Entries |
Document | Title | Date |
20100003586 | Redox flow cell - A redox flow cell is presented that utilizes a porous membrane separating a first half cell and a second half cell. The porous membrane is chosen to have a figure of merit (FOM) is at least a minimum FOM. A method of providing a porous membrane for a flow cell can include determining a figure of merit; determining a first parameter from a pore size or a thickness for the porous membrane; determining a second parameter from the pore size or the thickness that is not the first parameter for the porous membrane, based on the figure of merit; and constructing a porous membrane having the pore size and the thickness. | 01-07-2010 |
20100021805 | Electrochemical energy generation system - An electrochemical energy generation system can include a sealed vessel that contains inside (i) at least one electrochemical cell, which has two electrodes and a reaction zone between them; (ii) a liquefied halogen reactant, such as a liquefied molecular chlorine; (iii) at least one metal halide electrolyte; and (iv) a flow circuit that can be used for delivering the halogen reactant and the electrolyte to the at least one cell. The sealed vessel can maintain an inside pressure above a liquefication pressure for the halogen reactant. Also disclosed are methods of using and methods of making for electrochemical energy generation systems. | 01-28-2010 |
20110027637 | Fluid-surfaced electrode - An electrochemical device (such as a battery) includes at least one electrode having a fluid surface, which may employ a surface energy effect to maintain a position of the fluid surface and/or to modulate flow within the fluid. Fluid-directing structures may also modulate flow or retain fluid in a predetermined pattern. An electrolyte within the device may also include an ion-transport fluid, for example infiltrated into a porous solid support. | 02-03-2011 |
20110027638 | Fluid-surfaced electrode - An electrochemical device (such as a battery) includes at least one electrode having a fluid surface, which may employ a surface energy effect to maintain a position of the fluid surface and/or to modulate flow within the fluid. Fluid-directing structures may also modulate flow or retain fluid in a predetermined pattern. An electrolyte within the device may also include an ion-transport fluid, for example infiltrated into a porous solid support. | 02-03-2011 |
20110027639 | Fluid-surfaced electrode - An electrochemical device (such as a battery) includes at least one electrode having a fluid surface, which may employ a surface energy effect to maintain a position of the fluid surface and/or to modulate flow within the fluid. Fluid-directing structures may also modulate flow or retain fluid in a predetermined pattern. An electrolyte within the device may also include an ion-transport fluid, for example infiltrated into a porous solid support. | 02-03-2011 |
20110171510 | NON-AQUEOUS ELECTROLYTE BATTERY - A non-aqueous electrolyte battery using an oxyhalide as an anodic action material, which can improve pulse discharge characteristics and provide a sufficient operating voltage. A non-aqueous electrolyte battery using an oxyhalide such as thionyl chloride, sulfuric chloride and phosphoryl chloride that are liquid at room temperature as an anodic action material, wherein, in place of a conventionally used metal lithium, a lithium alloy containing at least one kind of element selected from a group consisting of Zn, Ga, Cd, In, Sn, Sb and Bi is used as a cathode to thereby reduce the impedance of a battery and prevent a reduction in operating voltage at pulse discharging. Especially, a battery is obtained that gives a significant improvement effect at high temperature and is excellent in pulse discharge characteristics having long discharge duration days. | 07-14-2011 |
20120028096 | ELECTROCHEMICAL ENERGY GENERATION SYSTEM - An electrochemical energy generation system can include a sealed vessel that contains inside (i) at least one electrochemical cell, which has two electrodes and a reaction zone between them; (ii) a liquefied halogen reactant, such as a liquefied molecular chlorine; (iii) at least one metal halide electrolyte; and (iv) a flow circuit that can be used for delivering the halogen reactant and the electrolyte to the at least one cell. The sealed vessel can maintain an inside pressure above a liquefication pressure for the halogen reactant. Also disclosed are methods of using and methods of making for electrochemical energy generation systems. | 02-02-2012 |
20120077066 | Water based biological and photochemical batteries - The designs of prototype batteries are described based on some biological Fenton reactions and the photo-excitation of singlet oxygen. The biological battery consists of hydrogen peroxide (or an acid) and ferrous gluconate complexed with a second ligand. Salts such as sodium chloride or ammonium chloride are used as the electrolyte. The photochemical battery uses an aqueous paste of ferrous gluconate with an additional ligand and is irradiated by light. The power of the battery is higher by adding small amount of titanium oxide to ferrous gluconate. The power of these batteries can be increased by using higher concentration of the chemicals or connecting multiple batteries in sequence and/or in parallel. Replacing ferrous ion with cupric ions increases the current of the battery by about 20 times. | 03-29-2012 |
20120282508 | PARTIAL FLOW CELL - A partial flow cell may include a cathode chamber, an anode chamber, and a separator arrangement sandwiched between the cathode and anode chambers. The separator arrangement may be configured to permit ionic flow between electroactive materials disposed within the cathode and anode chambers. One of the cathode and anode chambers may be configured to permit an electroactive material to flow through the chamber during operation. The other of the cathode and anode chambers may be configured to hold an electroactive material fixed within the chamber during operation. | 11-08-2012 |
20120308867 | FLOWING ELECTROLYTE RESERVOIR SYSTEM - A flowing electrolyte reservoir system for a flowing electrolyte battery. The system comprises an outer electrolyte tank and an inner electrolyte tank placed under a battery cell stack. The inner tank is transversely positioned between opposite corners of the outer electrolyte tank, and beneath opposite corners of the battery cell stack. | 12-06-2012 |
20130011711 | MODULAR STACKED BATTERY SYSTEM - An energy storage cell charged and discharged by electrolyte fluid. The cell includes a module that comprises a wall that separates an anode plate from a cathode plate. An anode hub is connected to the anode plate and a cathode hub is connected to the cathode plate. The anode hub and cathode hub are assembled together through an opening in the wall. An electrical connector connects the anode hub to the cathode hub to electrically connect the anode plate to the cathode plate maintaining the plates on separate sides of the wall at the same electrical potential. A plurality of energy storage cells are connected together to provide a flow cell battery system. | 01-10-2013 |
20130059189 | PRESSURE DENSITY DIFFERENTIAL DEVICE - An electrochemical cell provided with two half cells. A pressure or density differential is created between the cathode and anode electrodes, each of which is contained in one of the half cells. The pressure or density differential is created by single or multiple sources including compression, vacuum, weight (gravity) of mass, chemical, molecular, or, pressure or density differentials created by thermal gradients. | 03-07-2013 |
20130071714 | FLOW BATTERY STACK WITH AN INTEGRATED HEAT EXCHANGER - A flow battery stack includes a plurality of flow battery cells, a manifold and a heat exchanger. Each flow battery cell includes an electrode layer that is wet by an electrolyte solution having a reversible redox couple reactant. The manifold includes a solution passage that exchanges the electrolyte solution with the flow battery cells. The heat exchanger includes a heat exchange fluid passage. The heat exchanger exchanges heat between the electrolyte solution in the solution passage and a heat exchange fluid directed through the heat exchange fluid passage. The flow battery cells, the manifold and the heat exchanger are arranged between first and second ends of the flow battery stack. | 03-21-2013 |
20130095361 | HIGH SURFACE AREA FLOW BATTERY ELECTRODES - A flow cell battery includes at least one anode and at least one cathode, with a separator membrane disposed between each anode and each cathode. Each anode and cathode includes a bipolar plate and a carbon nanotube material positioned proximally at least one side of the bipolar plate. | 04-18-2013 |
20130101880 | HIGH TEMPERATURE LITHIUM BATTERY, HAVING INITIAL LOW TEMPERATURE USE CAPABILITY - A battery and method of making such battery, adapted to operate at low (typically ambient) temperatures for a short initial period and thereafter at higher temperatures. A Li—Mg alloy anode is provided, comprising up to 25% magnesium, in a liquid thionyl chloride bath which as the cathode for high temperature operation. A thin, substantially pure lithium layer is applied to a surface of the Li—Mg anode, preferably in the range of 0.0019 to 0.0025 inches (0.04826-0.0635 mm), to allow obtaining of sufficiently high power and voltage output at lower temperatures for a short period where at such lower temperatures the required voltage and power would not otherwise be available from a Li—Mg anode. Thereafter, the battery may thereafter be used in, and exposed to, higher temperatures of up to 220° C. where at such temperatures the necessary voltage and power from the remaining Li—Mg alloy anode is then available. | 04-25-2013 |
20130115504 | ION EXCHANGE MEMBRANE FILLING COMPOSITION, METHOD OF PREPARING ION EXCHANGE MEMBRANE, ION EXCHANGE MEMBRANE, AND REDOX FLOW BATTERY - A composition for filling an ion exchange membrane, a method of preparing the ion exchange membrane, the filled ion exchange membrane, and a redox flow battery using the filled ion exchange membrane. The composition includes an ion conductive material and a water soluble support. | 05-09-2013 |
20130196206 | ORGANIC ELECTROLYTE SOLUTION AND REDOX FLOW BATTERY INCLUDING THE SAME - An organic electrolyte solution including a solvent; an electrolyte including a metal-ligand coordination compound; and an additive including a hydrophobic group and a metal affinic group. | 08-01-2013 |
20130344367 | HIGH ENERGY DENSITY REDOX FLOW DEVICE - Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described. | 12-26-2013 |
20140038019 | BIPOLAR ION EXCHANGE MEMBRANES FOR BATTERIES AND OTHER ELECTROCHEMICAL DEVICES - A bipolar ion exchange membrane suitable for use in ZnBr batteries, LiBr batteries, and electrolyzers. The membrane is produced by hot pressing or extruding a mixture of an anion exchange ionomer powder, a cation exchange ionomer powder, and a non-porous polymer powder. | 02-06-2014 |
20140065460 | REDOX AND PLATING ELECTRODE SYSTEMS FOR AN ALL-IRON HYBRID FLOW BATTERY - A system for a flow cell for a hybrid flow battery, comprising: a redox plate comprising a plurality of electrolyte flow channels; conductive inserts attached to the redox plate between adjacent electrolyte flow channels; a redox electrode attached to a surface of the redox plate; a plating electrode, comprising: a plurality of folded fins with an oscillating cross-section, the plurality of folded fins comprising: a first planar surface; a second planar surface, parallel to the first planar surface; a plurality of ridges intersecting the first and second planar surfaces such that the plurality of ridges divide the first planar surface into a first plurality of strips, and divide the second planar surface into a second plurality of strips; and a membrane barrier. In this way, the capacity and performance of hybrid flow batteries may be maximized, through decreasing the reaction kinetics, mass transport and ohmic resistance losses at both electrodes. | 03-06-2014 |
20140154546 | High Energy Density Redox Flow Device - Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume. | 06-05-2014 |
20140162104 | Battery Electrode Material Formulation and Manufacturing Process - An improved chemical composition and manufacturing process for a battery electrode are disclosed. This battery electrode may be later arranged in flowing electrolyte battery cells. Battery electrode material formulation may include a mixture of polypropylene, carbon black, graphite, bonding additives and other substances in different concentrations. The inclusion of graphite may reduce the amount of carbon black in the mixture, thereby reducing the swelling of the battery electrode in the presence of bromine. Moreover, material formulation may reduce warpage caused by the swelling of electrode material, and may additionally improve the performance and properties of flowing electrolyte batteries. An extrusion molding process may be employed in order to fabricate the disclosed battery electrode. | 06-12-2014 |
20140302370 | METAL SULFIDE ELECTRODES AND ENERGY STORAGE DEVICES THEREOF - The present invention generally relates to energy storage devices, and to metal sulfide energy storage devices in particular. Some aspects of the invention relate to energy storage devices comprising at least one flowable electrode, wherein the flowable electrode comprises an electroactive metal sulfide material suspended and/or dissolved in a carrier fluid. In some embodiments, the flowable electrode further comprises a plurality of electronically conductive particles suspended and/or dissolved in the carrier fluid, wherein the electronically conductive particles form a percolating conductive network. An energy storage device comprising a flowable electrode comprising a metal sulfide electroactive material and a percolating conductive network may advantageously exhibit, upon reversible cycling, higher energy densities and specific capacities than conventional energy storage devices. | 10-09-2014 |
20140342209 | Lithium-sulfur secondary battery containing gradient electrolyte - A rechargeable lithium-sulfur cell comprising a cathode, an anode, a separator electronically separating the two electrodes, a first electrolyte in contact with the cathode, and a second electrolyte in contact with the anode, wherein the first electrolyte contains a first concentration, C | 11-20-2014 |
20150050537 | Li/Metal Battery with Composite Solid Electrolyte - In accordance with one embodiment, an electrochemical cell includes a first anode including a form of lithium a first cathode including an electrolyte, and a first composite electrolyte structure positioned between the first anode and the first cathode, the first composite electrolyte structure including (i) a first support layer adjacent the first anode and configured to mechanically suppress roughening of the form of lithium in the first anode, and (ii) a first protective layer positioned between the first support layer and the first cathode and configured to prevent oxidation of the first support layer by substances in the first cathode. | 02-19-2015 |
20150099150 | ELECTROCHEMICAL SYSTEMS AND METHODS FOR HARVESTING HEAT ENERGY - Electrochemical systems for harvesting heat energy, and associated electrochemical cells and methods, are generally described. | 04-09-2015 |
20150118535 | BATTERY BASED ON ORGANOSULFUR SPECIES - Metal-sulfur batteries, such as lithium-sulfur batteries, are prepared using one or more organosulfur species such as organic polysulfides and organic polythiolates as part of the liquid or gel electrolyte solution, as part of the cathode, and/or as part of a functionalized porous polymer providing an intermediate separator element. | 04-30-2015 |
20150325821 | ELECTROCHEMICAL ENERGY STORAGE DEVICES AND HOUSINGS - The disclosure provides electrochemical batteries, electrochemical battery housings and methods for assembling electrochemical batteries. The battery housing can include a container, a container lid assembly and an electrical conductor. The container can include a cavity that extends into the container from a cavity aperture. The lid assembly can seal the cavity, and can include an electrically conductive container lid and an electrically conductive flange. The container lid can cover the cavity aperture and can include a conductor aperture that extends through the container lid. The flange can cover the conductor aperture and can be electrically isolated from the container lid. The conductor can be connected to the flange and can extend through the conductor aperture into the cavity. The conductor can be electrically isolated from the container lid. | 11-12-2015 |
20150357125 | Printable Ionic Gel Separation Layer For Energy Storage Devices - Representative embodiments provide a liquid or gel separator utilized to separate and space apart first and second conductors or electrodes of an energy storage device, such as a battery or a supercapacitor. A representative liquid or gel separator comprises a plurality of particles, typically having a size (in any dimension) between about 0.5 to about 50 microns; a first, ionic liquid electrolyte; and a polymer. In another representative embodiment, the plurality of particles comprise diatoms, diatomaceous frustules, and/or diatomaceous fragments or remains. Another representative embodiment further comprises a second electrolyte different from the first electrolyte; the plurality of particles are comprised of silicate glass; the first and second electrolytes comprise zinc tetrafluoroborate salt in 1-ethyl-3-methylimidalzolium tetrafluoroborate ionic liquid; and the polymer comprises polyvinyl alcohol (“PVA”) or polyvinylidene fluoride (“PVFD”). Additional components, such as additional electrolytes and solvents, may also be included. | 12-10-2015 |
20150364767 | POROUS ELECTRODE ASSEMBLY, LIQUID-FLOW HALF-CELL, AND LIQUID-FLOW CELL STACK - The disclosure discloses a porous electrode assembly, a flow half-cell and a flow cell stack. The porous electrode assembly includes multiple porous electrodes which are stacked, wherein at least two porous electrodes are flow passage electrodes with flow passage, and a part of flow passages of at least two flow passage electrodes are mutually communicated to form a flow field. The flow field used for circulating an electrolyte and formed by communicating the flow passages one another is arranged in at least one porous electrode of the porous electrode assembly, and the electrolyte flows in the porous electrodes under a flow guide effect of the flow field, so that surface areas, permeated by the electrolyte, of solid parts of the porous electrodes are enlarged, flow resistance of the porous electrodes to the flowing of the electrolyte is reduced, and a flow pressure difference is reduced. | 12-17-2015 |
20160056491 | SEMI-SOLID ELECTRODES HAVING HIGH RATE CAPABILITY - Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell includes an anode, a semi-solid cathode that includes a suspension of an active material and a conductive material in a liquid electrolyte, and an ion permeable membrane disposed between the anode and the cathode. The semi-solid cathode has a thickness in the range of about 250 μm-2,500 μm, and the electrochemical cell has an area specific capacity of at least 5 mAh/cm | 02-25-2016 |
20160126579 | FLOW BATTERY WITH HYDRATED ION-EXCHANGE MEMBRANE HAVING MAXIMUM WATER DOMAIN CLUSTER SIZES - A flow battery includes a cell that has a first electrode, a second electrode spaced apart from the first electrode and an electrolyte separator layer arranged between the first electrode and the second electrode. A supply/storage system is external of the at least one cell and includes first and second vessels that are fluidly connected with the at least one cell. First and second fluid electrolytes are located in the supply/storage system. The electrolyte separator layer includes a hydrated ion-exchange membrane of a polymer that has a carbon backbone chain and side chains extending from the carbon backbone chain. The side chains include hydrophilic chemical groups with water molecules attached by secondary bonding to form clusters of water domains. The clusters have an average maximum cluster size no greater than 4 nanometers, with an average number of water molecules per hydrophilic chemical group, λ (lambda), being greater than zero. | 05-05-2016 |
20160254551 | FLOW BATTERY AND SUPPLY/DISCHARGE PLATE OF FLOW BATTERY | 09-01-2016 |