| GTL.F1 AG Patent applications |
| Patent application number | Title | Published |
|---|
| 20130210939 | FISCHER-TROPSCH CATALYST REGENERATION - A process for the regeneration of deactivated catalyst from a Fischer-Tropsch synthesis reactor, the catalyst being a supported cobalt catalyst. The process comprises the following steps: a withdrawal step, in which a portion of deactivated catalyst together with liquid hydrocarbon is withdrawn from the reactor; a concentration step, in which the concentration of the catalyst in the liquid hydrocarbon is increased; a calcination step, in which the deactivated catalyst composition is subjected to an oxidising gas to oxidise carbonaceous material contained in the deactivated catalyst in to gaseous oxides of the components of the carbonaceous material; and a reactivation step, in which the deactivated catalyst composition is reactivated to produced a regenerated catalyst. | 08-15-2013 |
| 20130199966 | FISCHER-TROPSCH CATALYSTS - A method of producing an aluminium oxide supported catalyst for use in a Fischer-Tropsch synthesis reaction, which comprises: spray-drying a slurry of γ-alumina and a source of a spinel forming metal to form a solid precursor material; calcining the precursor material to form a modified support material including a metal aluminate spinel; impregnating the modified alumina support material with a source of cobalt; calcining the impregnated support material, and activating the catalyst. | 08-08-2013 |
| 20130184360 | CATALYST TREATMENT - A method of preparing a Fischer-Tropsch catalyst for handling, storage, transport and deployment, including the steps of impregnating a porous support material with a source of cobalt, calcining the impregnated support material activating the catalyst, and passivating the activated catalyst. | 07-18-2013 |
| 20130158136 | APPARATUS AND METHOD FOR CONDUCTING A FISCHER-TROPSCH SYNTHESIS REACTION - In order to avoid fouling (precipitation of solid matter on cold surfaces) in heat-exchangers down-stream of the gas outlet of a Fischer-Tropsch reactor, the reactor gas stream containing hydrocarbon products that are solid at lower temperatures is fed into a liquid wash tank. Condensation of heavy oil in the liquid wash tank is effected by feeding an evaporable light oil into the liquid wash tank. Heavy oil is recovered as a bottom product from the liquid wash tank while a gaseous product is taken out of the liquid wash tank as the top product. The light oil is obtained from the wash tank top product. | 06-20-2013 |
| 20130012606 | FISCHER-TROPSCH SYNTHESIS - A process for the preparation of an F-T catalyst in which the presence of alkaline earth metals is minimized in the support itself and in the processing conditions, in order to provide a catalyst with an alkaline earth metal content of less than 2000 ppm. | 01-10-2013 |
| 20120157555 | APPARATUS AND PROCESS FOR THREE-PHASE REACTION - A system and process for removing catalyst fines from a gas stream overhead the slurry in a Fischer-Tropsch slurry bubble column reactor. The gas phase at the top of the slurry bubble column reactor containing small amounts of entrained liquid and catalyst particles. The unreacted gases are passed through a demister, which removes larger droplets and catalyst particles. Smaller droplets and catalyst fines are conveyed to a secondary gas cleaner, such as a cyclone, whereby substantially all remaining particles are removed from the gas phase. A particle-containing liquid produced in the secondary gas cleaner can be further subjected to a filtrate cleaning unit to filter out fine catalyst particles and produce a substantially particle-free liquid product stream and a slurry stream of liquid product containing catalyst particles. | 06-21-2012 |
| 20120149787 | FISCHER-TROPSCH CATALYSTS - A method of producing an alumina-supported cobalt catalyst for use in a Fischer-Tropsch synthesis reaction, which comprises: calcining an initial γ-alumina support material at a temperature to produce a modified alumina support material; impregnating the modified alumina support material with a source of cobalt; calcining the impregnated support material, activating the catalyst with a reducing gas, steam treating the activated catalyst, and activating the steam treated catalyst with a reducing gas. | 06-14-2012 |
| 20110313063 | APPARATUS AND METHOD FOR CONDUCTING A FISCHER-TROPSCH SYNTHESIS REACTION - A system for a Fischer-Tropsch synthesis using a three-phase reactor in which a primary filter removes coarse catalyst particles from the product and in which catalyst fines are removed in a secondary filter. Some or all portion of the product wax from the secondary filter can be recycled back to the reactor, either as a back flush medium for the primary filter or directly to the slurry in the reactor, whereby removal of catalyst fines is rendered independent of the rate of wax production. | 12-22-2011 |
| 20110313062 | SLURRY BUBBLE COLUMN REACTOR - A slurry bubble column reactor with a gas distribution arrangement comprising an upper sparger, a lower sparger, and an open-ended tube. Gas from the lower sparger enters the tube and lowers the density of slurry in the tube. The difference in slurry density causes the slurry in the tube to rise, causing slurry outside the tube to move down, maintaining circulation and flushing catalyst from the vessel wall. | 12-22-2011 |
| 20100184872 | PREPARATION OF FISCHER-TROPSCH CATALYSTS - A method of producing a catalyst for use in a Fischer-Tropsch synthesis reaction. The method comprises the steps of: impregnating a catalyst support material with an active cobalt catalyst component to form a catalyst precursor; and calcining the catalyst precursor in an atmosphere of a dry calcining gas. | 07-22-2010 |
| 20100137458 | GAS TO LIQUIDS PLANT WITH CONSECUTIVE FISCHER-TROPSCH REACTORS AND HYDROGEN MAKE-UP - A process for converting synthesis gas to hydrocarbons, using a Fischer-Tropsch synthesis. Two F-T reactors are used in series with water removal between them and additional hydrogen added to the second reactor in an embodiment. | 06-03-2010 |
