Class / Patent application number | Description | Number of patent applications / Date published |
208112000 | Metal or metal oxide catalyst | 36 |
20080210599 | Process For Upgrading An Fcc Equilibrium Catalyst - “FCC equilibrium catalysts, even when highly contaminated with vanadium, can be upgraded to make them suitable again for use in catalytic processes, for instance, as catalyst additives in FCC, by employing a process comprising the steps of (a) treating an FCC equilibrium catalyst that contains alumina and zeolite with an acidic solution to obtain an acid-treated equilibrium catalyst, and (b) contacting the acid-treated equilibrium catalyst with an aqueous solution or suspension of a divalent metal compound.” | 09-04-2008 |
20080272029 | SYSTEMS AND METHODS OF PRODUCING A CRUDE PRODUCT - Contact of a crude feed with a hydrogen source in the presence of an inorganic salt catalyst produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The inorganic salt catalyst comprises alkali metals, alkaline earth metals, or mixtures thereof. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. | 11-06-2008 |
20090114566 | METHOD OF UPGRADING HEAVY HYDROCARBON STREAMS TO JET PRODUCTS - A process of upgrading a heavy hydrocarbon feedstock comprising contacting a heavy hydrocarbon feedstock with a catalyst in the presence of hydrogen in a reactor system, containing the catalyst as the only catalyst, wherein the catalyst, is prepared by sulfiding a catalyst precursor obtained by mixing at reaction conditions, to form a precipitate or cogel, at least a Promoter metal compound in solution; at least a Group VIB metal compound in solution; and, at least an organic oxygen containing ligand in solution, and thereby producing a fuel product. | 05-07-2009 |
20090173665 | CATALYST FOR HYDROCRACKING HYDROCARBONS CONTAINING POLYNUCLEAR AROMATIC COMPOUNDS - Oil soluble catalysts are used to convert polynuclear aromatic compounds in a hydrocarbon feedstock to higher value mono-aromatic compounds. The catalyst complex includes a catalytic metal center that is bonded to a plurality of organic ligands that make the catalyst complex oil-soluble. The ligands include an aromatic ring and a ligand spacer group. The ligand spacer group provides spacing of 2-6 atoms between the metal center and the aromatic ring. The spacing between the aromatic group and the catalytic metal center advantageously allows the catalyst to selectively crack polynuclear aromatic rings while preserving one of the aromatic rings, thereby increasing the content of mono-aromatic compounds in the hydrocarbon feedstock. | 07-09-2009 |
20090173666 | PROCESS FOR INCREASING THE MONO-AROMATIC CONTENT OF POLYNUCLEAR-AROMATIC-CONTAINING FEEDSTOCKS - Hydrocarbons containing polynuclear aromatics, such as cycle oil and pyrolysis fuel oil (PFO), are upgraded using an catalyst complex that selectively cracks the polynuclear aromatic compounds to form higher value mono-aromatic compounds, such as benzene toluene, xylenes and ethyl benzene (i.e., BTX). The catalyst complexes include a catalytic metal center and a plurality of organic ligands. During the hydrocracking procedure, the organic ligand preserves one of the aromatic rings of the polynuclear aromatic compounds while the catalytic metal breaks the other aromatic rings thereby yielding a monoaromatic compound. | 07-09-2009 |
20090230022 | Hydroconversion process for petroleum resids using selective membrane separation followed by hydroconversion over carbon supported metal catalyst - A heavy residual petroleum feed boiling above 650° F. | 09-17-2009 |
20090283444 | SYSTEMS, METHODS, AND CATALYSTS FOR PRODUCING A CRUDE PRODUCT - Contact of a crude feed with one or more catalysts containing a Column 6 metal and having a pore size distribution having a median pore size diameter of at least 90 Å wherein at least 60% of the total number of pores in the pore size distribution have a pore diameter within about 45 Å of the median pore diameter produces a total product that includes a crude product. The crude feed includes organic oxygen containing compounds and has a TAN of at least 0.3. The crude product is a liquid mixture at 25 ° C. and 0.101 MPa and has a TAN of at most 90% of the TAN of the crude feed and an organic oxygen content of at most 90% of the organic oxygen content of the crude feed. | 11-19-2009 |
20090288989 | SYSTEMS, METHODS, AND CATALYSTS FOR PRODUCING A CRUDE PRODUCT - Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude product is a liquid mixture at 25° C. and 0.101 MPa. The one or more catalyst may include an uncalcined catalyst. One or more other properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. | 11-26-2009 |
20090308791 | SYSTEMS, METHODS, AND CATAYLSTS FOR PRODUCING A CRUDE PRODUCT - Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude product is a liquid mixture at 25° C. and 0.101 MPa. The one or more catalyst may include an uncalcined catalyst. One or more other properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. | 12-17-2009 |
20090321314 | Process for Using Iron Oxide and Alumina Catalyst with Large Particle Diameter for Slurry Hydrocracking - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. Performance of the iron oxide and alumina catalyst at high mean particle diameters is comparable to performance at low mean particle diameters. | 12-31-2009 |
20090321315 | Process for Using Hydrated Iron Oxide and Alumina Catalyst for Slurry Hydrocracking - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. Performance of the iron oxide and alumina catalyst is not substantially affected by significant quantities of water on the catalyst. | 12-31-2009 |
20090321316 | Process for Using Catalyst with Rapid Formation of Iron Sulfide in Slurry Hydrocracking - A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron oxide in the catalyst converts to catalytically active iron sulfide in the presence of hydrogen and sulfur. | 12-31-2009 |
20100006475 | CATALYST COMPOSITION AND A PROCESS THAT USES THE CATALYST COMPOSITION FOR THE HYDROCONVERSION OF A HEAVY HYDROCARBON FEEDSTOCK - A catalyst composition that provides for a high percentage conversion of the pitch component of a heavy hydrocarbon feedstock and a process of using the catalyst composition. The catalyst composition comprises a nickel component, a molybdenum component in an amount less than 12 wt % of the catalyst composition, and it may also include an alumina support material having special properties. The weight ratio of the nickel component-to-molybdenum component exceeds 0.25, and the support material preferably has a median pore diameter of from 100-140 Å. The catalyst composition has a characteristically unique Raman spectrum that distinguishes it over other compositions. | 01-14-2010 |
20100243526 | HIGH SURFACE AREA COMPOSITION FOR USE IN THE CATALYTIC HYDROCONVERSION OF A HEAVY HYDROCARBON FEEDSTOCK, A METHOD MAKING SUCH COMPOSITION AND ITS USE - A catalyst composition that is especially useful in the hydroconversion of pitch, micro carbon residue and sulfur contents of a heavy hydrocarbon feedstock without the excessive formation of sediment. The catalyst composition is a reasonably high surface area composition containing alumina and a low molybdenum content with a high ratio of nickel-to-molybdenum. The catalyst composition further has a unique pore distribution that in combination with the special metals loading provide for good conversion of pitch and micro carbon residue without an excessive yield of sediment. | 09-30-2010 |
20110108461 | COMPOSITION USEFUL IN THE HYDROPROCESSING OF A HYDROCARBON FEEDSTOCK - A composition having a substantial or material absence of or no phosphorous and comprising a support material, a metal compound and either a hydrocarbon oil or a polar additive or a combination of both a hydrocarbon oil and polar additive. The polar additive has particularly defined properties including having a dipole moment of at least 0.45. The composition is useful in the hydroprocessing of hydrocarbon feedstocks, and it is especially useful in the hydrotreating of vacuum gas oils and petroleum resid feedstocks. | 05-12-2011 |
20110174690 | ADDITIVE FOR HYDROCONVERSION PROCESS AND METHOD FOR MAKING AND USING SAME - An additive for hydroconversion processes includes a solid organic material having a particle size of between about 0.1 and about 2,000 μm, a bulk density of between about 500 and about 2,000 kg/m3, a skeletal density of between about 1,000 and about 2,000 kg/m3 and a humidity of between 0 and about 5 wt %. Methods for preparation and use of the additive are also provided. By the use of the additive of the present invention, the hydroconversion process can be performed at high conversion level. | 07-21-2011 |
20110226667 | METHODS FOR HYDROCRACKING A HEAVY OIL FEEDSTOCK USING AN IN SITU COLLOIDAL OR MOLECULAR CATALYST AND RECYCLING THE COLLOIDAL OR MOLECULAR CATALYST - An ebullated bed hydroprocessing system, and also a method for upgrading an existing ebullated bed hydroprocessing system, involves introducing a colloidal or molecular catalyst, or a catalyst precursor capable of forming the colloidal or molecular catalyst, into an ebullated bed reactor. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the catalyst precursor to form the colloidal or molecular catalyst in situ. The improved ebullated bed hydroprocessing system includes at least one ebullated bed reactor that employs both a porous supported catalyst and the colloidal or molecular catalyst to catalyze hydroprocessing reactions involving the feedstock and hydrogen. The colloidal or molecular catalyst provides catalyst in what would otherwise constitute catalyst free zones within the ebullated bed hydroprocessing system. Asphaltene or other hydrocarbon molecules too large to diffuse into the pores of the supported catalyst can be upgraded by the colloidal or molecular catalyst. A slurry phase reactor may be positioned upstream from one or more ebullated bed reactors or converted from an existing ebullated bed reactor. | 09-22-2011 |
20110303583 | PROCESS FOR USING SUPPORTED MOLYBDENUM CATALYST FOR SLURRY HYDROCRACKING - A process is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising molybdenum supported on a base, such as boehmite or pseudo-boehmite alumina. Iron oxide may also be in the base. The base is preferably bauxite. The heavy hydrocarbon slurry is hydrocracked in the presence of the catalyst to produce lighter hydrocarbons. | 12-15-2011 |
20110303584 | PROCESS FOR USING SUPPORTED MOLYBDENUM CATALYST FOR SLURRY HYDROCRACKING - A process is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising molybdenum supported on a base, such as boehmite or pseudo-boehmite alumina. Iron oxide may also be in the base. The base is preferably bauxite. The heavy hydrocarbon slurry is hydrocracked in the presence of the catalyst to produce lighter hydrocarbons. | 12-15-2011 |
20110308997 | PROCESS FOR USING CATALYST WITH RAPID FORMATION OF IRON SULFIDE IN SLURRY HYDROCRACKING - A process is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron oxide in the catalyst converts to catalytically active iron sulfide in the presence of hydrogen and sulfur. | 12-22-2011 |
20120000820 | HYDROPROCESSING PROCESS FOR THE IMPROVEMENT OF THE CATALYST LIFE - This invention relates to a hydroprocessing process for the improvement of catalyst life. Such inventive process is carried out with intermittent or discontinuous addition of a co-feed stream when hydroprocessing petroleum based feedstock or an oxygen containing feedstock. More specifically, it has been found that intermittent or discontinuous addition of the co-feed stream such as carbon monoxide, carbon dioxide, or their precursors to the hydrogen stream can reduce the long term deactivation, extend the life and increase run length of a cobalt/molybdenum hydrotreating catalyst. | 01-05-2012 |
20120111767 | INTERSTITIAL METAL HYDRIDE CATALYST SYSTEMS AND ASSOCIATED PROCESSES - Exemplary embodiments of the present invention relate to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride containing catalyst comprising a surface, and a Group VI/Group VIII metal sulfide coated onto the surface of the interstitial metal hydride. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams. | 05-10-2012 |
20120111768 | INTEGRATED INTERSTITIAL METAL HYDRIDE CATALYST SUPPORT SYSTEMS AND ASSOCIATED PROCESSES - Exemplary embodiments of the present invention relate to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride comprising a surface, with a metal oxide integrally synthesized and providing a coating on the surface of the interstitial metal hydride. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as sulfur and nitrogen reduction in hydrocarbon feedstreams. | 05-10-2012 |
20120145596 | PROCESS FOR TREATING A HYDROCARBON-CONTAINING FEED - A process is provided in which a first hydrocarbon-containing composition is provided where the first hydrocarbon-containing composition comprises hydrocarbons having a boiling range from 25° C. to 538° C. and from 0.1 wt. % to 5 wt. % sulfur, where at least 40 wt. % of the sulfur is contained in hydrocarbons having a boiling point of less than 343° C. where at least 40 wt. % of the sulfur contained in hydrocarbons having a boiling point less than 343° C. is contained in benzothiophenic compounds, and the first hydrocarbon-containing compound is hydrotreated to produce a second hydrocarbon-containing compound. | 06-14-2012 |
20120168350 | HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF - An improved process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs a polar aprotic solvent to mix with the inorganic metal precursor feed to form an oil-dispersible inorganic metal precursor, at a weight ratio of solvent to inorganic metal precursor of 1:1 to 10:1; the oil-dispersible inorganic metal precursor is subsequently sulfided forming the slurry catalyst. In one embodiment, the sulfiding is in-situ upon mixing the oil-dispersible inorganic metal precursor with a hydrocarbon diluent containing a heavy oil feedstock under in-situ sulfiding conditions. | 07-05-2012 |
20130048540 | ULTRA-DISPERSED CATALYST AND METHOD FOR PREPARING SAME - A catalyst composition comprising an emulsion of an aqueous phase in an oil phase, wherein the aqueous phase contains a group 6 metal, and wherein between about 55 and 100 wt % of the group 6 metal is sulfurated. A method for making a catalyst emulsion, comprising the steps of providing an aqueous phase comprising an aqueous solution of a group 6 metal, wherein between about 55 and 100 wt % of the group 6 metal is sulfurated; and mixing the aqueous phase into an oil phase to form an emulsion of the aqueous phase in the oil phase. A hydroconversion process, comprising the steps of contacting the catalyst of claim | 02-28-2013 |
20130126393 | HIGH SURFACE AREA COMPOSITION FOR USE IN THE CATALYTIC HYDROCONVERSION OF A HEAVY HYDROCARBON FEEDSTOCK, A METHOD MAKING SUCH COMPOSITION AND ITS USE - A catalyst composition that is especially useful in the hydroconversion of pitch, micro carbon residue and sulfur contents of a heavy hydrocarbon feedstock without the excessive formation of sediment. The catalyst composition is a reasonably high surface area composition containing alumina and a low molybdenum content with a high ratio of nickel-to-molybdenum. The catalyst composition further has a unique pore distribution that in combination with the special metals loading provide for good conversion of pitch and micro carbon residue without an excessive yield of sediment. | 05-23-2013 |
20130140215 | PROCESS FOR HYDROCRACKING A HYDROCARBON FEED IN THE PRESENCE OF A SULPHIDE CATALYST PREPARED USING A CYCLIC OLIGOSACCHARIDE - Hydrocracking a hydrocarbon feed in the presence of a catalyst comprising an acidic support and an active phase formed from at least one metal from group VIII and at least one metal from group VIB, said catalyst being prepared using a process comprising, in succession:
| 06-06-2013 |
20130248422 | HIGHLY STABLE HYDROCARBON-SOLUBLE MOLYBDENUM CATALYST PRECURSORS AND METHODS FOR MAKING SAME - Hydrocarbon-soluble molybdenum catalyst precursors include a plurality of molybdenum cations and a plurality of carboxylate anions having at least 8 carbon atoms. The carboxylate anions are alicyclic, aromatic, or branched, unsaturated and aliphatic, and can derived from carboxylic acids selected from 3-cyclopentylpropionic acid, cyclohexanebutyric acid, biphenyl-2-carboxylic acid, 4-heptylbenzoic acid, 5-phenylvaleric acid, geranic acid, 10-undecenoic acid, dodecanoic acid, and combinations thereof. The molybdenum salts have decomposition temperatures higher than 210° C. The catalyst precursors can form a hydroprocessing molybdenum sulfide catalyst in heavy oil feedstocks. Also disclosed are methods for making catalyst precursors and hydrocracking heavy oil using active catalysts. | 09-26-2013 |
20140102944 | SLURRY HYDROCRACKING PROCESS - One exemplary embodiment can be a slurry hydrocracking process. The process can include providing one or more hydrocarbon compounds having an initial boiling point temperature of at least about 340° C., and a slurry catalyst to a slurry hydrocracking zone. The slurry catalyst may have about 32- about 50%, by weight, iron; about 3- about 14%, by weight, aluminum; no more than about 10%, by weight, sodium; and about 2- about 10%, by weight, calcium. Typically, all catalytic component percentages are as metal and based on the weight of the dried slurry catalyst. | 04-17-2014 |
20140183099 | HIGH SURFACE AREA COMPOSITION FOR USE IN THE CATALYTIC HYDROCONVERSION OF A HEAVY HYDROCARBON FEEDSTOCK, A METHOD MAKING SUCH COMPOSITION AND ITS USE - A catalyst composition that is especially useful in the hydroconversion of pitch, micro carbon residue and sulfur contents of a heavy hydrocarbon feedstock without the excessive formation of sediment. The catalyst composition is a reasonably high surface area composition containing alumina and a low molybdenum content with a high ratio of nickel-to-molybdenum. The catalyst composition further has a unique pore distribution that in combination with the special metals loading provide for good conversion of pitch and micro carbon residue without an excessive yield of sediment. | 07-03-2014 |
20150076034 | COKING PROCESS AND SYSTEM FOR ENHANCED CATALYTIC REACTIONS TO IMPROVE PROCESS OPERATION AND ECONOMICS - Heavy gas oil components, coking process recycle, and heavier hydrocarbons in the delayed coking process are cracked in the coking vessel by injecting a catalytic additive into the vapors above the gas/liquid-solid interface in the coke drum during the coking cycle. The additive may comprise cracking catalyst(s) and quenching agent(s), alone or in combination with seeding agent(s), excess reactant(s), carrier fluid(s), or any combination thereof to modify reaction kinetics to preferentially crack these components. The quenching effect of the additive may be effectively used to condense the highest boiling point compounds of the traditional recycle onto the catalyst(s), thereby focusing the catalyst exposure to these target reactants. Exemplary embodiments of the present invention may also provide systems and methods to (1) reduce coke production, (2) reduce fuel gas production, and (3) increase liquids production. | 03-19-2015 |
20150129463 | NANOCATALYST FOR HEAVY CRUDE OIL UPGRADING AND METHOD FOR SYNTHESIZING SAME - A dispersing-type nanocatalyst for catalytic hydrocracking of heavy oil, a method for preparing the same, and the use thereof in catalytic hydrocracking of heavy oil. The present invention is also directed to reducing the operational temperature of catalytic hydrocracking of heavy crude oil, and also increasing the yield of the process by utilizing a lower concentration of said nanocatalyst. | 05-14-2015 |
20150144531 | PROCESS FOR THE CATALYTIC CONVERSION OF MICRO CARBON RESIDUE CONTENT OF HEAVY HYDROCARBON FEEDSTOCKS AND A LOW SURFACE AREA CATALYST COMPOSITION FOR USE THEREIN - An improved process for the hydroconversion of micro carbon residue content of heavy hydrocarbon feedstocks by the use of a catalyst composition that is especially useful in the conversion of micro carbon residue of such feedstocks. The catalyst composition is a low surface area composition that further has a specifically define pore structure the combination of which provides for its enhance micro carbon residue conversion property. | 05-28-2015 |
20160045910 | PROCESS FOR REJUVENATION OF A USED HYDROTREATING CATALYST - The invention provides a process for rejuvenation of a used hydrotreating catalyst comprising at least 8% wt of coke and one or more non-noble Group VIII and/or Group VIb metals, which process comprises the steps of: (i) removing coke from the used hydrotreating catalyst; and (ii) treating the catalyst obtained in step (i) with of from 2 to 60% wt of gluconic acid, based on weight of dry catalyst. | 02-18-2016 |
20190144764 | PROCESS AND APPARATUS FOR STRIPPING SLURRY HYDROCRACKED PRODUCT | 05-16-2019 |