JAPAN PETROLEUM EXPLORATION CO., LTD. Patent applications |
Patent application number | Title | Published |
20150065761 | DIESEL FUEL OR DIESEL FUEL BASE STOCK AND PRODUCTION METHOD THEREOF - Provided is a hydrotreating step (A) containing a hydroisomerization step (A1) that obtains a hydroisomerized oil (a1) by bringing a FT synthesis oil into contact with a hydroisomerization catalyst and/or a hydrocracking step (A2) that obtains a hydrocracked oil (a2) by bringing it into contact with a hydrocracking catalyst, and a fractionation step (B) that transfers at least a portion of the hydrotreated oil (a) composed of the hydroisomerized oil (a1) and/or the hydrocracked oil (a2) to a fractionator and, at the very least, obtains a middle distillate (b1) with a 5% distillation point of 130 to 170° C. and a 95% distillation point of 240 to 300° C., and a heavy oil (b2) that is heavier than the middle distillate (b1). | 03-05-2015 |
20150056112 | METHOD AND SYSTEM FOR SYNTHESIZING LIQUID HYDROCARBON COMPOUNDS - Provided is a method for synthesizing liquid hydrocarbon compounds wherein synthesizing liquid hydrocarbon compounds from a synthesis gas by a Fisher-Tropsch synthesis reaction. The method includes a first absorption step of absorbing a carbon dioxide gas, which is contained in gaseous by-products generated in the Fisher-Tropsch synthesis reaction, with an absorbent, and a second absorption step of absorbing a carbon dioxide gas, which is contained in the synthesis gas, with the absorbent which is passed through the first absorption step. | 02-26-2015 |
20150011662 | HYDROCARBON PRODUCTION APPARATUS AND HYDROCARBON PRODUCTION PROCESS - The hydrocarbon production apparatus is provided with a gas-liquid separator for cooling gaseous state hydrocarbons drawn out from a gas phase portion of a reactor for the Fischer-Tropsch synthesis reaction and liquefying a portion of the hydrocarbons. A light liquid hydrocarbon supply line for supplying light hydrocarbons is disposed between a downstream side line which is downstream from the last stage of a gas-liquid separating unit of the gas-liquid separator, and an upstream side line which is upstream from the last stage of the gas-liquid separating unit of the gas-liquid separator, wherein the downstream side line is a liquid hydrocarbon line on the downstream side through which the light hydrocarbons having cloud points lower than the temperature at an outlet of a cooler in the last stage of the gas-liquid separating unit are flowed. | 01-08-2015 |
20140326642 | HYDROGENATION REFINING CATALYST AND METHOD FOR PRODUCING A HYDROCARBON OIL - The hydrotreating catalyst of the present invention is a hydrotreating catalyst including a catalyst support including an amorphous composite metal oxide having solid acidity, and at least one active metal supported by the catalyst support and selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the hydrotreating catalyst contains a carbonaceous substance including a carbon atom, and the content of the carbonaceous substance in the hydrotreating catalyst is 0.05 to 1% by mass in terms of the carbon atom. | 11-06-2014 |
20140322095 | METHOD FOR RECOVERING HYDROCARBON COMPOUNDS AND A HYDROCARBON RECOVERY APPARATUS FROM A GASEOUS BY-PRODUCT - There is provided a method for recovering hydrocarbon compounds from gaseous by-products generated in a Fischer-Tropsch synthesis reaction. The method includes absorbing light hydrocarbon compounds and a carbon dioxide gas from the gaseous by-products using an absorption solvent including liquid hydrocarbon compounds and a carbon dioxide gas absorbent, separating the absorption solvent which has absorbed the light hydrocarbon compounds and the carbon dioxide gas into the liquid hydrocarbon compounds and the carbon dioxide gas absorbent, heating the separated liquid hydrocarbon compounds to recover the light hydrocarbon compounds from the separated liquid hydrocarbon compounds, heating the separated carbon dioxide gas absorbent to strip the carbon dioxide gas from the separated carbon dioxide gas absorbent, and reusing the gaseous by-products from which the light hydrocarbon compounds and the carbon dioxide gas are absorbed as a feedstock gas for the Fischer-Tropsch synthesis reaction. | 10-30-2014 |
20140305839 | KEROSENE BASE MATERIAL PRODUCTION METHOD AND KEROSENE BASE MATERIAL - A process for producing a kerosene base fuel according to the present invention comprises removing paraffins having carbon number of 7 or less from a first fraction having an initial boiling point of 95 to 140° C. and a final boiling point of 240 to 280° C. obtained from a hydrotreated oil of a Fischer-Tropsch synthetic oil to obtain a second fraction having a content of paraffins having carbon number of 7 or less of 0.1 to 0.7% by mass. | 10-16-2014 |
20140250946 | METHOD FOR RECOVERING HYDROCARBON COMPOUNDS AND A HYDROCARBON RECOVERY APPARATUS FROM A GASEOUS BY-PRODUCT - There is provided a method for recovering hydrocarbon compounds from a gaseous by-products generated in the Fisher-Tropsch synthesis reaction, the method comprising a pressurizing step in which the gaseous by-products are pressurized, a cooling step in which the pressurized gaseous by-products are pressurized to liquefy hydrocarbon compounds in the gaseous by-products, and a separating step in which the hydrocarbon compounds liquefied in the cooling step are separated from the remaining gaseous by-products. | 09-11-2014 |
20140183124 | FILTER CLEANING APPARATUS - A filter cleaning apparatus used in a reaction system including; a reaction tank having a filter, first feed line connected to the filter at one end, a recovery tank connected to the other end of the first feed line, and second feed line connected to the recovery tank at one end, is provided. The filter cleaning apparatus includes; first return line connected the second feed line at one end, first and second reverse cleaning solution tanks connected to the first return line, a first flow rate adjusting valve that can adjust filtered fluid to be supplied to the first reverse cleaning solution tank, a second flow rate adjusting valve that can adjust filtered fluid to be supplied to the second reverse cleaning solution tank, and a switching section that carries either one of the filtered fluids accommodated in these reverse cleaning solution tanks by switching. | 07-03-2014 |
20140162871 | METHOD FOR PRODUCING HYDROGENATION CATALYST - The present invention provides a method for producing a hydroprocessing catalyst including a supporting step of allowing a catalyst support having a content of a carbonaceous substance containing carbon atoms of 0.5% by mass or less in terms of carbon atoms to support an active metal component containing at least one active metal element selected from metals belonging to Group 6, Group 8, Group 9 and Group 10 in the periodic table, to obtain a catalyst precursor, and a calcining step of calcining the catalyst precursor obtained in the supporting step to obtain the hydroprocessing catalyst. | 06-12-2014 |
20140157813 | TEMPERATURE CONTROL SYSTEM - A temperature control system of the invention recovers reaction heat in a reactor in which an exothermal reaction occurs, to control the temperature in the reactor. The temperature control system includes: a refrigerant drum in which vapor and a liquid refrigerant are stored in a vapor-liquid equilibrium state; a heat removing section arranged in the reactor to evaporate a part of the liquid refrigerant supplied from the refrigerant drum by the reaction heat; a Return line that returns mixed phase fluid of vapor and the liquid refrigerant generated in the heat removing section to the refrigerant drum; a Vapor outlet line that supplies vapor in the refrigerant drum to outside of the system; and a Replenishing line that supplies makeup water in an amount matched with an amount of vapor discharged to the outside of the system, to the Return line. | 06-12-2014 |
20140135410 | HYDROCARBON SYNTHESIS REACTION APPARATUS, START-UP PROCESS THEREOF, AND HYDROCARBON SYNTHESIS REACTION SYSTEM - The hydrocarbon synthesis reaction apparatus is provided with a synthesis gas supply line in which a synthesis gas is compressed and supplied by a first compressor, a reactor configured to accommodate a catalyst slurry, a gas-liquid separator configured to separate an unreacted synthesis gas and hydrocarbons discharged from the reactor into a gas and a liquid, a first recycle line in which the unreacted synthesis gas after separation into a gas and a liquid is compressed and recycled into the reactor by a second compressor, and a second recycle line configured to recycle a residual unreacted synthesis gas after separation into a gas and a liquid into the inlet side of the first compressor at the time of start-up operation when the synthesis gas is gradually increased in the amount to be introduced. | 05-15-2014 |
20140124411 | HYDROCRACKING CATALYST AND METHOD FOR PRODUCING A HYDROCARBON OIL - The hydrocracking catalyst of the present invention is a hydrocracking catalyst comprising a catalyst support comprising a zeolite and an amorphous composite metal oxide having solid acidity, and at least one active metal supported by the catalyst support and selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the hydrocracking catalyst contains a carbonaceous substance comprising a carbon atom, and the content of the carbonaceous substance in the hydrocracking catalyst is 0.05 to 1% by mass in terms of the carbon atom. | 05-08-2014 |
20140107231 | METHOD FOR STARTING UP BUBBLE-COLUMN-TYPE SLURRY-BED REACTOR, START-UP SOLVENT, AND METHOD FOR PRODUCING HYDROCARBON OIL - A method for starting up a bubble column slurry bed reactor of the present invention includes, when restarting operation of a bubble column slurry bed reactor for producing hydrocarbons by the Fischer-Tropsch synthesis reaction, feeding a hydroprocessed oil produced in the bubble column slurry bed reactor and hydroprocessed that contains 40% by mass or more of paraffin hydrocarbons having carbon number of 21 or more and that has a peroxide value of 1 ppm or less, to the bubble column slurry bed reactor. | 04-17-2014 |
20140088204 | METHOD FOR PRODUCING HYDROCARBON OIL, FISCHER-TROPSCH SYNTHESIS REACTION DEVICE, AND HYDROCARBON OIL PRODUCTION SYSTEM - The present invention provides a process for producing a hydrocarbon oil by performing a Fischer-Tropsch synthesis reaction using a reactor for a Fischer-Tropsch synthesis including a reaction apparatus having a slurry containing catalyst particles and a gaseous phase located above the slurry to obtain a hydrocarbon oil, wherein the Fischer-Tropsch reaction is performed while controlling a temperature of the slurry so that a difference T | 03-27-2014 |
20140083907 | REGENERATED HYDROCRACKING CATALYST AND METHOD FOR PRODUCING A HYDROCARBON OIL - The regenerated hydrocracking catalyst according to the present invention is a regenerated hydrocracking catalyst prepared by regenerating a used hydrocracking catalyst including: a catalyst support containing zeolite and an amorphous composite metal oxide having solid acidity; and at least one active metal supported by the catalyst support, selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the regenerated hydrocracking catalyst contains 0.05 to 1% by mass of a carbonaceous substance in terms of carbon atoms based on the entire mass of the catalyst. | 03-27-2014 |
20140080926 | METHOD FOR ESTIMATING CONTENT OF FINE PARTICLES IN SLURRY AND PROCESS FOR PRODUCING HYDROCARBON OIL - A method for estimating a particulate content in a slurry of the present invention is a method for estimating a content of particulates having a predetermined particle size or less in a slurry with solid particles dispersed in hydrocarbons including a wax, the method including, based on a correlation between a visible light transmittance and a content of solid particles having the predetermined particle size or less at a temperature at which hydrocarbons including a wax are liquefied when the solid particles having the predetermined particle size or less are dispersed in the hydrocarbons, estimating a content of particulates having the predetermined particle size or less in the slurry from a visible light transmittance of a supernatant part when the slurry is left to stand at the temperature. | 03-20-2014 |
20140076782 | REGENERATED HYDROGENATION REFINING CATALYST AND METHOD FOR PRODUCING A HYDROCARBON OIL - The regenerated hydrotreating catalyst of the present invention is a regenerated hydrotreating catalyst prepared by regenerating a used hydrotreating catalyst comprising a catalyst support including an amorphous composite metal oxide having solid acidity, and at least one active metal supported by the catalyst support and selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the regenerated hydrotreating catalyst contains 0.05 to 1% by mass of a carbonaceous substance in terms of a carbon atom based on the entire mass of the catalyst. | 03-20-2014 |
20140021095 | METHOD FOR PRODUCING HYDROCARBON OIL - The present invention provides a method for producing a hydrocarbon oil, including performing a hydrocracking by continuously feeding, to a hydrocracking reactor containing a hydrocracking catalyst, a wax to be processed including: a raw wax containing 70% by mass or more of straight-chain hydrocarbons with a boiling point of higher than 360° C.; and an uncracked wax containing 70% by mass or more of straight-chain hydrocarbons with a boiling point of higher than 360° C., which uncracked wax is separated from a hydrocracking product discharged from the reactor, to thereby yield a hydrocarbon oil including hydrocarbons with a boiling point of 360° C. or lower. | 01-23-2014 |
20140021094 | METHOD OF REMOVING HEAVY HYDROCARBONS - Heavy hydrocarbons contained in FT off gas of a GTL process are removed by bringing the FT off gas into contact with absorption oil, by introducing the FT off gas into a distillation tower, by cooling the FT off gas or by driving the FT off gas into an adsorbent. A burner tip for heating a reformer tube, using FT off gas as fuel, is prevented from being plugged by the deposition of heavy hydrocarbons contained in the FT off gas. | 01-23-2014 |
20140018454 | ACTIVATED FISCHER-TROPSCH SYNTHESIS REACTION CATALYST AND METHOD FOR PRODUCING HYDROCARBONS - A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g. | 01-16-2014 |
20140018450 | METHOD OF SUPPRESSING METAL CONTAMINATION OF SYNTHESIS GAS PRODUCTION APPARATUS - A synthesis gas production apparatus (reformer) to be used for a synthesis gas production step in a GTL (gas-to-liquid) process is prevented from being contaminated by metal components. A method of suppressing metal contamination of a synthesis gas production apparatus operating for a GTL process that includes a synthesis gas production step of producing synthesis gas by causing natural gas and gas containing steam and/or carbon dioxide to react with each other for reforming in a synthesis gas production apparatus in which, at the time of separating and collecting a carbon dioxide contained in the synthesis gas produced in the synthesis gas production step and recycling the separated and collected carbon dioxide as source gas for the reforming reaction in the synthesis gas production step, a nickel concentration in the recycled carbon dioxide is not higher than 0.05 ppmv. | 01-16-2014 |
20140018449 | METHOD FOR PRODUCING HYDROCARBONS - A method for producing hydrocarbons includes: a synthesis step of synthesizing hydrocarbons by the Fischer-Tropsch synthesis reaction using a slurry bubble column reactor having a slurry containing catalyst particles and liquid hydrocarbons retained inside the reactor, and having a gas phase portion located above the slurry; a discharging step of passing the slurry through a filter positioned inside and/or outside the reactor, thereby separating and discharging the heavy liquid hydrocarbons; a backwash step of flushing liquid hydrocarbons through the filter in the opposite direction to the flow of the slurry, thereby returning the catalyst particles to the reactor; and a cooling and gas-liquid separation step of cooling the hydrocarbons discharged from the gas phase portion, and then separating and collecting the condensed light liquid hydrocarbons. The liquid hydrocarbons flushed through the filter in the backwash step include the light liquid hydrocarbons obtained in the cooling and gas-liquid separation step. | 01-16-2014 |
20140014089 | TEMPERATURE CONTROL SYSTEM, HYDROCARBON SYNTHESIS REACTION APPARATUS, HYDROCARBON SYNTHESIS REACTION SYSTEM, AND TEMPERATURE CONTROL PROCESS - The temperature control system is provided with a lower heat removing unit which is disposed at the bottom of a reactor inside which an exothermic reaction takes place and through which a liquid coolant is flowed, and an upper heat removing unit which is disposed in the reactor further above from the lower heat removing unit and through which the liquid coolant is flowed, recovering reaction heat inside the reactor and controlling a temperature inside the reactor. The lower heat removing unit is supplied with the liquid coolant which is adjusted for temperature by a first temperature adjustment unit, and the upper heat removing unit is supplied with the liquid coolant which is adjusted for temperature by a second temperature adjustment unit different from the first temperature adjustment unit. | 01-16-2014 |
20140011896 | METHOD FOR STOPPING OPERATION OF REACTOR - The method for stopping operation of a reactor is provided with a stop step of stopping supply of a synthesis gas containing a carbon monoxide gas and a hydrogen gas into the reactor; a slurry discharge step of discharging slurry from the reactor; a steam supply step of supplying steam higher in temperature than the decomposition temperatures of metal carbonyls into the reactor, thereby discharging gaseous matters inside the reactor; and a carbon monoxide gas detecting step of detecting an amount of carbon monoxide gas contained in the gaseous matters discharged from the reactor. In the steam supply step, supply of the steam is stopped when an amount of the detected carbon monoxide gas continuously declines to be lower than a predetermined reference value. | 01-09-2014 |
20130306299 | TEMPERATURE CONTROL SYSTEM - The temperature control system of the present invention is a temperature control system for recovering reaction heat inside a reactor in which an exothermic reaction takes place, thereby controlling a temperature inside the reactor. The temperature control system is provided with a coolant drum in which a liquid coolant is accommodated in a vapor-liquid equilibrium state, a heat removing unit which is disposed on the reactor to internally circulate the liquid coolant supplied from the coolant drum, a temperature determining unit which determines a temperature inside the reactor, and a pressure controller which controls pressure inside the coolant drum. The pressure controller controls the pressure inside the coolant drum based on a difference between an actual temperature inside the reactor determined by the temperature determining unit and a preset temperature value inside the reactor, thereby controlling the temperature of the liquid coolant inside the coolant drum. | 11-21-2013 |
20130146088 | METHOD FOR WASHING REACTOR - The method for cleaning a reactor of the present invention comprises passing a solvent through a wax-fraction hydrocracking apparatus which is charged with a catalyst and to which supply of a wax fraction is stopped, wherein the solvent comprising at least one oil selected from a group consisting of hydrocarbon and vegetable oils, and having a sulfur content of less than 5 ppm and being in a liquid state at 15° C. | 06-13-2013 |
20130144099 | METHOD FOR PRODUCING HYDROCARBON OIL AND SYSTEM FOR PRODUCING HYDROCARBON OIL - Hydrocarbon oil obtained by Fischer-Tropsch (FT) synthesis reaction using a catalyst within a slurry bed reactor is fractionated into a distilled oil and a column bottom oil in a rectifying column, part of the column bottom oil is flowed into a first transfer line that connects a column bottom of the rectifying column to a hydrocracker, at least part of the column bottom oil is flowed into a second transfer line branched from the first transfer line and connected to the first transfer line downstream of the branching point, the amount of the catalyst fine powder to be captured is monitored while the catalyst fine powder in the column bottom oil that flows in the second transfer line are captured by a detachable filter provided in the second transfer line, and the column bottom oil is hydrocracked within the hydrocracker. | 06-06-2013 |
20130143971 | PROCESS FOR PRODUCING HYDROCARBON OIL AND SYSTEM FOR PRODUCING HYDROCARBON OIL - Hydrocarbon oil obtained by Fischer-Tropsch synthesis reaction using a slurry bed reactor holding a slurry of a liquid hydrocarbon in which a catalyst is suspended; the hydrocarbon oil is fractionated into a distilled oil and a column bottom oil containing the catalyst fine powder by a rectifying column; at least part of the column bottom oil is transferred to a storage tank, and the catalyst fine powder is sedimented to the bottom of the storage tank to capture the catalyst fine powder; a residue of the column bottom oil is transferred from the rectifying column to a hydrocracker, and/or the supernatant of the column bottom oil from which the catalyst fine powder is captured by the storage tank is transferred from the storage tank to the hydrocracker; and using the hydrocracker, the residue of the column bottom oil and/or the supernatant of the column bottom oil is hydrocracked. | 06-06-2013 |
20120317833 | METHOD FOR REMOVING SULFUR COMPOUNDS IN CASTABLE - A situation where sulfur compounds originating from a castable are mixed into synthesis gas produced by way of a reforming reaction and the mixed sulfur compounds are separated and collected with carbon dioxide and further fed into a reformer to thereby degrade the reforming catalyst of the reformer by sulfur poisoning is avoided. Purge gas that is steam or steam-containing gas is made to flow into the piping to be used for a synthesis gas production apparatus and dried out to remove the sulfur compounds contained in the castable prior to the start-up of operation of the synthesis gas production apparatus, in order to prevent the sulfur compounds from being released by hot synthesis gas. | 12-20-2012 |
20120316252 | METHOD FOR PRODUCING SYNTHESIS GAS - It is avoided that the sulfur compounds originating from the castable is mixed into produced synthesis gas, the mixed sulfur compounds are separated and collected with carbon dioxide, the collected carbon dioxide is recycled as raw material gas and then the sulfur compounds is directly supplied to the reformer to consequently degrade the reforming catalyst in the reformer by sulfur poisoning. The carbon dioxide separated and collected in the carbon dioxide removal step is introduced into the desulfurization apparatus of the desulfurization step or the sulfur compounds adsorption apparatus before being recycled to the reformer to remove the sulfur compounds. | 12-13-2012 |
20120010304 | Method and System for Synthesizing Liquid Hydrocarbon Compounds - Provided is a method for synthesizing liquid hydrocarbon compounds wherein synthesizing liquid hydrocarbon compounds from a synthesis gas by a Fisher-Tropsch synthesis reaction. The method includes a first absorption step of absorbing a carbon dioxide gas, which is contained in gaseous by-products generated in the Fisher-Tropsch synthesis reaction, with an absorbent, and a second absorption step of absorbing a carbon dioxide gas, which is contained in the synthesis gas, with the absorbent which is passed through the first absorption step. | 01-12-2012 |
20110218096 | SPRAY CAN PRODUCT AND METHOD OF MANUFACTURING SPRAY CAN PRODUCT - A spray can product capable of preventing leakage where used or stored in a tilted or an inverted position, and keeping good safety and liquid retention even where a flammable liquefied gas is used. The spray can product is formed by filling a spray can having an ejection opening with a liquefied gas and an absorbing body for retaining liquid, and the absorbing body is composed of an assembly of cellulose fibers containing at least 45 mass % of fine cellulose fibers having a fiber length of 0.35 mm or less. The absorbing body compressed into a block-shaped configuration corresponding to that of the spray can is accommodated within the spray can while defining a space on the side of an ejection opening, and a lid-like member is provided between the space and the absorbing body to protect a surface of the absorbing body in a gas permeable manner. | 09-08-2011 |
20110017941 | Refrigerant Composition - The present invention is directed to using a composition comprising carbon dioxide and dimethyl ether as a refrigerant. In particular, the refrigerant composition comprises 3-6% by mole dimethyl ether and 97-94% by mole of carbon dioxide on the basis of a total number of moles of dimethyl ether and carbon dioxide. Advantageously, the refrigerant composition does not cause ozonosphere depletion, has a low global warming potential, and is safe and nontoxic. | 01-27-2011 |
20110017940 | Refrigerant Composition - [Problems] To provide a safe, nontoxic, and high-performance mixed refrigerant for hot water supply/heating system which is prepared by mixing dimethyl ether with carbon dioxide and which does not deplete the ozone layer, has a low global warming potential, and permits low-pressure operation. | 01-27-2011 |
20110015282 | PRODUCTION METHOD OF LIQUID HYDROCARBONS FROM NATURAL GAS - In a so-called GTL process for producing liquid hydrocarbons containing fuel oil by producing synthesis gas from natural gas, subsequently producing Fischer-Tropsch oil from the obtained synthesis gas by way of Fischer-Tropsch synthesis and upgrading the produced Fischer-Tropsch oil, the synthesis gas produced from a synthesis gas production step is partly branched at a stage prior to getting to a Fischer-Tropsch oil production step and high-purity hydrogen is separated and produced from the synthesis gas entering the branch line. All the separated high-purity hydrogen is supplied to an upgrading reaction step and consumed as hydrogen for an upgrading reaction. Additionally, the synthesis gas entering the branch line is subjected to a water gas shift reaction to raise the hydrogen concentration before the step of separating and producing high-purity hydrogen and the residual gas left after the separation may be circulated to the synthesis gas production step as raw material for producing synthesis gas. | 01-20-2011 |
20110003900 | PRODUCTION METHOD OF LIQUID HYDROCARBONS FROM NATURAL GAS - In a so-called GTL process of producing synthesis gas from natural gas, producing Fischer-Tropsch oil by way of Fischer-Tropsch synthesis of the obtained synthesis gas and producing liquid hydrocarbons containing fuel oil by upgrading, the synthesis gas produced from the synthesis gas production step is partly branched off prior to getting to the Fischer-Tropsch oil production step and the synthesis gas entering the branch line is subjected to a water gas shift reaction to raise the hydrogen concentration thereof. Subsequently, high-purity hydrogen is isolated from the synthesis gas and the residual gas left after the isolation is circulated to the synthesis gas production step and used as raw material for synthesis gas production. As a result, a significant improvement can be achieved in terms of raw material consumption per product of the entire process. | 01-06-2011 |
20100317747 | Medium oil used for a synthesis reaction, process for preparing dimethyl ether and process for preparing a mixture of dimethyl ether and methanol - A medium oil to be used for a synthesis reaction in a slurry-bed reaction procedure. The medium oil has as a main component, a branched, saturated aliphatic hydrocarbon having 16 to 50 carbon atoms, 1 to 7 tertiary carbon atoms, 0 quaternary carbon atoms, and 1 to 16 carbon atoms in the branched chains bonded to the tertiary carbon atoms; and at least one of the tertiary carbon atoms is bonded to hydrocarbon chains with a chain length having 4 or more carbon atoms in three directions. | 12-16-2010 |
20100282621 | SPRAY PRODUCT - A high-quality spray product that uses a less expensive propellant exhibiting a lower ozone-depleting potential and a lower global warming potential without using any fluorocarbon, any alternative thereto, etc., and exhibits an improved safety and an improved liquid retention. A dust blower as the spray product uses a propellant composed of a mixture of dimethyl ether and carbon dioxide, and an absorbent adapted to retain the propellant, which is composed of an assembly of pulverized cellulose fibers such that the cellulose fibers include at least 45 mass % of fine cellulose fibers having a fiber length of 0.35 mm or less. The propellant and the absorbent are charged in a spray can having a spray nozzle, thereby preparing a dust blower. | 11-11-2010 |
20100197814 | METHOD FOR EFFICIENT USE OF HEAT FROM TUBULAR REFORMER - In a GTL process of producing various kinds of hydrocarbon oils from natural gas, provided is improved heat efficiency in the case of using a steam reforming process or a carbon dioxide reforming process in the reforming. The process includes producing a synthesis gas by converting the natural gas and at least one of steam and carbon dioxide into a synthesis gas through a tubular reformer filled with a reforming catalyst, producing Fischer-Tropsch oil by subjecting the produced synthesis gas to a Fischer-Tropsch reaction, and upgrading in which the Fischer-Tropsch oil is subjected to hydrotreatment and distillation to produce various kinds of hydrocarbon oils, in which excess heat generated in the synthesis gas production is recovered, and the recovered heat is used as heat for at least one of hydrotreatment and distillation in the upgrading. | 08-05-2010 |
20090260373 | Refrigerant Composition - [Problems] To provide a refrigerant which is obtained by mixing a refrigerant, dimethyl ether, and carbon dioxide and which has such excellent performances that it does not cause ozonosphere depletion, has extremely low global warming potential, and is safe and nontoxic. | 10-22-2009 |
20090045375 | Refrigerant Composition - [Problems] To provide a safe, nontoxic, and high-performance mixed refrigerant for hot water supply/heating system which is prepared by mixing dimethyl ether with carbon dioxide and which does not deplete the ozone layer, has a low global warming potential, and permits low-pressure operation. | 02-19-2009 |
20090005626 | Hydrotreating Method - To provide a method for hydrotreating a synthetic hydrocarbon oil, which removes olefins and oxygen-containing compounds by hydrotreatment with the gasification rate restrained and can efficiently convert the synthetic hydrocarbon oil generated by the FT process to a liquid fuel suitable as a fuel for diesel-powered vehicles. | 01-01-2009 |
20080222945 | Method for Producing Hydrocarbon Fuel Oil - To efficiently obtain a liquid fuel containing no sulfur and having good cold flow properties by hydrotreating heavy wax generated by the Fischer-Tropsch (FT) synthesis to perform cracking with the gasification rate restrained and also increase an isomerization reaction which occurs at the same time. | 09-18-2008 |