Patent application number | Description | Published |
20100048971 | SEPARATION OF OLEFINS FROM OLEFINS/PARAFFINS MIXED GAS - The present invention relates to a method and an apparatus for the separation of C4 olefins (butene-1, trans-2-butene, cis-2-butene, etc.) and C4 paraffins (normal butane, isobutane, etc.) from a C4 hydrocarbon mixed gas including butene-1, trans-2-butene, cis-2-butene, normal butane, isobutane, etc. The method of the present invention produces C4 olefins with high purity by introducing a gaseous C4 mixture into the adsorption tower loaded with adsorbent selectively adsorbing olefins to adsorb C4 olefins and to discharge C4 paraffins to the outlet of the tower, desorbing C4 olefins adsorbed on the adsorption tower with a desorbent (C5 hydrocarbon, C6 hydrocarbon, etc.), and then separating the C4 olefin and the desorbent by a distillation process. The apparatus of the present invention is composed of several adsorption towers loaded with an adsorbent which selectively adsorb olefins and two distillation towers for the separation of the mixture gases of olefins/desorbents and paraffins/desorbents respectively, The basic operating process of the adsorption tower comprises a adsorption step of selectively adsorbing C4 olefin from the feeding mixture, a C4 olefin rinse step of removing a small amount of C4 paraffins adsorbed together with C4 olefins, and a desorption step of desorbing C4 olefins by using a desorbent, and further comprises a pressure equalization step, a cocurrent depressurization step, and a accumulation pressure step in order to increase the yield and concentration of olefins depending on the operation pressure of the adsorption tower. The desorbent discharged from the process together with olefins or paraffins is separated in the distillation tower and then recycled. | 02-25-2010 |
20100116639 | PRODUCTION OF HIGH PURITY BUTENE-1 FROM C4 OLEFINS/PARAFFINS MIXED GAS - The present invention relates to a hybrid process comprising an adsorption process and a distillation process for the separation of butene-1 from a C4 hydrocarbon mixture gas including butene-1, trans-2-butene, cis-2-butene, normal butane, isobutane, etc. The above hybrid process comprises introducing a gaseous C4 mixture into the adsorption tower loaded with adsorbents which adsorb olefins selectively to discharge C4 paraffins to the outlet of the tower, desorbing C4 olefins selectively adsorbed in the adsorption tower to produce high purity C4 olefins mixture gas in which isobutane and normal butane was removed, and separating the high C4 olefins mixture gas (a mixture of butene-1, trans-2-butene, cis-2-butene, and a trace amount of C4 paraffins) via distillation to obtain high purity butene-1 including a trace amount of isobutane in the top of the distillation tower and obtain a mixture gas including trans-2-butene, cis-2-butene and a trace amount of normal butane in the bottom of the tower. | 05-13-2010 |
20100204043 | ADSORBENT FOR SELECTIVE ADSORPTION OF CARBON MONOXIDE AND PROCESS FOR PREPARATION THEREOF - The present invention relates to an adsorbent for separating carbon monoxide from a gas mixture including hydrogen gas and a method of preparing the same. The adsorbent for selectively separating monoxide includes a solid material, which is a solid support impregnated and dispersed with a cuprous salt by bringing the solid support into contact with a cuprous salt solution stabilized by dissolving a cuprous salt or a cuprous salt mixture in a solvent. The adsorbent is advantageous in that the selectivity for carbon monoxide is improved, so that the amount of carbon monoxide included in the gas mixture is decreased to infinitesimal quantities, thereby producing high-purity hydrogen products. | 08-12-2010 |
20110005391 | PRESSURE SWING ADSORPTION APPARATUS AND METHOD FOR HYDROGEN PURIFICATION USING THE SAME - Disclosed are a pressure swing adsorption apparatus for hydrogen purification and a hydrogen purification method using the same. The pressure swing adsorption apparatus for hydrogen purification includes a plurality of adsorption columns connected with a feed supply pipe, a hydrogen storage tank for collecting purified hydrogen from the adsorption columns, and valves for opening or closing a plurality of pipes connected to the respective adsorption columns, and the adsorption columns are packed with adsorbent beds of active alumina or silica gel, activated carbon, zeolite 13X, zeolite 5A, and a carbon monoxide-selective adsorbent other than the zeolite 5A, in order to remove carbon dioxide, methane, and carbon monoxide from a hydrogen-containing gas mixture supplied through the feed supply pipe, and the content of carbon monoxide in the discharged hydrogen is minimized through sequential adsorption on the adsorbents in the adsorption columns. The content of carbon monoxide in the purified hydrogen product can be decreased to 10 ppm or less, thus facilitating the production of highly pure hydrogen products. | 01-13-2011 |
20120253091 | METHOD FOR MAKING HYDROCARBONS BY USING A LIPID DERIVED FROM A BIOLOGICAL ORGANISIM AND HYDROTALCITE - The present invention relates to a method in which a catalytic reaction is used in order to produce hydrocarbons from renewable starting material derived from biological organisms such as vegetable lipids, animal lipids, and lipids extracted from macroalgae and microalgae, and more specifically relates to a method for selectively making a hydrocarbon, which is suitable for making gasoline or diesel, by removing the oxygen contained in the starting material without consuming hydrogen. In the present invention, the production takes place by bringing the starting material into contact with hydrotalcite, which constitutes a catalyst, thereby removing oxygen via a decarboxylation or decarbonylation reaction; and the starting material is one or more such material selected from triglycerides, fatty acids, and fatty acid derivatives obtained from a renewable source of supply originating from a biological organism. | 10-04-2012 |
20130206575 | PRODUCTION OF HIGH PURITY BUTENE-1 FROM C4 OLEFINS/PARAFFINS MIXED GAS - A hybrid process comprising an adsorption process and a distillation process for the separation of butene-1 from a C4 hydrocarbon mixture gas including butene-1, trans-2-butene, cis-2-butene, normal butane, isobutane, etc. is provided. The hybrid process comprises introducing a gaseous C4 mixture into the adsorption tower loaded with adsorbents which adsorb olefins selectively to discharge C4 paraffins to the outlet of the tower, desorbing C4 olefins selectively adsorbed in the adsortion tower to produce high purity C4 olefins mixture gas in which isobutane and normal butane was removed, and separating the high C4 olefins mixture gas (a mixture of butene-1, trans-2-butene, cis-2-butene, and a trace amount of C4 paraffins) via distinction to obtain high purity butene-1 including a trace amount of isobutane in the top of the distillation tower and obtain a mixture gas including trans-2-butene, cis-2-butene and a trace amount of normal butane in the bottom of the tower. | 08-15-2013 |
20130213793 | SEPARATION OF OLEFINS FROM OLEFINS/PARAFFINS MIXED GAS - A method and apparatus for the separation of C4 olefins (butene-1, trans-2-butene, cis-2-butene, etc.) and C4 paraffins (normal butane, isobutane, etc) from a C4 hydrocarbon mixed gas including butene-1, trans-2-butene, cis-2-butene, normal butane, isobutane, etc. is provided. The apparatus includes several adsorption towers loaded with an adsorbent which selectively adsorb olefins and two distillation towers for the separation of the mixture gases of olefins/desorbents and paraffins/desorbents respectively. The basic operating process of the adsorption tower comprises an adsorption step of selectively adsorbing C4 olefin from the feeding mixture, a C4 olefin rinse step of removing a small amount of C4 paraffins adsorbed together with C4 olefins, and a desorption step of desorbing C4 olefins by using a desorbent, and further comprises pressure equalization step, concurrent depressurization step, and accumulation pressure step to increase the yield and concentration of olefins depending on the operation pressure of the adsorption tower. | 08-22-2013 |
20130299737 | OXYGEN-SELECTIVE ADSORBENT HAVING FAST ADSORPTION RATE AND PREPARATION METHOD THEREOF - Provided is a preparation method of an oxygen-selective adsorbent selectively adsorbing oxygen in the air and an oxygen-selective adsorbent prepared thereby. The preparation method includes: preparing BaMg(CO | 11-14-2013 |
20150047504 | CONTINUOUS OXYGEN PRODUCTION METHOD AND CONTINUOUS OXYGEN ADSORPTION AND DESORPTION DEVICE USING OXYGEN ADSORBING AGENT - Provided are a continuous oxygen adsorption and desorption device and an continuous oxygen adsorption and desorption method using the device, and more particularly, an continuous oxygen adsorption and desorption device for producing high-purity oxygen products by using a plurality of adsorption and desorption towers filled with an oxygen-selecting adsorption and desorption agent selected from BaMg(CO | 02-19-2015 |