| Class / Patent application number | Description | Number of patent applications / Date published |
|---|
| 208213000 | With solid catalyst or absorbent | 82 |
| 20090050534 | PROCESS FOR REMOVING SULFUR FROM SEPARATE LESS REACTIVE AND MORE REACTIVE FUEL GAS STREAMS CONTAINING ORGANIC SULFUR AND LIGHT OLEFINS - Disclosed is a process for removing organic sulfur from more than one reactive fuel gas stream. A reactor vessel that is provided with at least one bed of hydrodesulfurization catalyst is used to hydrodesulfurize multiple reactive fuel gas streams with a less reactive fuel gas stream being introduced into the reactor vessel at a point above the introduction point of a more reactive fuel gas stream. An hydrotreated fuel gas is yielded from the reactor vessel having a hydrogen sulfide concentration and a low organic sulfur content. | 02-26-2009 |
| 20090236266 | Diesel desulfurization method - A diesel desulfurization method has various steps including: implementing a modified oxidative desulfurization (UAOD) process. The UAOD has the steps of: mixing diesel fuel with room temperature ionic liquid, oxidant, phase transfer catalyst, and acid catalyst in a tank in a mix; recycling the ionic liquid and recycling the acid catalyst in aqueous phase. A step is to move the sulfur from the diesel fuel in a fluidized bed reactor (FBR) having bed reactor material. The process can be improved with ultrasound during mixing, or a high shear mixer. The bed reactor is preferably acidic alumina for adsorbing oxidized sulfur. The oxidant is preferably hydrogen peroxide (H2O2). The acid catalyst is preferably a mixture of Acetic acid and Tri-fluoro acetic acid. | 09-24-2009 |
| 20090242459 | OXIDATIVE DESULFURIZATION OF FUEL OIL - A method for purifying a sulfur-containing fuel oil comprising (a) contacting in a first reaction mixture the sulfur-containing fuel oil with an exogenous binary catalyst, hydrogen peroxide, and a water-soluble acid at a temperature in a range of from about 25° C. to about 150° C. to provide a first oxidized mixture; and (b) separating at least one oxidized sulfur compound from the first oxidized mixture to provide a purified fuel oil. The first reaction mixture may further comprise a phase transfer catalyst. Furthermore, the sulfur-containing fuel oil may be deasphalted prior to contacting with the catalyst, hydrogen peroxide, and the water-soluble acid. | 10-01-2009 |
| 20090242460 | OXIDATIVE DESULFURIZATION OF FUEL OIL - A method for purifying a sulfur-containing fuel oil comprising (a) contacting the fuel oil with a supported exogenous binary catalyst and oxygen at a temperature in a range of from about 25° C. to about 150° C., and at a pressure in a range of from about 1 atmosphere to about 150 atmospheres to provide a first oxidized mixture; and (b) separating at least one oxidized sulfur compound from the first oxidized mixture to a provide a purified fuel oil. In one embodiment, the sulfur-containing fuel oil is deasphalted prior to contacting with the supported exogenous binary catalyst and oxygen. | 10-01-2009 |
| 20100084316 | Desulfurization of heavy hydrocarbons and conversion of resulting hydrosulfides utilizing a transition metal oxide - The present invention is a process for desulfurizing hydrocarbon feedstreams with alkali metal compounds and regenerating the alkali metal compounds via the use of a transition metal oxide. The present invention employs the use of a transition metal oxide, preferably copper oxide, in order to convert spent alkali metal hydrosulfides in the regeneration of the alkali hydroxide compounds for reutilization in the desulfurization process for the hydrocarbon feedstreams. Additionally, in preferred embodiments of the processes disclosed herein, carbonates which may be detrimental to the overall desulfurization process and related equipment are removed from the regenerated alkali metal stream. | 04-08-2010 |
| 20100084317 | Desulfurization of heavy hydrocarbons and conversion of resulting hydrosulfides utilizing copper metal - The present invention is a process for desulfurizing hydrocarbon feedstreams with alkali metal compounds and regenerating the alkali metal compounds via the use of a copper metal reagent. The present invention employs the use of a copper metal reagent to convert spent alkali metal hydrosulfides in the regeneration of the alkali hydroxide compounds for reutilization in the desulfurization process for the hydrocarbon feedstreams. Additionally, in preferred embodiments of the processes disclosed herein, carbonates which may be detrimental to the overall desulfurization process and related equipment are removed from the regenerated alkali metal stream. | 04-08-2010 |
| 20100084318 | DESULFURIZATION OF HEAVY HYDROCARBONS AND CONVERSION OF RESULTING HYDROSULFIDES UTILIZING COPPER SULFIDE - The present invention is a process for desulfurizing hydrocarbon feedstreams with alkali metal compounds and regenerating the alkali metal compounds via the use of a copper sulfide reagent. The present invention employs the use of a copper sulfide reagent to convert alkali metal hydrosulfides in the generation or regeneration of the alkali hydroxide compounds which may be utilized in a desulfurization process for hydrocarbon feedstreams. Additionally, in preferred embodiments of the processes disclosed herein, carbonates which form as byproducts of the desulfurization process, and are non-regenerable with copper sulfide, are removed from the alkali hydroxide stream. | 04-08-2010 |
| 20100187160 | METHOD FOR PURIFYING MINERAL OIL FRACTIONS AND DEVICE SUITABLE FOR CONDUCTING SAID METHOD - Disclosed is a method for reducing the organic sulfur content in a sulfur-containing liquid fuel, wherein the sulfur-containing fuel is first brought in contact with a hydrogen-containing gas in a presaturator and subsequently the hydrogen-enriched liquid fuel is brought in contact with a suitable adsorbent in a reactor. The adsorbent is able to adsorb at least part of the sulfur and/or of the sulfur compound from the fuel at the surface. The contact with the adsorbent can advantageously take place not only at higher temperatures of approximately 400° C., but also at moderate temperatures, as low as room temperature, because the use of liquid fuel ensures very good contact between the fuel and the surface of the adsorbent, and therefore ensures reduction of the sulfur content. | 07-29-2010 |
| 20100326889 | METHOD OF RESTORING CATALYTIC ACTIVITY TO A SPENT HYDROTREATING CATALYST, THE RESULTING RESTORED CATALYST, AND A METHOD OF HYDROPROCESSING - A method of restoring catalytic activity to a spent hydroprocessing catalyst that has a first carbon concentration. The concentration of carbon on the spent hydroprocessing catalyst is reduced to provide a carbon-reduced catalyst having a second carbon concentration that is less than the first carbon concentration. The carbon-reduced catalyst is exposed to a solution, comprising a chelating agent and a solvent, for an aging time period sufficient to provide for a restored catalytic activity thereby resulting in an aged catalyst having incorporated therein the chelating agent and the solvent. The aged catalyst is exposed to conditions, including a drying temperature, so as to remove from the aged catalyst a portion of the solvent without removing a significant portion of the chelating agent from the aged catalyst thereby resulting in a dried aged catalyst. The dried aged catalyst is then sulfur treated to thereby provide a restored catalyst. The restored catalyst and those catalysts made by the treatment method can be used in a hydroprocessing process comprising contacting the restored catalyst with a hydrocarbon feedstock under hydroprocessing conditions. | 12-30-2010 |
| 20120205290 | Hydroprocessing Catalyst Prepared with Waste Catalyst Fines and Its Use - A hydroprocessing catalyst composition that comprises a shaped support that is formed from a mixture of inorganic oxide powder and catalyst fines and wherein the shaped support has incorporated therein at least one metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition is prepared by incorporating into the shaped support a metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition has particular application in the catalytic hydroprocessing of petroleum derived feedstocks. | 08-16-2012 |
| 20120205291 | Method of Making a Hydroprocessing Catalyst with a Single Step Metal and Chelant Incorporation, the Catalyst, and the Use of the Catalyst - A hydroprocessing catalyst composition that comprises a metal-incorporated support having incorporated therein a metal component and a chelating agent, and, further comprising a polar additive. The catalyst composition is prepared by incorporating in a single step at least one metal component and a chelating agent into a support material to form a metal-incorporated support followed by drying the metal-incorporated support and thereafter incorporating therein a polar additive. | 08-16-2012 |
| 20120305450 | NANOPOROUS ARTICLES AND METHODS OF MAKING SAME - A method is provided for producing an ultra-low sulfur hydrocarbon product from a hydrocarbon feedstock containing refractory sulfur compounds utilizing a carbon adsorbent. Also described is a hydrocarbon processing system configured to produce an ultra-low sulfur hydrocarbon product from hydrocarbon feedstock containing refractory sulfur compounds. The hydrocarbon processing system also utilizes a carbon adsorbent. | 12-06-2012 |
| 20140166541 | HYDROPROCESSING CO-CATALYST COMPOSITIONS AND METHODS OF INTRODUCTION THEREOF INTO HYDROPROCESSING UNITS - A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed. | 06-19-2014 |
| 20140339135 | COMPOSITION AND A METHOD OF MAKING AND USE OF SUCH COMPOSITION - A composition and method of making such a composition that has application in the hydroprocessing of hydrocarbon feedstocks. The method comprises selecting an organic additive by the use of a correlation model for predicting catalytic activity as a function of a physical property that is associated with the organic additive and incorporating the organic additive into a support material to provide the additive impregnated composition. | 11-20-2014 |
| 20140367311 | SILICA CONTAINING ALUMINA SUPPORTS, CATALYSTS MADE THEREFROM AND PROCESSES USING THE SAME - Alumina support compositions comprising at least 0.1 wt % of silica are disclosed. The alumina support are characterized by a pore volume of greater than 0.60 cc/g, a median pore size ranging from about 70 to about 120, a pore size distribution such that at least 90% of the total pore volume falls within the range of about 20 to about 250, and a pore size distribution width of no less than about 40. Alumina compositions of the present invention exhibit a primary peak mode at a pore diameter less than the median pore diameter. Also provided are catalysts made from the alumina supports, and processes of preparing and using the supports and catalysts. | 12-18-2014 |
| 20160060547 | HYDROPROCESSING WITH DRUM BLANKETING GAS COMPOSITIONAL CONTROL - A catalytic naphtha hydrodesulfurization process is operated in a process unit having a surge drum with equipped for gas blanketing with a blanketing gas containing controlled levels of CO and CO | 03-03-2016 |
| 208214000 | With hydrogen yielding material (H donor) | 2 |
| 20100018905 | Deep hydrodesulfurization of hydrocarbon feedstreams - The distillate catalytic hydrodesulfurization of hydrocarbon fuels wherein the optimum hydrogen treat gas rate to maximize desulfurization is determined and introduced into the reaction zone to maintain a controlled amount of hydrogen at the surface of the catalyst during hydrodesulfurization. | 01-28-2010 |
| 20100108571 | HYDROTREATING PROCESS WITH IMPROVED HYDROGEN MANAGEMENT - This invention relates to an improved hydrotreating process for removing sulfur from naphtha and distillate feedstreams. This improved process utilizes a hydrotreating zone, an acid gas removal zone, and a pressure swing adsorption zone having a total cycle time of less than about 30 seconds for increasing the concentration of hydrogen utilized in the process. | 05-06-2010 |
| 208215000 | With heavy metal sulfide | 11 |
| 20100294699 | PROCESS FOR HYDRODESULFURIZATION, HYDRODENITROGENATION, HYDROFINISHING, OR AMINE PRODUCTION - Herein disclosed is a method for hydrodesulfurization, hydrodenitrogenation, hydrofinishing, amine production or a combination thereof. The method comprises forming a dispersion comprising hydrogen-containing gas bubbles dispersed in a liquid feedstock, wherein the bubbles have a mean diameter of less than about 5 μm and wherein the feedstock comprises a mixture of petroleum-derived hydrocarbons and a naturally derived renewable oil. The feedstock comprises hydrocarbons selected from the group consisting of liquid natural gas, crude oil, crude oil fractions, gasoline, diesel, naphtha, kerosene, jet fuel, fuel oils, and combinations thereof. The method further comprises contacting the dispersion with a catalyst that is active for hydrodesulfurization, hydrodenitrogenation, hydrofinishing, amine production, or a combination thereof. The catalyst comprises homogeneous catalysts and heterogeneous catalysts. The catalyst may be utilized in fixed-bed or slurry applications. | 11-25-2010 |
| 20110017641 | PRE-SULFIDING AND PRE-CONDITIONING OF RESIDUUM HYDROCONVERSION CATALYSTS FOR EBULLATED-BED HYDROCONVERSION PROCESSES - A hydroconversion process is disclosed, including contacting of hydrogen and a residuum hydrocarbon with a pre-conditioned and at least partially sulfided hydroconversion catalyst for converting at least a portion of the residuum hydrocarbon into at least one of a hydrotreated product and a hydrocracked product. Pre-sulfiding and pre-conditioning of the catalyst may include: intermittently or continuously: feeding a hydroconversion catalyst comprising a metal oxide to a pre-reactor; feeding hydrogen and the residuum hydrocarbon comprising sulfur-containing compounds to the pre-reactor; contacting the hydroconversion catalyst with hydrogen and the sulfur-containing compounds in the pre-reactor at conditions of temperature and pressure to concurrently: i) convert at least a portion of the metal oxide to a metal sulfide; and ii) pre-condition the catalyst; recovering a residuum hydrocarbon having a reduced sulfur content from the pre-reactor; and transporting the pre-conditioned and at least partially sulfided hydroconversion catalyst from the pre-reactor to the ebullated-bed hydroconversion reactor. | 01-27-2011 |
| 20120145600 | Solutions and Catalysts Comprising Group VI Metal, Group VIII Metal, Phosphorus and An Additive - This invention provides a process for forming a solution composition, which process comprises forming a primary solution by bringing together, in an aqueous medium, i) at least one phosphorus compound, ii) at least one Group VI metal compound, iii) at least one Group VIII metal compound, and iv) an additive which is a) tetraethylene glycol, b) polyethylene glycol having an average molecular weight in the range of about 200 to about 400, c) a mixture of tetraethylene glycol and polyethylene glycol having an average molecular weight in the range of about 200 to about 400, or d) a mixture of (1) tetraethylene glycol and/or polyethylene glycol having an average molecular weight in the range of about 200 to about 400 and (2) one or more of monoethylene glycol, diethylene glycol, and triethylene glycol. The molar ratio of additive to the total moles of Group VI metal and Group VIII metal is above 0.30:1, and the atomic ratio of phosphorus to Group VI metal is at least about 0.33:1. Optionally, the primary solution is heated at a temperature above about 40° C. to form a heated solution. The heated solution is optionally cooled to form a cooled solution. Also provided are compositions formed by such processes, processes for forming catalyst compositions from these compositions, and catalyst compositions formed by these processes. | 06-14-2012 |
| 20130153467 | HYDRODESULFURIZATION CATALYST FOR HYDROCARBON OIL, PROCESS OF PRODUCING SAME AND METHOD FOR HYDROREFINING - A hydrodesulfurization catalyst is produced by pre-sulfurizing a hydrodesulfurization catalyst Y including a support containing silica, alumina and titania and at least one metal component supported thereon and selected from VIA and VIII groups of the periodic table (comprising at least Mo), in which the total area of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes in the support, measured by X-ray diffraction analysis being ¼ or less of the alumina diffraction peak area assigned to γ-alumina (400) planes. The molybdenum is formed into molybdenum disulfide crystal disposed in layers on the support by the pre-sulfurization, and having an average length of longer than 3.5 nm and 7 nm or shorter in the plane direction and an average number of laminated layers of more than 1.0 and 1.9 or fewer. | 06-20-2013 |
| 20130168292 | PROCESS FOR THE HYDRODESULPHURIZATION OF A GASOLINE CUT IN THE PRESENCE OF A SUPPORTED SULPHIDE CATALYST PREPARED USING AT LEAST ONE CYCLIC OLIGOSACCHARIDE - Hydrodesulphurization of a gasoline cut containing hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting the gasoline cut with at least one catalyst having an active phase of at least one metal from group VIII and at least one metal from group VIB deposited on a support, said catalyst being prepared using a process of:
| 07-04-2013 |
| 20140374319 | HYDROPROCESSING CATALYSTS AND THEIR PRODUCTION - The precursor of a hydroprocessing catalyst is made by impregnating a metal oxide component comprising at least one metal from Group 6 of the Periodic Table and at least one metal from Groups 8-10 of the Periodic Table with an amide formed from a first organic compound containing at least one amine group, and a second organic compound containing at least one carboxylic acid group. Following impregnation heat treatment follows to form in situ generated unsaturation additional to that in the two organic compounds. The catalyst precursor is sulfided to form an active, sulfide hydroprocessing catalyst. | 12-25-2014 |
| 20150337221 | COMPOSITION USEFUL IN THE HYDROPROCESSING OF A HYDROCARBON FEEDSTOCK - A composition having a substantial or material absence of or no phosphorous and comprising a support material, a metal compound and either a hydrocarbon oil or a polar additive or a combination of both a hydrocarbon oil and polar additive. The polar additive has particularly defined properties including having a dipole moment of at least 0.45. The composition is useful in the hydroprocessing of hydrocarbon feedstocks, and it is especially useful in the hydrotreating of vacuum gas oils and petroleum resid feedstocks. | 11-26-2015 |
| 20160067685 | SELENIUM-CONTAINING HYDROPROCESSING CATALYST, ITS USE, AND METHOD OF PREPARATION - A hydroprocessing catalyst composition that comprises a support material and a selenium component and which support material further includes at least one hydrogenation metal component. The hydroprocessing catalyst is prepared by incorporating a selenium component into a support particle and, after calcination thereof, incorporating at least one hydrogenation metal component into the selenium-containing support. The metal-incorporated, selenium-containing support is calcined to provide the hydroprocessing catalyst composition. | 03-10-2016 |
| 20160067686 | PROCESS FOR PREPARING A SULPHIDED CATALYST - The invention provides a process for preparing a sulphided catalyst comprising the steps of (a) treating a catalyst carrier with one or more Group VIB metal components, one or more Group VIII metal components and a glycolic acid ethoxylate ether compound according to the formula (I) R—(CH | 03-10-2016 |
| 20160129428 | SELF-ACTIVATING HYDROPROCESSING CATALYST HAVING ENHANCED ACTIVITY AND SELF-ACTIVATION CHARACTERISTICS AND ITS USE FOR TREATING RESID FEEDSTOCKS - A self-activating catalyst for treating heavy hydrocarbon feedstocks that comprises a calcined particle treated with a sulfoxide compound in the presence of hydrogen. The calcined particle comprises a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound and then forming the co-mulled mixture into a particle that is calcined to thereby provide the calcined particle. The calcined particle comprises from 1 to 10 weight percent molybdenum and nickel that is present in an amount such that the weight ratio of said nickel-to-molybdenum is less than 0.4. The calcined particle has a pore size distribution that contributes to the unique properties of the catalyst. The enhanced self-activating catalyst is used in the hydroprocessing of heavy residue feedstocks that have high nickel, vanadium and sulfur concentrations. | 05-12-2016 |
| 20160152901 | PROCESS FOR THE START-UP OF HYDROTREATMENT OR HYDROCONVERSION UNITS | 06-02-2016 |
| 208216000 | With group VI metal or compound | 41 |
| 20080308462 | Bulk Catalyst Composition And A Process Preparing The Bulk Catalyst Composition - The invention relates to a bulk catalyst composition comprising metal oxidic particles comprising one or more Group VIII metals and two or more Group VIB metals, which bulk catalyst composition comprises first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals and separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, wherein the first and second oxidic bulk particles-are separately shaped to separate first and second shaped bulk catalyst particles, which are combined, preferably into a homogeneous blend, to form the bulk catalyst composition. The invention further relates to a process for the preparation of the bulk catalyst composition and to hydroprocessing a hydrocarbon feed using the bulk catalyst composition. | 12-18-2008 |
| 20090008294 | Hydroprocessing Of Naphtha Streams At Moderate Conditions - The invention is drawn to a catalyst having a substantially bimodal support phase and an active metal phase that is suitable and stable for desulfurization of high-olefin content naphtha streams with minimal octane-loss running at low hydrogen pressure. The active metal phase preferably includes cobalt, molybdenum and at least one additional metal selected from the alkali-metals group. | 01-08-2009 |
| 20090107891 | PROCESS FOR PREPARING HYDROPROCESSING BULK CATALYSTS - A process to prepare hydroprocessing bulk catalysts is provided. The hydroprocessing catalyst has the formula (M | 04-30-2009 |
| 20090127165 | Bulk Catalyst Comprising Nickel Tungsten Metal Oxidic Particles - The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst. | 05-21-2009 |
| 20090145808 | CATALYST TO ATTAIN LOW SULFUR DIESEL - This invention relates to a hydrodesulfurization catalyst and a method for preparing the catalyst by spray pyrolysis. The catalyst is useful for the hydrodesulfurization of gas oils, particularly diesel. The catalyst particles can include at least one metal selected from molybdenum, cobalt and nickel, and a silicon dioxide support. The spray pyrolysis technique allows for the preparation of catalyst particles having high loading of catalyst on the substrate. | 06-11-2009 |
| 20090166263 | Low pressure selective desulfurization of naphthas - A low hydrogen partial pressure process for desulfurizing naphtha in the presence of a hydrodesulfurization catalyst which catalyst is selective for suppressing hydrogenation of olefins and in the presence. This invention also relates to the use of optimum metals loading for achieving a high level of hydrodesulfurization with a low level of olefin saturation. | 07-02-2009 |
| 20090230026 | Catalyst To Attain Low Sulfur Gasoline - This invention relates to a hydrodesulfurization catalyst, a method for preparing the catalyst, and a method for the preparation of low sulfur gasoline fuel with minimal loss of RON. The catalyst particles include a group VIB metal and a support material having relatively high surface area, and optionally includes one or more group VIIIB metal. The method for preparing the catalyst allows for greater loading of the active metal species on the surface of the support material under aqueous reaction conditions. | 09-17-2009 |
| 20090266744 | PROCESS FOR PRE-TREATING A DESULFURIZATION SORBENT - A process for presulfiding a plurality of sorbent particles prior to using at least a portion of the particles to at least partially desulfurize a hydrocarbon feed stream. Typically, presulfiding can be carried out in a presulfiding zone under presulfiding conditions. In one embodiment, the process can be carried out in a desulfurization system comprising a fluidized bed reactor and fluidized bed regenerator and can be completed in less than about 36 hours. | 10-29-2009 |
| 20090308792 | CATALYST AND METHOD FOR HYDRODESULFURIZATION OF HYDROCARBONS - Oil soluble catalysts are used in a process to hydrodesulfurize petroleum feedstock having a high concentration of sulfur-containing compounds and convert the feedstock to a higher value product. The catalyst complex includes at least one attractor species and at least one catalytic metal that are bonded to a plurality of organic ligands that make the catalyst complex oil-soluble. The attractor species selectively attracts the catalyst to sulfur sites in sulfur-containing compounds in the feedstock where the catalytic metal can catalyze the removal of sulfur. Because the attractor species selectively attracts the catalysts to sulfur sites, non-productive, hydrogen consuming side reactions are reduced and greater rates of hydrodesulfurization are achieved while consuming less hydrogen per unit sulfur removed. | 12-17-2009 |
| 20110068047 | Methods and Units for Mitigation of Carbon Oxides During Hydrotreating - This invention relates to methods and units for mitigation of carbon oxides during hydrotreating hydrocarbons including mineral oil based streams and biological oil based streams. A hydrotreating unit includes a first hydrotreating reactor for receiving a mineral oil based hydrocarbon stream and forming a first hydrotreated product stream, and a second hydrotreating reactor for receiving a biological oil based hydrocarbon stream and forming a second hydrotreated product stream. | 03-24-2011 |
| 20120037540 | Hydrotreating Catalyst Containing Phosphorus And Boron - A catalyst having at least one Group VIB metal component, at least one Group VIII metal component, a phosphorus component, and a boron-containing carrier component. The amount of the phosphorus component is at least 1 wt %, expressed as an oxide (P | 02-16-2012 |
| 20120318717 | HYDROTREATING CATALYST FOR HYDROCARBON OIL AND METHOD FOR PRODUCING SAME, AND HYDROCARBON OIL HYDROTREATING METHOD USING SAME - Provided are: a hydrotreating catalyst for hydrocarbon oil having a hydrodesulfurization activity additionally improved by: simultaneously and continuously adding an aqueous solution of an acidic compound containing titanium and an aqueous solution containing an alkaline compound to a hydrosol containing an alumina hydrate particle at a temperature of 10 to 100° C. and a pH of 4.5 to 6.5; washing the resultant to remove a contaminating ion; forming the washed product after dehydration so as to have a moisture content at which it is formable; drying the resultant; impregnating the dried product with a catalytic component aqueous solution containing at least one kind of periodic table group 6 metal compound, at least one kind of periodic table group 8-10 metal compound, at least one kind of phosphorus compound, and at least one kind of saccharide; and drying the resultant; a manufacturing method for the catalyst; and a hydrodesulfurization treatment method for hydrocarbon oil using the catalyst. | 12-20-2012 |
| 20130233769 | METHOD OF PRODUCING REGENERATED HYDROTREATING CATALYST AND METHOD OF PRODUCING PETROLEUM PRODUCTS - A method of producing a regenerated hydrotreating catalyst, including a first step of preparing a hydrotreating catalyst that has been used for hydrotreatment of a petroleum fraction and has a metal element selected from Group 6 elements of the periodic table; a second step of performing regeneration treatment for part of the catalyst prepared in the first step, then performing X-ray absorption fine structure analysis for the catalyst after the regeneration treatment, and obtaining regeneration treatment conditions in which a ratio IS/IO of a peak intensity IS of a peak attributed to a bond between the metal element and a sulfur atom to a peak intensity IO of a peak attributed to a bond between the metal element and an oxygen atom is in the range of 0.1 to 0.3 in a radial distribution curve obtained from an extended X-ray absorption fine structure spectrum. | 09-12-2013 |
| 20130256195 | SELENIUM-CONTAINING HYDROPROCESSING CATALYST, ITS USE, AND METHOD OF PREPARATION - A hydroprocessing catalyst composition that comprises a support material and a selenium component and which support material further includes at least one hydrogenation metal component. The hydroprocessing catalyst is prepared by incorporating a selenium component into a support particle and, after calcination thereof, incorporating at least one hydrogenation metal component into the selenium-containing support. The metal-incorporated, selenium-containing support is calcined to provide the hydroprocessing catalyst composition. | 10-03-2013 |
| 20140174989 | TRANSITION METAL CATALYSTS FOR HYDRODESULFURIZATION - Phosphoranimide-metal catalysts and their role in hydrodesulfurization are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and catalyze hydrodesulfurization of a range of sulfur-containing organic compounds under lower temperature and pressure conditions than those commonly used in industrial hydrodesulfurization. | 06-26-2014 |
| 20140183100 | PROCESS FOR HYDRODESULPHURATION OF GASOLINE CUTS USING A CATALYST BASED ON HETEROPOLYANIONS TRAPPED IN A MESOSTRUCTURED SILICA SUPPORT - The invention relates to a process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (H | 07-03-2014 |
| 20140305842 | Process for Upgrading a High Endpoint Gas Oil Containing High Concentrations of Thiophenes and Nitrogen and Providing for a Reduced Hydrogen Consumption Rate. - A process and catalyst that provides for the upgrading of a high endpoint gas oil feedstock that contains significant concentrations of organic sulfur compound and organic nitrogen compounds. Included among the sulfur compounds are the dimethyl-dibenzothiophenes and derivative thereof. The catalyst of the process is an additive impregnated composition or a derivative thereof that further comprises cobalt and molybdenum. The process provides for the upgrading the high endpoint gas oil feedstock by significantly reducing the difficult to remove thiophene and nitrogen compounds and the process does this with a significantly reduced hydrogen consumption relative to processes using comparative catalysts. | 10-16-2014 |
| 20140305843 | LOW-PRESSURE PROCESS UTILIZING A STACKED-BED SYSTEM OF SPECIFIC CATALYSTS FOR THE HYDROTREATING OF A GAS OIL FEEDSTOCK - A low-pressure process for hydrodenitrogenation and hydrodesulfurization of a gas oil feedstock. The process uses a multi-bed, stacked-bed reactor system. The first and third beds of the multi-bed, stacked-bed reactor system include catalysts that comprise cobalt and molybdenum supported on alumina. The middle, second bed, includes a catalyst comprising nickel and molybdenum supported on alumina that preferably includes an additive. The stacked bed arrangement with the use of the specific catalysts provides for the low-pressure operation and significantly improved HDN and HDS activity with relatively insignificant differences in hydrogen consumption. | 10-16-2014 |
| 20150108039 | CATALYST FOR THE HYDROTREATMENT OF A HEAVY HYDROCARBON FEEDSTOCK - Disclosed is a method of hydrotreating a heavy hydrocarbon feedstock using a hydrotreating catalyst having specific properties that make it effective in converting nitrogen, sulfur and micro-carbon residue of a heavy hydrocarbon feedstock. The catalyst comprises a calcined support particle impregnated with a Group 6 metal component (e.g., molybdenum), a nickel component, and a phosphorus component present at concentrations in the catalyst such that the atomic ratio of the Group 6 metal-to nickel metal are within a specified range. The nickel metal acid extractability property of the catalyst is at least 50 percent. | 04-23-2015 |
| 20150122702 | CATALYST TO ATTAIN LOW SULFUR GASOLINE - This invention relates to a hydrodesulfurization catalyst, a method for preparing the catalyst, and a method for the preparation of low sulfur gasoline fuel with minimal loss of RON. The catalyst particles include a group VIB metal and a support material having relatively high surface area, and optionally includes one or more group VIIIB metal. The method for preparing the catalyst allows for greater loading of the active metal species on the surface of the support material under aqueous reaction conditions. | 05-07-2015 |
| 20150306579 | A HYDROTREATING CATALYST, PRODUCTION AND USE THEREOF - This invention relates to a hydrotreating catalyst suitable for heavy distillate oil hydrodesulfurization, production and use thereof. The present hydrotreating catalyst exhibits significantly improved heavy distillate oil (deep) hydrodesulfurization activity. | 10-29-2015 |
| 20150307789 | HIGH ACTIVITY HYDROTREATING CATALYSTS AND PROCESSES USING THE SAME - This disclosure relates to supported multi-metallic catalysts for use in the hydrotreating of hydrocarbon feeds. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIB metal, at least one Group VIII metal and an organic acid. The catalyst precursor is thermally treated to partially decompose the organic acid, then sulfided. The catalysts have a high carbon-as-carboxyl to total carbon ratio (C | 10-29-2015 |
| 20160008792 | PROCEDIMIENTO DE OBTENCION DE UNA FORMULACION CATALITICA PARA LA PRODUCCION DE DIESEL DE ULTRABAJO AZUFRE, EL PRODUCTO OBTENIDO Y SU APLICACION | 01-14-2016 |
| 20090272674 | Nano zeolite containing hydrotreating catalyst and method of preparation - The present invention provides nano zeolite containing hydrotreating catalyst and methods of preparation, and more particularly to a nano-sized zeolite beta composite hydrotreating catalyst. The hydrotreating catalyst for desulfurization of diesel distillates includes between about 5 to about 75 wt % nano-sized zeolite beta composite, about 10 to about 30 wt % of a hydrogenation metal/alloy and between about 5 to about 20 wt % binder. | 11-05-2009 |
| 20100320123 | Selective Catalysts Having Silica Supports For Naphtha Hydrodesulfurization - A method for hydrodesulfurizing FCC naphtha is described. More particularly, a Co/Mo metal hydrogenation component is loaded on a silica or modified silica support in the presence of organic ligand and sulfided to produce a catalyst which is then used for hydrodesulfurizing FCC naphtha. The silica support has a defined pore size distribution which minimizes olefin saturation. | 12-23-2010 |
| 20100326890 | HIGHLY STABLE HEAVY HYDROCARBON HYDRODESULFURIZATION CATALYST AND METHODS OF MAKING AND USE THEREOF - Described is a catalyst useful in the hydroprocessing of a heavy hydrocarbon feedstock wherein the catalyst comprises a calcined mixture made by calcining a formed particle of a mixture comprising molybdenum trioxide, a nickel compound, and an inorganic oxide material. The catalyst may be made by mixing an inorganic oxide material, molybdenum trioxide, and a nickel compound to form a mixture that is formed into a particle and calcined to provide a calcined mixture. The process involves the hydrodesulfurization and hydroconversion of a heavy hydrocarbon feedstock which process may include the conversion of a portion of the pitch content of the heavy hydrocarbon feedstock and the yielding of a treated product having an enhanced stability as reflected by its P-value. | 12-30-2010 |
| 20120067780 | Process For Hydrodesulphurizing Gasoline Employing A Catalyst With Controlled Porosity - A novel process is described which allows selective hydrodesulphurizing gasoline cuts containing sulphur-containing compounds and olefins. The process employs a catalyst comprising a support selected, for example, from refractory oxides such as aluminas, silicas, silica-aluminas or magnesia, used alone or as a mixture, a group VI metal, preferably Mo or W which may or may not be promoted by a group VIII metal, Co or Ni. The catalyst is characterized by a mean pore diameter of more than 22 nm. The process may comprise one or more steps. | 03-22-2012 |
| 20120091039 | EBULLATED BED HYDROTREATING SYSTEMS AND PROCESSES OF HEAVY CRUDE OIL - Disclosed are a mixed catalyst comprising catalyst A and catalyst B mixed in a volume ratio ranging from 1:0.1 to 1:10, heavy crude oil ebullated-bed hydrotreating systems comprising at least one ebullated-bed reactor comprising the mixed catalyst, and heavy crude oil ebullated-bed hydrotreating processes comprising: introducing heavy crude oil and hydrogen into at least one ebullated-bed reactor, reacting the heavy crude oil and the hydrogen with the mixed catalyst in the at least one ebullated-bed reactor to produce reaction products; and discharging the reaction products from the top of the at least one ebullated-bed reactor. | 04-19-2012 |
| 20120181219 | HYDRODESULFURIZATION CATALYST FOR HYDROCARBON OIL, PROCESS OF PRODUCING SAME AND METHOD FOR HYDROREFINING - The present invention provides a hydrodesulfurization catalyst that exhibits a high desulfurization activity when used in hydrotreatment of hydrocarbon oil, in particular straight-run gas oil. The catalyst includes at least one type of metal component selected from Groups VIA and VIII in the periodic table, supported on a silica-titania-alumina support where the total of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes is ¼ or less of the diffraction peak area indicating the aluminum crystal structure ascribed to γ-alumina (400) planes, as measured by X-ray diffraction analysis. The catalyst has (a) a specific surface area (SA) of 150 m | 07-19-2012 |
| 20120205292 | Chelant and Polar Additive Containing Composition Useful in the Hydroprocessing of Hydrocarbon Feedstocks and Method of Making and Use Thereof - A hydroprocessing catalyst composition that comprises a chelant treated metal containing support material having incorporated therein a polar additive. The catalyst composition is prepared by incorporating at least one metal component into a support material followed by treating the metal incorporated support with a chelating agent and thereafter incorporating a polar additive into the chelant treated composition. | 08-16-2012 |
| 20120292231 | A HIGH ACTIVITY HYDRODESULFURIZATION CATALYST, A METHOD OF MAKING A HIGH ACTIVITY HYDRODESULFURIZATION CATALYST, AND A PROCESS FOR MANUFACTURING AN ULTRA-LOW SULFUR DISTILLATE PRODUCT - A method of making a high activity catalyst composition suitable for use in the hydrodesulfurization of a middle distillate feed, such as diesel fuel, having a high concentration of sulfur, to thereby provide a low sulfur middle distillate product. The method comprises heat treating aluminum hydroxide under controlled temperature conditions thereby converting the aluminum hydroxide to gamma-alumina to give a converted aluminum hydroxide, and controlling the fraction of converted aluminum hydroxide that is gamma-alumina. A catalytic component is incorporated into the converted aluminum hydroxide to provide an intermediate, which is heat treated to provide the high activity catalyst composition. The high activity catalyst composition can suitably be used in the hydrodesulfurization of a middle distillate feed containing a high sulfur concentration. | 11-22-2012 |
| 20130105364 | LOW COST AND HIGH ACTIVITY HYDROPROCESSING CATALYST | 05-02-2013 |
| 20130284640 | HYDROPROCESSING CATALYST AND PROCESS FOR TREATING HEAVY HYDROCARBON FEEDSTOCKS - A catalyst for treating heavy hydrocarbon feedstocks. The catalyst comprises a calcined particle comprising a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound or cobalt compound, or both compounds, and then forming the co-mulled mixture into a particle that is calcined to provide the calcined particle. The calcination is conducted at a temperature such that at least 20% of the pore volume of the calcined particle is in pores of greater than 5,000 Å and less than 70% of the pore volume of the calcined particle is in the pores having a pore size in the range of from 70 to 250 Å. | 10-31-2013 |
| 20140076783 | HIGH ACTIVITY HYDRODESULFURIZATION CATALYST, A METHOD OF MAKING A HIGH ACTIVITY HYDRODESULFURIZATION CATALYST, AND A PROCESS FOR MANUFACTURING AN ULTRA-LOW SULFUR DISTILLATE PRODUCT - A method of making a high activity catalyst composition suitable for use in the hydrodesulfurization of a middle distillate feed, such as diesel fuel, having a high concentration of sulfur, to thereby provide a low sulfur middle distillate product. The method comprises heat treating aluminum hydroxide under controlled temperature conditions thereby converting the aluminum hydroxide to gamma-alumina to give a converted aluminum hydroxide, and controlling the fraction of converted aluminum hydroxide that is gamma-alumina. A catalytic component is incorporated into the converted aluminum hydroxide to provide an intermediate, which is heat treated to provide the high activity catalyst composition. The high activity catalyst composition can suitably be used in the hydrodesulfurization of a middle distillate feed containing a high sulfur concentration. | 03-20-2014 |
| 20140116924 | SELF-ACTIVATING HYDROPROCESSING CATALYST AND PROCESS FOR TREATING HEAVY HYDROCARBON FEEDSTOCKS - A self activating catalyst for treating heavy hydrocarbon feedstocks that comprises a calcined particle comprising a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound and then forming the co-mulled mixture into a particle that is calcined to thereby provide the calcined particle. The calcined particle comprises from 1 to 10 weight percent molybdenum and nickel that is present in an amount such that the weight ratio of said nickel-to-molybdenum is less than 0.4. The calcined particle has a pore size distribution that contributes to the unique properties of the catalyst. The calcined particle and catalyst also exhibits a unique Raman spectrum. The self activating catalyst is activated when contacted under suitable process conditions with a heavy residue feedstock having high nickel, vanadium and sulfur concentrations. | 05-01-2014 |
| 20140190869 | SELECTIVE CATALYSTS HAVING HIGH TEMPERATURE ALUMINA SUPPORTS FOR NAPHTHA HYDRODESULFURIZATION - This invention relates to a catalyst and method for hydrodesulfurizing naphtha. More particularly, a Co/Mo metal hydrogenation component is loaded on a high temperature alumina support in the presence of a dispersion aid to produce a catalyst that is then used for hydrodesulfurizing naphtha. The high temperature alumina support has a defined surface area that minimizes olefin saturation. | 07-10-2014 |
| 20140231310 | PROCESS FOR HYDRODESULPHURATION OF GASOIL CUTS USING A CATALYST BASED ON HETEROPOLYANIONS TRAPPED IN A MESOSTRUCTURED SILICA SUPPORT - The invention relates to a process of hydrodesulphuration of at least one gasoil cut implementing a catalyst containing, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (H | 08-21-2014 |
| 20150314282 | CATALYST AND ITS USE FOR THE SELECTIVE HYDRODESULFURIZATION OF AN OLEFIN CONTAINING HYDROCARBON FEEDSTOCK - A catalyst and its use for selectively desulfurizing sulfur compounds present in an olefin-containing hydrocarbon feedstock to very low levels with minimal hydrogenation of olefins. The catalyst comprises an inorganic oxide substrate containing a nickel compound, a molybdenum compound and optionally a phosphorus compound, that is overlaid with a molybdenum compound and a cobalt compound. The catalyst is further characterized as having a bimodal pore size distribution with a large portion of its total pore volume contained in pores having a diameter less than 250 angstroms and in pores having a diameter greater than 1000 angstroms. | 11-05-2015 |
| 20160059223 | HYDRODESULFURIZATION CATALYST FOR DIESEL OIL AND HYDROTREATING METHOD FOR DIESEL OIL - A hydrodesulfurization catalyst supports one or more metals selected from elements in Group 6 of the Periodic table, one or more metals selected from elements in Group 9 or Group 10 of the same, phosphorus, and an organic acid on a composite oxide support having a specific content of both alumina and HY zeolite having a specific crystallite size. The catalyst includes 10% to 40% by mass of the Group 6 metal, 1% to 15% by mass of the Group 9 or Group 10 metal, and 1.5% to 8% by mass of phosphorus in terms of an oxide based on the catalyst. The catalyst includes 0.8% to 7% by mass of carbon derived from an organic acid and for 1 mole of the Group 9 or Group 10 element metal in terms of an element based on the catalyst, and includes 0.2 to 1.2 moles of the organic acid. | 03-03-2016 |
| 20160250622 | RESID HYDROTREATING CATALYST CONTAINING TITANIA | 09-01-2016 |
| 20220135888 | Hydrotreating Catalyst for Heavy Hydrocarbon Oil, Method for Producing the Same, and Method for Hydrotreating Heavy Hydrocarbon Oil - Provided is a hydrotreating catalyst for a heavy hydrocarbon oil, the catalyst including an inorganic oxide carrier including alumina as a main component and a metal component supported on the inorganic oxide carrier, the catalyst having a specific surface area within a predetermined range, a reduction peak temperature that is lower than 450° C. in temperature-programmed reduction measurement of the catalyst and that is higher than or equal to a predetermined temperature, and an amount of nitrogen monoxide adsorbed on the sulfided catalyst within a predetermined range. | 05-05-2022 |
| 208216000 | With specific porosity or pore volume | 18 |
| 20080308462 | Bulk Catalyst Composition And A Process Preparing The Bulk Catalyst Composition - The invention relates to a bulk catalyst composition comprising metal oxidic particles comprising one or more Group VIII metals and two or more Group VIB metals, which bulk catalyst composition comprises first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals and separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, wherein the first and second oxidic bulk particles-are separately shaped to separate first and second shaped bulk catalyst particles, which are combined, preferably into a homogeneous blend, to form the bulk catalyst composition. The invention further relates to a process for the preparation of the bulk catalyst composition and to hydroprocessing a hydrocarbon feed using the bulk catalyst composition. | 12-18-2008 |
| 20090008294 | Hydroprocessing Of Naphtha Streams At Moderate Conditions - The invention is drawn to a catalyst having a substantially bimodal support phase and an active metal phase that is suitable and stable for desulfurization of high-olefin content naphtha streams with minimal octane-loss running at low hydrogen pressure. The active metal phase preferably includes cobalt, molybdenum and at least one additional metal selected from the alkali-metals group. | 01-08-2009 |
| 20090107891 | PROCESS FOR PREPARING HYDROPROCESSING BULK CATALYSTS - A process to prepare hydroprocessing bulk catalysts is provided. The hydroprocessing catalyst has the formula (M | 04-30-2009 |
| 20090127165 | Bulk Catalyst Comprising Nickel Tungsten Metal Oxidic Particles - The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst. | 05-21-2009 |
| 20090145808 | CATALYST TO ATTAIN LOW SULFUR DIESEL - This invention relates to a hydrodesulfurization catalyst and a method for preparing the catalyst by spray pyrolysis. The catalyst is useful for the hydrodesulfurization of gas oils, particularly diesel. The catalyst particles can include at least one metal selected from molybdenum, cobalt and nickel, and a silicon dioxide support. The spray pyrolysis technique allows for the preparation of catalyst particles having high loading of catalyst on the substrate. | 06-11-2009 |
| 20090166263 | Low pressure selective desulfurization of naphthas - A low hydrogen partial pressure process for desulfurizing naphtha in the presence of a hydrodesulfurization catalyst which catalyst is selective for suppressing hydrogenation of olefins and in the presence. This invention also relates to the use of optimum metals loading for achieving a high level of hydrodesulfurization with a low level of olefin saturation. | 07-02-2009 |
| 20090230026 | Catalyst To Attain Low Sulfur Gasoline - This invention relates to a hydrodesulfurization catalyst, a method for preparing the catalyst, and a method for the preparation of low sulfur gasoline fuel with minimal loss of RON. The catalyst particles include a group VIB metal and a support material having relatively high surface area, and optionally includes one or more group VIIIB metal. The method for preparing the catalyst allows for greater loading of the active metal species on the surface of the support material under aqueous reaction conditions. | 09-17-2009 |
| 20090266744 | PROCESS FOR PRE-TREATING A DESULFURIZATION SORBENT - A process for presulfiding a plurality of sorbent particles prior to using at least a portion of the particles to at least partially desulfurize a hydrocarbon feed stream. Typically, presulfiding can be carried out in a presulfiding zone under presulfiding conditions. In one embodiment, the process can be carried out in a desulfurization system comprising a fluidized bed reactor and fluidized bed regenerator and can be completed in less than about 36 hours. | 10-29-2009 |
| 20090308792 | CATALYST AND METHOD FOR HYDRODESULFURIZATION OF HYDROCARBONS - Oil soluble catalysts are used in a process to hydrodesulfurize petroleum feedstock having a high concentration of sulfur-containing compounds and convert the feedstock to a higher value product. The catalyst complex includes at least one attractor species and at least one catalytic metal that are bonded to a plurality of organic ligands that make the catalyst complex oil-soluble. The attractor species selectively attracts the catalyst to sulfur sites in sulfur-containing compounds in the feedstock where the catalytic metal can catalyze the removal of sulfur. Because the attractor species selectively attracts the catalysts to sulfur sites, non-productive, hydrogen consuming side reactions are reduced and greater rates of hydrodesulfurization are achieved while consuming less hydrogen per unit sulfur removed. | 12-17-2009 |
| 20110068047 | Methods and Units for Mitigation of Carbon Oxides During Hydrotreating - This invention relates to methods and units for mitigation of carbon oxides during hydrotreating hydrocarbons including mineral oil based streams and biological oil based streams. A hydrotreating unit includes a first hydrotreating reactor for receiving a mineral oil based hydrocarbon stream and forming a first hydrotreated product stream, and a second hydrotreating reactor for receiving a biological oil based hydrocarbon stream and forming a second hydrotreated product stream. | 03-24-2011 |
| 20120037540 | Hydrotreating Catalyst Containing Phosphorus And Boron - A catalyst having at least one Group VIB metal component, at least one Group VIII metal component, a phosphorus component, and a boron-containing carrier component. The amount of the phosphorus component is at least 1 wt %, expressed as an oxide (P | 02-16-2012 |
| 20120318717 | HYDROTREATING CATALYST FOR HYDROCARBON OIL AND METHOD FOR PRODUCING SAME, AND HYDROCARBON OIL HYDROTREATING METHOD USING SAME - Provided are: a hydrotreating catalyst for hydrocarbon oil having a hydrodesulfurization activity additionally improved by: simultaneously and continuously adding an aqueous solution of an acidic compound containing titanium and an aqueous solution containing an alkaline compound to a hydrosol containing an alumina hydrate particle at a temperature of 10 to 100° C. and a pH of 4.5 to 6.5; washing the resultant to remove a contaminating ion; forming the washed product after dehydration so as to have a moisture content at which it is formable; drying the resultant; impregnating the dried product with a catalytic component aqueous solution containing at least one kind of periodic table group 6 metal compound, at least one kind of periodic table group 8-10 metal compound, at least one kind of phosphorus compound, and at least one kind of saccharide; and drying the resultant; a manufacturing method for the catalyst; and a hydrodesulfurization treatment method for hydrocarbon oil using the catalyst. | 12-20-2012 |
| 20130233769 | METHOD OF PRODUCING REGENERATED HYDROTREATING CATALYST AND METHOD OF PRODUCING PETROLEUM PRODUCTS - A method of producing a regenerated hydrotreating catalyst, including a first step of preparing a hydrotreating catalyst that has been used for hydrotreatment of a petroleum fraction and has a metal element selected from Group 6 elements of the periodic table; a second step of performing regeneration treatment for part of the catalyst prepared in the first step, then performing X-ray absorption fine structure analysis for the catalyst after the regeneration treatment, and obtaining regeneration treatment conditions in which a ratio IS/IO of a peak intensity IS of a peak attributed to a bond between the metal element and a sulfur atom to a peak intensity IO of a peak attributed to a bond between the metal element and an oxygen atom is in the range of 0.1 to 0.3 in a radial distribution curve obtained from an extended X-ray absorption fine structure spectrum. | 09-12-2013 |
| 20130256195 | SELENIUM-CONTAINING HYDROPROCESSING CATALYST, ITS USE, AND METHOD OF PREPARATION - A hydroprocessing catalyst composition that comprises a support material and a selenium component and which support material further includes at least one hydrogenation metal component. The hydroprocessing catalyst is prepared by incorporating a selenium component into a support particle and, after calcination thereof, incorporating at least one hydrogenation metal component into the selenium-containing support. The metal-incorporated, selenium-containing support is calcined to provide the hydroprocessing catalyst composition. | 10-03-2013 |
| 20140174989 | TRANSITION METAL CATALYSTS FOR HYDRODESULFURIZATION - Phosphoranimide-metal catalysts and their role in hydrodesulfurization are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and catalyze hydrodesulfurization of a range of sulfur-containing organic compounds under lower temperature and pressure conditions than those commonly used in industrial hydrodesulfurization. | 06-26-2014 |
| 20140183100 | PROCESS FOR HYDRODESULPHURATION OF GASOLINE CUTS USING A CATALYST BASED ON HETEROPOLYANIONS TRAPPED IN A MESOSTRUCTURED SILICA SUPPORT - The invention relates to a process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (H | 07-03-2014 |
| 20140305842 | Process for Upgrading a High Endpoint Gas Oil Containing High Concentrations of Thiophenes and Nitrogen and Providing for a Reduced Hydrogen Consumption Rate. - A process and catalyst that provides for the upgrading of a high endpoint gas oil feedstock that contains significant concentrations of organic sulfur compound and organic nitrogen compounds. Included among the sulfur compounds are the dimethyl-dibenzothiophenes and derivative thereof. The catalyst of the process is an additive impregnated composition or a derivative thereof that further comprises cobalt and molybdenum. The process provides for the upgrading the high endpoint gas oil feedstock by significantly reducing the difficult to remove thiophene and nitrogen compounds and the process does this with a significantly reduced hydrogen consumption relative to processes using comparative catalysts. | 10-16-2014 |
| 20140305843 | LOW-PRESSURE PROCESS UTILIZING A STACKED-BED SYSTEM OF SPECIFIC CATALYSTS FOR THE HYDROTREATING OF A GAS OIL FEEDSTOCK - A low-pressure process for hydrodenitrogenation and hydrodesulfurization of a gas oil feedstock. The process uses a multi-bed, stacked-bed reactor system. The first and third beds of the multi-bed, stacked-bed reactor system include catalysts that comprise cobalt and molybdenum supported on alumina. The middle, second bed, includes a catalyst comprising nickel and molybdenum supported on alumina that preferably includes an additive. The stacked bed arrangement with the use of the specific catalysts provides for the low-pressure operation and significantly improved HDN and HDS activity with relatively insignificant differences in hydrogen consumption. | 10-16-2014 |
| 20150108039 | CATALYST FOR THE HYDROTREATMENT OF A HEAVY HYDROCARBON FEEDSTOCK - Disclosed is a method of hydrotreating a heavy hydrocarbon feedstock using a hydrotreating catalyst having specific properties that make it effective in converting nitrogen, sulfur and micro-carbon residue of a heavy hydrocarbon feedstock. The catalyst comprises a calcined support particle impregnated with a Group 6 metal component (e.g., molybdenum), a nickel component, and a phosphorus component present at concentrations in the catalyst such that the atomic ratio of the Group 6 metal-to nickel metal are within a specified range. The nickel metal acid extractability property of the catalyst is at least 50 percent. | 04-23-2015 |
| 20150122702 | CATALYST TO ATTAIN LOW SULFUR GASOLINE - This invention relates to a hydrodesulfurization catalyst, a method for preparing the catalyst, and a method for the preparation of low sulfur gasoline fuel with minimal loss of RON. The catalyst particles include a group VIB metal and a support material having relatively high surface area, and optionally includes one or more group VIIIB metal. The method for preparing the catalyst allows for greater loading of the active metal species on the surface of the support material under aqueous reaction conditions. | 05-07-2015 |
| 20150306579 | A HYDROTREATING CATALYST, PRODUCTION AND USE THEREOF - This invention relates to a hydrotreating catalyst suitable for heavy distillate oil hydrodesulfurization, production and use thereof. The present hydrotreating catalyst exhibits significantly improved heavy distillate oil (deep) hydrodesulfurization activity. | 10-29-2015 |
| 20150307789 | HIGH ACTIVITY HYDROTREATING CATALYSTS AND PROCESSES USING THE SAME - This disclosure relates to supported multi-metallic catalysts for use in the hydrotreating of hydrocarbon feeds. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIB metal, at least one Group VIII metal and an organic acid. The catalyst precursor is thermally treated to partially decompose the organic acid, then sulfided. The catalysts have a high carbon-as-carboxyl to total carbon ratio (C | 10-29-2015 |
| 20160008792 | PROCEDIMIENTO DE OBTENCION DE UNA FORMULACION CATALITICA PARA LA PRODUCCION DE DIESEL DE ULTRABAJO AZUFRE, EL PRODUCTO OBTENIDO Y SU APLICACION | 01-14-2016 |
| 20090272674 | Nano zeolite containing hydrotreating catalyst and method of preparation - The present invention provides nano zeolite containing hydrotreating catalyst and methods of preparation, and more particularly to a nano-sized zeolite beta composite hydrotreating catalyst. The hydrotreating catalyst for desulfurization of diesel distillates includes between about 5 to about 75 wt % nano-sized zeolite beta composite, about 10 to about 30 wt % of a hydrogenation metal/alloy and between about 5 to about 20 wt % binder. | 11-05-2009 |
| 20100320123 | Selective Catalysts Having Silica Supports For Naphtha Hydrodesulfurization - A method for hydrodesulfurizing FCC naphtha is described. More particularly, a Co/Mo metal hydrogenation component is loaded on a silica or modified silica support in the presence of organic ligand and sulfided to produce a catalyst which is then used for hydrodesulfurizing FCC naphtha. The silica support has a defined pore size distribution which minimizes olefin saturation. | 12-23-2010 |
| 20100326890 | HIGHLY STABLE HEAVY HYDROCARBON HYDRODESULFURIZATION CATALYST AND METHODS OF MAKING AND USE THEREOF - Described is a catalyst useful in the hydroprocessing of a heavy hydrocarbon feedstock wherein the catalyst comprises a calcined mixture made by calcining a formed particle of a mixture comprising molybdenum trioxide, a nickel compound, and an inorganic oxide material. The catalyst may be made by mixing an inorganic oxide material, molybdenum trioxide, and a nickel compound to form a mixture that is formed into a particle and calcined to provide a calcined mixture. The process involves the hydrodesulfurization and hydroconversion of a heavy hydrocarbon feedstock which process may include the conversion of a portion of the pitch content of the heavy hydrocarbon feedstock and the yielding of a treated product having an enhanced stability as reflected by its P-value. | 12-30-2010 |
| 20120067780 | Process For Hydrodesulphurizing Gasoline Employing A Catalyst With Controlled Porosity - A novel process is described which allows selective hydrodesulphurizing gasoline cuts containing sulphur-containing compounds and olefins. The process employs a catalyst comprising a support selected, for example, from refractory oxides such as aluminas, silicas, silica-aluminas or magnesia, used alone or as a mixture, a group VI metal, preferably Mo or W which may or may not be promoted by a group VIII metal, Co or Ni. The catalyst is characterized by a mean pore diameter of more than 22 nm. The process may comprise one or more steps. | 03-22-2012 |
| 20120091039 | EBULLATED BED HYDROTREATING SYSTEMS AND PROCESSES OF HEAVY CRUDE OIL - Disclosed are a mixed catalyst comprising catalyst A and catalyst B mixed in a volume ratio ranging from 1:0.1 to 1:10, heavy crude oil ebullated-bed hydrotreating systems comprising at least one ebullated-bed reactor comprising the mixed catalyst, and heavy crude oil ebullated-bed hydrotreating processes comprising: introducing heavy crude oil and hydrogen into at least one ebullated-bed reactor, reacting the heavy crude oil and the hydrogen with the mixed catalyst in the at least one ebullated-bed reactor to produce reaction products; and discharging the reaction products from the top of the at least one ebullated-bed reactor. | 04-19-2012 |
| 20120181219 | HYDRODESULFURIZATION CATALYST FOR HYDROCARBON OIL, PROCESS OF PRODUCING SAME AND METHOD FOR HYDROREFINING - The present invention provides a hydrodesulfurization catalyst that exhibits a high desulfurization activity when used in hydrotreatment of hydrocarbon oil, in particular straight-run gas oil. The catalyst includes at least one type of metal component selected from Groups VIA and VIII in the periodic table, supported on a silica-titania-alumina support where the total of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes is ¼ or less of the diffraction peak area indicating the aluminum crystal structure ascribed to γ-alumina (400) planes, as measured by X-ray diffraction analysis. The catalyst has (a) a specific surface area (SA) of 150 m | 07-19-2012 |
| 20120205292 | Chelant and Polar Additive Containing Composition Useful in the Hydroprocessing of Hydrocarbon Feedstocks and Method of Making and Use Thereof - A hydroprocessing catalyst composition that comprises a chelant treated metal containing support material having incorporated therein a polar additive. The catalyst composition is prepared by incorporating at least one metal component into a support material followed by treating the metal incorporated support with a chelating agent and thereafter incorporating a polar additive into the chelant treated composition. | 08-16-2012 |
| 20120292231 | A HIGH ACTIVITY HYDRODESULFURIZATION CATALYST, A METHOD OF MAKING A HIGH ACTIVITY HYDRODESULFURIZATION CATALYST, AND A PROCESS FOR MANUFACTURING AN ULTRA-LOW SULFUR DISTILLATE PRODUCT - A method of making a high activity catalyst composition suitable for use in the hydrodesulfurization of a middle distillate feed, such as diesel fuel, having a high concentration of sulfur, to thereby provide a low sulfur middle distillate product. The method comprises heat treating aluminum hydroxide under controlled temperature conditions thereby converting the aluminum hydroxide to gamma-alumina to give a converted aluminum hydroxide, and controlling the fraction of converted aluminum hydroxide that is gamma-alumina. A catalytic component is incorporated into the converted aluminum hydroxide to provide an intermediate, which is heat treated to provide the high activity catalyst composition. The high activity catalyst composition can suitably be used in the hydrodesulfurization of a middle distillate feed containing a high sulfur concentration. | 11-22-2012 |
| 20130105364 | LOW COST AND HIGH ACTIVITY HYDROPROCESSING CATALYST | 05-02-2013 |
| 20130284640 | HYDROPROCESSING CATALYST AND PROCESS FOR TREATING HEAVY HYDROCARBON FEEDSTOCKS - A catalyst for treating heavy hydrocarbon feedstocks. The catalyst comprises a calcined particle comprising a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound or cobalt compound, or both compounds, and then forming the co-mulled mixture into a particle that is calcined to provide the calcined particle. The calcination is conducted at a temperature such that at least 20% of the pore volume of the calcined particle is in pores of greater than 5,000 Å and less than 70% of the pore volume of the calcined particle is in the pores having a pore size in the range of from 70 to 250 Å. | 10-31-2013 |
| 20140076783 | HIGH ACTIVITY HYDRODESULFURIZATION CATALYST, A METHOD OF MAKING A HIGH ACTIVITY HYDRODESULFURIZATION CATALYST, AND A PROCESS FOR MANUFACTURING AN ULTRA-LOW SULFUR DISTILLATE PRODUCT - A method of making a high activity catalyst composition suitable for use in the hydrodesulfurization of a middle distillate feed, such as diesel fuel, having a high concentration of sulfur, to thereby provide a low sulfur middle distillate product. The method comprises heat treating aluminum hydroxide under controlled temperature conditions thereby converting the aluminum hydroxide to gamma-alumina to give a converted aluminum hydroxide, and controlling the fraction of converted aluminum hydroxide that is gamma-alumina. A catalytic component is incorporated into the converted aluminum hydroxide to provide an intermediate, which is heat treated to provide the high activity catalyst composition. The high activity catalyst composition can suitably be used in the hydrodesulfurization of a middle distillate feed containing a high sulfur concentration. | 03-20-2014 |
| 20140116924 | SELF-ACTIVATING HYDROPROCESSING CATALYST AND PROCESS FOR TREATING HEAVY HYDROCARBON FEEDSTOCKS - A self activating catalyst for treating heavy hydrocarbon feedstocks that comprises a calcined particle comprising a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound and then forming the co-mulled mixture into a particle that is calcined to thereby provide the calcined particle. The calcined particle comprises from 1 to 10 weight percent molybdenum and nickel that is present in an amount such that the weight ratio of said nickel-to-molybdenum is less than 0.4. The calcined particle has a pore size distribution that contributes to the unique properties of the catalyst. The calcined particle and catalyst also exhibits a unique Raman spectrum. The self activating catalyst is activated when contacted under suitable process conditions with a heavy residue feedstock having high nickel, vanadium and sulfur concentrations. | 05-01-2014 |
| 20140190869 | SELECTIVE CATALYSTS HAVING HIGH TEMPERATURE ALUMINA SUPPORTS FOR NAPHTHA HYDRODESULFURIZATION - This invention relates to a catalyst and method for hydrodesulfurizing naphtha. More particularly, a Co/Mo metal hydrogenation component is loaded on a high temperature alumina support in the presence of a dispersion aid to produce a catalyst that is then used for hydrodesulfurizing naphtha. The high temperature alumina support has a defined surface area that minimizes olefin saturation. | 07-10-2014 |
| 20140231310 | PROCESS FOR HYDRODESULPHURATION OF GASOIL CUTS USING A CATALYST BASED ON HETEROPOLYANIONS TRAPPED IN A MESOSTRUCTURED SILICA SUPPORT - The invention relates to a process of hydrodesulphuration of at least one gasoil cut implementing a catalyst containing, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (H | 08-21-2014 |
| 20150314282 | CATALYST AND ITS USE FOR THE SELECTIVE HYDRODESULFURIZATION OF AN OLEFIN CONTAINING HYDROCARBON FEEDSTOCK - A catalyst and its use for selectively desulfurizing sulfur compounds present in an olefin-containing hydrocarbon feedstock to very low levels with minimal hydrogenation of olefins. The catalyst comprises an inorganic oxide substrate containing a nickel compound, a molybdenum compound and optionally a phosphorus compound, that is overlaid with a molybdenum compound and a cobalt compound. The catalyst is further characterized as having a bimodal pore size distribution with a large portion of its total pore volume contained in pores having a diameter less than 250 angstroms and in pores having a diameter greater than 1000 angstroms. | 11-05-2015 |
| 20160059223 | HYDRODESULFURIZATION CATALYST FOR DIESEL OIL AND HYDROTREATING METHOD FOR DIESEL OIL - A hydrodesulfurization catalyst supports one or more metals selected from elements in Group 6 of the Periodic table, one or more metals selected from elements in Group 9 or Group 10 of the same, phosphorus, and an organic acid on a composite oxide support having a specific content of both alumina and HY zeolite having a specific crystallite size. The catalyst includes 10% to 40% by mass of the Group 6 metal, 1% to 15% by mass of the Group 9 or Group 10 metal, and 1.5% to 8% by mass of phosphorus in terms of an oxide based on the catalyst. The catalyst includes 0.8% to 7% by mass of carbon derived from an organic acid and for 1 mole of the Group 9 or Group 10 element metal in terms of an element based on the catalyst, and includes 0.2 to 1.2 moles of the organic acid. | 03-03-2016 |
| 20160250622 | RESID HYDROTREATING CATALYST CONTAINING TITANIA | 09-01-2016 |
| 20220135888 | Hydrotreating Catalyst for Heavy Hydrocarbon Oil, Method for Producing the Same, and Method for Hydrotreating Heavy Hydrocarbon Oil - Provided is a hydrotreating catalyst for a heavy hydrocarbon oil, the catalyst including an inorganic oxide carrier including alumina as a main component and a metal component supported on the inorganic oxide carrier, the catalyst having a specific surface area within a predetermined range, a reduction peak temperature that is lower than 450° C. in temperature-programmed reduction measurement of the catalyst and that is higher than or equal to a predetermined temperature, and an amount of nitrogen monoxide adsorbed on the sulfided catalyst within a predetermined range. | 05-05-2022 |
| 208217000 | With Group VIII metal or compound | 12 |
| 20080251422 | PROCESS FOR TREATING HYDROCARBON FEEDS WITH ELECTROLYTIC HYDROGEN - A process for treating hydrocarbon feeds includes the steps of providing a hydrocarbon feed containing sulfur and/or metalloporphyrins; providing a cell having two compartments and a membrane separating the compartments; flowing a hydrogen source through one compartment; flowing the hydrocarbon feed through the other compartment; applying a current across the hydrogen source compartment whereby hydrogen diffuses through the membrane from the hydrogen source to the hydrocarbon feed, whereby the hydrogen reacts with sulfur and/or metalloporphyrins to form H | 10-16-2008 |
| 20090159502 | Decomposition of peroxides using iron-containing acidic zeolites - The present invention provides a catalyst particle for decomposing a peroxide compound into an alcohol compound, the catalyst particle having an acidic zeolite material having an iron containing material in the framework position or the non-framework position and being present in an amount by weight of the catalyst particle from 100 ppm to 10,000 ppm. | 06-25-2009 |
| 20100089798 | USE OF SOLIDS BASED ON ZINC FERRITE IN A PROCESS FOR DEEP DESULPHURIZING OXYGEN-CONTAINING FEEDS - The invention concerns a process for desulphurizing a feed comprising oxygen-containing compounds, hydrocarbon-containing compounds and organic sulphur-containing compounds, by capturing sulphur on a capture mass comprising iron oxides or zinc oxides and more than 20% by weight of zinc ferrite. The process is operated in the presence of hydrogen at a temperature in the range 200° C. to 400° C. | 04-15-2010 |
| 20100089799 | USE OF ZINC FERRITE-BASED SOLIDS IN A PROCESS FOR DEEP DESULFURIZATION OF HYDROCARBON FRACTIONS - The invention relates to a process for desulfurization of a non-oxidized hydrocarbon feedstock, comprising organic sulfur compounds, by adsorption, especially chemisorption of sulfur on a composition in bulk form consisting essentially of 70% by weight of zinc ferrite and optionally iron oxides or zinc oxides. The process is performed in the presence of hydrogen at a temperature of between 200° C. and 450° C. | 04-15-2010 |
| 20100116717 | METHOD FOR THE DESULFURIZATION OF FUELS AND HIGHLY ACTIVE NICKEL CARRIER CATALYST BASED ON ALUMINUM OXIDE SUITABLE FOR SAID METHOD - A highly active nickel carrier catalyst based on aluminium oxide has a nickel content of approximately 20 to 70 wt.-% (as Ni) and optionally comprises a bonding agent and optionally a promoter, selected from the compounds of Mg, Ti, Pb, Pt, Ba, Ca and/or Cu, wherein the size of the Ni crystallites in the reduced state is in the range of approximately 3.5 to 4.5 nm and the distortion factor of the Ni crystallites is approximately 2 to 5%. In a method for the reduction of the content of sulphur compounds in hydrocarbon-based fuels by selective adsorption of the sulphur compounds on a nickel catalyst, a nickel catalyst based on aluminium oxide is used, particularly the nickel catalyst described above. A nickel catalyst based on aluminium oxide may be used for reducing the sulphur compound content in hydrocarbon-based fuels by selective adsorption of the sulphur compounds on said catalyst and/or for the hydrogenation of aromatic compounds. | 05-13-2010 |
| 20100236988 | OIL AND POLAR ADDITIVE IMPREGNATED COMPOSITION USEFUL IN THE CATALYTIC HYDROPROCESSING OF HYDROCARBONS, A METHOD OF MAKING SUCH CATALYST, AND A PROCESS OF USING SUCH CATALYST - A composition that comprises a support material having incorporated therein a metal component and impregnated with both hydrocarbon oil and a polar additive. The composition that is impregnated with both hydrocarbon oil and polar additive is useful in the hydrotreating of hydrocarbon feedstocks, and it is especially useful in applications involving delayed feed introduction whereby the composition is first treated with hot hydrogen, and, optionally, with a sulfur compound, prior to contacting it with a hydrocarbon feedstock under hydrodesulfurization process conditions. | 09-23-2010 |
| 20110108463 | CATALYST AND ITS USE IN DESULPHURISATION - A catalyst is provided comprising nickel in a reduced valence state on a carrier comprising zinc oxide and alumina, wherein the Zn:Ni atomic ratio is at least 12, and the catalyst particles are prepared by:
| 05-12-2011 |
| 20130153468 | UNSUPPORTED AND SUPPORTED NON-PROMOTED RUTHENIUM SULFIDE CATALYST WITH HIGH CATALYTIC ACTIVITY FOR HYDROCARBON HYDROTREATMENTS AND ITS METHOD - The present invention relates to a synthesis method for unsupported and supported ruthenium base (RuS2) catalysts from a ruthenium complex precursor, which is decomposed and activated by a simple activation process; these steps provide a catalyst with very high catalytic activity, in addition the incorporation of ruthenium complex precursor to a support by methods of incipient and wet impregnating is described; the obtained catalytic activities in this invention are in the order of 100 times the molybdenum sulfide catalyst without support and without promoter, 14 times the industrial supported catalyst, and 5 times the activity of the currently most active commercial unsupported catalyst. | 06-20-2013 |
| 20130199969 | COMPOSITION AND A METHOD OF MAKING AND USE OF SUCH COMPOSITION - A composition and method of making such a composition that has application in the hydroprocessing of hydrocarbon feedstocks. The method comprises selecting an organic additive by the use of a correlation model for predicting catalytic activity as a function of a physical property that is associated with the organic additive and incorporating the organic additive into a support material to provide the additive impregnated composition. | 08-08-2013 |
| 20140346087 | CATALYSTS FOR HYDRODESULFURIZATION - Phosphoranimide-metal catalysts and their role in hydrodesulfurization and hydrogenation are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and have no inactive bulk phase and no dative ancillary ligands. In one embodiment, the catalysts comprise discrete mixed-valent precatalyst clusters, the electronic state of which can be adjusted to optimize catalytic activity. The catalysts catalyze the hydrodesulfurization of a range of sulfur-containing organic compounds under lower temperature and pressure conditions than those conditions commonly used in industrial hydrodesulfurization. The catalysts also catalyze the hydrogenation of substrates comprising at least one carbon-carbon double bond which is not present in an aromatic moiety, although the substrate itself may include an aromatic moiety. | 11-27-2014 |
| 20150041366 | HYDROCARBON OIL DESULFURIZATION ADSORBING AGENT, PRODUCTION AND USE THEREOF - This disclosures provides an adsorbent which, on the basis of the total weight of the adsorbent, comprises: 1) a Si—Al molecular sieve having an A-FAU structure, wherein A represents a monovalent cation, in an amount of 1-20 wt %, 2) at least one binder selected from the group consisting of titanium dioxide, stannic oxide, zirconium oxide and alumina, in an amount of 3-35 wt %, 3) a silica source, in an amount of 5-40 wt %, 4) zinc oxide, in an amount of 10-80 wt %, and 5) at least one promoter metal selected from the group consisting of cobalt, nickel, iron and manganese, based on the metal, in an amount of 5-30 wt %, wherein at least 10 wt % of the promoter metal is present in a reduced valence state. This adsorbent exhibits improved activity and stability, and at the same time, is capable of significantly improving the octane number of the product gasoline. | 02-12-2015 |
| 20160114315 | HYDROPROCESSING CATALYST COMPOSITION CONTAINING AN ACETOACETIC ACID COMPOUND, A METHOD OF MAKING SUCH A CATALYST, AND A PROCESS OF USING SUCH CATALYST - A composition that comprises a support material having incorporated therein a metal component and impregnated with an additive compound that is an acetoacetic acid compound. The composition includes the support material that is impregnated with the additive compound and is useful in the hydroprocessing of hydrocarbon feedstocks, especially in the denitrogenation and desulfurization of distillate feedstocks to make ultra low sulfur diesel. | 04-28-2016 |
