Class / Patent application number | Description | Number of patent applications / Date published |
208088000 | Refining | 83 |
20110036753 | METHOD OF PRODUCING SYNTHETIC FUEL - An object of the invention is to provide a method of producing synthetic fuel from Fischer-Tropsch synthetic crude oil obtained by a Fischer-Tropsch synthesis method, the method comprising the steps of: (a) fractionating, in a fractionator, Fischer-Tropsch synthetic crude oil obtained by a Fischer-Tropsch synthesis method into at least two fractions of a middle fraction containing a component having a boiling range corresponding to diesel fuel oil, and a wax fraction containing a wax component heavier than the middle fraction; (b) separating and removing a magnetic particle contained in the wax fraction obtained in the step (a) at 100° C. to 450° C. by using a high gradient magnetic separator; and (c) hydrocracking the wax fraction obtained in the step (b) from which the magnetic particle is separated and removed. | 02-17-2011 |
20110049012 | CONVERSION OF CRUDE TALL OIL TO RENEWABLE FEEDSTOCK FOR DIESEL RANGE FUEL COMPOSITIONS - There is disclosed a method for conversion of crude tall oil into high-quality diesel fuels comprising the steps of: (a) removal of non-oil contaminants present in the crude tall oil and recovering valuable organic compounds present in the crude tall oil, thereby forming a refined tall oil stream; (b) removal of the volatile fraction of the refined tall oil stream from step a), thereby forming a volatiles free oil stream comprising organic components with boiling points, at atmospheric pressure, of 170 degrees C. or higher; (c) separation in a vacuum distillation column of the volatiles free oil stream of step b) into two process streams or phases wherein a first process stream or phase is substantially comprising components with boiling points, at atmospheric pressure, in the range of 170-400 degrees C. and a second process stream or phase is substantially comprising components with boiling points, at atmospheric pressure, over 400 degrees C.; (d) lowering the oxygen content in the stream comprised of components with boiling points in the range 200-400 degrees C. from step c) by decarboxylation and/or decarbonylation. | 03-03-2011 |
20110083999 | HYDROCRACKING METHOD USING A MODIFIED ZEOLITE - The present invention describes a method for hydrocracking and/or hydrotreating hydrocarbon-containing feeds using a catalyst comprising at least one hydro-dehydrogenizing metal selected from the group made up of group VIB and non-noble group VIII metals of the periodic table and a support comprising at least one zeolite having at least pore openings containing 12 oxygen atoms, modified by a) at least a stage of introducing at least one alkaline cation belonging to groups IA or IIA of the periodic table, b) a stage of treating said zeolite in the presence of at least one molecular compound containing at least one silicon atom, c) at least one stage of partial exchange of said alkaline cations by NH | 04-14-2011 |
20110147267 | RAPID CYCLE REFORMING PROCESS - This invention relates to process for producing a reformate or gasoline product. The process involves a rapid cycle of reacting hydrocarbon feedstock to form the product and then regenerating the catalyst used in the reaction. The process can be carried out at relatively high liquid hourly space velocities and preferably at relatively low hydrogen to hydrocarbon ratios to produce a reformed product having relatively high liquid yield and hydrogen content. | 06-23-2011 |
20110155636 | HYDROPROCESSING OF BIOCOMPONENT FEEDSTOCKS WITH LOW PURITY HYDROGEN-CONTAINING STREAMS - A biocomponent feedstock can be hydroprocessed using a hydrogen-containing refinery as a source of hydrogen gas. A relatively low cost catalyst, such as a water gas shift catalyst and/or spent hydrotreating catalyst, can be used as a hydrogenation catalyst for the process. The hydroprocessing can allow for olefin saturation and/or deoxygenation of the biocomponent feed by using a relatively low value refinery stream, e.g., containing from about 20 mol % to about 60 mol % hydrogen. | 06-30-2011 |
20110155637 | PROCESS FOR REMOVING NITROGEN FROM VACUUM GAS OIL - A process for removing a nitrogen compound from a vacuum gas oil feed includes contacting the vacuum gas oil feed comprising the nitrogen compound with a VGO-immiscible phosphonium ionic liquid to produce a vacuum gas oil and VGO-immiscible phosphonium ionic liquid mixture, and separating the mixture to produce a vacuum gas oil effluent having a reduced nitrogen content relative to the vacuum gas oil feed. | 06-30-2011 |
20110155638 | PROCESS FOR REMOVING SULFUR FROM VACUUM GAS OIL - A process for removing a sulfur compound from a vacuum gas oil feed includes contacting the vacuum gas oil feed comprising the sulfur compound with a VGO-immiscible ionic liquid to produce a vacuum gas oil and VGO-immiscible ionic liquid mixture, and separating the mixture to produce a vacuum gas oil effluent having a reduced sulfur content relative to the vacuum gas oil feed. | 06-30-2011 |
20120312721 | PREDICTING PETROLEUM COKE MORPHOLOGY FROM FEEDSTOCK PROPERTIES - According to one embodiment, a method includes desulfurizing a hydrocarbon feedstock in the presence of a desulfurization catalyst. A hydrocarbon product is recovered. The color of the hydrocarbon product is improved and the sulfur content of the hydrocarbon product is reduced by flash distilling the product. | 12-13-2012 |
20130068660 | METHOD FOR INCREASING THERMAL STABILITY OF A FUEL COMPOSITION USING A SOLID PHOSPHORIC ACID CATALYST - This invention relates to a method for increasing thermal stability of fuel, as well as in reducing nitrogen content and/or enhancing color quality of the fuel. According to the method, a fuel feedstock can be treated with a solid phosphoric acid catalyst under appropriate catalyst conditions, e.g., to increase the thermal stability of the fuel feedstock. Preferably, the fuel feedstock can be treated with the solid phosphoric acid catalyst at a ratio of catalyst mass within a contact zone to a mass flow rate of feedstock through the zone of at least about 18 minutes to increase the thermal stability of the fuel feedstock, along with reducing nitrogen content and/or enhancing color quality. | 03-21-2013 |
20130105362 | SYSTEMS AND METHODS FOR INTEGRATING BITUMEN EXTRACTION WITH BITUMEN UPG... | 05-02-2013 |
20140054199 | Hydrovisbreaking Process for Feedstock Containing Dissolved Hydrogen - An improved hydrovisbreaking process for reducing the viscosity of a liquid hydrocarbon feedstock is provided. A substantially single-phase hydrogen-enriched liquid hydrocarbon feedstock is obtained by mixing the feedstock with hydrogen gas and flashing off the excess hydrogen gas. Comparatively smaller reactor vessels can be used without a gas recycle system, thus reducing the capital cost of hydrovisbreaking process. Further the need for cutter stocks can be minimized or eliminated. | 02-27-2014 |
20140158584 | PROCEDURE FOR THE IMPROVEMENT OF HEAVY AND EXTRA-HEAVY CRUDES - The physical and chemical properties of heavy and extra-heavy crudes are improved by a procedure that uses a homogeneous type catalyst and involves the stages: 1. separation and removal of the water fraction that is contained in the hydrocarbons, 2. catalyst injection and activation of the reaction system, 3. elimination of gaseous hydrocarbons and recovery of the partial pressure of hydrogen at different times, 4. reaction and 5. recovery of distillated products. | 06-12-2014 |
20140209507 | SYSTEM AND PROCESS FOR CATALYTIC CRACKING AND REFORMING - Herein disclosed is a method for catalytic cracking or reforming of hydrocarbons comprising: supersaturating a hydrocarbonaceous liquid or slurry stream in a high shear device with a gas stream comprising one or more C1-C6 hydrocarbons and optionally hydrogen to form a supersaturated dispersion; introducing the supersaturated dispersion into a catalytic cracking or reforming reactor in the presence of a cracking or reforming catalyst to generate a product stream. In some embodiments, the catalyst is present as a slurry or a fluidized or fixed bed of catalyst. In some embodiments, the cracking or reforming catalyst is mixed with the hydrocarbonaceous liquid or slurry stream and the gas stream in the high shear device. Herein also disclosed is a system for catalytic cracking or reforming of hydrocarbons. | 07-31-2014 |
20140209508 | SYSTEM AND PROCESS FOR THERMAL CRACKING AND STEAM CRACKING - Herein disclosed is a method for thermal cracking or steam cracking of hydrocarbons comprising: supersaturating a hydrocarbonaceous liquid or slurry stream in a high shear device with a gas stream comprising steam or hydrogen and optionally one or more C1-C6 hydrocarbons to form a supersaturated dispersion; and introducing the supersaturated dispersion into a thermal cracking or steam cracking reactor to generate a product stream. In some embodiments, the method further comprises contacting the supersaturated dispersion with a cracking catalyst in a slurry, a fluidized catalyst bed, or a fixed catalyst bed. In some embodiments, the cracking catalyst is mixed with the hydrocarbonaceous liquid or slurry stream and the gas stream in the high shear device. Herein also disclosed is a system for thermal cracking or steam cracking of hydrocarbons. | 07-31-2014 |
20140251869 | METHOD FOR PRODUCING BASE LUBRICATING OIL FROM OILS RECOVERED FROM COMBUSTION ENGINE SERVICE - A method for producing ILSAC GF5 or higher compatible oils from used oil, comprising separating material having a boiling point less than about 350° F. from recovered oil to produce de-volatized oil fraction and light oil fraction. Separating material with a boiling point greater than about 350° F. and less than about 650° F. from the de-volatized oil fraction to produce fuel oil fraction and heavy oil fraction. Separating material with a boiling point greater than about 1200° F. from the heavy oil fraction to produce partially purified oil fraction and residual fraction. Treating the partially purified oil fraction to separate it into purified oil fraction and contaminant fraction. Hydrogenating the contaminant fraction to remove predetermined compounds, further saturating the fraction and thereby creating a saturated oil fraction. Fractionating the saturated oil stream to produce one or more of naphtha fraction, diesel oil fraction and base oil fraction. | 09-11-2014 |
20140299509 | PROCESS FOR REDUCTION OF SULFUR IN FCC LIQUID PRODUCTS THROUGH THE USE OF CARBON MONOXIDE AS A REDUCING AGENT - Disclosed herein is an improved fluidized catalytic cracking process for converting normally liquid hydrocarbon feedstock with simultaneous reduction of sulfur content in the liquid products obtained therefrom which comprises carrying out the cracking process in the presence of carbon monoxide gas as a reducing agent. The process optionally includes a step of premixing the hydrocarbon feedstock with carbon monoxide gas causing major sulfur reduction before effecting the cracking. The premixing is done in a specified nozzle assembly linked to the FCC unit. | 10-09-2014 |
20140332444 | PROCESS FOR HYDROCONVERTING OIL FEEDS IN FIXED BEDS FOR THE PRODUCTION OF LOW SULPHUR FUELS - A process for the conversion of oil feeds for the production of low sulphur fuels comprises the following steps in succession:
| 11-13-2014 |
20140353208 | HYDROCARBON CONVERSION PROCESSES USING IONIC LIQUIDS - A method of hydrocarbon conversion is described. The hydrocarbon feed is decontaminated using an ionic liquid and introduced into a conversion zone. The conversion of the decontaminated feed is increased compared to the conversion of the contaminated feed and the yield of the desired product made from the decontaminated hydrocarbon feed is increased compared to the yield of the desired product made from the contaminated hydrocarbon feed. | 12-04-2014 |
20160053190 | Processing Diesel Fuel From Waste Oil - There is disclosed a system and method for processing diesel fuel from petroleum-based waste oil on a small scale compared to conventional methods for re-refining waste oil to a valuable product. In an embodiment, the method comprises dehydrating waste oil to remove water from the waste oil, and operating a vertical cylindrical reactor to induce pyrolysis of the dehydrated waste oil and convert it into a hydrocarbon vapour phase. The hydrocarbon vapour derived from pyrolysis is condensed and distilled using a distillation tower to produce diesel fuel, heavy liquid hydrocarbon, light liquid hydrocarbon and light hydrocarbon vapour. A filtering step cleans the processed diesel fuel to obtain a clean diesel fuel product. | 02-25-2016 |
20160060549 | PROCESS FOR PARTIAL UPGRADING OF HEAVY AND/OR EXTRA-HEAVY CRUDE OILS FOR TRANSPORTATION - The present invention relates to a process for the partial upgrading of properties of heavy and/or extra-heavy crude oil by low severity catalytic hydrotreatment in only one reaction step. The process of the present invention is obtained upgraded oil with properties required for its transportation from offshore platforms either to maritime terminal or to refining centers. The process reduces the viscosity of heavy and/or extra-heavy crude oil, and decreases the concentration of impurities, such as sulfur, nitrogen, and metals, in such a way that heavy and/or extra-heavy crude oils can be transported to maritime terminals or to refining centers. The process increases the lifetime of the catalyst and decreased operating costs by reducing consumption of utilities because the operation of the process is carried out at lower severity. The partially upgraded oils obtained in this process can be transported directly to the maritime terminals or to existing refineries. | 03-03-2016 |
20160145501 | CONTAMINANT REMOVAL FROM HYDROCARBON STREAMS WITH CARBENIUM PSEUDO IONIC LIQUIDS - Processes for removing sulfur and nitrogen contaminants from hydrocarbon streams are described. The processes include contacting the hydrocarbon stream comprising the contaminant with lean carbenium pseudo ionic liquid or a combination of carbenium pseudo ionic liquid and ionic liquid to produce a mixture comprising the hydrocarbon and rich carbenium pseudo ionic liquid or carbenium pseudo ionic liquid and ionic liquid comprising the contaminant. The mixture is separated to produce a hydrocarbon effluent and a rich carbenium pseudo ionic liquid or carbenium pseudo ionic liquid and ionic liquid effluent comprising the rich carbenium pseudo ionic liquid or carbenium pseudo ionic liquid and ionic liquid comprising the contaminant. | 05-26-2016 |
208089000 | With hydrogen | 47 |
20080237090 | PROCESS AND SYSTEM FOR REDCUING THE OLEFIN CONTENT OF A HYDROCARBON FEED GAS AND PRODUCTION OF A HYDROGEN-ENRICHED GAS THEREFROM - Olefins can impose deleterious effect on hydrocarbon reforming processes used to generate hydrogen-enriched gas, and thus are converted into saturated compounds. Since the hydrogenation process to convert the olefins into saturated compound, difficulties arise in attempting to regulate the temperature of the hydrogenation. To facilitate temperature regulation, the hydrogenation reaction is carried out in a shell-tube reactor, containing catalyst-filled tubes, which is operated under isothermal or essentially isothermal conditions. Preferably, the heat exchange medium introduced into the shell side of the reactor to regulate the hydrogenation temperature is boiling water. | 10-02-2008 |
20090050524 | METHOD FOR PRODUCING FEEDSTOCKS OF HIGH QUALITY LUBE BASE OIL FROM UNCONVERTED OIL - The present invention relates to a method of producing a feedstock for high-quality lube base oil from unconverted oil (UCO) obtained from fuel oil hydrocracking, and more particularly to a method of producing a feedstock for high-quality lube base oil by treating vacuum gas oil (VGO) or a mixture of vacuum gas oil (VGO) with coker gas oil (CGO) or deasphalted oil (NAO) as a feedstock in a hydrotreating unit and a first hydrocracking unit and recycling the resulting unconverted oil (UCO) through a second hydrocracking unit. | 02-26-2009 |
20090107882 | Adsorbents for denitrogenation desulfurization of hydrocarbon oils and methods of producing - The present invention provides adsorbents for deep denitrogenation/desulfurization of hydrocarbon oils, and more particularly to an adsorbent material that selectively adsorbs organonitrogen and organosulfur from transportation fuels at room temperature and atmospheric pressure. | 04-30-2009 |
20090166256 | Staged co-processing of biofeeds for manufacture of diesel range hydrocarbons - Processes are provided for producing a diesel fuel product having a sulfur content of 10 ppm by weight or less from feed sources that include up to 20% by weight of a biocomponent feedstock. The mineral hydrocarbon portions of the feed sources can be distillate or heavier feed sources. | 07-02-2009 |
20090206005 | SYSTEMS, METHODS, AND CATALYSTS FOR PRODUCING A CRUDE PRODUCT - Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude product is a liquid mixture at 25° C. and 0.101 MPa. The one or more catalysts may include a catalyst that has a median pore diameter of at least 90 Å. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. | 08-20-2009 |
20090321311 | PRODUCTION OF DIESEL FUEL FROM RENEWABLE FEEDSTOCKS CONTAINING PHOSPHORUS - A process has been developed for producing diesel fuel from renewable feedstocks such as plant oils, animal oils and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a diesel boiling range fuel hydrocarbon product. If desired, the hydrocarbon product can be isomerized to improve cold flow properties. A portion of the hydrocarbon product is recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture. The renewable feedstock comprises from about 1 to about 20 wt. ppm phosphorus measured as elemental phosphorus. | 12-31-2009 |
20100025291 | Process for the Treatment of Heavy Oils Using Light Hydrocarbon Components as a Diluent - The present invention relates to a process for the treatment of heavy oils using a catalytic hydrotreating process. More specifically, the invention relates to the presence of light hydrocarbon components in conjunction with the heavy oils for improved treatment of the heavy oils utilizing moderate temperature and pressure. | 02-04-2010 |
20100038284 | PROCESS FOR HYDROTREATING A DIESEL FUEL FEEDSTOCK, HYDROTREATING UNIT FOR IMPLEMENTING SAID PROCESS, AND CORRESPONDING HYDROREFINING UNIT - The invention relates to a method for the catalytic hydrotreatment of a load based on a diesel fuel oil and a biological load based on plant oils and/or animal fats in a hydrotreatment unit. The invention is characterised in that the hydrotreatment unit comprises at least one hydrotreatment reactor operating on a countercurrent. The invention also relates to a hydrotreatment unit for implementing said method, and a corresponding hydrorefining unit. | 02-18-2010 |
20100155296 | SYSTEMS AND METHODS OF GENERATING RENEWABLE DIESEL - A method of manufacturing a purified renewable diesel product from a biofeedstock includes filtering the biofeedstock, heating the biofeedstock to about 520° F., introducing hydrogen into the biofeedstock, and treating the biofeedstock in a reactor to generate a renewable diesel product. Additionally, the method includes cooling the renewable diesel product wherein the renewable diesel product comprises a liquid, separating vapors from the liquid, and distilling the liquid in a distillation column to generate the purified renewable diesel product. In at least one embodiment the biofeedstock comprises at least one of waste grease, tallow, algae, algal oil, vegetable oil, and soybean oil. | 06-24-2010 |
20100219103 | PROCESS FOR THE PURIFICATION OF BENZENE FEEDSTOCK CONTAINING CONTAMINATING SULFUR COMPOUNDS - The invention is directed to a process for the purification of benzene feedstock containing contaminating sulfur compounds, more in particular thiophenic sulfur compounds, said process comprising contacting the benzene feedstock in the presence of hydrogen with a sulfided nickel adsorbent, wherein in said adsorbent part of the nickel is present in the metallic form, and subsequently contacting the said feedstock with a supported metallic copper adsorbent. | 09-02-2010 |
20110000819 | Process and System for Preparation of Hydrocarbon Feedstocks for Catalytic Cracking - A process, apparatus and system for forming light olefins, the process including heating a resid-containing hydrocarbon feedstock containing at least 10 ppmw of metals to vaporize at least 90 wt. % of said hydrocarbon feedstock; separating in a knockout drum a hydrocarbon vapor portion having less than 10 ppmw metals from a non-vaporized resid-containing portion; and feeding said hydrocarbon vapor to a catalytic cracking process to form light olefins. | 01-06-2011 |
20110079542 | STACKING OF LOW ACTIVITY OR REGENERATED CATALYST ABOVE HIGHER ACTIVITY CATALYST - Processes are provided for using employing lower activity hydrodesulfurization catalysts while achieving a desired product sulfur content. After determining effective reaction conditions for hydrodesulfurization using a reference catalyst system, an upstream portion of the catalyst system can be replaced with a lower activity upstream portion. The process allows tailored product sulfur levels to be achieved using reaction conditions similar to those for the reference catalyst system. | 04-07-2011 |
20110108459 | HYDROCRACKING PROCESS USING A ZEOLITE MODIFIED BY BASIC TREATMENT - The present invention describes a hydrocracking and/or hydrotreatment process using a catalyst comprising an active phase containing at least one hydrogenating/dehydrogenating component selected from the group VIB elements and the non-precious elements of group VIII of the periodic table, used alone or in a mixture, and a support comprising at least one dealuminated zeolite Y having an overall initial atomic ratio of silicon to aluminium between 2.5 and 20, an initial weight fraction of extra-lattice aluminium atoms greater than 10%, relative to the total weight of aluminium present in the zeolite, an initial mesopore volume measured by nitrogen porosimetry greater than 0.07 ml·g | 05-12-2011 |
20110174683 | METHOD AND EQUIPMENT FOR MULTISTAGE LIQUEFYING OF CARBONACEOUS SOLID FUEL - A method for multistage transforming carbonaceous solid fuel to oil, includes mixing solid fuel ( | 07-21-2011 |
20110203969 | PROCESS, SYSTEM, AND APPARATUS FOR A HYDROCRACKING ZONE - One exemplary embodiment can be a process for a hydrocarbon feed. The process can include passing a stream through a separation zone forming a void for separating one or more gases from one or more liquids and at least partially containing a catalyst. The catalyst may include at least one group VIII noble metal. Typically, the separation zone is downstream of a hydrocracking zone for reducing the operating pressure in the hydrocracking zone. | 08-25-2011 |
20110240521 | HYDROPROCESSING OF GAS OIL BOILING RANGE FEEDS - A system and method for producing fuels and lubricant basestocks from gas oil boiling range feeds is provided. Desulfurization and conversion stages are used to form fuel and lubricant products. The product from a desulfurization stage can be fractionated, and a portion of the fractionated bottoms can be used as an input feed for a conversion or hydrocracking stage. The configuration can advantageously allow for reduced amounts of catalyst in the conversion stage. | 10-06-2011 |
20110253595 | COMBINED SOLID ADSORPTION-HYDROTREATING PROCESS FOR WHOLE CRUDE OIL DESULFURIZATION - A whole crude oil desulfurization system and process includes a combination of an adsorption zone and a hydroprocessing zone. This combined process and system reduces the requisite throughput for the hydroprocessing unit, conventionally a very costly and process both in terms of energy expenditures and catalyst depletion. By first contacting the whole crude oil feedstock with an adsorbent for the sulfur-containing compounds, the adsorption effluent having a relatively lower sulfur content can be collected and provided to refiners without further treatment. The adsorbates, including adsorbed organosulfur compounds, are solvent desorbed resulting in a stream containing high levels of organosulfur compounds and a solvent. Following recovery of the solvent, the volume of the sulfur-containing feedstream that remains to be desulfurized in the hydroprocessing zone is substantially less than the original amount of whole crude oil feedstock. | 10-20-2011 |
20110259793 | Low pressure production of low cloud point diesel - A diesel fuel product with beneficial cold flow properties can be produced. A suitable feedstock for forming a diesel boiling range product can be hydrotreated to have a sulfur content of at least about 100 wppm and then dewaxed. This two stage process can allow for production of an arctic or winter diesel without use of high pressures. Optionally, a divided wall column fractionator can be used to allow a single separation stage to handle the effluent from both the hydroprocessing and the dewaxing stages. | 10-27-2011 |
20120103868 | HYDROPROCESSING OF HEAVY HYDROCARBON FEEDS IN LIQUID-FULL REACTORS - A process to treat a heavy hydrocarbon feed in a liquid-full hydroprocessing reactor is disclosed. The heavy feed has a high asphaltenes content, high viscosity, high density and high end boiling point. Hydrogen is fed in an equivalent amount of at least 160 liters of hydrogen, per liter of feed, l/l (900 scf/bbl). The feed is contacted with hydrogen and a diluent, which comprises, consists essentially of, or consists of recycle product stream. The hydroprocessed product has increased value for refineries, such as a feed for an fluid catalytic cracking (FCC) unit. | 05-03-2012 |
20120118792 | Converting Heavy Sour Crude Oil/Emulsion to Lighter Crude Oil Using Cavitations and Filtration Based Systems - A process for converting heavy sulfur-containing crude oil into lighter crude oil with lower sulfur content and lower molecular weight is provided. The process is a low-temperature process using controlled cavitation. | 05-17-2012 |
20120205286 | HYDROCRACKING PROCESS USING A ZEOLITE CATALYST CONTAINING TWO DISTINCT HYDROGENATING FUNCTIONS - Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g | 08-16-2012 |
20120279900 | Energy-Efficient and Environmentally Advanced Configurations For Naptha Hydrotreating Process - Systems and methods of hydrotreating different naphtha feed stocks destined for a refining reforming unit and other applications with less energy consumption than conventionally possible, while producing less greenhouse gas emissions, and/or using a lesser number of heaters and correspondingly less capital investment in such heaters, air coolers, and water coolers, are provided. According to the more examples of such systems and methods, such reductions are accomplished by directly integrating a naphtha stripping process section with a naphtha splitting process section. Additional reductions can also be accomplished through directly integrating a naphtha hydrotreat reaction process section with the naphtha stripping process section. | 11-08-2012 |
20130112595 | HYDROCRACKING PROCESS WITH INTEGRAL INTERMEDIATE HYDROGEN SEPARATION AND PURIFICATION - An intermediate hydrogen separation and absorption-based purification system is integrated with a hydrocracking process for the production of relatively lower molecular weight products from a relatively heavy feedstock including sulfur-containing and nitrogen-containing hydrocarbon compounds. The integrated process allows the processing of heavy hydrocarbon feedstock having high nitrogen and high sulfur contents in a single-stage configuration and the using of noble metal catalyst in the hydrocracking reaction zone. The integrated process increases the overall catalytic activity and hydrogenation capability to produce superior distillate products. | 05-09-2013 |
20130112596 | HYDROTREATING AND AROMATIC SATURATION PROCESS WITH INTEGRAL INTERMEDIATE HYDROGEN SEPARATION AND PURIFICATION - An intermediate hydrogen separation and purification system is integrated with a hydrotreating and an aromatic saturation process for the production of relatively lower molecular weight products from a relatively heavy feedstock including sulfur-containing and aromatic-containing hydrocarbon compounds. The integrated process allows the processing of heavy hydrocarbon feedstock having high aromatic and high sulfur contents in a single-stage configuration and the using of noble metal catalyst in the aromatic saturation zone. The integrated process increases the overall catalytic activity and hydrogenation capability to produce superior distillate products. | 05-09-2013 |
20130118952 | PRETREATMENT OF FCC NAPHTHAS AND SELECTIVE HYDROTREATING - This invention provides methods for multi-stage hydroprocessing treatment of FCC naphthas for improving the overall production quantity of naphtha boiling-range materials during naphtha production for low sulfur gasolines. Of particular benefit of the present processes is the selective treating of cat naphthas to remove gums instead of undercutting the overall naphtha pool by lowering the end cutpoints of the cat naphtha fraction. This maximizes the amount of refinery cat naphtha that can be directed to the gasoline blending pool while eliminating existing processing problems in hydrodesulfurization units. The processes disclosed herein have the additional benefit of minimizing octane losses in the increased naphtha pool volume. | 05-16-2013 |
20130161234 | Alkali Metal Hydroprocessing of Heavy Oils with Enhanced Removal of Coke Products - Hydrocarbon feedstreams are desulfurized using an alkali metal reagent, optionally in the presence of hydrogen. Improved control over reaction conditions can be achieved in part by controlling the particle size of the alkali metal salt and by using multiple desulfurization reactors. The processes herein allow a simple and effective method for removing the majority of coke formed in the alkali metal reagent reactions with the hydrocarbon feedstreams. This makes it cost effective to run such processes at higher severities (which result in higher coke production) thereby resulting in increased amounts of valuable converted hydrocarbon product yields. The process improvements herein may also be used to increase total throughput through a unit due to the ability to effectively manage higher coke content in the reaction products. | 06-27-2013 |
20130161235 | METHOD FOR PRODUCING RENEWABLE FUELS - According to the present invention, organic material is converted to biogas through anaerobic digestion and the biogas is purified to yield a combustible fluid feedstock comprising methane. A fuel production facility utilizes or arranges to utilize combustible fluid feedstock to generate renewable hydrogen that is used to hydrogenate crude oil derived hydrocarbons in a process to make liquid transportation or heating fuel. The renewable hydrogen is added to a reactor operated so as to simultaneously desulfurize and hydrogenate crude oil derived hydrocarbons. | 06-27-2013 |
20130186805 | SELECTIVE MIDDLE DISTILLATE HYDROTREATING PROCESS - A selective mid-distillate hydrotreating process is provided for production of hydrocarbon fuels with an ultra-low level of sulfur in which the initial hydrocarbon feedstock is introduced into to an aromatic extraction zone to produce an aromatic-lean fraction and an aromatic-rich fraction, which contain different classes of organosulfur compounds having different reactivities when subjected to hydrotreating reactions. The aromatic-lean fraction contains primarily labile heteroatom-containing compounds, and is passed to a first hydrotreating zone operating under mild conditions to remove the sulfur heteroatom from organosulfur hydrocarbon compounds. The aromatic-rich fraction contains primarily refractory heteroatom-containing compounds, including aromatic molecules such as certain benzothiophenes (e.g., long chain alkylated benzothiophenes), dibenzothiophene and alkyl derivatives, such as sterically hindered 4,6-dimethyldibenzothiophene, and is passed to a hydrotreating zone operating under relatively severe conditions to remove the heteroatom from sterically hindered refractory compounds. | 07-25-2013 |
20130193035 | CATALYST PREPARATION REACTORS FROM CATALYST PRECURSOR USED FOR FEEDING REACTORS TO UPGRADE HEAVY HYDROCARBONACEOUS FEEDSTOCKS - A process for upgrading heavy hydrocarbonaceous feedstocks in at least one hydroconversion reactor for hydroconversion of the heavy hydrocarbonaceous feedstocks and in at least one hydrotreatment reactor for hydrotreatment of the heavy hydrocarbonaceous feedstocks, comprising the preparation of two or more catalysts, each catalyst being prepared from one or more catalyst precursor in at least one specific preparation reactor, the catalyst precursor containing at least one transition metal selected from group IIA, IIIB, IVB, VB, VIB, VIIB, VIII, IB or IIB of the periodic table of elements, and each preparation reactor feeding one or more hydroconversion or hydrotreatment reactor, each catalyst contained in preparation reactors being dedicated to hydroconversion or hydrotreatment of the feedstocks. | 08-01-2013 |
20130306517 | CATALYST AND PROCESS FOR HYDROCONVERSION OF A HEAVY FEEDSTOCK - A hydroconversion catalyst comprising a Group VIB metal component, a Group VIII metal component and a carrier material is disclosed wherein said catalyst has a total surface area of 240 to 360 m | 11-21-2013 |
20130334099 | PROCESS FOR THE HYDROCRACKING OF HYDROCARBON CUTS USING A CATALYST BASED ON HETEROPOLYANIONS TRAPPED IN A MESOSTRUCTURED OXIDE SUPPORT - A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (H | 12-19-2013 |
20140001090 | PROCESS FOR HYDROTREATING HEAVY RAW OILS | 01-02-2014 |
20140027346 | SPHERICAL MATERIAL COMPRISING METALLIC NANOPARTICLES TRAPPED IN A MESOSTRUCTURED OXIDE MATRIX AND ITS USE AS A CATALYST IN REFINING PROCESSES - An inorganic material is described, constituted by at least two elementary spherical particles, each of said spherical particles comprising metallic nanoparticles having at least one band with a wave number in the range 750 to 1050 cm | 01-30-2014 |
20140174983 | CATALYST SUPPORT AND CATALYSTS PREPARED THEREFROM - A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 A. | 06-26-2014 |
20140197071 | FIELD ENHANCED SEPARATION OF HYDROCARBON FRACTIONS - Systems and methods are provided for using field enhanced separations to produce multiple fractions from a petroleum input. A liquid thermal diffusion and/or electric field separation is used to produce the fractions. The fractions can then be used to form multiple outputs that share a first feature while being different with regard to a second feature. For example, a first fraction from the plurality of fractions can have a desired value for a first property such as viscosity index. Two or more additional fractions from the plurality of fractions can then be blended together to make a blended fraction or output. The blended fraction can have a value for the first property that is substantially similar to the value for the first fraction. However, for a second property, the first fraction and the blended fraction can have distinct values. As a result, multiple output fractions can be formed that share a first feature but differ in a second feature. | 07-17-2014 |
20140262945 | PROCESS FOR IMPROVING COLD FLOW PROPERTIES AND INCREASING YIELD OF MIDDLE DISTILLATE FEEDSTOCK THROUGH LIQUID FULL HYDROTREATING AND DEWAXING - Novel liquid-full process for improving cold flow properties and increasing yield of middle distillate fuel feedstock by hydrotreating and dewaxing the feedstock in liquid-full reactors. | 09-18-2014 |
20140299510 | SLURRY OIL UPGRADING WHILE PRESERVING AROMATIC CONTENT - Methods relating to methods for producing a needle coke precursor from slurry oil having low levels of nitrogen and sulfur. Nitrogen-containing compounds are removed by chromatography, followed by hydrotreating at relatively mild conditions that focus on the more easily-removed sulfur-containing compounds while largely preserving aromatic content of the slurry oil. The resulting needle coke precursor can be converted to a premium needle coke in a delayed coking system. | 10-09-2014 |
20140339133 | TWO STAGE DIESEL AROMATICS SATURATION PROCESS USING BASE METAL CATALYST - A process that provides for the improvement of the properties of a distillate feedstock that has significant concentrations of nitrogen and polyaromatic compounds. The process includes a first reaction zone that uses a base metal catalyst and is operated under high pressure conditions to provide for the hydrodenitrogenation of organic nitrogen and saturation of polyaromatic compounds contained in the distillate feedstock. The first reaction zone treated effluent is separated into a heavy fraction and a lighter fraction with the heavy fraction being charged to a second reaction zone that also uses a base metal catalyst and is operated under high pressure conditions to provide for the saturation of monaromatic compounds that are contained in the heavy fraction. The inventive process provides for a high quality, low-sulfur and low-nitrogen diesel product that has a significantly lower aromatics content than the distillate feedstock and having a high value for its high Cetane Index. | 11-20-2014 |
20150083643 | GAS OIL HYDROPROCESS - A process for the hydroprocessing of a gas oil (GO) hydrocarbon feed to provide high yield of a diesel fraction. The process comprises a liquid-full hydrotreating reaction zone followed by a liquid-full hydrocracking reaction zone. A refining zone may be integrated with the hydrocracking reaction zone. Ammonia and other gases formed during the hydrotreatment are removed in a separation step prior to hydrocracking. | 03-26-2015 |
20150129461 | APPARATUSES AND METHODS FOR HYDROTREATING COKER KEROSENE - Embodiments of apparatuses and methods for hydrotreating coker kerosene or other thermally or catalytically cracked hydrocarbon stream are provided. In one example, a method comprises splitting a feed comprising coker kerosene into first and second feed streams. The first feed stream is heated to form a heated first feed stream. The second feed stream is partially heated to form a partially heated second feed stream. The heated first feed stream is contacted with a first hydrotreating catalyst to form a first hydrotreated intermediate stream. The first hydrotreated intermediate stream is combined with the partially heated second feed stream to form a partially quenched first hydrotreated intermediate combined stream. The partially quenched first hydrotreated intermediate combined stream is contacted with a second hydrotreating catalyst to further hydrotreat the partially quenched first hydrotreated intermediate combined stream. | 05-14-2015 |
20150136648 | METHOD FOR TREATING COAL TAR USING REACTIVE DISTILLATION - Methods of treating coal tar using reactive distillation are described. The methods include introducing a coal tar stream into a reactive distillation zone which has a reaction zone and a separation zone. The reaction zone contains a hydrotreating catalyst and an absorbent. The coal tar stream is contacted with a hydrogen stream in the reaction zone to remove contaminants from the coal tar stream, and the treated coal tar stream is separated into at least two fractions. | 05-21-2015 |
20150136649 | HYDROTREATING AND AROMATIC SATURATION PROCESS WITH INTEGRAL INTERMEDIATE HYDROGEN SEPARATION AND PURIFICATION - An intermediate hydrogen separation and purification system is integrated with a hydrotreating and an aromatic saturation process for the production of relatively lower molecular weight products from a relatively heavy feedstock including sulfur-containing and aromatic-containing hydrocarbon compounds. The integrated process allows the processing of heavy hydrocarbon feedstock having high aromatic and high sulfur contents in a single-stage configuration and the using of noble metal catalyst in the aromatic saturation zone. The integrated process increases the overall catalytic activity and hydrogenation capability to produce superior distillate products. | 05-21-2015 |
20150144529 | VACUUM DISTILLATE HYDROTREATMENT PROCESS EMPLOYING A CONCATENATION OF CATALYSTS - A process for the hydrotreatment of a vacuum distillate type hydrocarbon feed containing nitrogen-containing compounds is described, comprising a first step in which the feed is brought into contact with a catalyst in its oxide form, then a second step in which the feed is brought into contact with a dried catalyst comprising at least one organic compound containing oxygen and/or nitrogen. | 05-28-2015 |
20160115400 | INTEGRATED HYDROTREATING AND SLURRY HYDROCRACKING PROCESS - Slurry hydrocracking processes are described. The methods include hydrotreating a heavy residual hydrocarbon feed in a hydrotreating zone under residual hydrotreating conditions to form a hydrotreated effluent. The hydrotreated effluent is separated in an first separator to form an overhead vapor stream and a bottoms stream. The bottoms stream is hydrocracked in a slurry hydrocracking zone under slurry hydrocracking conditions. The effluent from the slurry hydrocracking zone is fractionated in a fractionation zone into at least two streams. Slurry hydrocracking apparatus is also described. | 04-28-2016 |
20160122662 | PROCESS FOR CONVERTING PETROLEUM FEEDSTOCKS COMPRISING A VISBREAKING STAGE, A MATURATION STAGE AND A STAGE OF SEPARATING THE SEDIMENTS FOR THE PRODUCTION OF FUEL OILS WITH A LOW SEDIMENT CONTENT - The invention relates to a process for converting a hydrocarbon-containing feedstock containing at least one hydrocarbon fraction having a sulphur content of at least 0.1% by weight, an initial boiling temperature of at least 340° C. and a final boiling temperature of at least 440° C., making it possible to obtain a heavy fraction having a sediment content after ageing of less than or equal to 0.1% by weight, said process comprising the following stages: a) a stage of visbreaking the feedstock in at least one maturation chamber (soaker), b) a stage of separating the effluent obtained at the end of stage a), c) a stage of maturation of the heavy fraction originating from stage b), d) a stage of separating the sediments from the heavy fraction originating from the maturation stage c) in order to obtain said heavy fraction. | 05-05-2016 |
20160145508 | HYDROPROCESSING FOR DISTILLATE PRODUCTION - Methods are provided for hydrotreating a feed to generate a product with a reduced or minimized aromatics content and/or an increased distillate product yield. A distillate boiling range feed having an elevated content of sulfur and/or nitrogen can be hydrotreated using at least two hydrotreating stages with intermediate separation to produce a hydrotreated distillate boiling range product with a reduced or minimized aromatics content. Additionally or alternately, a mixed metal catalyst formed from a suitable precursor can be used during the hydrotreating. A mixed metal catalyst formed from a suitable precursor can provide an unexpectedly superior activity for aromatic saturation. A still further unexpected benefic can be achieved by combining a multi-stage hydrotreating process with intermediate separation with hydrotreating in the presence of a mixed metal catalyst formed from a suitable precursor. | 05-26-2016 |
20220135890 | SIMULTANEOUS PROCESSING OF CATALYTIC AND THERMALLY CRACKED MIDDLE DISTILLATE FOR PETROCHEMICAL FEEDSTOCK - The present invention discloses an integrated process scheme for producing (i) high-octane gasoline blending stream (ii) high aromatic heavy naphtha stream which is a suitable feedstock for benzene, toluene, and xylene (BTX) production and (iii) high cetane ultra-low sulphur diesel (ULSD) stream suitable for blending in refinery diesel pool. | 05-05-2022 |
208090000 | With acids | 3 |
20120055845 | Desulfurization and Sulfone Removal Using A Coker - A method and apparatus for upgrading a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds present in the hydrocarbon feedstock; (c) separating the hydrocarbons and the oxidized sulfur compounds by solvent extraction; (d) collecting a residue stream that includes the oxidized sulfur compounds; and (e) supplying the residue stream to a coker to produce coker gases and solid coke. | 03-08-2012 |
20150322353 | CONTAMINANT REMOVAL FROM HYDROCARBON STREAMS WITH LACTAMIUM BASED IONIC LIQUIDS - A process for removing a contaminant from a hydrocarbon stream using a lactamium based ionic liquid is described. The process includes contacting the hydrocarbon stream comprising the contaminant with a lean hydrocarbon-immiscible lactamium ionic liquid to produce a mixture comprising the hydrocarbon and a rich hydrocarbon-immiscible lactamium ionic liquid comprising at least a portion of the removed contaminant; and separating the mixture to produce a hydrocarbon effluent and a rich hydrocarbon-immiscible lactamium ionic liquid effluent comprising the rich hydrocarbon-immiscible lactamium ionic liquid. | 11-12-2015 |
20160168483 | CONTAMINANT REMOVAL FROM KEROSENE STREAMS WITH LACTAMIUM BASED IONIC LIQUIDS | 06-16-2016 |
208091000 | With solid absorbents | 12 |
20090321312 | INTEGRATED PROCESS FOR UPGRADING A VAPOR FEED - Processes and systems are provided for removing contaminants from a vapor stream containing hydrocarbon and hydrogen, and can include: providing a feed stream to a first pressurized vapor liquid separator that produces a liquid stream and a vapor stream containing hydrocarbon and hydrogen, passing the vapor stream to an inlet of a particulate trap containing a plurality of treatment zones that remove contaminants from the vapor stream to produce a particulate trap effluent, and passing the particulate trap effluent directly to a catalytic hydrogenation zone. The processes and systems can also include: passing the liquid stream from the first pressurized vapor liquid separator to a second vapor liquid separator that produces an overhead vapor stream and a liquid bottoms stream, condensing the overhead vapor stream from the second vapor liquid separator to form a liquid overhead stream, routing the liquid overhead stream to the inlet of the particulate trap. | 12-31-2009 |
20100147745 | METHOD FOR REDUCING THE MERCURY CONTENT OF NATURAL GAS CONDENSATE AND NATURAL GAS PROCESSING PLANT - A method for reducing the mercury content of natural gas condensate, comprising the steps of providing a nanofiltration membrane having a feed side and a permeate side; contacting the natural gas condensate with the feed side of the membrane; and obtaining a mercury-depleted natural gas condensate at the permeate side of the membrane; and a natural gas processing plant comprising a condensate workup section including a nanofiltration membrane separation unit for reducing the mercury content of natural gas condensate. | 06-17-2010 |
20100155297 | REMOVAL OF NITROGEN COMPOUNDS - A process for the removal of one or more nitrogen compounds, e.g. basic nitrogen compound from a fluid stream is described in which the fluid is contacted with a functionalized polymer fibre material having functional groups capable of reacting with the nitrogen compounds. | 06-24-2010 |
20100176029 | Upgrading Slurry Oil Using Chromatographic Reactor Systems - Methods and apparatus relate to reducing content of nitrogen-containing compounds within slurry oil using a chromatographic based assembly, which may not affect aromatic content, prior to feeding the slurry oil into a coking system. The slurry oil passes through the chromatographic based assembly to upgrade the slurry oil and make the slurry oil suitable for feedstock in making needle coke. Further, a hydrotreater utilized in combination with the chromatographic based assembly may provide additional upgrading of the slurry oil. | 07-15-2010 |
20100252483 | PROCESS FOR REMOVAL OF NITROGEN AND POLY-NUCLEAR AROMATICS FROM FCC FEEDSTOCKS - A feedstream to an FCC unit is treated to remove or reduce the content of polynuclear aromatics and nitrogen-containing compounds by contacting the feedstream with an adsorbent compound selected from attapulgus clay, alumina, silica gel and activated carbon in a fixed bed or slurry column and separating the treated feedstream that is lower in the undesired compounds from the adsorbent material. The adsorbent can be mixed with a solvent for the undesired compounds and stripped for re-use. | 10-07-2010 |
20100300935 | Process for Desulfurization and Denitration of a Gas-Oil-Type Hydrocarbon Fraction that Contains Nitrogen Compounds - The invention describes an improved process for deep desulfurization of a gas-oil-type hydrocarbon fraction that comprises a catalytic hydrodesulfurization unit that is preceded by a unit for adsorption of the nitrogen compounds that inhibit the hydrodesulfurization reaction. | 12-02-2010 |
20100326886 | LIGHT PARAFFIN ISOMERIZATION WITH IMPROVED FEED PURIFICATION - The service life and deactivation rate of a paraffin isomerization catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water and deactivation of an isomerization catalyst is practically eliminated. The fact that the guard bed material preserves the active metal phase-copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product. | 12-30-2010 |
20120024756 | TREATMENT OF A HYDROCARBON FEED - A method is disclosed for removing impurities such as nitrogen and/or sulfur compounds from a hydrocarbon feed, in which the feed is contacted with an adsorbent including a nitrogen-containing organic heterocyclic salt deposited on a porous support, e.g., a supported ionic liquid. Additionally, a method for hydrotreating a hydrocarbon feed which includes a hydroprocessing step is disclosed, wherein prior to hydroprocessing, the feed is contacted with an adsorbent including a supported ionic liquid. Additionally, a method for producing a lube oil which includes isomerization dewaxing of a base oil fraction is disclosed, wherein prior to the isomerization dewaxing step, the base oil fraction is contacted with an adsorbent including a supported ionic liquid. In one embodiment, the adsorbent is regenerated to restore its treatment capacity. | 02-02-2012 |
20120187027 | HYDROCRACKING PROCESS WITH FEED/BOTTOMS TREATMENT - A hydrocracking process is provided for treating a first heavy hydrocarbon feedstream and a second heavy hydrocarbon feedstream, in which the first heavy hydrocarbon feedstream contains undesired nitrogen-containing compounds, sulfur-containing compounds and poly-nuclear aromatic compounds. The process includes contacting the first heavy hydrocarbon feedstream with adsorbent material to produce an adsorbent-treated heavy hydrocarbon stream having a reduced content of nitrogen-containing, sulfur-containing compounds and poly-nuclear aromatic compounds. The second heavy hydrocarbon feedstream is combined with the adsorbent-treated heavy hydrocarbon stream. The combined stream is charged to a hydrocracking reaction unit. The hydrocracked effluent is fractioned to recover hydrocracked products and a bottoms stream containing heavy poly-nuclear aromatic compounds. Fractionator bottoms are contacted with adsorbent material (which can be the same or different than the adsorbent material used to treat the initial feed) to produce an adsorbent-treated fractionator bottoms stream having a reduced content of heavy poly-nuclear aromatic compounds, and are recycled to the hydrocracking reaction unit. | 07-26-2012 |
20130062257 | Integrated Isomerization and Hydrotreating Process - Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A low boiling temperature fraction contains refractory, sterically hindered sulfur-containing compounds, which have a boiling point at or above the target cut point temperature. A high boiling temperature fraction, having a boiling point below the target cut point temperature, is substantially free of refractory sulfur-containing compounds. The high boiling temperature fraction is contacted with isomerization catalyst, and the isomerized effluent and the low boiling temperature fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level. | 03-14-2013 |
20140021094 | METHOD OF REMOVING HEAVY HYDROCARBONS - Heavy hydrocarbons contained in FT off gas of a GTL process are removed by bringing the FT off gas into contact with absorption oil, by introducing the FT off gas into a distillation tower, by cooling the FT off gas or by driving the FT off gas into an adsorbent. A burner tip for heating a reformer tube, using FT off gas as fuel, is prevented from being plugged by the deposition of heavy hydrocarbons contained in the FT off gas. | 01-23-2014 |
20140360918 | HYDROCRACKING PROCESS WITH FEED/BOTTOMS TREATMENT - A hydrocracking process is provided for treating a first heavy hydrocarbon feedstream and a second heavy hydrocarbon feedstream, in which the first heavy hydrocarbon feedstream contains undesired nitrogen-containing compounds, sulfur-containing compounds and poly-nuclear aromatic compounds. The process includes contacting the first heavy hydrocarbon feedstream with adsorbent material to produce an adsorbent-treated heavy hydrocarbon stream having a reduced content of nitrogen-containing, sulfur-containing compounds and poly-nuclear aromatic compounds. The second heavy hydrocarbon feedstream is combined with the adsorbent-treated heavy hydrocarbon stream. The combined stream is charged to a hydrocracking reaction unit. The hydrocracked effluent is fractioned to recover hydrocracked products and a bottoms stream containing heavy poly-nuclear aromatic compounds. Fractionator bottoms are contacted with adsorbent material (which can be the same or different than the adsorbent material used to treat the initial feed) to produce an adsorbent-treated fractionator bottoms stream having a reduced content of heavy poly-nuclear aromatic compounds, and are recycled to the hydrocracking reaction unit. | 12-11-2014 |