Dalian Institute of Chemical Physics, Chinese Academy of Sciences Patent applications |
Patent application number | Title | Published |
20150298108 | METHOD FOR PREPARING METHYL ACETATE - The present invention provides a method for preparing methyl acetate, in which a feed gas containing an organic amine, dimethyl ether, carbon monoxide and optional hydrogen gas goes through a reactor loaded with a H-type mordenite catalyst, to produce methyl acetate; wherein said H-type mordenite catalyst is a H-type mordenite catalyst with adsorption of an organic amine. The method in the present invention improves the catalyst stability and prolongs the catalyst life, by using the H-type mordenite catalyst with adsorption of an organic amine as the catalyst and adding the organic amine in the feed gas to replenish the organic amine desorbed from the catalyst during the reaction. | 10-22-2015 |
20150232345 | SAPO-34 Molecular Sieve and Method for Preparing the Same - The present invention concerns a SAPO-34 molecular sieve and method for preparing the same, whose chemical composition in the anhydrous state is expressed as: mDIPA·(Si | 08-20-2015 |
20150231616 | SAPO-34 molecular sieve and method for preparing the same - A SAPO-34 molecular sieve and method for preparing the same, whose chemical composition in the anhydrous state is expressed as: mSDA.(Si | 08-20-2015 |
20150203425 | METHOD FOR PRODUCING CRESOL FROM PHENOL AND METHANOL VIA GAS PHASE ALKYLATION - The present invention relates to a method for producing cresol from phenol and methanol via gas phase alkylation, in which phenol and methanol are preheated and mixed with diluent gas, then the mixture continuously go through a catalyst bed comprising the catalyst for alkylation of phenol with methanol, to produce cresol by gas phase reaction at the reaction temperature of 200-500° C. and the weight hourly space velocity of 0.5˜20 h | 07-23-2015 |
20150190789 | PREPARATION AND APPLICATION OF ULTRA-DEEP HYDRODESULFURIZATION MULTI-METAL BULK CATALYST OF LAYERED STRUCTURE - An unsupported multi-metallic layered catalyst which comprises two or more Group VIB metals, one Group VIII metals, and one divalent metal, is used in ultra-deep hydrodesulfurization of diesel. And on oxide basis, it comprises 1-50 wt % Group VIII metals, 1-50 wt % divalent metals, and 5-60 wt % two Group VIB metals. Under hydrodesulfurization conditions, it can reduce sulfur content (in the form of 4, 6-DMDBT) of diesel from 500 wppm to less than 10 wppm. Besides, it also lowers the cost of catalysts. | 07-09-2015 |
20150147269 | METAL SILICOALUMINOPHOSPHATE MOLECULAR SIEVE WITH RHO FRAMEWORK STRUCTURE, AND METHOD FOR PREPARING THE SAME - The present invention relates to a metal silicoaluminophosphate molecular sieve MeAPSO with a RHO framework structure and a preparation method thereof. The metal silicoaluminophosphate molecular sieve is characterized in that: the metal atoms are at least one of vanadium, copper, molybdenum, zirconium, cobalt, manganese, magnesium, iron, nickel and zinc. The chemical composition of said metal silicoaluminophosphate molecular sieve in anhydrous state is expressed as: mR.nMe.(SixAlyPz)O | 05-28-2015 |
20140343337 | CATALYST FOR PRODUCING PARAXYLENE BY CO-CONVERSION OF METHANOL AND/OR DIMETHYL ETHER AND C4 LIQUEFIED GAS, METHOD FOR PREPARING THE SAME AND METHOD FOR USING THE SAME - This application provides a catalyst for producing paraxylene by co-conversion of methanol and/or dimethyl ether and C | 11-20-2014 |
20140316177 | CATALYST FOR USE IN PRODUCTION OF HYDROCARBONS - A modified catalyst is described which can be used as a dehydration/hydrogenation catalyst in a multistage catalyst system for the catalysed production of saturated hydrocarbons from carbon oxides and hydrogen. The modified catalyst comprises: an acidic substrate comprising an M1-zeolite or M1-silicoalumino phosphate (SAPO) catalyst, where M1 is a metal; and a modifier including a metal M2. M2 comprises an alkali metal or alkaline earth metal. In examples described the modifier includes a Group II metal, for example Ca. | 10-23-2014 |
20140212940 | MEMBRANES - Mixed matrix pervaporation membranes are described which include i) a matrix phase comprising a polymeric material, and ii) a zeolitic imidazolate framework (ZIF) dispersed in the matrix phase. In membranes described, the thickness of the membrane is greater than 0.5 μm. The membranes may in examples be used in a process for separating an organic compound from an aqueous liquid mixture. An example process includes contacting the liquid mixture on one side of a mixed matrix pervaporation membrane to cause the organic compound to permeate the mixed matrix membrane, and removing from the other side of the membrane a permeate composition comprising a portion of the organic compound which permeated the membrane. Example membranes described have relatively good selectivity for separation of the organic compound from the liquid mixture. | 07-31-2014 |
20140163122 | PRODUCTION OF SATURATED HYDROCARBONS FROM SYNTHESIS GAS - An integrated process for the generation of saturated C | 06-12-2014 |
20140151265 | CATALYST FOR USE IN PRODUCTION OF SATURATED HYDROCARBONS FROM SYNTHESIS GAS - A catalyst composition is provided for use in the conversion of carbon oxide(s) to saturated hydrocarbons. The catalyst composition comprises a carbon oxide(s) conversion catalyst; and a dehydration/hydrogenation catalyst comprising a silicoalumino phosphate (SAPO) molecular sieve and a metal M, for example Pd. In one embodiment, the target saturated hydrocarbons include LPG, the SAPO comprises SAPO-5 and/or SAPO-37. | 06-05-2014 |
20140066533 | CONJUGATED MICROPOROUS MACROMOLECULE CATALYST COMPLEXED WITH COBALT, CHROMIUM, ZINC, COPPER OR ALUMINIUM, PREPARATION AND USE THEREOF - Disclosed are a type of catalyst which can catalyse the ring-addition reaction of CO | 03-06-2014 |
20140051900 | PROCESS FOR METHANOL COUPLED CATALYTIC CRACKING REACTION OF NAPHTHA USING A MODIFIED ZSM-5 MOLECULAR SIEVE CATALYST - The present invention provides a process for methanol coupled catalytic cracking reaction of naphtha using a modified ZSM-5 molecular sieve catalyst, comprising performing a co-feeding reaction of methanol and naphtha on the modified ZSM-5 molecular sieve catalyst to produce low carbon olefins and/or aromatic hydrocarbons. In the process, the modified ZSM-5 molecular sieve catalyst comprises, in term of weight percent, 25-80 wt % of a ZSM-5 molecular sieve, 15-70 wt % of a binder, and 2.2-6.0 wt % of lanthanum and 1.0-2.8 wt % of phosphorus loaded on the ZSM-5 molecular sieve. The naphtha comprises 63.8-89.5 wt % of saturated chain alkanes and 5.6-29.8 wt % of cyclic alkanes. The naphtha and methanol concurrently pass through the catalyst bed, which are reacted during contacting with the catalyst under a reaction condition of a reaction temperature of 550-670° C., a mass ratio of methanol to naphtha of 0.05-0.8, and a total mass space velocity of naphtha and methanol of 1.0-5 h | 02-20-2014 |
20140021100 | VISIBLE LIGHT CATALYST FOR REMOVING SULFUR-CONTAINING COMPOUNDS IN FUEL OIL, AND PREPARATION AND USE - This invention relates to a visible-light-responsive photocatalyst for photocatalyticly oxidation desulphurization and method for preparation and application thereof. The catalyst is comprised of one type of metal M | 01-23-2014 |
20130316007 | Microcapsule Preparation of Alginate-Chitosan Acyl Derviatives, Preparation and Application Thereof - The present invention relates to a microcapsule preparation product of alginate-chitosan acyl derivatives, which is produced by mixing microcapsules of alginate-chitosan acyl derivatives with an aqueous solution, wherein the biomicrocapsule structureconsists of two parts, a microcapsule membrane and an inner core; the microcapsule membrane is a polyelectrolyte composite hydrogel membrane formed by chitosan, alginates and chitosan acyl derivatives, and the inner core is an alginate liquid or a hydrogel environment containing cells. | 11-28-2013 |
20130281719 | METHOD OF CATALYTIC CONVERSION OF CARBOHYDRATES INTO 5-HYDROXYMETHYLFURFURAL - The present invention relates to a method for efficient conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) in the presence of tantalum-containing solid acid, which shows good activity and high selectivity for HMF preparation from saccharides. The catalyst is stable in aqueous system which makes it as an ideal catalyst for HMF production. High HMF yield was obtained even in mild condition. The catalysts of the invention are advantageous in that they are environment-friendly, easy separation and recovery, can be re-used in subsequent reactions, do not corrode reaction reactors. These features make the catalyst as an ideal catalyst for HMF preparation and have strong industrial application significance. | 10-24-2013 |
20130280161 | SOLVOTHERMAL SYNTHESIS PROCESS OF SAPO MOLECULAR SIEVES AND CATALYSTS PREPARED THEREBY - A solvothermal synthesis process of the SAPO molecular sieves and catalysts prepared thereby are provided. The synthesis process comprises the following steps: a) an organic amine, an aluminum source, a phosphorus source, a silicon source, and water are mixed in a molar ratio of 6-30:1:0.5-5:0.01-1.0:0.1-15, to obtain an initial mixture for preparing the SAPO molecular sieves, wherein the molar ratio of water to the organic amine is less than 2.0; b) the initial mixture obtained in the step a) is maintained at 30-60° C. to and aged with stirring for not more than 24 hours, to obtain an initial gel; c) the initial gel obtain in the step b) is crystallized at 150-250° C. for 0.5-15 days. The SAPO molecular sieves prepared thereby are used, after being calcined at 400-700° C. in air, as catalysts for acid-catalyzed reactions or for conversion reactions of oxygen-containing compounds to olefins. | 10-24-2013 |
20130252806 | Ag/MnyOx/C CATALYST, PREPARATION AND APPLICATION THEREOF | 09-26-2013 |
20120283487 | METHODS OF USING TUNGSTEN CARBIDE CATALYSTS IN PREPARATION OF ETHYLENE GLYCOL - Tungsten carbide catalysts are used in preparation of ethylene glycol by hydrogenating degradation of cellulose. The catalyst includes tungsten carbide as main catalytic active component, added with small amount of one or more transition metals such as nickel, cobalt, iron, ruthenium, rhodium, palladium, osmium, iridium, platinum, and copper as the second metal, supported on one or more porous complex supports such as active carbon, alumina, silica, titanium dioxide, silicon carbide, zirconium oxide, for conversion of cellulose to ethylene glycol. The catalyst realizes high efficiency, high selectivity, and high yield in the conversion of cellulose to ethylene glycol at the temperature of 120-300° C., hydrogen pressure of 1-10 MPa, and hydrothermal conditions. Compared to the existing industrial synthetic method of ethylene glycol using ethylene as feedstock, the invention has the advantages of using renewable raw material resources, environment friendly process, and excellent atom economy. | 11-08-2012 |
20120196188 | AROMATIC POLYMER ION EXCHANGE MEMBRANES, ITS COMPOSITE MEMBRANCE, AND ITS APPLICATION IN ACIDIC ELECTROLYTE FLOW BATTERY - A polymer ion exchange membrane for acidic electrolyte flow battery. The membrane is nitrogen heterocycles aromatic polymer, especially polybenzimidazole type polymer. A nitrogen heterocycles in the membrane interact with acid in the electrolyte to form donor-receptor proton transport network, so as to keep the proton transport performance of the membrane. The preparation condition for the membrane is mild, and the process is simplicity. The preparation method is suitable for mass production. The membrane is used in acidic electrolyte flow battery, especially in vanadium flow energy storage battery. The membrane has excellent mechanical stability and thermostability. In vanadium redox flow battery, the membrane has excellent proton conduct performance and excellent resistance to the permeation of vanadium ions. | 08-02-2012 |
20120178974 | MESOPOROUS CARBON SUPPORTED TUNGSTEN CARBIDE CATALYSTS, PREPARATION AND APPLICATIONS THEREOF - A supported tungsten carbide catalyst comprises tungsten carbide as its active component and a mesoporous carbon as its support, wherein tungsten carbide is highly dispersed on the surface and in the channels of the mesoporous carbon, and the content of tungsten element is in the range from 30% to 42% by mass based on the mesoporous carbon. This catalyst can be prepared by impregnation process. This catalyst can be used for the direct catalytic conversion of cellulose to ethylene glycol under the hydrothermal conditions and at a temperature of 245° C. and the hydrogen pressure of 6 MPa with high reactivity, selectivity and stability. | 07-12-2012 |
20120172633 | METHODS FOR PREPARING ETHYLENE GLYCOL FROM POLYHYDROXY COMPOUNDS - This invention provides methods for producing ethylene glycol from polyhydroxy compounds such as cellulose, starch, hemicellulose, glucose, sucrose, fructose, fructan, xylose and soluble xylooligosaccharides. The methods uses polyhydroxy compounds as the reactant, a composite catalyst having active components comprising one or more transition metals of Groups 8, 9, or 10, including iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, as well as tungsten oxide, tungsten sulfide, tungsten hydroxide, tungsten chloride, tungsten bronze oxide, tungsten acid, tungstate, metatungstate acid, metatungstate, paratungstate acid, paratungstate, peroxotungstic acid, pertungstate, heteropoly acid containing tungsten. Reacting at a temperature of 120-300° C. and a hydrogen pressure of 1-13 MPa under hydrothermal conditions to accomplish one-step catalytic conversion. It realizes efficient, highly selective, high yield preparation of ethylene glycol and propylene glycol from polyhydroxy compounds. The advantage of processes disclosed in this invention include renewable raw material and high atom economy. At the same time, compared with other technologies that converts biomass raw materials into polyols, methods disclosed herein enjoy advantages including simple reaction process, high yield of targeted products, as well as easy preparation and low cost for the catalysts. | 07-05-2012 |
20120035388 | PLATINUM/CARBON NANOTUBE CATALYST, THE PREPARATION PROCESS AND USE THEREOF - This invention provides a platinum/carbon nanotube catalyst applicable to heterogeneous asymmetric hydrogenation, which is fabricated by supporting platinum on carbon nanotube carriers. The catalyst is prepared by the steps of: heating purified carbon nanotubes in nitric acid, filtering and washing the same with water until pH value of the filtrate becomes neutral, drying the carbon nanotubes; immersing the carbon nanotube carriers obtained in an aqueous chloroplatinic acid solution and carrying out ultrasonic treatment at room temperature; immersing the mixture of the carbon nanotubes and the aqueous chloroplatinic acid solution under stirring; drying the material by heating to 110° C. from room temperature and maintaining this temperature; grinding the product to fine powders, reducing the fine powders with an aqueous sodium formate solution under a heating condition, filtering and washing the product with deionized water, and drying the product. The invention further provides a process for preparing a platinum/carbon nanotube catalyst and a use thereof in heterogeneous asymmetric hydrogenation. | 02-09-2012 |
20110158881 | METHOD OF SYNTHESIZING CRYSTALLINE POLYMERIC BORON-NITROGEN COMPOUND AND DEHYDROGENATION OF BORON-NITROGEN-HYDROGEN COMPLEX - The present invention provides a method for synthesis of crystalline polymeric boron-nitrogen compounds comprising a step of dehydrogenation of a boron-nitrogen-hydrogen compound on catalyst, wherein the boron-nitrogen-hydrogen compound is selected from the group consisting of ammonia borane, metal amidoboranes, amine boranes or mixtures thereof, and the catalyst is selected from the group consisting of transition metals, transition metal salts or alloys. | 06-30-2011 |
20110046419 | METHOD FOR PRODUCING ETHYLENE GLYCOL FROM POLYHYDROXY COMPOUND - A method for producing ethylene glycol, including (a) adding a polyhydroxy compound and water to a sealed high-pressure reactor, (b) removing air and introducing hydrogen, and (c) allowing the polyhydroxy compound to react in the presence of a catalyst while stiffing. The catalyst includes a first active ingredient and a second active ingredient. The first active ingredient includes a transition metal of Group 8, 9, or 10 selected from iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, and/or a mixture thereof. The second active ingredient includes a metallic state of molybdenum and/or tungsten, or a carbide, nitride, or phosphide thereof. The method is carried out at a hydrogen pressure of 1-12 MPa, at a temperature of 120-300° C. for not less than 5 min in a one-step catalytic reaction. The efficiency, selectivity, and the yield of ethylene glycol are high. The preparation process is simple and the materials used are renewable. | 02-24-2011 |
20100196262 | SAPO-34 MOLECULAR SIEVE HAVING BOTH MICROPORES AND MESOPORES AND SYNTHESIS METHODS THEREOF - The present invention relates to a SAPO-34 molecular sieve having both micropores and mesopores and synthesis method thereof. The mesopore diameter in the molecular sieve is in a range of 2-10 nm and the mesopore volume thereof is 0.03-0.3 cm | 08-05-2010 |
20090264543 | Integrated Process for the Co-Production of Methanol and Demethyl Ether From Syngas Containing Nitrogen - The present invention relates to a novel integrated process for the co-production of methanol and dimethyl ether (DME) from syngas containing nitrogen, which is based on a two-stage reaction. In the first stage, most of the syngas is converted into methanol by using one reactor or two tandem reactors or multistage series reactors. In the second stage, the small amount of remaining syngas is further diluted by N2 and is converted to DME in the following reactor. Thus, the catalyst sintering is avoided due to the alleviated heat transfer limitations. An overall CO single pass conversion as high as | 10-22-2009 |
20080293563 | Activated carbon supported cobalt based catalyst for directly converting of synthesis gas to mixed linear alpha-alcohols and parafins - The invention provides an activated carbon supported cobalt based catalyst for directly converting of synthesis gas to mixed linear alpha-alcohols and paraffins, comprising cobalt, an activated carbon carrier, a metal promoter which is at least one selected from the group consisting of a zirconium component, a lanthanum component, a cerium component, a chromium component, a vanadium component, a titanium component, a manganese component, a rhenium component, a potassium component, a ruthenium component, a magnesium component and a mixture thereof, wherein the cobalt and the promoter are deposited on the activated carbon carrier or substantially uniformly dispersed therein, and the metal promoter is present in the form of a metal, an oxide or a combination thereof. | 11-27-2008 |