Patent application number | Description | Published |
20080202575 | METHODS FOR HIGH FIGURE-OF-MERIT IN NANOSTRUCTURED THERMOELECTRIC MATERIALS - Thermoelectric materials with high figures of merit, ZT values, are disclosed. In many instances, such materials include nano-sized domains (e.g., nanocrystalline), which are hypothesized to help increase the ZT value of the material (e.g., by increasing phonon scattering due to interfaces at grain boundaries or grain/inclusion boundaries). The ZT value of such materials can be greater than about 1, 1.2, 1.4, 1.5, 1.8, 2 and even higher. Such materials can be manufactured from a thermoelectric starting material by generating nanoparticles therefrom, or mechanically alloyed nanoparticles from elements which can be subsequently consolidated (e.g., via direct current induced hot press) into a new bulk material. Non-limiting examples of starting materials include bismuth, lead, and/or silicon-based materials, which can be alloyed, elemental, and/or doped. Various compositions and methods relating to aspects of nanostructured thermoelectric materials (e.g., modulation doping) are further disclosed. | 08-28-2008 |
20080264486 | Guided-wave photovoltaic devices - A photovoltaic device comprises: a first cladding material; a photosensitive material having an index of refraction larger than the first cladding material index of refraction, the photosensitive material disposed adjacent the first cladding material; and a second cladding material having an index of refraction smaller than the photosensitive material index of refraction, the photosensitive material disposed between the first cladding material and the second cladding material so as to form a waveguide for confining propagating photons; and first and second electrodes in electrical contact with the photosensitive material. | 10-30-2008 |
20090068465 | NANOCOMPOSITES WITH HIGH THERMOELECTRIC FIGURES OF MERIT - The present invention is generally directed to nanocomposite thermoelectric materials that exhibit enhanced thermoelectric properties. The nanocomposite materials include two or more components, with at least one of the components forming nano-sized structures within the composite material. The components are chosen such that thermal conductivity of the composite is decreased without substantially diminishing the composite's electrical conductivity. Suitable component materials exhibit similar electronic band structures. For example, a band-edge gap between at least one of a conduction band or a valence band of one component material and a corresponding band of the other component material at interfaces between the components can be less than about 5k | 03-12-2009 |
20090260667 | Solar Thermoelectric Conversion - Systems and methods utilizing solar-electrical generators are discussed. Solar-electrical generators are disclosed having a radiation-capture structure and one or more thermoelectric converters. Heat produced in a capture structure via impingement of solar radiation can maintain a portion of a thermoelectric converter at a high temperature, while the use of a low temperature at another portion allows electricity generation. Thus, unlike photovoltaic cells which are generally primarily concerned with optical radiation management, solar thermoelectrics converters are generally concerned with a variety of mechanisms for heat management. Generators can include any number of features including selective radiation surfaces, low emissivity surfaces, flat panel configurations, evacuated environments, and other concepts that can act to provide thermal concentration. Designs utilizing one or more optical concentrators are also disclosed. | 10-22-2009 |
20100186794 | SOLAR THERMOELECTRIC AND THERMAL COGENERATION - An energy generation method includes receiving solar radiation at a solar absorber, providing heat from the solar absorber to a hot side of a set of thermoelectric converters, generating electricity from the set of thermoelectric converters, and providing heat from a cold side of the set of thermoelectric converters to a fluid being provided into a solar fluid heating system or a solar thermal to electrical conversion plant. A system for carrying out the method includes at least one thermoelectric device and a solar fluid heating system or a solar thermal to electrical conversion plant | 07-29-2010 |
20100301258 | POLYMER SHEETS AND OTHER BODIES HAVING ORIENTED CHAINS AND METHOD AND APPARATUS FOR PRODUCING SAME - that are made up of oriented polymer chains are provided. Chains of polymer may be oriented or substantially aligned in one or more directions exhibiting enhanced thermal conductivity along the direction of orientation. Orientation of polymers within sheets may lead to a wide range of thermally relevant applications. | 12-02-2010 |
20110108481 | Water Desalination Using Directional Solvent Extraction - Substantially pure water is produced via desalination using a directional solvent that directionally dissolves water but does not dissolve salt. The directional solvent is heated to dissolve water from the salt solution into the directional solvent. The remaining highly concentrated salt water is removed, and the solution of directional solvent and water is cooled to precipitate substantially pure water out of the solution. | 05-12-2011 |
20110108778 | THERMOELECTRIC SKUTTERUDITE COMPOSITIONS AND METHODS FOR PRODUCING THE SAME - Compositions related to skutterudite-based thermoelectric materials are disclosed. Such compositions can result in materials that have enhanced ZT values relative to one or more bulk materials from which the compositions are derived. Thermo-electric materials such as n-type and p-type skutterudites with high thermoelectric figures-of-merit can include materials with filler atoms and/or materials formed by compacting particles (e.g., nanoparticles) into a material with a plurality of grains each having a portion having a skutterudite-based structure. Methods of forming thermoelectric skutterudites, which can include the use of hot press processes to consolidate particles, are also disclosed. The particles to be consolidated can be derived from (e.g., grinded from), skutterudite-based bulk materials, elemental materials, other non-Skutterudite-based materials, or combinations of such materials. | 05-12-2011 |
20110140033 | GRAPHITE MICROFLUIDS - Fluids comprising graphite particles and related methods are generally described. In some embodiments, “microfluids” are described. Generally, the microfluids can comprise a fluid and a plurality of graphite particles with microscale dimensions. | 06-16-2011 |
20110197597 | System and method for thermal process including a thermoelectric heat pump and internal heat exchanger - A system for using a thermal cycle for heating or cooling. The system comprises a thermoelectric module flowing a gas; and an internal heat exchanger flowing the gas and exchanging heat between the gas and another fluid; the gas flow from at least one of the thermoelectric module and the internal heat exchanger flowing for heating or cooling. The system may be for using a closed cycle to remove a liquid from at least one object comprising moisture, the system comprising an enclosure containing the at least one object and arranged to receive a hot and dry gas for flow over the at least one object and thereby to produce a flow of moist gas at an intermediate temperature. The internal heat exchanger is arranged to exchange heat between the flow of the moist gas at the intermediate temperature and a flow of cold dry gas, thereby producing cooled moist gas and pre-warmed dry gas. The thermoelectric module comprises a first heat exchanger in heat exchange relationship with a cold side of the thermoelectric module and a second heat exchanger in heat exchange relationship with a hot side of the thermoelectric module. The first heat exchanger is arranged to flow the cooled moist gas in heat exchange relationship with the cold side of the thermoelectric module thereby condensing the liquid in the cooled moist gas and producing cold dry gas, which is arranged to be flowed through the internal heat exchanger thereby producing the pre-warmed dry gas. The second heat exchanger is arranged to flow the pre-warmed dry gas in heat exchange relationship with the hot side of the thermoelectric module, thereby closing the cycle by producing the hot dry gas arranged to be received by the enclosure. | 08-18-2011 |
20110220841 | THERMAL AND/OR ELECTRICAL CONDUCTIVITY CONTROL IN SUSPENSIONS - Articles, systems, and methods involving the control of thermal and/or electrical conductivity in suspensions are generally described. | 09-15-2011 |
20120128958 | SILICA AEROGELS AND THEIR PREPARATION - Silica aerogels with improved properties are disclosed together with methods for synthesizing such aerogels. The improved properties include lower thermal conductivity (better insulating capacity), lower acoustic velocity, lower dielectric constant and improved ductility. Greater tunability of the refractive index can also be achieved. The silica aerogels are prepared by a sol-gel processing method that provides better control of the formation of aerogel structures. Generally speaking, the improvements arise from control of the synthesis to create a morphology of primary clusters and diverse-sized secondary clusters of dense silica aerogels separated by less densely packed regions. By providing a broader range of secondary clusters and/or pore sizes and loose connectivity between clusters, reductions can be achieved in thermal conductivity and flexural modulus. | 05-24-2012 |
20120138532 | Water Desalination Using Directional Solvent Extraction - Substantially pure water is produced via desalination using a directional solvent that directionally dissolves water but does not dissolve salt. The directional solvent is heated to dissolve water from the salt solution into the directional solvent. The remaining highly concentrated salt water is removed, and the solution of directional solvent and water is cooled to precipitate substantially pure water out of the solution. | 06-07-2012 |
20120160290 | THERMOELECTRIC SYSTEM AND METHOD OF OPERATING SAME - An apparatus includes an evacuated enclosure which comprises a tubular member extending along a longitudinal axis, a radiation absorber disposed in the enclosure and having a front surface and a back surface, the front surface being adapted for exposure to solar radiation so as to generate heat, at least one thermoelectric converter disposed in the enclosure and thermally coupled to the absorber, the converter having a high-temperature end to receive at least a portion of the generated heat, such that a temperature differential is achieved across the at least one thermoelectric converter, a support structure disposed in the enclosure coupled to a low-temperature end of the thermoelectric converter, where the support structure removes heat from a low-temperature end of the thermoelectric converter, and a heat conducting element extending between the support structure and the evacuated enclosure and adapted to transfer heat from the support structure to the enclosure. The absorber, the at least one thermoelectric converter, and the support structure are arranged as a planar unit located within the tubular member. | 06-28-2012 |
20120180840 | SOLAR THERMOELECTRIC CONVERSION - Systems and methods utilizing solar-electrical generators are discussed. Solar-electrical generators are disclosed having a radiation-capture structure and one or more thermoelectric converters. Heat produced in a capture structure via impingement of solar radiation can maintain a portion of a thermoelectric converter at a high temperature, while the use of a low temperature at another portion allows electricity generation. Thus, unlike photovoltaic cells which are generally primarily concerned with optical radiation management, solar thermoelectrics converters are generally concerned with a variety of mechanisms for heat management. Generators can include any number of features including selective radiation surfaces, low emissivity surfaces, flat panel configurations, evacuated environments, and other concepts that can act to provide thermal concentration. Designs utilizing one or more optical concentrators are also disclosed. | 07-19-2012 |
20120217165 | Metal deposition using seed layers - Methods of forming a conductive metal layers on substrates are disclosed which employ a seed layer to enhance bonding, especially to smooth, low-roughness or hydrophobic substrates. In one aspect of the invention, the seed layer can be formed by applying nanoparticles onto a surface of the substrate; and the metallization is achieved by electroplating an electrically conducting metal onto the seed layer, whereby the nanoparticles serve as nucleation sites for metal deposition. In another approach, the seed layer can be formed by a self-assembling linker material, such as a sulfur-containing silane material. | 08-30-2012 |
20120326097 | Half-Heusler Alloys with Enhanced Figure of Merit and Methods of Making - Thermoelectric materials and methods of making thermoelectric materials having a nanometer mean grain size less than 1 micron. The method includes combining and arc melting constituent elements of the thermoelectric material to form a liquid alloy of the thermoelectric material and casting the liquid alloy of the thermoelectric material to form a solid casting of the thermoelectric material. The method also includes ball milling the solid casting of the thermoelectric material into nanometer mean size particles and sintering the nanometer size particles to form the thermoelectric material having nanometer scale mean grain size. | 12-27-2012 |
20130014814 | NANOSTRUCTURED ARRAYS FOR RADIATION CAPTURE STRUCTURES - Silicon nanohole arrays are disclosed as light absorbing structures for various devices such as solar photovoltaics. To obtain the same ultimate efficiency as a standard 300 micrometer crystalline silicon wafer, nanohole arrays require less silicon by mass. Moreover, calculations suggest that nanohole arrays may have efficiencies superior to nanorod arrays for practical thicknesses. With well-established fabrication techniques, nanohole arrays have great potential for efficient solar photovoltaics. | 01-17-2013 |
20130082003 | Water Extraction Using a Directional Solvent - Purified water can be obtained via a continuous or semi-continuous process by mixing a liquid composition (e.g., sea water or produced frac water) including water with a directional solvent to selectively dissolve water from the liquid composition into the directional solvent. The concentrated remainder of the liquid composition (e.g., brine) is removed, and the water is precipitated from the directional solvent and removed in a purified form. The solvent is then reused as the process is repeated in a continuous or semi-continuous operation. | 04-04-2013 |
20130175484 | Half-Heusler Alloys with Enhanced Figure of Merit and Methods of Making - Thermoelectric materials and methods of making thermoelectric materials having a nanometer mean grain size less than 1 micron. The method includes combining and arc melting constituent elements of the thermoelectric material to form a liquid alloy of the thermoelectric material and casting the liquid alloy of the thermoelectric material to form a solid casting of the thermoelectric material. The method also includes ball milling the solid casting of the thermoelectric material into nanometer mean size particles and sintering the nanometer size particles to form the thermoelectric material having nanometer scale mean grain size. | 07-11-2013 |
20130234375 | Methods of Synthesizing Thermoelectric Materials - Methods for synthesis of thermoelectric materials are disclosed. In some embodiments, a method of fabricating a thermoelectric material includes generating a plurality of nanoparticles from a starting material comprising one or more chalcogens and one or more transition metals; and consolidating the nanoparticles under elevated pressure and temperature, wherein the nanoparticles are heated and cooled at a controlled rate. | 09-12-2013 |
20130247953 | ELECTRODE MATERIALS AND CONFIGURATIONS FOR THERMOELECTRIC DEVICES - Thermoelectric devices and associated materials and assembly methods are generally described. Certain aspects relate to electrode materials and electrode configurations for use in thermoelectric devices. In some embodiments, the inventive thermoelectric devices comprise electrodes comprising silicon, such as silicides of cobalt, iron, and/or nickel. Such electrode materials can be useful for making electrical contact with a wide variety of thermoelectric materials, including skutterudite materials. The thermoelectric devices described herein can be used to convert applied voltages to thermal gradients and or to convert thermal gradients to electricity. | 09-26-2013 |
20130256587 | THERMAL AND/OR ELECTRICAL CONDUCTIVITY CONTROL IN SUSPENSIONS - Articles, systems, and methods involving the control of thermal and/or electrical conductivity in suspensions are generally described. | 10-03-2013 |
20130256609 | Thermoelectric Materials and Methods for Synthesis Thereof - Materials having improved thermoelectric properties are disclosed. In some embodiments, lead telluride/selenide based materials with improved figure of merit and mechanical properties are disclosed. In some embodiments, the lead telluride/selenide based materials of the present disclosure are p-type thermoelectric materials formed by adding sodium (Na), silicon (Si) or both to thallium doped lead telluride materials. In some embodiments, the lead telluride/selenide based materials are formed by doping lead telluride/selenides with potassium. | 10-03-2013 |
20140014841 | DIRECT AND QUANTITATIVE BROADBAND ABSORPTANCE SPECTROSCOPY WITH MULTILAYER CANTILEVER PROBES - A system for measuring the absorption spectrum of a sample is provided that includes a broadband light source that produces broadband light defined within a range of an absorptance spectrum. An interferometer modulates the intensity of the broadband light source for a range of modulation frequencies. A bi-layer cantilever probe arm is thermally connected to a sample arm having at most two layers of materials. The broadband light modulated by the interferometer is directed towards the sample and absorbed by the sample and converted into heat, which causes a temperature rise and bending of the bi-layer cantilever probe arm. A detector mechanism measures and records the deflection of the probe arm so as to obtain the absorptance spectrum of the sample. | 01-16-2014 |
20140060604 | Solar Power Conversion System with Directionally - And Spectrally - Selective Properties Based on a Reflective Cavity - Solar power conversion system. The system includes a cavity formed within an enclosure having highly specularly reflecting in the IR spectrum inside walls, the enclosure having an opening to receive solar radiation. An absorber is positioned within the cavity for receiving the solar radiation resulting in heating of the absorber structure. In a preferred embodiment, the system further contains an energy conversion and storage devices thermally-linked to the absorber by heat conduction, convection, far-field or near-field thermal radiation. | 03-06-2014 |
20140070167 | Solid State Cloaking for Electrical Charge Carrier Mobility Control - An electrical mobility-controlled material includes a solid state host material having a controllable Fermi energy level and electrical charge carriers with a charge carrier mobility. At least one Fermi level energy at which a peak in charge carrier mobility is to occur is prespecified for the host material. A plurality of particles are distributed in the host material, with at least one particle disposed with an effective mass and a radius that minimize scattering of the electrical charge carriers for the at least one prespecified Fermi level energy of peak charge carrier mobility. The minimized scattering of electrical charge carriers produces the peak charge carrier mobility only at the at least one prespecified Fermi level energy, set by the particle effective mass and radius, the charge carrier mobility being less than the peak charge carrier mobility at Fermi level energies other than the at least one prespecified Fermi level energy. | 03-13-2014 |
20140109895 | METALLIC COMPOSITE PHASE-CHANGE MATERIALS AND METHODS OF USING THE SAME - Metallic composite phase-change materials and methods of using are disclosed. In some embodiments, a thermal energy storage module is provide that included one or more phase change alloys having a variable phase transition temperature between about 400° C. and about 1200° C. and having a latent heat of more than about 200 kJ/kg. | 04-24-2014 |
20140186209 | THERMOELECTRIC SKUTTERUDITE COMPOSITIONS AND METHODS FOR PRODUCING THE SAME - Compositions related to skutterudite-based thermoelectric materials are disclosed. Such compositions can result in materials that have enhanced ZT values relative to one or more bulk materials from which the compositions are derived. Thermoelectric materials such as n-type and p-type skutterudites with high thermoelectric figures-of-merit can include materials with filler atoms and/or materials formed by compacting particles (e.g., nanoparticles) into a material with a plurality of grains each having a portion having a skutterudite-based structure. Methods of forming thermoelectric skutterudites, which can include the use of hot press processes to consolidate particles, are also disclosed. The particles to be consolidated can be derived from (e.g., grinded from), skutterudite-based bulk materials, elemental materials, other non-Skutterudite-based materials, or combinations of such materials. | 07-03-2014 |
20140191435 | NANOCOMPOSITES WITH HIGH THERMOELECTRIC FIGURES OF MERIT - The present invention is generally directed to nanocomposite thermoelectric materials that exhibit enhanced thermoelectric properties. The nanocomposite materials include two or more components, with at least one of the components forming nano-sized structures within the composite material. The components are chosen such that thermal conductivity of the composite is decreased without substantially diminishing the composite's electrical conductivity. Suitable component materials exhibit similar electronic band structures. For example, a band-edge gap between at least one of a conduction band or a valence band of one component material and a corresponding band of the other component material at interfaces between the components can be less than about 5 k | 07-10-2014 |
20140230869 | Self-Powered Boiler Using Thermoelectric Generator - A self-powered boiler comprising a burner that burns a fuel to produce a hot combustion product that is used to heat a fluid and a thermoelectric generator (TEG) system comprising a first side in thermal communication with the hot combustion product and a second side in thermal communication with a lower temperature region of the boiler, and a plurality of thermoelectric converters disposed therebetween for generating electric power, wherein the electric power generated by the TEG system is equal to or greater than a total electric power consumed by the boiler under normal operating conditions. | 08-21-2014 |
20140261607 | Thermoelectric Module with Flexible Connector - A thermoelectric power generating module incorporates compliance into the module using a three-dimensional flexible connector. The flexible connector may relieve thermal stress and improve reliability for thermoelectric modules. In addition, the connector may provide a buffer layer (e.g., cushion) to damp mechanical vibrations. In further embodiments, a thermal interface structure for a thermoelectric device includes a thermally conductive body comprising a first compliant surface for directly interfacing with a first component of the thermoelectric device and a second compliant surface, opposite the first surface, for directly interfacing with a second component of the thermoelectric device. | 09-18-2014 |
20150053266 | Internally-Heated Thermal and Externally-Cool Photovoltaic Cascade Solar Energy System for Full Solar Spectrum Utilization - A single-stack, solar power receiver comprising both a thermal absorber layer and a photovoltaic cell layer. The stack includes an aerogel layer, that is optically transparent and thermally insulating (“OTTI”); a spectrally selective high thermal conductivity (“SSTC”) thermal absorber layer; a bottom OTTI layer; and a PV cell layer. The SSTC layer includes a set of fins that substantially blocks solar radiation absorption in the band where PV cells are most sensitive. Photons with energies above or below this band block range are absorbed by the fins and the absorbed heat is conducted to pipes in the fin structure carrying a heated thermal working fluid to heat storage. Photons with energy in the band block range are reflected by the SSTC fins to the PV cell layer. The bottom OTTI aerogel layer keeps the PV cell operating near ambient temperature. The PV cell converts incident solar radiation to electrical energy. | 02-26-2015 |
20150068574 | METHODS FOR HIGH FIGURE-OF-MERIT IN NANOSTRUCTURED THERMOELECTRIC MATERIALS - Thermoelectric materials with high figures of merit, ZT values, are disclosed. In many instances, such materials include nano-sized domains (e.g., nanocrystalline), which are hypothesized to help increase the ZT value of the material (e.g., by increasing phonon scattering due to interfaces at grain boundaries or grain/inclusion boundaries). The ZT value of such materials can be greater than about 1, 1.2, 1.4, 1.5, 1.8, 2 and even higher. Such materials can be manufactured from a thermoelectric starting material by generating nanoparticles therefrom, or mechanically alloyed nanoparticles from elements which can be subsequently consolidated (e.g., via direct current induced hot press) into a new bulk material. Non-limiting examples of starting materials include bismuth, lead, and/or silicon-based materials, which can be alloyed, elemental, and/or doped. Various compositions and methods relating to aspects of nanostructured theromoelectric materials (e.g., modulation doping) are further disclosed. | 03-12-2015 |
20150072133 | Localized Solar Collectors - A localized heating structure, and method of forming same, for use in solar systems includes a thermally insulating layer having interconnected pores, a density of less than about 3000 kg/m | 03-12-2015 |