Patent application number | Description | Published |
20080279753 | Method and Apparatus for Growth of High Quality Carbon Single-Walled Nanotubes - Method and processes for synthesizing single-wall carbon nanotubes is provided. A carbon precursor gas is contacted with metal catalysts deposited on a support material. The metal catalysts are preferably nanoparticles having diameters less than about 50 nm. The reaction temperature is selected such that it is near the eutectic point of the mixture of metal catalyst particles and carbon. | 11-13-2008 |
20090274609 | Synthesis Of High Quality Carbon Single-Walled Nanotubes - Methods and processes for synthesizing high quality carbon single-walled nanotubes (SWNTs) are provided. A carbon precursor gas at reduced concentration (pressure) is contacted with a catalyst deposited on a support and at temperature about 10° C. above the SWNT synthesis onset temperature, but below the thermal decomposition temperature of the carbon precursor gas for given growth conditions. The concentration (pressure) of the carbon precursor gas can be controlled by reducing the total pressure of the gas, or by diluting with an inert carrier gas, or both. The methods produce SWNTs with the ratio of G-band to D-band in Raman spectra (I | 11-05-2009 |
20090324484 | Effect Of Hydrocarbon And Transport Gas Feedstock On Efficiency And Quality Of Grown Single-Walled Nanotubes - Methods and processes for synthesizing high quality carbon single-walled nanotubes (SWNTs) are provided. The method provides the means for optimization of amount of carbon precursor and transport gas per unit weight of catalyst. Efficiencies of about 20% can be achieved when contacting the catalyst deposited on a support with a carbon precursor gas with a flow rates of about 4.2×10 | 12-31-2009 |
20120138148 | INJECTOR FOR LARGE AMOUNT OF AEROSOL POWDER FOR SYNTHESIS OF CARBON NANOTUBES - Methods, processes, and apparatuses for the large scale synthesis of carbon nanostructures are provided. The apparatus for continuous large scale production of SWNTs includes a chamber. Positioned in one end of the chamber is a piston and at the other end is a tangential vortex created by gases forced into the chamber from opposite sides of the chamber walls. The chamber can be heated to reduce or eliminate agglomeration of small particles. The piston is used to push the catalyst towards the vortex, and the injection rate is controlled by the speed of the piston and the gas flow rate to create the vortex that also act as the transport gas. Thus, greater than 1 kg/h of an aerosolized, deagglomerated dry powder catalyst can be delivered to the reactor at a constant flow rate. | 06-07-2012 |
20120237436 | Catalyst For The Growth Of Carbon Single-Walled Nanotubes - Methods and processes for synthesizing single-wall carbon nanotubes are provided. A carbon precursor gas is contacted with metal catalysts deposited on a support material. The metal catalysts are preferably nanoparticles having diameters less than about 3 nm. The reaction temperature is selected such that it is near the eutectic point of the mixture of metal catalyst particles and carbon. Further, the rate at which hydrocarbons are fed into the reactor is equivalent to the rate at which the hydrocarbons react for given synthesis temperature. The methods produce carbon single-walled nanotubes having longer lengths. | 09-20-2012 |
20120282594 | METHOD OF ENHANCED DETECTION FOR NANOMATERIAL-BASED MOLECULAR SENSORS - Sensors based on single-walled carbon nanotubes and graphene which demonstrate extreme sensitivity as reflected in their electrical conductivity to gaseous molecules, such as NO, NO | 11-08-2012 |
20130180018 | QUANTITATIVE CHARACTERIZATION OF METALLIC AND SEMICONDUCTOR SINGLE-WALLED CARBON NANOTUBE RATIOS - Methods and processes for quantitatively determining the ratio of the metallic to semiconductor tubes in the sample single-wall carbon nanotubes is provided. The single-walled carbon nanotubes can be sonicated to debundle the bulk material. The debundled SWNTs can be coated with a polymer, such as sulfonated polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene (SDPS), and the coated SWNTs can be deposited on a substrate. The total number of tubes can be determined by atomic force microscopy (AFM). The semiconducting nanotubes can be determined by photoluminescence spectroscopy. The combination of photoluminescence and AFM measurements provides a quantitative ratio of the metallic to semiconductor tubes in the sample. | 07-11-2013 |
20140194658 | New Class Of Tunable Gas Storage And Sensor Materials - The electronic structure of nanowires, nanotubes and thin films deposited on a substrate is varied by doping with electrons or holes. The electronic structure can then be tuned by varying the support material or by applying a gate voltage. The electronic structure can be controlled to absorb a gas, store a gas, or release a gas, such as hydrogen, oxygen, ammonia, carbon dioxide, and the like. | 07-10-2014 |