Ethylbenzene From Non-Extracted Feed and Non-Extracted Reformate Useful Therein - A process for producing an ethylbenzene product having a purity of at least 99.50 percent based on the weight of ethylbenzene present in the product by the ethylation of the benzene present in non-extracted feed, e.g., non-extracted hydrocarbon composition. The non-extracted feed is substantially free of both C | 08-19-2010 |
20100217056 | ALKYLATION PROCESS - A process is disclosed for the alkylation of aromatics by charging a hydrocarbon feed containing aromatic hydrocarbons and olefinic hydrocarbons to a distillation column for separation into at least one fraction; removing an aromatics/olefin stream containing at least a portion of the aromatic hydrocarbons and at least a portion of the olefinic hydrocarbons; charging the aromatics/olefin stream to an alkylation reactor, operated at a temperature in the range of from about 80° C. to about 220° C., for alkylation of at least a portion of the aromatic hydrocarbons with the olefinic hydrocarbons; recycling at least a portion of the resulting reactor effluent to the distillation column; and removing a product stream containing alkylated aromatics from the distillation column. | 08-26-2010 |
20100249472 | Alkylaromatics Production - A process is described for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene and one or more alkanes are introduced into said first alkylation reaction zone, having operating conditions, e.g., temperature and pressure, which are controlled effective to cause the alkylatable aromatic compound to be partly in the vapor phase and partly in the liquid phase with the ratio of liquid volume to vapor volume of the feed in each zone to be from about 0.5 to about 10. The aromatic compound and the alkene are reacted in the presence of the alkylation catalyst to form an effluent comprising the alkylaromatic compound, unreacted alkylatable aromatic compound, any unreacted alkene and the alkane, which is withdrawn and then supplied to the second alkylation reaction zone without removal of the alkane. | 09-30-2010 |
20100298617 | Process and Catalyst for the Transalkylation of Aromatics - Disclosed herein is a process and catalyst for producing an ethylbenzene feed from a polyethylbenzene feed, comprising the step of contacting a benzene feed with a polyethylbenzene feed under at least partial liquid phase conditions in the presence of a zeolite beta catalyst having a phosphorus content in the range of 0.01 wt. % to 0.5 wt. % of said catalyst, to provide a product which comprises ethylbenzene. | 11-25-2010 |
20110137095 | PROCESS FOR PRODUCING OLEFINS - The present invention provides a process for producing olefins, comprising:
| 06-09-2011 |
20110160506 | Alkylaromatics Production Using Dilute Alkene - A process for producing an alkylated aromatic product in a reactor by reacting an alkylatable aromatic compound feedstock with another feedstock comprising alkene component and alkane component in a reaction zone containing an alkylation catalyst. The reaction zone is operated in predominantly liquid phase without inter-zone alkane removal. The polyalkylated aromatic compounds can be separated as feed stream for transalkylation reaction in a transalkylation reaction zone. | 06-30-2011 |
20110166399 | METHOD FOR IMPROVING PRODUCTIVITY AND PROCESS STABILITY IN STYRENE MANUFACTURING SYSTEM HAVING MULTIPLE REACTORS CONNECTED IN SERIES - Provided is a method for improving productivity and process stability in styrene monomer manufacturing system which uses ethylbenzene dehydrogenation and multiple reactors connected in series by divergence of the feed containing steam and ethylbenzene and injection thereof into a certain point of the system. | 07-07-2011 |
20110224469 | Alkylated Aromatics Production - Disclosed is a process for the production of alkylated aromatics by contacting a feed stream comprising an alkylatable aromatic, an alkylating agent and trace amounts of water and impurities in the presence of first and second alkylation catalysts wherein the water and impurities are removed in order to improve the cycle length of such alkylation catalysts. Water and a portion of impurities are removed in a dehydration zone. A first alkylation zone having a first alkylation catalyst which, in some embodiments is a large pore molecular sieve, acts to remove a larger portion of impurities, such as nitrogenous and other species, and to alkylate a smaller portion of the alkylatable aromatic compound. A second alkylation zone, which in some embodiments is a medium pore molecular sieve, acts to remove a smaller portion of impurities, and to alkylate a larger portion of the alkylatable aromatic compound. | 09-15-2011 |
20110245558 | Cumene Production with High Selectivity - Cumene production methods are disclosed, based on the alkylation of benzene with propylene, in which byproducts of the alkylation reaction are advantageously reduced to achieve a high cumene selectivity. This may be attained by (i) reducing the portion of the total alkylation effluent that is recycled, after cooling, to the alkylation reaction zone for quenching or direct heat exchange and/or (ii) reducing the benzene:propylene molar ratio of the alkylation feedstock. To manage the temperature differential across catalyst bed(s) in the alkylation reaction zone, indirect heat exchange may be used to remove heat. | 10-06-2011 |
20110245559 | PROCESS FOR INCREASING WEIGHT OF OLEFINS - The process converts FCC olefins to heavier compounds. The heavier compounds are more easily separated from the unconverted paraffins. The heavier compounds can be recycled to an FCC unit or delivered to a separate FCC unit. Suitable conversion zones are oligomerization and aromatic alkylation zones. | 10-06-2011 |
20110275871 | PROCESS FOR THE PRODUCTION OF BRANCHED ALKYLBENZENES THAT USES A RENEWABLE CARBON SOURCE - A process for the production of alkylbenzenes in the presence of an aromatic feedstock and an olefinic stream produced from an ethanol feedstock, itself produced from a renewable source obtained from biomass, is described, with said process comprising at least:
| 11-10-2011 |
20110282120 | Selective Oligomerization of Isobutene - A process for oligomerizing isobutene comprises contacting a feedstock comprising isobutene with a catalyst comprising a MCM-22 family molecular sieve under conditions effective to oligomerize the isobutene, wherein said conditions including a temperature from about 45° C. to less than 140° C. The isobutene may be a component of a hydrocarbon feedstock containing at least one additional C | 11-17-2011 |
20110282121 | PROCESS FOR THE PRODUCTION OF ALKYLBENZENES FROM AN OLEFINIC FEEDSTOCK PRODUCED BY OLIGOMERIZATION THAT IS CATALYZED HOMOGENEOUSLY - A process for the production of a mixture of alkylbenzenes in the presence of an aromatic feedstock and an olefinic stream produced from an ethylene feedstock is described, with said process comprising at least:
| 11-17-2011 |
20110306809 | PROCESS FOR THE REDUCTION OF GASOLINE BENZENE CONTENT BY ALKYLATION WITH DILUTE ETHYLENE - The process converts ethylene in a dilute ethylene stream and dilute benzene in an aromatic containing stream via alkylation to heavier hydrocarbons. The catalyst may be a zeolite such as UZM-8. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, and hydrogen and selectively converts benzene. At least 40 wt-% of the ethylene in the dilute ethylene stream and at least 20 wt-% of the benzene in the dilute benzene stream can be converted to heavier hydrocarbons. | 12-15-2011 |
20110306810 | PROCESSES FOR SYNTHESIZING ETHYLBENZENE FROM ETHANOL AND BENZENE - Processes for catalytically synthesizing ethylbenzene from ethanol and benzene comprising:
| 12-15-2011 |
20120108873 | Catalysts Containing Nano-Materials and Methods of Making and Using Same - A method of making a catalyst containing nanosize zeolite particles supported on a support material is disclosed. A process for making styrene or ethylbenzene by reacting toluene with a C | 05-03-2012 |
20120149959 | Method to Adjust 2-Phenyl Content of an Alkylation Process for the Production of Linear Alkyl Benzene - A process is presented for controlling the output of monoalkylated benzenes. The alkylbenzenes are linear alkylbenzenes and the process controls the 2-phenyl content of the product stream. The control of the process to generate a linear alkylbenzene with a 2-phenyl content within a desired range by recycling a portion of the effluent from the alkylation reactor to the inlet of the reactor. | 06-14-2012 |
20120271084 | RECYCLE OF TRANSALKYLATION EFFLUENT FRACTIONS ENRICHED IN TRIMETHYLBENZENE - Methods are disclosed for producing C | 10-25-2012 |
20120277509 | Alkylation of Toluene to Form Styrene and Ethylbenzene - A process is disclosed for making styrene and/or ethylbenzene by reacting toluene with a C1 source over a catalyst in one or more reactors to form a product stream comprising styrene and/or ethylbenzene where the catalyst time on stream prior to regeneration is less than 1 hour. | 11-01-2012 |
20120283497 | Monoalkylated Aromatic Compound Production - A process for producing a monoalkylated aromatic compound in an alkylation reaction zone, said process comprising the steps of:
| 11-08-2012 |
20120296130 | METHOD FOR ALKYLATION OF TOLUENE TO FORM STYRENE UTILIZING AN OXY-DEHYDROGENATION REACTOR - A process for making styrene is disclosed that includes reacting toluene with a C | 11-22-2012 |
20120296131 | METHOD FOR ALKYLATION OF TOLUENE IN A PRE-EXISTING DEHYDROGENATION PLANT - A process for making styrene in a pre-existing facility including an infrastructure capable of producing styrene, wherein the infrastructure includes at least one dehydrogenation unit. The process includes coupling an alkylation unit including an alkylation reactor to the infrastructure and contacting toluene with a C | 11-22-2012 |
20120296132 | USE OF AN OXIDANT IN THE COUPLING OF TOLUENE WITH A CARBON SOURCE - A process for making styrene including reacting toluene with a C | 11-22-2012 |
20120296133 | PROCESS FOR TOLUENE AND METHANE COUPLING IN A MICROREACTOR - A process for making ethylbenzene and/or styrene by reacting toluene with methane in one or more microreactors is disclosed. In one embodiment a method of revamping an existing styrene production facility by adding one or more microreactors capable of reacting toluene with methane to produce a product stream comprising ethylbenzene and/or styrene is disclosed. | 11-22-2012 |
20130023708 | PROCESSES FOR MAKING CX-CY OLEFINS FROM C5 AND C6 PARAFFINS - Processes for making C | 01-24-2013 |
20130072734 | Monoalkylated Aromatic Compound Production - A process for producing a monoalkylated aromatic compound in an alkylation reaction zone, said process comprising the steps of:
| 03-21-2013 |
20130079573 | METHODS FOR CO-PRODUCTION OF ALKYLBENZENE AND BIOFUEL FROM NATURAL OILS - Embodiments of methods for co-production of linear alkylbenzene and biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. A first portion of the paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. A second portion of the paraffins is processed to form biofuel. | 03-28-2013 |
20130096357 | HEAVY ALKYLBENZENE TRANSALKYLATION OPERATING COST REDUCTION - A process for increasing the production of monoalkylbenzenes is presented. The process includes utilizing a transalkylation process to convert dialkylbenzenes to monoalkylbenzenes. The transalkylation process recycles a portion of the effluent stream from the transalkylation reactor back to the feed of the transalkylation reactor. The recycled dialkylbenzenes and a portion of the recycled benzene are converted to monoalkylbenzenes. | 04-18-2013 |
20130116492 | Preparation of Alkyl Aromatic Compounds - Provided is a process for preparing alkyl aromatic compounds. The process comprises contacting an alkane under dehydrogenation conditions in the presence of a dehydrogenation catalyst, e.g., a pincer iridium catalyst, to form olefins, and then contacting the olefins generated with an aromatic compound under alkylation conditions. Both reactions are conducted in a single reactor, and occur simultaneously. | 05-09-2013 |
20130131415 | Process for Ethylbenzene Production From Ethanol - A method of producing an alkylaromatic by the alkylation of an aromatic with ethanol, such as producing ethylbenzene by an alkylation reaction of benzene, is disclosed. | 05-23-2013 |
20130172646 | Method to Adjust 2-Phenyl Content of an Alkylation Process for the Production of Linear Alkyl Benzene - A process is presented for controlling the output of monoalkylated benzenes. The alkylbenzenes are linear alkylbenzenes and the process controls the 2-phenyl content of the product stream. The control of the process to generate a linear alkylbenzene with a 2-phenyl content within a desired range by recycling a portion of the effluent from the alkylation reactor to the inlet of the reactor. | 07-04-2013 |
20130211164 | Alkylation Process - The present invention provides an improved process for producing an alkylated aromatic compound from an at least partially untreated alkylatable aromatic compound having catalyst poisons and an alkylating agent, wherein said alkylatable aromatic compound stream is treated to reduce catalyst poisons with a treatment composition having a surface area/surface volume ratio of greater than or equal to 30 in | 08-15-2013 |
20130217937 | Processes for The Reduction of Alkylation Catalyst Deactivation Utilizing Stacked Catalyst Bed - Alkylation systems and methods of minimizing alkylation catalyst regeneration are discussed herein. The alkylation systems generally include a preliminary alkylation system adapted to receive an input stream including an alkyl aromatic hydrocarbon and contact the input stream with a first preliminary alkylation catalyst disposed therein to form a first output stream. The first preliminary alkylation catalyst generally includes a Y zeolite. The systems further include a first alkylation system adapted to receive the first output stream and contact the first output stream with a first alkylation catalyst disposed therein and an alkylating agent to form a second output stream. | 08-22-2013 |
20130225888 | Process for the Reduction of Alkylation Catalyst Deactivation - Alkylation systems and methods of minimizing alkylation catalyst regeneration are described herein. The alkylation systems generally include a preliminary alkylation system adapted to receive an input stream including an alkyl aromatic hydrocarbon and contact the input stream with a preliminary alkylation catalyst disposed therein to form a first output stream. The preliminary alkylation catalyst generally includes a zeolite catalyst having a SiO | 08-29-2013 |
20130237733 | PROCESSES FOR PREPARING ALKYLATED AROMATIC COMPOUNDS - Processes for preparing alkylation aromatic compounds are provided herein. In an embodiment, a process for preparing alkylated aromatic compounds includes reacting an aromatic compound and an olefin in a first alkylation reaction in the presence of a first alkylation catalyst to produce a first effluent that includes an alkylated aromatic compound and unreacted aromatic compound. Unreacted aromatic compound from the first effluent and additional olefin are reacted in at least one downstream alkylation reaction in the presence of a second alkylation catalyst to produce a second effluent including the alkylated aromatic compound. A recycle stream including the alkylated aromatic compound is recycled from the second effluent to the at least one downstream alkylation reaction and, optionally, the first alkylation reaction. A ratio of the recycle stream to a total mass flow is greater in the at least one downstream alkylation reaction than in the first alkylation reaction. | 09-12-2013 |
20130253242 | METHOD FOR PRODUCING HIGH-ADDED-VALUE AROMATIC PRODUCTS AND OLEFINIC PRODUCTS FROM AN AROMATIC-COMPOUND-CONTAINING OIL FRACTION - The present invention relates to a method for manufacturing aromatic products (benzene/toluene/xylene) and olefinic products from an aromatic-compound-containing oil fraction, whereby it is possible to substitute naphtha as a feedstock for aromatic production and so make stable supply and demand, and it is possible to substantially increase the yield of high-added-value olefinic and high-added-value aromatic components, by providing a method for manufacturing olefinic and aromatic products from light cycle oil comprising a hydrogen-processing reaction step, a catalytic cracking step, an separation step and a transalkylation step, and optionally also comprising a recirculation step. | 09-26-2013 |
20130324776 | PROCESS FOR REDUCING THE BENZENE CONTENT OF GASOLINE - A process is disclosed for alkylating benzene contained in a benzene-containing refinery gasoline stream also comprising at least 0.1 wt % of at least one C6 to C8 olefin. In the process, the refinery gasoline stream is contacted under alkylation conditions with an alkylating agent selected from one or more C2 to C5 olefins in at least a first alkylation reaction zone and a second alkylation reaction zone connected in series to produce an alkylated effluent, which has reduced benzene content as compared with said refinery gasoline stream. All of the refinery gasoline stream is introduced into the first alkylation reaction stage, whereas an aliquot of the alkylated effluent is recycled and introduced to the second, but not the first, alkylation reaction zone. | 12-05-2013 |
20130338416 | METHODS FOR REMOVING WEAKLY BASIC NITROGEN COMPOUNDS FROM A HYDROCARBON STREAM USING ACIDIC CLAY - Disclosed is a method for removing weakly basic nitrogen compounds from a hydrocarbon feed stream by contacting the hydrocarbon feed stream with acidic clay to produce a hydrocarbon effluent stream having a lower weakly basic nitrogen compound content relative to the hydrocarbon feed stream. The hydrocarbon feed stream comprises an aromatic compound and a weakly basic nitrogen compound. | 12-19-2013 |
20130338417 | Methods for Removing Weakly Basic Nitrogen Compounds from a Hydrocarbon Stream Using Basic Molecular Sieves - Disclosed is a method for removing weakly basic nitrogen compounds from a hydrocarbon feed stream by contacting the hydrocarbon feed stream with a basic catalyst to convert a portion of the weakly basic nitrogen compounds to basic nitrogen compounds. The method also includes contacting the hydrocarbon feed stream with an acidic adsorbent to adsorb the basic nitrogen compounds from the stream. The hydrocarbon feed stream comprises an aromatic compound and a weakly basic nitrogen compound. | 12-19-2013 |
20140005452 | METALLOPHOSPHATE MOLECULAR SIEVES, METHODS OF PREPARATION AND USE | 01-02-2014 |
20140094631 | Method for Production of Styrene from Toluene and Methane - A process is disclosed for making styrene by converting methanol to formaldehyde in a reactor then reacting the formaldehyde with toluene to form styrene in a separate reactor. | 04-03-2014 |
20140121431 | HIGHLY SELECTIVE ALKYLATION PROCESS WITH LOW ZEOLITE CATALYST COMPOSITION - A method for alkylation of a feedstock is described. The method includes contacting the feedstock comprising at least one alkylatable aromatic compound and an alkylating agent with a first alkylating catalyst composition under alkylating conditions, the first alkylating catalyst composition comprising UZM-8 zeolite and a binder, the first alkylating catalyst composition having less than 50 wt % UZM-8 zeolite; wherein a total alkylated selectivity at a temperature and a molar ratio of alkylatable aromatic compound to alkylating agent is greater than 99.0%. | 05-01-2014 |
20140135548 | Alkylated Aromatics Production - Disclosed is a process for the production of alkylated aromatics by contacting a feed stream comprising an alkylatable aromatic, an alkylating agent and trace amounts of water and impurities in the presence of a first catalyst and an alkylation catalyst wherein such water and impurities are removed in order to improve the cycle length of such alkylation catalysts. Water and at least a portion of impurities are removed in a dehydration zone. A reaction zone having a first catalyst which, in some embodiments is a large pore molecular sieve, acts to remove another portion of impurities, such as nitrogenous and other species. An alkylation zone having an alkylation catalyst which, in some embodiments is a medium pore molecular sieve or a MCM-22 family material, acts to remove additional impurities, and to alkylate the alkylatable aromatic compound. | 05-15-2014 |
20140163278 | METHODS AND APPARATUSES FOR PREPARING NORMAL PARAFFINS AND HYDROCARBON PRODUCT STREAMS - Methods and apparatuses for preparing normal paraffins and hydrocarbon product streams are provided herein. A method of preparing normal paraffins includes providing an unsaturated feed that includes an unsaturated compound that has at least one alkenyl group. The unsaturated feed is epoxidized to convert the at least one alkenyl group in the unsaturated compound to an epoxide functional group, thereby converting the unsaturated compound to an epoxide compound that has at least one epoxide functional group. The at least one epoxide functional group in the epoxide compound is converted to at least one secondary hydroxyl functional group, thereby converting the epoxide compound to a hydroxyl-functional compound that has at least one hydroxyl functional group. The hydroxyl-functional compound is deoxygenated to form normal paraffins. | 06-12-2014 |
20140243567 | Liquid Phase Alkylation Process - The present invention provides a process for producing a monoalkylated benzene comprising the step of contacting benzene with an alkylating agent in the presence of a catalyst composition under effective alkylation conditions to form said monoalkylated benzene and polyalkylated benzene, said catalyst composition comprising MCM-56 and a binder, such that the crystal/binder weight ratio in said catalyst composition is from about 20/80 to about 80/20, wherein said polyalkylated benzene comprises dialkylated benzene and trialkylated benzene, and the weight ratio of trialkylated benzene to dialkylated benzene is in the range from about 0.08 to about 0.12. | 08-28-2014 |
20140378724 | RECYCLE OF REACTOR EFFLUENT IN AN ALKYLAROMATIC PROCESS - A method of making alkylaromatics is described. The process includes recycling a portion of the alkylation reaction zone effluent back to the alkylation zone to maintain the product quality while reducing energy usage. | 12-25-2014 |
20150315096 | Process for Producing Cumene With Alkylation Effluent Recycle - In a process for producing cumene, a C | 11-05-2015 |
20150361012 | METHODS FOR PRODUCING LINEAR ALKYLBENZENES, PARAFFINS, AND OLEFINS FROM NATURAL OILS AND KEROSENE - A method for producing a linear paraffin product from natural oil and kerosene includes providing a first feed stream comprising kerosene, pre-fractionating the first feed stream to generate a paraffin stream comprising at least paraffins in a desired range, and combining paraffin stream with a second feed stream comprising natural oil to form a combined stream. The method further includes deoxygenating the natural oil and fractionating the combined stream to remove paraffins that are heavier than the desired range. | 12-17-2015 |
20160068453 | METHODS FOR PRODUCING NORMAL PARAFFIN FROM A RENEWABLE FEEDSTOCK - Methods are provided for producing normal paraffins. A method includes contacting a feedstock with a deoxygenation catalyst to produce a paraffin stream, where the feedstock includes a natural oil, and where the deoxygenation catalyst is sulfided. The reactions conditions are controlled when the feedstock contacts the deoxygenation catalyst to control a C11 to C12 normal paraffin ratio, by weight to within about 0.4 to about 1.7. | 03-10-2016 |
20160102032 | APPARATUS AND PROCESS FOR PRODUCING GASOLINE, OLEFINS AND AROMATICS FROM OXYGENATES - Apparatuses and processes for converting an oxygenate feedstock, such as methanol and/or dimethyl ether, in a fluidized bed containing a catalyst to hydrocarbons, such as gasoline boiling components, olefins and aromatics are provided herein. | 04-14-2016 |
20160115093 | Method for Upgrading Hydrocarbon Using C4, C5 and C6 Streams - The present disclosure relates to a method for upgrading hydrocarbon using C4, C5 and C6 streams, and more specifically, to a method for upgrading hydrocarbons using C4, C5 and C6 streams. The method includes the steps of: preparing C4, C5 and C6 streams, which are the products of naphtha catalytic cracking (NCC) process, heavy oil upgrading process, thermal cracking process, or fluidized catalytic cracking (FCC or RFCC) process; oligomerizing the C4, C5 and C6 streams with a catalyst to produce branched unsaturated hydrocarbons; and fractional distillating the branched unsaturated hydrocarbons to separate into C14-18 products or C32-40 products. | 04-28-2016 |
20160186077 | INTEGRATED CATALYTIC CRACKING WITH ETHANOL CONVERSION TO FUEL - Processes relating to the conversion of ethanol in a stripper unit of a fluidized catalytic cracking system. An ethanol stream comprising at least 4 volume percent water mixes with a catalyst in the stripper unit under conditions of temperature that favor conversion of the ethanol to hydrocarbons, thereby increasing incorporation of ethanol into liquid transportation fuels without exceeding regulatory limits on fuel vapor pressure. Certain embodiments additionally combine the ethanol stream with a hydrocarbon stream in the stripper and react in the presence of a catalyst to produce hydrocarbons that may have an increased boiling point, increased octane rating, decreased vapor pressure, decreased benzene content, or combinations of these properties. | 06-30-2016 |