Class / Patent application number | Description | Number of patent applications / Date published |
562531000 | Of aldehyde | 66 |
20090247786 | Process For Producing 3,3,3-Trifluoropropionic Acid - A benzyl vinyl ether represented by the following formula | 10-01-2009 |
20100312011 | Process Of Separation Of Glyoxylic Acid From An Aqueous Reaction Medium Containing Glyoxylic Acid And Hydrochloric Acid - The invention relates to a process for separating glyoxylic acid starting from an aqueous reaction medium containing glyoxylic acid and hydrochloric acid, comprising a step of countercurrent steam stripping of the reaction medium in order to obtain, on the one hand, a gas phase containing the volatile hydrochloric acid and, on the other hand, a liquid phase containing the purified glyoxylic acid. | 12-09-2010 |
20110137077 | PROCESS AND APPARATUS FOR OXIDIZING ORGANIC COMPOUNDS - The invention relates to a process for oxidizing at least one organic substance with oxygen, which comprises the following steps:
| 06-09-2011 |
20110144388 | PROCESS FOR PRODUCTION OF GLYCOLIC ACID - A process for producing glycolic acid from carbon monoxide and formaldehyde, optionally in a solvent, using a catalyst comprising an acidic polyoxometalate compound insoluble in formaldehyde, glycolic acid and the optional solvent, wherein the insoluble acidic polyoxometalate compound has a concentration of acid sites of greater than 60 μmol g | 06-16-2011 |
20110306790 | Oxidation Catalysts - Disclosed are catalysts comprised of platinum and gold. The catalysts are generally useful for the selective oxidation of compositions comprised of a primary alcohol group and at least one secondary alcohol group wherein at least the primary alcohol group is converted to a carboxyl group. More particularly, the catalysts are supported catalysts including particles comprising gold and particles comprising platinum, wherein the molar ratio of platinum to gold is in the range of about 100:1 to about 1:4, the platinum is essentially present as Pt(0) and the platinum-containing particles are of a size in the range of about 2 to about 50 nm. Also disclosed are methods for the oxidative chemocatalytic conversion of carbohydrates to carboxylic acids or derivatives thereof. Additionally, methods are disclosed for the selective oxidation of glucose to glucaric acid or derivatives thereof using catalysts comprising platinum and gold. Further, methods are disclosed for the production of such catalysts. | 12-15-2011 |
20120035393 | METHOD FOR PRODUCING ALIPHATIC CARBOXYLIC ACIDS FROM ALDEHYDES BY MICROREACTION TECHNOLOGY - A process for preparing aliphatic carboxylic acids having 3 to 10 carbon atoms by oxidizing the corresponding aldehydes with oxygen or oxygen-containing gases, characterized in that (i) the oxidation is performed in a microreactor at elevated pressure and with an oxygen excess based on the stoichiometrically required amount of oxygen, and (ii) in that the reaction mixture removed from the microreactor is passed through at least one postreactor without further addition of oxygen, and (iii) wherein the oxidation reaction in the microreactor is performed under such conditions that aldehyde and corresponding peracid formed are present in the reaction mixture removed in a molar ratio within a range of | 02-09-2012 |
20130245318 | METHOD FOR THE CONVERSION OF METHYLMERCAPTOPROPIONALDEHYDE FORMED FROM CRUDE ACROLEIN AND CRUDE METHYL MERCAPTAN - A reactive rectification column suitable for the production of 2-hydroxy-4-methylmercaptobutyric acid and/or methionine contains a weir having a height of 100 mm or more. | 09-19-2013 |
20130245319 | METHOD FOR CATALYTICALLY PRODUCING FORMIC ACID - The invention relates to a method for catalytically producing formic acid. A polyoxometallate ion, which is used as a catalyst, of the general formula [PMo | 09-19-2013 |
20130331605 | HYDROCARBOXYLATION OF AQUEOUS FORMALDEHYDE USING A DEHYDRATING RECYCLE STREAM TO DECREASE WATER CONCENTRATION - Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of aqueous formaldehyde. The water in the hydrocarboxylation zone is reduced via reaction with the ester bonds in a recycle stream comprising glycolic acid oligomers and/or methyl glycolate oligomers. | 12-12-2013 |
20130345473 | PROCESS FOR THE SEPARATION OF MONO- AND DI-CARBOXYLIC ACID COMPOUNDS - The present disclosure relates to processes for the separation of at least one di-carboxylic acid compound and/or at least one mono-carboxylic acid compound from a mixture. The separation processes involve contacting the mixture with an ion exchange medium to cause at least one of the mono- and/or di-carboxylic acid compounds to be retained by the medium, eluting at least one of the mono-carboxylic acid compound or the di-carboxylic acid compound using an eluent to form an eluate, wherein the eluate is enriched in at least one of the mono-carboxylic acid compound or di-carboxylic acid relative to the concentration of such eluted acid in the mixture having contacted the medium and wherein the eluent comprises an organic acid. The process has particular utility in the production of di-carboxylic acid compounds from glucose. | 12-26-2013 |
20140275621 | OXIDATION PROCESS - A process utilizing nitric acid and oxygen as co-oxidants to oxidize aldehydes, alcohols, polyols, preferably carbohydrates, specifically reducing sugars to produce the corresponding carboxylic acids. | 09-18-2014 |
20140275622 | NITRIC ACID OXIDATION PROCESS - A process utilizing nitric acid and oxygen as co-oxidants to oxidize aldehydes, alcohols, polyols, preferably carbohydrates, specifically reducing sugars to produce the corresponding carboxylic acids. | 09-18-2014 |
20140275623 | NITRIC ACID OXIDATION PROCESSES - A process utilizing nitric acid and oxygen as co-oxidants to oxidize aldehydes, alcohols, polyols, preferably carbohydrates, specifically reducing sugars to produce the corresponding carboxylic acids. | 09-18-2014 |
20150065749 | CATALYTIC OXIDATION OF URONIC ACIDS TO ALDARIC ACIDS - Disclosed is the oxidation of uronic acids, such as galacturonic acid, to the corresponding aldaric acids (characterized by the formula HOOC—(CHOH)n-COOH, with n being an integer of from 1 to 5) such as galactaric acids. The starting material comprising the uronic acid is subjected to oxygen under the influence of a supported gold catalyst and in the presence of a base. The oxidation occurs in good selectivity and yield, under unexpectedly mild conditions. A source of galacturonic acids is pectin, such as that derived from sugar beet pulp. | 03-05-2015 |
20150321187 | SHAPED POROUS CARBON PRODUCTS - Shaped porous carbon products and processes for preparing these products are provided. The shaped porous carbon products can be used, for example, as catalyst supports and adsorbents. Catalyst compositions including these shaped porous carbon products, processes of preparing the catalyst compositions, and various processes of using the shaped porous carbon products and catalyst compositions are also provided. | 11-12-2015 |
20160039735 | NITRIC ACID OXIDATION PROCESSES - A process utilizing nitric acid and oxygen as co-oxidants to oxidize aldehydes, alcohols, polyols, preferably carbohydrates, specifically reducing sugars to produce the corresponding carboxylic acids. | 02-11-2016 |
20180022678 | METHOD FOR CATALYTIC GENERATION OF FORMIC ACID AT AN OXYGEN PARTIAL PRESSURE BELOW 1 BAR AND REGENERATION OF THE CATALYST USED THEREFOR | 01-25-2018 |
562532000 | Producing unsaturated acid | 49 |
20080269521 | PROCESS FOR STARTING-UP A HETEROGENEOUSLY CATALYZED PARTIAL GAS PHASE OXIDATION OF ACROLEIN TO ACRYLIC ACID OR OF METHACROLEIN TO METHACRYLIC ACID - A process for starting-up a heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid or of methacrolein to methacrylic acid over a fixed catalyst bed disposed in a tube bundle reactor cooled by a heat exchange medium, wherein the temperature of the heat exchange medium is ≧290° C. and the temperature of that reactor plate surface which faces the reaction gas entry mixture and the temperature of the reaction gas entry mixture itself are ≦285° C. | 10-30-2008 |
20090247787 | METHOD OF PRODUCING UNSATURATED ALDEHYDE AND/OR UNSATURATED ACID - Disclosed is a shell-and-tube reactor that may be used for fixed-bed catalytic partial oxidation, the reactor being characterized by including at least one reaction zone of a first-step reaction zone for mainly producing unsaturated aldehydes and a second-step reaction zone for mainly producing unsaturated acids, wherein at least one reaction zone of the above reaction zones comprises two or more catalytic layers; each of the catalytic layers is packed with a formed product of catalyst that is different in pore density and/or pore size in a catalytically active component; and the pore density and/or pore size is controlled in such a manner that specific surface area of the catalytically active component increases from the inlet of the reactor to the outlet of the reactor. A method for producing unsaturated aldehydes and/or unsaturated fatty acids from olefins using the same reactor is also disclosed. According to the present invention, it is possible to control the temperature efficiently at a hot spot, thereby permitting stable use of a catalyst, and to produce unsaturated aldehydes and/or unsaturated fatty acids with high yield. | 10-01-2009 |
20090259071 | METHOD FOR REGENERATING CATALYST FOR THE PRODUCTION OF METHACRYLIC ACID AND PROCESS FOR PREPARING METHACRYLIC ACID - A catalyst for the production of methacrylic acid comprising a heteropolyacid compound containing phosphorus and molybdenum is regenerated by a method comprises the steps of heat-treating a deactivated catalyst at a temperature of at least 350° C., mixing the deactivated catalyst with water, a nitrate ion and an ammonium ion, then drying the mixture to obtain a dried catalyst, and calcining the dried catalyst. | 10-15-2009 |
20100168471 | METHOD FOR PREPARING ACRYLIC ACID FROM GLYCEROL - The invention relates to a method for preparing acrylic acid from an aqueous glycerol solution, comprising a first step of dehydration of the glycerol to acrolein, carried out in the gas phase in the presence of a catalyst and under a pressure of between 1 and 5 bar, and a second step of oxidation of the acrolein to acrylic acid, in which an intermediate step is implemented, consisting in at least partly condensing the water and heavy by-products present in the stream issuing from the first dehydration step. This method serves to obtain high acrylic acid productivity and selectivity. | 07-01-2010 |
20100168472 | Process for production of acrolein from glycerol - The present invention relates to a process for producing acrolein by liquid phase dehydration of glycerol by preparing a mixture of a catalyst suspended in an organic solvent comprising one or more vinyl polymers and glycerol; and then mixing and heating the mixture to between 150° C. and 350° C. to dehydrate the glycerol and form acrolein. The vinyl polymers are selected from the group consisting of polyolefins, polystyrene, and mixtures thereof. The polyolefins may be polyethylene, polypropylene, polybutylene, polyisobutylene, polyisoprene, polypentene, or mixtures thereof. The acrolein may be subjected to vapor phase oxidation in the presence of a catalyst, such as a mixed metal oxide, to produce acrylic acid. | 07-01-2010 |
20100249454 | Process for producing acrylic acid - The invention offers an improvement in a process for start-up in the occasion of producing acrylic acid by catalytically oxidizing acrolein at vapor phase under high load conditions, the start-up meaning the step of increasing the acrolein supply rate (loading) from the non-reacting condition to the prescribed reaction conditions. This process is characterized in that the acrolein supply rate is increased in the start-up stage of the reaction until the prescribed composition of starting reactant gas and the flow rate of the starting reactant gas are obtained, while adjusting at least one of the reaction temperature, the composition of the starting reactant gas and the flow rate of the starting reactant gas, so as to maintain the acrolein conversion at not lower than 90 mol %, the maximum peak temperature of the catalyst layer in each reaction zone at no higher than 400° C., and the sum of each ΔT (maximum peak temperature of a catalyst layer-reaction temperature) at the catalyst layer in each of the reaction zones to be no more than 150° C., respectively. According to this process, the reaction speedily reaches the steady state (standard operating conditions) and a high acrylic acid yield is stably achieved from the start of the reaction. | 09-30-2010 |
20100280269 | METHOD FOR PRODUCTION OF ACRYLIC ACID - To provide a method of producing acrylic acid which enables low energy-consumption production of acrylic acid from glycerin mixtures including glycerin and one or more compound selected from the group consisting of fatty acids, fatty acid salts, glycerides, fatty acid esters, alkali compounds and alkali compound salts. The method of producing acrylic acid according to the present invention includes the steps of obtaining an acrolein mixture by causing a dehydration reaction to a glycerin mixture; and obtaining an acrylic acid mixture by causing an oxidation reaction to the acrolein mixture; and recovering acrylic acid from the acrylic acid mixture. | 11-04-2010 |
20100331571 | MOLDING AND METHOD FOR PRODUCING THE SAME, AND CATALYST AND METHOD FOR PRODUCING THE SAME - An object of the present invention is to provide a molding and a method for producing the same; a catalyst for the production of an unsaturated aldehyde and an unsaturated carboxylic acid, and a method for producing the same; and a catalyst for the production of methacrylic acid, and a method for producing the same. | 12-30-2010 |
20110065953 | PROCESS FOR THE LONG-TERM OPERATION OF A HETEROGENEOUSLY CATALYZED PARTIAL GAS PHASE OXIDATION OF AN ORGANIC STARTING COMPOUND - A process for the long-term operation of a heterogeneously catalyzed partial gas phase oxidation of an organic starting compound, in which the reaction gas input mixture is partially oxidized over a fixed catalyst bed which is accommodated in two successive temperature zones A, B whose temperature is changed with increasing operating time such that the initially lower temperature increases and the difference between the two temperatures decreases. | 03-17-2011 |
20110087050 | ACROLEIN MANUFACTURING METHOD AND ACRYLIC ACID MANUFACTURING METHOD - The present invention relates to a method for producing acrolein, comprising step (1) of subjecting glycerol to dehydration reaction in the presence of a copper compound and a compound containing a heteroatom; step (2) of recovering acrolein generated in the dehydration reaction step (1); step (3) of recovering part or all of the copper compound which remained after the recovery of acrolein; step (4) of treating part or all of the recovered copper compound with at least one member selected from a group consisting of an oxidizing agent and acid; and step (5) of returning part or all of the copper compound treated in the above step to step (1); and a method for producing acrylic acid, comprising reacting acrolein obtained by the above method with molecular oxygen. The production method of the present invention enables efficient production of acrolein and acrylic acid from glycerol contained in plant oil and animal fats derived from carbon dioxide in air without depending on the oxidation of propylene derived from fossil resources. | 04-14-2011 |
20110137078 | Catalyst And Method For Producing Unsaturated Aldehyde And Unsaturated Carboxylic Acid - Provided is a catalyst which can prevent a lowering in selectivity for a target product in a gas phase catalytic reaction and has an excellent frictional resistance. A catalyst which is a supported catalyst comprising an inert support that is coated with a catalyst powder, characterized in that the inert support is ring-shaped and has an outer periphery that is curved in the lengthwise direction of the support, and the catalyst is produced by granulation in a moisten environment. The above described catalyst is useful in the gas phase oxidation of propylene, isobutylene, tertiary-butyl alcohol or methyl tertiary-butyl ether to thereby produce an unsaturated aldehyde corresponding thereto, or in the gas phase oxidation of such an unsaturated aldehyde as described above to thereby produce an unsaturated carboxylic acid. | 06-09-2011 |
20110237828 | ACROLEIN PRODUCTION METHOD AND ACRYLIC ACID PRODUCTION METHOD - Disclosed are an acrolein production method capable of producing acrolein from a glycerin mixture including either one or both of a fatty acid and a fatty acid salt, a glycerin; a fatty acid ester, and the like with a little consumption of energy, and an acrylic acid production method. Specifically disclosed is an acrolein production method having the steps of: dehydrating glycerin in the glycerin mixture to produce an acrolein mixture including acrolein; either one of a fatty acid and a fatty acid salt, and the like; and collecting acrolein from the acrolein mixture. Also specifically disclosed is an acrylic acid production method having the step of reacting acrolein produced by the acrolein production method with molecular oxygen. | 09-29-2011 |
20120016159 | Catalyst for Oxidation of Saturated and Unsaturated Aldehydes to Unsaturated Carboxylic Acid, Method of Making and Method of Using Thereof - The invention is a heteropoly acid compound catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition is a heteropoly acid compound containing molybdenum, vanadium, phosphorus, cesium, bismuth, copper and antimony. Thermal stability is achieved with higher cesium content (up to less than 3.0) but antimony, copper and bismuth must be present to maintain good activity. | 01-19-2012 |
20120178965 | METHOD FOR PRODUCING BIORESOURCED ACRYLIC ACID FROM GLYCEROL - An aim of the present invention is to produce, from glycerol, a bioresourced acrylic acid, that is to say an acrylic acid essentially based on a carbon source of natural origin, meeting all the quality criteria of monomers customarily used as starting material in processes for polymerization of acrylic acid and of its esters, via an economical process. The process according to the invention comprises a final stage of extraction of acrylic acid by fractional crystallization applied to one of the effluents resulting from the acrylic acid purification chain, the location of this final stage possibly depending on the initial feedstock treated, the nature and the source of the glycerol used in the process, purity specifications to be achieved for the final acrylic acid, or finally economic criteria. | 07-12-2012 |
20130165690 | METHOD FOR MANUFACTURING POLYMER-GRADE BIO-BASED ACRYLIC ACID FROM GLYCEROL - The present invention relates to a process for the manufacture of hioresourced acrylic acid of polymer grade having a content by weight of acrylic acid greater than 99% and the following contents of impurities: protoanemonin less than 5 ppm, total aldehydes less than 10 ppm, maleic anhydride less than 30 ppm, nonphenolic polymerization inhibitors less than 10 ppm, and a content by weight of | 06-27-2013 |
20130317253 | PROCESS FOR CONTINUOUS RECOVERING (METH) ACRYLIC ACID AND APPARATUS FOR THE PROCESS (AS AMENDED) - The present invention relates to a method and apparatus for continuous recovery of (meth)acrylic acid, and more specifically to a method of continuous recovery of (meth)acrylic acid, including: conducting gas phase oxidation of at least one compound selected from the group consisting of propane, propylene, butane, i-butylene, t-butylene, and (meth)acrolein in the presence of a catalyst to obtain a mixed gas containing (meth)acrylic acid; quenching the (meth)acrylic acid-containing mixed gas to remove high boiling point by-products in the (meth)acrylic acid-containing mixed gas; contacting the high boiling point by-product-free (meth)acrylic acid-containing mixed gas with water or an aqueous solution to obtain an aqueous solution containing (meth)acrylic acid; and purifying the aqueous solution containing (meth)acrylic acid to obtain (meth)acrylic acid. | 11-28-2013 |
20150087861 | METHOD FOR PRODUCING ACROLEIN AND/OR ACRYLIC ACID FROM GLYCEROL - The invention relates to the production of acrolein and/or acrylic acid from glycerol, and more particularly to a method for continuous production of a stream comprising acrolein by dehydration of glycerol, comprising cycles of reaction and regeneration of a dehydration catalyst. | 03-26-2015 |
20150344393 | PRODUCTION OF ACRYLIC ACID - The invention relates to a process for producing acrylic acid, comprising: converting a C3-oxygenate into acrolein, wherein said C3-oxygenate is selected from the group consisting of 1-propanol, monohydroxyacetone, 2-hydroxypropanal, 3-hydroxypropanal, dihydroxyacetone and 2,3-dihydroxypropanal; and converting the acrolein into acrylic acid. Said C3-oxygenate preferably contains 2 oxygen atoms, and most preferably it is monopropylene glycol. | 12-03-2015 |
20150353466 | PRODUCTION OF ACRYLIC ACID - The invention relates to a process for producing acrylic acid, comprising: converting a C3-oxygenate into propanoic acid, wherein said C3-oxygenate is a compound selected from the group consisting of 1-propanol, monopropylene glycol, monohydroxyacetone, 2-hydroxypropanal, glycerol and dihydroxyacetone; and converting the propanoic acid into acrylic acid. Said C3-oxygenate preferably contains 2 oxygen atoms, and most preferably it is monopropylene glycol. | 12-10-2015 |
20150360191 | PLANT AND PROCESS FOR PERFORMANCE OF HETEROGENEOUSLY CATALYZED GAS PHASE REACTIONS - The present invention relates to a plant ( | 12-17-2015 |
20160107968 | METHOD FOR PRODUCING ACROLEIN - The present invention relates to a process for preparing acrolein from propylene by catalytic gas phase oxidation with molecular oxygen (for example air). The invention further relates to the use of particular propylene-containing starting materials, for example refinery grade propylene, for preparation of acrolein. | 04-21-2016 |
562533000 | Liquid phase oxidation | 3 |
20100137638 | METHOD FOR PRODUCING ALPHA, BETA-UNSATURATED CALBOXYLIC ACID - Disclosed is a method for producing an α, β-unsaturated carboxylic acid from an olefin or an α, β-unsaturated aldehyde, while suppressing dissolution of a silica carrier, which is a carrier for a silica-supported noble metal-containing catalyst, in a water-containing solvent. Specifically disclosed is a method for producing an α, β-unsaturated carboxylic acid through oxidation of an olefin or an α, β-unsaturated aldehyde in a water-containing solvent in the presence of a silica-supported noble metal-containing catalyst in a reactor, in which at least one of silicic acid and ions thereof is supplied into the reactor. | 06-03-2010 |
20100234639 | METHOD FOR PRODUCING PALLADIUM-CONTAINING CATALYST - Disclosed is a palladium-containing catalyst for producing an α,β-unsaturated carboxylic acid from an olefin or an α,β-unsaturated aldehyde in high productivity. Also disclosed are a method for producing such a catalyst, and a method for producing an α,β-unsaturated carboxylic acid in high productivity. Specifically, a palladium-containing catalyst is produced by a method containing a step in which palladium in an oxidation state is reduced by a compound (A) which is represented by the following formula (1). | 09-16-2010 |
20120330058 | PROCESS FOR MANUFACTURING ACROLEIN AND/OR ACRYLIC ACID FROM GLYCEROL - The present invention relates to the manufacture of bioresourced acrolein and bioresourced acrylic acid from glycerol as starting material and more particularly comes within the scope of a process for the manufacture of acrolein and acrylic acid according to which the reaction for the dehydration of glycerol to give acrolein is carried out and the organic compounds which are heavier than water liable to be present in the various streams of the process arc removed, so as to obtain a stream which can be recycled to the dehydration stage without accumulation of heavy impurities, while minimizing the consumption of water and the discharge of polluted aqueous streams. | 12-27-2012 |
562534000 | Group VIII metal containing catalyst utilized | 7 |
20090171117 | METHOD FOR PRODUCING A MULTI METAL OXIDE CATALYST, METHOD FOR PRODUCING UNSATURATED ALDEHYDES AND/OR CARBOXYLIC ACIDS AND BAND CALCINATION DEVICE - A catalyst suitable for the gas-phase oxidation of organic compounds to α,β-unsaturated aldehydes and/or carboxylic acids and having an active phase comprising a multimetal oxide material is prepared by a process in which a particulate catalyst precursor which contains oxides and/or compounds of the elements other than oxygen which constitute the multimetal oxide material, which compounds can be converted into oxides, is prepared and said catalyst precursor is converted by calcination into a catalytically active form, wherein a stream of the particulate catalyst precursor is passed at substantially constant speed through at least one calcination zone at constant temperature for calcination. | 07-02-2009 |
20100298601 | Catalyst System, Oxidation Reactor Containing The Same, And Preparation Method For Acrolein And Acrylic Acid Using The Same - The present invention relates to a catalyst system, an oxidation reactor comprising the same, and a method for producing an acrolein and an acrylic acid by using the same. By using the catalyst system according to the present invention, when acrolein and acrylic acid are produced, since heat accumulation in a catalyst layer may be effectively prevented, catalyst deterioration may be prevented, and the catalyst may be stably used for a long period of time. In addition, an acrolein and an acrylic acid may be produced at high selectivity and high yield. | 11-25-2010 |
20110028760 | METHOD FOR THE REACTIVE VAPORIZATION OF GLYCEROL - The subject of the present invention is a method for the reactive vaporization of aqueous solutions of glycerol in a fluidized bed containing a reactive solid. The method of the invention makes it possible to simultaneously vaporize an aqueous solution of glycerol, to remove the impurities that are present in this solution or that are generated during the evaporation, and to carry out the dehydration reaction of the glycerol to acrolein and/or the oxydehydration reaction of the glycerol to acrylic acid. | 02-03-2011 |
20110178331 | OXIDE CATALYST, PROCESS FOR PRODUCING ACROLEIN OR ACRYLIC ACID AND PROCESS FOR PRODUCING WATER-ABSORBENT RESIN - The invention provides a process which enables, in preparation of acrolein by catalytic gas-phase oxidation of propylene in the presence of molecular oxygen or a molecular oxygen-containing gas or in preparation of acrylic acid by catalytic gas-phase oxidation of acrolein in the presence of molecular oxygen or a molecular oxygen-containing gas, using single kind of catalyst, to suppress occurrence of localized extraordinarily high temperature spots (hot spots) in the catalyst layer and can stably maintain high acrolein or acrylic acid yield for a long time. The process is characterized by use of an oxide catalyst containing molybdenum as an essential component and having relative standard deviation of its particle size in a range of 0.02 to 0.20. | 07-21-2011 |
20130261335 | PROCESS FOR PRODUCING ALKYL METHACRYLATE - An object of the present invention is to provide a process for producing methacrylic acid with good productivity over a long period of time. | 10-03-2013 |
20130274508 | SHELL AND TUBE OXIDATION REACTOR WITH IMPROVED RESISTANCE TO FOULING - The present disclosure relates to a single shell open interstage reactor (“SSOI”). The SSOI comprises a first reaction stage, an interstage heat exchanger, an open interstage region, and a second reaction stage. The SSOI may be configured for upflow or downflow operation. Further, the open interstage region of the SSOI may comprise a supplemental oxidant feed. When the open interstage region comprises a supplemental oxidant feed, the SSOI may further comprise a supplemental oxidant mixing assembly. Processes for producing acrylic acid through the oxidation of propylene are also disclosed. | 10-17-2013 |
20160175818 | HIGH PERFORMANCE POLYOXOMETAL CATALYST AND METHOD FOR PRODUCING THE SAME | 06-23-2016 |
562535000 | Group V metal containing catalyst utilized | 18 |
20080214863 | PROCESS FOR PREPARING A CATALYST CONSISTING OF A SUPPORT BODY AND A CATALYTICALLY ACTIVE COMPOSITION APPLIED ON THE SURFACE OF THE SUPPORT BODY - A process for preparing a coated catalyst in which a finely divided mixture of a multielement oxide comprising the elements Mo and V and a molybdenum oxide or a molybdenum oxide former is applied to the surface of a support body as an active composition. | 09-04-2008 |
20090043127 | COMPLEX METAL OXIDE CATALYST WITH HIGH (METH) ACRYLIC ACID SELECTIVITY - Disclosed are a Mo—Bi—Nb—Te based composite metal oxide; and a process for producing (meth)acrylic acid from at least one reaction material selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, wherein the Mo—Bi—Nb—Te based composite metal oxide is used as a catalyst. Also, disclosed is a process for producing (meth)acrylic acid comprising a first step of producing (meth)acrolein as a main product from at least one reaction material selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, and a second step of producing (meth)acrylic acid from the (meth)acrolein, wherein yield of (meth)acrylic acid in the product of the first step is 20 mole % or higher. | 02-12-2009 |
20090043128 | Catalyst and process for production of acrylic acid - An object of the present invention is to provide: a catalyst for production of acrylic acid which is a catalyst usable for production of acrylic acid and is excellent in the catalytic performances such as catalytic activity and in the physical properties such as physical strength of the catalyst itself; and a process for production of acrylic acid using this catalyst. As a means of achieving this object, a catalyst for production of acrylic acid according to the present invention is a catalyst obtained by drying a mixed liquid of starting materials including molybdenum and vanadium as essential components to give a dried material, molding the dried material with a liquid binder, and calcining the resultant molding, with the catalyst being characterized in that an ignition loss ratio of the dried material is from 5 to 40% by mass. A process for production of acrylic acid according to the present invention comprises the step of: subjecting acrolein to a catalytic gas phase oxidation in the presence of a molecular oxygen, with the process being characterized in that the above catalyst for production of acrylic acid according to the present invention is used. | 02-12-2009 |
20100204513 | Preparation process of a complex oxide catalyst and application thereof to the synthesis of the acrylic acid - The present invention provides a complex oxide catalyst whose general formula is Mo | 08-12-2010 |
20100240925 | METHODS FOR MAKING UNSATURATED ACIDS USING CATALYSTS FOR METHACROLEIN OXIDATION - Methods for making unsaturated acids using catalysts for oxidation of unsaturated and/or Saturated aldehyde to unsaturated acids is disclosed where the catalyst including at least molybdenum (Mo) and phosphorus (P), where the catalyst has a pore size distribution including at least 50% medium pores and if bismuth is present, a nitric acid to molybdenum mole ratio of at least 0.5:1 or at least 6.0:1 moles of HNO | 09-23-2010 |
20110166384 | CATALYST FOR PRODUCING ACRYLIC ACID AND PROCESS FOR PRODUCING ACRYLIC ACID USING THE CATALYST - A catalyst for producing acrylic acid from propane and/or acrolein by gas-phase catalytic oxidation with molecular oxygen-containing gas, comprising a catalytic active component containing molybdenum and vanadium as essential elements, and having a crystallinity T of 5% or more and 20% or less in the 20 range of 5° to 90°, measured by an X-ray diffraction analysis with Cu-Kα radiation; and a process for producing acrylic acid by gas-phase catalytic oxidation of propane and/or acrolein with molecular oxygen, comprising the step of conducting the gas-phase catalytic oxidation in the presence of the catalyst. According to the catalyst and the process for producing acrylic acid of the present invention, it is possible to stably produce acrylic acid at a high yield for a long period. | 07-07-2011 |
20110237829 | Method For Manufacturing Catalyst For Use In Production Of Methacrylic Acid - It is an object of the present invention to provide a catalyst having excellent performance and high mechanical strength for use in the production of methacrylic acid. | 09-29-2011 |
20110245535 | MULTI-METAL OXIDE CATALYST AND METHOD FOR PRODUCING (METH)ACRYLIC ACID BY USING THE SAME - The present invention provides a Mo—Bi—Nb based composite metal oxide (with the proviso that Te is not included); a method for producing (meth)acrylic acid from at least one reactant selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, in which a Mo—Bi—Nb based composite metal oxide (with the proviso that Te is not included) is used as a catalyst; and a reactor used for producing (meth)acrylic acid from at least one reactant selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, in which a Mo—Bi—Nb based composite metal oxide (with the proviso that Te is not included) is used as a catalyst. Further, the present invention provides a method for producing the (meth)acrylic acid without any additional process of converting (meth)acrolein into (meth)acrylic acid. | 10-06-2011 |
20110275856 | EGGSHELL CATALYST CONSISTING OF A HOLLOW CYLINDRICAL SUPPORT BODY AND A CATALYTICALLY ACTIVE OXIDE MATERIAL APPLIED TO THE OUTER SURFACE OF THE SUPPORT BODY - An eggshell catalyst consisting of a hollow cylindrical support body of length 2 to 10 mm, external diameter 4 to 10 mm and wall thickness 1 to 4 mm, and an eggshell, applied to the outer surface of the support body, of catalytically active oxide material of the general formula I, | 11-10-2011 |
20120245382 | PRODUCING ACETALDEHYDE AND/OR ACETIC ACID FROM BIOETHANOL - The invention discloses a method for producing acetaldehyde and/or acetic acid, according to which method a gaseous flow, containing molecular oxygen, ethanol and at least one impurity selected from sulphur compounds, is brought into contact at a high temperature with a sulphur-resistant oxidation catalyst. The ethanol is preferably obtained from a biomass. Said sulphur-resistant oxidation catalyst comprises, for example, vanadium oxide and at least one oxide of zirconium, titanium and aluminium. In one embodiment, the gaseous flow is converted, on the sulphur-resistant oxidation catalyst, into a first oxidation mixture, acetaldehyde being the predominant oxidation product, and said first oxidation mixture is converted, on another oxidation catalyst, into a second oxidation mixture, acetic acid being the predominant oxidation product. Said other oxidation catalyst comprises, for example, a multi-metal oxide containing at least molybdenum and vanadium. | 09-27-2012 |
20130217915 | Catalyst and Method for Producing Acrylic Acid - The present invention relates to a method for producing acrylic acid through vapor-phase contact oxidation of acrolein, wherein a reactor tube is divided into at least two catalyst layers, and catalysts having a higher activity are charged in the reactor tube sequentially toward an outlet port side from a material source gas inlet port side for a reaction therein to give acrylic acid, and wherein a catalyst activity-controlling method is a method comprising: a step of mixing a molybdenum-containing compound, a vanadium-containing compound, a copper-containing compound and an antimony-containing compound with water, then drying and calcining a resulting mixture, in which a catalytically-active element composition is kept constant but material source compounds are made to vary in type to give composite metal oxides having a different activity. | 08-22-2013 |
20130253223 | CATALYST FOR PRODUCING UNSATURATED CARBOXYLIC ACID AND A PROCESS FOR PRODUCING UNSATURATED CARBOXYLIC ACID USING THE CATALYST - Provided is a catalyst for producing unsaturated carboxylic acid, which excels in mechanical strength and attrition loss and is capable of producing the object product at a high yield. This catalyst is formed of a catalytically active component comprising molybdenum and vanadium as the essential ingredients and inorganic fibers, which are supported on an inert carrier, said catalyst being characterized in that said inorganic fibers comprise at least an inorganic fiber having an average diameter less than 1.0 μm and another inorganic fiber having an average diameter ranging from 1.5 to 7 μm. | 09-26-2013 |
20140018572 | PROCESS FOR HETEROGENEOUSLY CATALYZED GAS PHASE PARTIAL OXIDATION OF (METH)ACROLEIN TO (METH)ACRYLIC ACID - A process for preparing (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of (meth)acrolein over a multimetal oxide composition which comprises the elements Mo, V and W and is obtained by a hydrothermal preparation route, and the multimetal oxide composition obtainable by this preparation route. | 01-16-2014 |
20140221683 | PROCESS FOR PRODUCING A CATALYTICALLY ACTIVE COMPOSITION BEING A MIXTURE OF A MULTIELEMENT OXIDE COMPRISING THE ELEMENTS MO AND V AND AT LEAST ONE OXIDE OF MOLYBDENUM - A process for producing a catalytically active composition being a mixture of a multielement oxide comprising the elements Mo and V and at least one oxide of molybdenum, in which spray drying of an aqueous solution or of an aqueous suspension of starting compounds comprising the elements of the multielement oxide produces a spray powder P, a pulverulent oxide of molybdenum and optionally shaping assistants are added thereto, shaped bodies are shaped from the resulting mixture and these are converted to the catalytically active composition by thermal treatment. | 08-07-2014 |
20150057464 | METHOD FOR PRODUCING ACRYLIC ACID WITH A FIXED-BED MULTITUBULAR REACTOR - This invention provides a method for producing acrylic acid by catalytic gas-phase oxidation, which method makes it possible to carry out a continuous operation steadily for a long period of time while a high yield is maintained. | 02-26-2015 |
20150080605 | CATALYST FOR PREPARATION OF AN UNSATURATED CARBOXYLIC ACID BY GAS PHASE OXIDATION OF AN UNSATURATED ALDEHYDE - What is described is a catalyst for preparation of an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q | 03-19-2015 |
20150105583 | Catalyst For Methacrylic Acid Production, Process For Producing The Same, And Process For Producing Methacrylic Acid Using The Catalyst - An object of the present invention is to provide a process for producing a catalyst for gas-phase contact oxidation of methacrolein, isobutyraldehyde or isobutyric acid to produce methacrylic acid in a high yield and a high selectivity, and a catalyst wherein an alkali metal element, particularly cesium among alkali metal elements, is added by a specific method in a partially neutralized salt of a hetero polyacid which contains Mo, V, P, an alkali metal element and NH | 04-16-2015 |
20160051970 | Catalyst For Producing Methacrylic Acid And Method For Producing The Same, And Method For Producing Methacrylic Acid - Disclosed is a method for producing a catalyst for producing methacrylic acid by subjecting methacrolein or the like to vapor phase catalytic oxidation, which contains, as essential active components, Mo, V, P, Cs, NH | 02-25-2016 |