Patent application number | Description | Published |
20140162400 | Alkali Metal-Doped Solution-Processed Metal Chalcogenides - A method is provided for forming an alkali metal-doped solution-processed metal chalcogenide. A first solution is formed that includes a first material group of metal salts, metal complexes, or combinations thereof, dissolved in a solvent. The first material group may include one or more of the following elements: copper (Cu), indium (In), and gallium (Ga). An alkali metal-containing material is added to the first solution, and the first solution is deposited on a conductive substrate. The alkali metal-containing material may be sodium (Na). An alkali metal-doped first intermediate film results, comprising metal precursors from corresponding members of the first material group. Then, thermally annealing is performed in an environment of selenium (Se), Se and hydrogen (H | 06-12-2014 |
20140216553 | Dye-Sensitized Solar Cell via Co-Sensitization with Cooperative Dyes - A co-sensitized dye-sensitized solar cell (DSC) is provided, made from a transparent substrate and a transparent conductive oxide (TCO) film overlying the transparent substrate. An n-type semiconductor layer overlies the TCO, and is co-sensitized with a first dye (D1) and a second dye (D2). A redox electrolyte is in contact with the co-sensitized n-type semiconductor layer, and a counter electrode overlies the redox electrolyte. The first dye (D1) has a first optical absorbance local maxima at a first wavelength (A1) and a second optical absorbance local maxima at a second wavelength (A2), longer than the first wavelength. The second dye (D2) has a third optical absorbance local maxima at a third wavelength (A3) between the first wavelength (A1) and the second wavelength (A2). In one aspect, the first dye (D1) includes a porphyrin material, for example, a metalloporphyrin obtained by complexation with a transition metal such as zinc (i.e. zinc porphyrin (ZnP)). | 08-07-2014 |
20140216554 | Dye-Sensitized Solar Cell with Energy-Donor Material Enhancement - A dye-sensitized solar cell (DSC) is provided with energy-donor enhancement. A transparent conductive oxide (TCO) film is formed overlying a transparent substrate, and an n-type semiconductor layer is formed overlying the TCO. The n-type semiconductor layer is exposed to a dissolved dye (D1) having optical absorbance local maximums at a first wavelength (A1) and second wavelength (A2), longer than the first wavelength. The n-type semiconductor layer is functionalized with the dye (D1), forming a sensitized n-type semiconductor layer. A redox electrolyte is added that includes a dissolved energy-donor material (ED1) in contact with the sensitized n-type semiconductor layer. The energy-donor material (ED1) is capable of non-radiative energy transfer to the dye (D1), which is capable of charge transfer to the n-type semiconductor. In one aspect, the dye (D1) is a metalloporphyrin, such as zinc porphyrin (ZnP), and the energy-donor material (ED1) includes a perylene-monoimide material or chemically modified perylene-monoimide material. | 08-07-2014 |
20140264160 | Method for the Synthesis of Metal Cyanometallates - Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of A | 09-18-2014 |
20140335409 | Transition Metal Hexacyanometallate Electrode with Water-soluble Binder - A method is provided for fabricating a transition metal hexacyanometallate (TMHCM) electrode with a water-soluble binder. The method initially forms an electrode mix slurry comprising TMHCF and a water-soluble binder. The electrode mix slurry is applied to a current collector, and then dehydrated to form an electrode. The electrode mix slurry may additionally comprise a carbon additive such as carbon black, carbon fiber, carbon nanotubes, graphite, or graphene. The electrode is typically formed with TMHCM greater than 50%, by weight, as compared to a combined weight of the TMHCM, carbon additive, and binder. Also provided are a TMHCM electrode made with a water-soluble binder and a battery having a TMHCM cathode that is made with a water-soluble binder. | 11-13-2014 |
20140370187 | Precipitation Method for the Synthesis if Iron Hexacyaoferrate - A method is provided for synthesizing iron hexacyanoferrate (FeHCF). The method forms a first solution of a ferrocyanide source [A | 12-18-2014 |
20150263383 | Electrolyte Additives for Transition Metal Cyanometallate Electrode Stabilization - A method is provided for the self-repair of a transition metal cyanometallate (TMCM) battery electrode. The battery is made from a TMCM cathode, an anode, and an electrolyte including solution formed from a solvent and an alkali or alkaline earth salt. The electrolyte includes an additive represented as G-R-g: where G and g are independently include materials with nitrogen (N) sulfur (S), oxygen (O), or combinations of the above-recited elements; and where R is an alkene or alkane group. In response to charging and discharging the battery in a plurality of cycles, the method creates vacancies in a surface of the TMCM cathode. Then, the method fills the vacancies in the surface of the TMCM cathode with the electrolyte additive. An electrolyte and TMCM battery using the above-mentioned additives are also provided. | 09-17-2015 |
20150270547 | Hard Carbon Composite for Alkali Metal-Ion Batteries - A method is provided for fabricating a graphene-doped, carbohydrate-derived hard carbon (G-HC) composite material for alkali metal-ion batteries. The method provides graphene oxide (GO) dispersed in an aqueous solution. A carbohydrate is dissolved into the aqueous solution and subsequently the water is removed to create a precipitate. In one aspect, the carbohydrate is sucrose. The precipitate is dehydrated and exposed to a thermal treatment of less than 1200 degrees C. to carbonize the carbohydrate. The result is the formation of a graphene-doped, carbohydrate-derived hard carbon (G-HC) composite. Typically, the G-HC composite is made up of graphene in the range of 0.1 and 20% by weight (wt %), and HC in the range of 80 to 99.9 wt %. The G-HC composite has a specific surface area of less than 10 square meters per gram (m | 09-24-2015 |